CN107245256A - 用于汽车的防水剂配方 - Google Patents
用于汽车的防水剂配方 Download PDFInfo
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- CN107245256A CN107245256A CN201710646090.5A CN201710646090A CN107245256A CN 107245256 A CN107245256 A CN 107245256A CN 201710646090 A CN201710646090 A CN 201710646090A CN 107245256 A CN107245256 A CN 107245256A
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- 239000000463 material Substances 0.000 claims abstract description 52
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 49
- 238000004078 waterproofing Methods 0.000 claims abstract description 32
- 239000005871 repellent Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002253 acid Substances 0.000 claims abstract description 16
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 13
- 239000011147 inorganic material Substances 0.000 claims abstract description 13
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 11
- 238000009833 condensation Methods 0.000 claims abstract description 11
- 230000005494 condensation Effects 0.000 claims abstract description 11
- 230000005012 migration Effects 0.000 claims abstract description 9
- 238000013508 migration Methods 0.000 claims abstract description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 20
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 18
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 16
- 229920000620 organic polymer Polymers 0.000 claims description 15
- 239000004115 Sodium Silicate Substances 0.000 claims description 10
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 10
- 230000003373 anti-fouling effect Effects 0.000 claims description 10
- 150000002617 leukotrienes Chemical class 0.000 claims description 10
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 10
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 10
- 235000011151 potassium sulphates Nutrition 0.000 claims description 10
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 10
- 239000004317 sodium nitrate Substances 0.000 claims description 10
- 235000010344 sodium nitrate Nutrition 0.000 claims description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 10
- 239000004156 Azodicarbonamide Substances 0.000 claims description 9
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 claims description 9
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 9
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 claims description 9
- 235000019399 azodicarbonamide Nutrition 0.000 claims description 9
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 claims description 9
- NTWZYMJGDYYGNL-UHFFFAOYSA-N [Na].C[Si] Chemical compound [Na].C[Si] NTWZYMJGDYYGNL-UHFFFAOYSA-N 0.000 claims description 8
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims description 8
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 8
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 8
- 229920002050 silicone resin Polymers 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 3
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 2
- SNDJGKIVHKOEHY-UHFFFAOYSA-M S(=S)(=O)(O)O.S[Na] Chemical compound S(=S)(=O)(O)O.S[Na] SNDJGKIVHKOEHY-UHFFFAOYSA-M 0.000 claims 1
- NTSNXSJENBZFSF-UHFFFAOYSA-N [Na+].[SiH3][O-] Chemical compound [Na+].[SiH3][O-] NTSNXSJENBZFSF-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 10
- 238000005034 decoration Methods 0.000 description 15
- 238000004140 cleaning Methods 0.000 description 6
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 230000002940 repellent Effects 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- SUDKDSWHVLJFHP-UHFFFAOYSA-N C(=O)N.C(=O)N.[N] Chemical compound C(=O)N.C(=O)N.[N] SUDKDSWHVLJFHP-UHFFFAOYSA-N 0.000 description 1
- HDETVIAMQNTONT-UHFFFAOYSA-N C[SiH2]O.[Na] Chemical compound C[SiH2]O.[Na] HDETVIAMQNTONT-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
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- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
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Abstract
本发明提供了一种用于汽车的防水剂配方，涉及防水材料技术领域，本发明提供的防水剂能缩合形成具有防水防污效果的防水性物质。该组成包括脂肪酸和无机材料，其中：所述脂肪酸和所述无机材料经过化学反应能形成水溶性防水剂溶液，所述水溶性防水剂溶液在水和二氧化碳的作用下能生成中间物质，所述中间物质经过缩合后能生成防水性物质。本发明提供的防水剂经过缩合后能生成具有憎水性和憎水迁移性的防水性物质，能起到防水防污的效果。
Description
技术领域
本发明涉及防水材料技术领域，尤其是涉及一种用于汽车的防水剂配方。
背景技术
汽车内顶棚的清洗是大多数车主们最容易忽略的一个清洗地方，而且汽车内顶棚清洗起来是很繁琐的事情，因为汽车内顶棚内的填充物是隔热吸音的材质，拥有很强的吸收水分能力，导致车顶很难干燥，清洗很麻烦，有时甚至会出现材料剥落的现象。
本发明提供的防水剂能缩合形成具有防水防污效果的防水性物质。
发明内容
本发明的目的在于提供用于汽车的防水剂配方，防水剂经过缩合后能生成防水性物质具有憎水性和憎水迁移性，能起到防水防污的效果。
为实现上述目的，本发明提供了以下技术方案：
本发明提供的一种用于汽车的防水剂配方，包括脂肪酸和无机材料，其中：所述脂肪酸和所述无机材料经过化学反应能形成水溶性防水剂溶液，所述水溶性防水剂溶液在水和二氧化碳的作用下能生成中间物质，所述中间物质经过缩合后能生成防水性物质。
优选地，所述中间物质包括甲基硅烷，所述水溶性溶液10.0wt％～60.0wt％；和/或，所述脂肪酸包括辛酸、癸酸、松香酸、蔻酸和亚麻酸；和/或，所述无机材料包括甲基硅醇钠、硫酸钾、硝酸钠、亚硝酸钠、硅酸钠、硫代硫酸钠、偶氮二甲酰胺和纳米磷酸钛。
优选地，所述防水剂各组分的重量份数：辛酸10～18份、癸酸2～10份、松香酸2～15份、蔻酸4～15份、亚麻酸3～15份、甲基硅醇钠20～50份、硫酸钾2～15份、硝酸钠2～8份、亚硝酸钠2～16份、硅酸钠2～17份、硫代硫酸钠3～14份、偶氮二甲酰胺2～12份、纳米磷酸钛1～14份。
优选地，所述防水剂各组分的重量份数：辛酸15份、癸酸3～7份、松香酸5～10份、蔻酸7～10份、亚麻酸6～10份、甲基硅醇钠25～40份、硫酸钾5～10份、硝酸钠3～4份、亚硝酸钠5～10份、硅酸钠5～10份、硫代硫酸钠5～7份、偶氮二甲酰胺5～6份、纳米磷酸钛3～7份。
优选地，所述防水剂为20.0wt％～40.0wt％的溶液。
优选地，所述防水剂涂布或浸渍于待防污的部件后经过缩合、干燥后能在所述待防污的部件外表面形成所述防水性物质，所述防水性物质为有机高分子防水层。
优选地，所述待防污的部件为无纺布。
优选地，所述有机高分子防水层为有机硅树脂膜。
优选地，所述有机高分子防水层为网状结构。
优选地，所述有机高分子防水层具有憎水性和憎水迁移性
本发明的目的在于提供用于汽车的防水剂配方，防水剂经过缩合后能生成具有憎水性和憎水迁移性的防水性物质，能起到防水防污的效果，可涂敷在汽车顶棚装饰面料上，提高汽车顶棚内饰面料的抗污性，且也使得顶棚内饰面料易清洗。
附图说明
为了更清楚地说明本发明实施例或现有技术中的技术方案，下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍，显而易见地，下面描述中的附图仅仅是本发明的一些实施例，对于本领域普通技术人员来讲，在不付出创造性劳动的前提下，还可以根据这些附图获得其他的附图。
图1是具有防水性的顶棚内饰面料的结构示意图。
图中1-顶棚内饰面料；2-防水性物质。
具体实施方式
为使本发明的目的、技术方案和优点更加清楚，下面将对本发明的技术方案进行详细的描述。显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动的前提下所得到的所有其它实施方式，都属于本发明所保护的范围。
本发明提供了一种用于汽车的防水剂配方，包括脂肪酸和无机材料，其中：防水材料脂肪酸和防水材料无机材料经过化学反应能形成水溶性防水剂溶液，防水材料水溶性防水剂溶液在水和二氧化碳的作用下能生成中间物质，防水材料中间物质经过缩合后能生成防水性物质2，缩合反应是两个或两个以上有机分子相互作用后以共价键结合成一个大分子，通过防水剂得到的防水性物质2能起到防水防污的效果。
作为可选地实施方式，防水材料中间物质包括甲基硅烷，防水材料水溶性溶液10.0wt％～60.0wt％；和/或，防水材料脂肪酸包括辛酸、癸酸、松香酸、蔻酸和亚麻酸；和/或，防水材料无机材料包括甲基硅醇钠、硫酸钾、硝酸钠、亚硝酸钠、硅酸钠、硫代硫酸钠、偶氮二甲酰胺和纳米磷酸钛，汽车的防水剂配方包括脂肪酸和无机材料，脂肪酸为辛酸、癸酸、松香酸、蔻酸和亚麻酸，无机材料包括甲基硅醇钠、硫酸钾、硝酸钠、亚硝酸钠、硅酸钠、硫代硫酸钠、偶氮二甲酰胺和纳米磷酸钛。
作为可选地实施方式，防水材料防水剂各组分的重量份数：辛酸10～18份、癸酸2～10份、松香酸2～15份、蔻酸4～15份、亚麻酸3～15份、甲基硅醇钠20～50份、硫酸钾2～15份、硝酸钠2～8份、亚硝酸钠2～16份、硅酸钠2～17份、硫代硫酸钠3～14份、偶氮二甲酰胺2～12份、纳米磷酸钛1～14份。
作为可选地实施方式，防水材料防水剂各组分的重量份数：辛酸15份、癸酸3～7份、松香酸5～10份、蔻酸7～10份、亚麻酸6～10份、甲基硅醇钠25～40份、硫酸钾5～10份、硝酸钠3～4份、亚硝酸钠5～10份、硅酸钠5～10份、硫代硫酸钠5～7份、偶氮二甲酰胺5～6份、纳米磷酸钛3～7份。
作为可选地实施方式，防水材料防水剂为20.0wt％～40.0wt％的溶液，防水剂的溶质的浓度太小会影响防水剂缩合形成的成防水性物质2防水效果差，防水剂的溶质的浓度太大又会使得防水剂过于粘稠，影响待防污材料本身的性能。
作为可选地实施方式，防水材料防水剂涂布或浸渍于待防污的部件后经过缩合、干燥后能在防水材料待防污的部件外表面形成防水性物质2，防水性物质2为有机高分子防水层。
作为可选地实施方式，待防污的部件为无纺布，顶棚内饰面料1沿从外侧朝内侧的方向依次包括无纺布层、海绵层以及高分子材料层，无纺布层裸露于汽车内的外表面，通过在无纺布的外表面涂布防水性物质2，使得顶棚内饰面料1很难湿润，也防止了污秽通过水滴渗进顶棚内饰面料1内，防水性物质2上的水是以不连续的小水珠而独立存在，不会形成水流和水膜滴落车内，且防水性物质2也使得顶棚内饰面料1易于清理，通过擦拭的方式即可清理防水防污层2上的污秽。
制备具有防水防污的顶棚内饰面料的方法：
制备防水剂溶液；使用防水剂溶液浸渍顶棚内饰面料1；对浸渍防水剂溶液的顶棚内饰面料1进行干燥处理形成憎水层22；对顶棚内饰面料1进行印刷花色图案处理；干燥、冷却、剪切、检验、收卷、包装，制成具有防水防污效果的顶棚内饰面料1。
作为可选地实施方式，有机高分子防水层为有机硅树脂膜。有机硅树脂具有优良的耐热、耐寒、耐候、憎水等特性，有机硅树脂无色透明、具有良好黏接性。
作为可选地实施方式，有机高分子防水层为网状结构。
作为可选地实施方式，有机高分子防水层具有憎水性和憎水迁移性，所谓憎水性是指有机硅树脂表面不易受潮，吸附的水分以不连续的孤立小水珠的形式存在，不形成连续水膜，所谓憎水迁移性是指有机高分子防水层表面脏污后，有机高分子防水层可以把本身的憎水性迁移到污秽层表面，即有机高分子防水层内的憎水基团可以迁移到污秽表面，使污秽层表面也有憎水性，机高分子防水层具同时具有憎水性和憎水迁移性，使得机高分子防水层具具有很好地防水防污的效果。
本发明的目的在于提供用于汽车的防水剂配方，防水剂经过缩合后能生成具有憎水性和憎水迁移性的防水性物质，能起到防水防污的效果，可涂敷在汽车顶棚装饰面料上，提高汽车顶棚内饰面料的抗污性，且也使得汽车顶棚内饰面料易清洗。
以上所述，仅为本发明的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，可轻易想到变化或替换，都应涵盖在本发明的保护范围之内。因此，本发明的保护范围应以所述权利要求的保护范围为准。
Claims (10)
1.一种用于汽车的防水剂配方，其特征在于，包括脂肪酸和无机材料，其中：所述脂肪酸和所述无机材料经过化学反应能形成水溶性防水剂溶液，所述水溶性防水剂溶液在水和二氧化碳的作用下能生成中间物质，所述中间物质经过缩合后能生成防水性物质(2)。
2.根据权利要求1所述的用于汽车的防水剂配方，其特征在于，所述中间物质包括甲基硅烷，所述水溶性溶液10.0wt％～60.0wt％；和/或，所述脂肪酸包括辛酸、癸酸、松香酸、蔻酸和亚麻酸；和/或，所述无机材料包括甲基硅醇钠、硫酸钾、硝酸钠、亚硝酸钠、硅酸钠、硫代硫酸钠、偶氮二甲酰胺和纳米磷酸钛。
3.根据权利要求2所述的用于汽车的防水剂配方，其特征在于，所述防水剂各组分的重量份数：辛酸10～18份、癸酸2～10份、松香酸2～15份、蔻酸4～15份、亚麻酸3～15份、甲基硅醇钠20～50份、硫酸钾2～15份、硝酸钠2～8份、亚硝酸钠2～16份、硅酸钠2～17份、硫代硫酸钠3～14份、偶氮二甲酰胺2～12份、纳米磷酸钛1～14份。
4.根据权利要求3所述的用于汽车的防水剂配方，其特征在于，所述防水剂各组分的重量份数：辛酸15份、癸酸3～7份、松香酸5～10份、蔻酸7～10份、亚麻酸6～10份、甲基硅醇钠25～40份、硫酸钾5～10份、硝酸钠3～4份、亚硝酸钠5～10份、硅酸钠5～10份、硫代硫酸钠5～7份、偶氮二甲酰胺5～6份、纳米磷酸钛3～7份。
5.根据权利要求4所述的用于汽车的防水剂配方，其特征在于，所述防水剂为20.0wt％～40.0wt％的溶液。
6.根据权利要求1所述的用于汽车的防水剂配方，其特征在于，所述防水剂涂布或浸渍于待防污的部件后经过缩合、干燥后能在所述待防污的部件外表面形成所述防水性物质(2)；
所述防水性物质(2)为有机高分子防水层。
7.根据权利要求6所述的用于汽车的防水剂配方，其特征在于，所述待防污的部件为无纺布。
8.根据权利要求6所述的用于汽车的防水剂配方，其特征在于，所述有机高分子防水层为有机硅树脂膜。
9.根据权利要求6所述的用于汽车的防水剂配方，其特征在于，所述有机高分子防水层为网状结构。
10.根据权利要求6所述的用于汽车的防水剂配方，其特征在于，所述有机高分子防水层具有憎水性和憎水迁移性。
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