CN107245005A - A kind of improving yield of wheat organic slow-release fertilizer resistant to lodging - Google Patents
A kind of improving yield of wheat organic slow-release fertilizer resistant to lodging Download PDFInfo
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- CN107245005A CN107245005A CN201710418296.2A CN201710418296A CN107245005A CN 107245005 A CN107245005 A CN 107245005A CN 201710418296 A CN201710418296 A CN 201710418296A CN 107245005 A CN107245005 A CN 107245005A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B3/00—Fertilisers based essentially on di-calcium phosphate
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- Life Sciences & Earth Sciences (AREA)
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- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
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Abstract
The invention discloses a kind of improving yield of wheat organic slow-release fertilizer resistant to lodging, its raw material includes cow dung, chicken manure, pig manure, Erucic acid, rice hull ash, yeast powder, stalk fermentation microbial inoculum, potassium breeze, potassium chloride, potassium sulfate, potassium nitrate, ammonium nitrate, ammonium molybdate, calcium carbonate, calcium phosphate, calcium monohydrogen phosphate, cerous nitrate, borax, manganese sulfate, zinc sulfate, filler, modified sustained release agent and soil conditioner.The wheat organic slow-release fertilizer of the present invention has excellent sustained release performance, disclosure satisfy that the nutriment needed for wheat growth, wheat growth-promoting, it is to avoid Wheat lodging, improves the yield and quality of wheat.
Description
Technical field
The present invention relates to the technical field of fertilizer, more particularly to a kind of improving yield of wheat organic slow-release fertilizer resistant to lodging.
Background technology
Fertilizer type used in wheat planting is a lot, and wherein fertilizer specially for wheat is answered using commercially available NPK mostly
Hefei, it is mainly made up of the big inorganic elements of N, P, K tri-, and the growth needs of wheat can be met in a short time.But it is used for a long time
Soil granular structure can be destroyed, easily cause soil hardening, soil property and be hardened, so as to influence wheat growth so that wheat
Cane and root system development are bad, cause wheat easily to lodge, and have had a strong impact on the yield and quality of wheat, while simple organic fertilizer
Though rich in organic matter, nutrients release is slow, and wheat absorption is slow, fertilizer efficiency is low, and the mirror of various available nutrients does not reach active balance.
So needing a kind of improving yield of wheat organic slow-release fertilizer resistant to lodging of design badly to solve the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of improving yield of wheat organic slow-release fertilizer resistant to lodging
Material, with excellent sustained release performance, disclosure satisfy that the nutriment needed for wheat growth, wheat growth-promoting, it is to avoid wheat falls
Volt, improves the yield and quality of wheat.
A kind of improving yield of wheat organic slow-release fertilizer resistant to lodging proposed by the present invention, its raw material includes by weight：Cow dung 35-
45 parts, 10-20 parts of chicken manure, 5-15 parts of pig manure, 3-6 parts of Erucic acid, 2-8 parts of rice hull ash, 2-4 parts of yeast powder, stalk hair
1-3 parts of yeast-like fungi agent, 1-5 parts of potassium breeze, 3-9 parts of potassium chloride, 2-6 parts of potassium sulfate, 1-4 parts of potassium nitrate, 3-5 parts of ammonium nitrate, molybdic acid
6-12 parts of ammonium, 1-3 parts of calcium carbonate, 2-4 parts of calcium phosphate, 4-8 parts of calcium monohydrogen phosphate, 2-5 parts of cerous nitrate, 3-6 parts of borax, manganese sulfate 1-
3 parts, 1-3 parts of zinc sulfate, 4-9 parts of filler, modified 5-15 parts of sustained release agent, 2-5 parts of soil conditioner.
Preferably, the raw material of filler includes by weight：1-5 parts of medical stone, 2-5 parts of montmorillonite powder, attapulgite 3-6
Part, 3-5 parts of chitosan, 2-5 parts of talcum powder, 1-6 parts of land plaster, 3-6 parts of cake-shaped rape seed dregs, 2-4 parts of seawood meal, 1-4 parts of diatomite, poly- third
2-5 parts of alkene, 3-6 parts of amide waxe, 4-6 parts of urea, 2-5 parts of lignin, 1-5 parts of calcium sulfate land plaster, silane resin acceptor kh-550
4-6 parts.
Preferably, filler is prepared by following technique：By medical stone, montmorillonite powder, attapulgite, chitosan, talcum
Accumulated after powder, land plaster, cake-shaped rape seed dregs, seawood meal, diatomite mixing, then room temperature 3-5d adds polypropylene, amide waxe, urine
Element, lignin and calcium sulfate land plaster are well mixed, are warming up to 130-150 DEG C, are incubated 1-3h, are subsequently added into silane coupler
KH-550 is well mixed, and 2-4h is stirred in 650-850r/min rotating speeds, is dried to constant weight, ground 40-60 mesh sieves are cooled to room
Temperature obtains filler.
Preferably, the raw material of modified sustained release agent includes by weight：5-15 parts of bentonite, hexadecyltrimethylammonium chloride
3-6 parts, 4-9 parts of water, 2-5 parts of phoxim, 1-4 parts of lactic acid, 3-6 parts of stannous chloride, 2-5 parts of dichloromethane, phosphorus pentachloride 1-4
Part, 3-5 parts of hexamethylene diamine, 2-6 parts of triethylamine.
Preferably, modified sustained release agent is prepared by following technique：By bentonite, hexadecyltrimethylammonium chloride and water
It is well mixed, vibrated in thermostatic control oscillator vibration, then add phoxim and be well mixed, vibrated in thermostatic control oscillator vibration,
It is cooled to room temperature and obtains material a；Lactic acid is heated up, is incubated, nitrogen is then passed through, stannous chloride is added and is well mixed, heat up, protect
Temperature, then cools, and separates out and is washed after precipitation, dries to constant weight and obtain material b；By dichloromethane under nitrogen protection, heat up, protect
Temperature, is subsequently added into phosphorus pentachloride and is well mixed, and hexamethylene diamine is added after centrifugation and is well mixed, and triethylamine mixing is added in ice-water bath
Uniformly, stir at room temperature, dried after washing, be cooled to room temperature and obtain material b；Material a and material b are well mixed, heated up, is protected
Temperature, is followed by stirring for, and is cooled to room temperature and obtains being modified sustained release agent.
Preferably, modified sustained release agent is prepared by following technique：By bentonite, hexadecyltrimethylammonium chloride and water
It is well mixed, with 250-350r/min speed oscillation 3-5h in 55-65 DEG C of thermostatic control oscillator vibration, then add phoxim and mix
Close uniform, with 150-250r/min speed oscillation 2-4h in 20-30 DEG C of thermostatic control oscillator vibration, be cooled to room temperature and obtain material
a；Lactic acid is warming up to 110-130 DEG C, 1-3h is incubated, nitrogen is then passed through, stannous chloride is added and is well mixed, be warming up to 170-
190 DEG C, 1-3h is incubated in 0.08-0.12MPa, 40-50 DEG C is then cooled to, separates out and is washed after precipitation, dried extremely in 35-45 DEG C
Constant weight obtains material b；By dichloromethane under nitrogen protection, 35-39 DEG C is warming up to, 5-15min is incubated, is subsequently added into phosphoric
Phosphorus is well mixed, and hexamethylene diamine is added after centrifugation and is well mixed, and triethylamine is added in ice-water bath and is well mixed, 6- is stirred at room temperature
8h, washes after 35-45 DEG C of dry 10-14h, is cooled to room temperature and obtains material b；Material a and material b are well mixed, heated up
To 120-140 DEG C, 10-20min is incubated, then 1-3h is stirred in 650-850r/min rotating speeds, room temperature is cooled to and obtains modified slow
Release agent.
Preferably, soil conditioner is by C12AESA and C12AEO is by weight
Amount compares 3-5：1-2 is mixed.
A kind of improving yield of wheat organic slow-release fertilizer resistant to lodging of the present invention, its raw material includes cow dung, chicken manure, pig manure, rape
Grouts, rice hull ash, yeast powder, stalk fermentation microbial inoculum, potassium breeze, potassium chloride, potassium sulfate, potassium nitrate, ammonium nitrate, molybdic acid
Ammonium, calcium carbonate, calcium phosphate, calcium monohydrogen phosphate, cerous nitrate, borax, manganese sulfate, zinc sulfate, filler, modified sustained release agent and soil conditioning
Agent.The wheat organic slow-release fertilizer of the present invention has excellent sustained release performance, disclosure satisfy that the nutriment needed for wheat growth, promotees
Enter wheat growth, it is to avoid Wheat lodging, improve the yield and quality of wheat.Sustained release agent is wherein modified by by bentonite, ten
Six alkyl trimethyl ammonium chlorides and water are well mixed, are vibrated in thermostatic control oscillator vibration, then add phoxim and are well mixed,
Vibrated in thermostatic control oscillator vibration, be cooled to room temperature and obtain material a；Lactic acid is heated up, is incubated, nitrogen is then passed through, chlorine is added
Change stannous to be well mixed, heat up, insulation then cools, separate out and washed after precipitation, dry to constant weight and obtain material b；By dichloromethane
Alkane is heated up under nitrogen protection, insulation, is subsequently added into phosphorus pentachloride and is well mixed, and hexamethylene diamine is added after centrifugation and is well mixed, in
Triethylamine is added in ice-water bath to be well mixed, and is stirred at room temperature, is dried after washing, be cooled to room temperature and obtain material b；By material a
It is well mixed with material b, heat up, insulation is followed by stirring for, is cooled to room temperature and obtains being modified sustained release agent, use phosphorus pentachloride for acyl
Chlorination reagent carries out acyl chloride reaction to PLA, then reacts to prepare the poly- breast of hexamethylene diamine modification with hexamethylene diamine
Acid, makes the hydroxy-acid group in PLA be converted to-COCl, recycles acid chloride groups and the-NH in hexamethylene diamine2Group reacts
Form amido link and obtain polydactyl acid；By the modified bentonite of hexadecyltrimethylammonium chloride, it is as phoxim
Carrier, blending and modifying is realized with modified polylactic acid blend, is realized to the twice-modified of PLA, is effectively improved modification
The sustained release performance of PLA.Wherein, filler is by by medical stone, montmorillonite powder, attapulgite, chitosan, talcum powder, gypsum
Powder, cake-shaped rape seed dregs, seawood meal, diatomite mixing after accumulate, room temperature, then add polypropylene, amide waxe, urea, lignin and
Calcium sulfate land plaster is well mixed, and is warming up to, and is incubated, and is subsequently added into silane resin acceptor kh-550 and is well mixed, and in stirring, is dried
To constant weight, grinding sieving is cooled to room temperature and obtains filler, by with medical stone, montmorillonite powder, attapulgite, chitosan, talcum
Powder, land plaster, cake-shaped rape seed dregs, seawood meal and diatomite using the coating of filler, filling, sustained release performance, and pass through silane as filler
Coupling agent KH-550 graft modifications on polypropylene, obtained filler apply to the present invention wheat organic slow-release fertilizer have it is excellent
Different release-controlled coated performance, can efficiently provide nutriment for wheat, improve the yield and quality of wheat.Wherein, it is concavo-convex
Rod soil is the aqueous aluminium magensium silicate mineral of one layer of chain structure, and its crystal is in through hole, surface in bar-shaped, threadiness, layer
Bumps are alternate to be covered with groove, with the larger most cation of specific surface area, hydrone and a certain size organic molecule
Directly it can be adsorbed into duct, therefore attapulgite has good suction-operated, catalytic action, rheological characteristic and heat resistance
Etc. property.Attapulgite can as fertilizer slow-release formulation and the carrier of slow-release fertilizer, to nutrient you that play slow releasing function.Addition
Soil conditioner by C12AESA and C12AEO mix by a certain percentage and
Into catalase is the oxidoreducing enzyme for participating in the conversion of matter and energy in soil, can be prevented during organic matter degradation
Only harm of the hydrogen peroxide to organism, can promote sucrose water as the content parameter for understanding the soil organism, invertase
Solution provides carbon source into glucose for edaphon, can influence C cellulose contents in soil, and soil conditioner inhibits the work of urase
Property, invertase, proteinase activity are improved, micro organism quantity is added, especially bacterium, the increase of nitrogen-fixing bacteria quantity is most notable, is led to
Cross influence soil enzyme activities and micro organism quantity improves utilization rate of the wheat to N elements and C elements in soil indirectly, soil conditioner increases
Add wheat fibrous root quantity, enhance the ability that wheat absorbs nutrient, and edaphon can produce some secondary metabolites,
The development of root system of plant can be stimulated, the C in the absorption of Plant To Nutrient element, soil conditioner is improved12Fatty alcohol polyoxy second
Alkene ether ammonium sulfate has very strong hydrophilic group-SO2NH4, can be by the H in inorganic grogs in soil layer2O parts are attracted on organic plastid,
Can be by the H in inorganic grogs in soil layer2O parts are attracted on organic plastid, are made grogs dehydration and are expanded, micropore is increased, and is entered
And strengthen soil aeration.C in soil conditioner12AESA can be by calcium ion in soil
Key bridge is tied with soil, is formed stable crumb structure, is made soil reclaimed water, fertilizer, air and heat mutually harmonious, promote soil micro-
Bioactivity, enzymatic activity is improved, and soil nutrient activation efficiency enhancing, speed nutrient increases.Nitrogen, available phosphorus contents are cracked in soil
Significantly improve.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
In embodiment, the parts by weight of cow dung can for 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts,
42 parts, 43 parts, 44 parts, 45 parts；The parts by weight of chicken manure can for 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17
Part, 18 parts, 19 parts, 20 parts；The parts by weight of pig manure can for 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts,
14 parts, 15 parts；The parts by weight of Erucic acid can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight of rice hull ash
It can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts to measure part；The parts by weight of yeast powder can for 2 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts；The parts by weight of stalk fermentation microbial inoculum can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The parts by weight of potassium breeze can
Think 1 part, 2 parts, 3 parts, 4 parts, 5 parts；The parts by weight of potassium chloride can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；Sulfuric acid
The parts by weight of potassium can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of potassium nitrate can for 1 part, 1.5 parts, 2 parts, 2.5 parts, 3
Part, 3.5 parts, 4 parts；The parts by weight of ammonium nitrate can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of ammonium molybdate can be
6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts；The parts by weight of calcium carbonate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；Phosphorus
The parts by weight of sour calcium can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of calcium monohydrogen phosphate can for 4 parts, 4.5 parts, 5
Part, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of cerous nitrate can for 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts,
4.5 parts, 5 parts；The parts by weight of borax can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of manganese sulfate
It can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The parts by weight of zinc sulfate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；Fill out
The parts by weight of material can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts；It is modified slow
The parts by weight for releasing agent can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；Soil conditioning
The parts by weight of agent can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts.
Embodiment 1
A kind of improving yield of wheat organic slow-release fertilizer resistant to lodging proposed by the present invention, its raw material includes by weight：Cow dung 40
Part, 15 parts of chicken manure, 10 parts of pig manure, 4.5 parts of Erucic acid, 5 parts of rice hull ash, 3 parts of yeast powder, 2 parts of stalk fermentation microbial inoculum, potassium
3 parts of miberal powder, 6 parts of potassium chloride, 4 parts of potassium sulfate, 2.5 parts of potassium nitrate, 4 parts of ammonium nitrate, 9 parts of ammonium molybdate, 2 parts of calcium carbonate, calcium phosphate 3
Part, 6 parts of calcium monohydrogen phosphate, 3.5 parts of cerous nitrate, 4.5 parts of borax, 2 parts of manganese sulfate, 2 parts of zinc sulfate, 6.5 parts of filler, modified sustained release agent
10 parts, 3.5 parts of soil conditioner.
Filler is prepared by following technique：By weight by 3 parts of medical stones, 3.5 parts of montmorillonite powders, 4.5 parts of concave convex rods
Heap after soil, 4 parts of chitosans, 3.5 parts of talcum powder, 3.5 parts of land plasters, 4.5 parts of cake-shaped rape seed dregs, 3 parts of seawood meals, 2.5 parts of diatomite mixing
Then product, room temperature 4d adds 3.5 parts of polypropylene, 4.5 parts of amide waxes, 5 parts of urea, 3.5 parts of lignin and 3 parts of calcium sulfate
Land plaster is well mixed, and is warming up to 140 DEG C, is incubated 2h, is subsequently added into 5 parts of silane resin acceptor kh-550s and is well mixed, in 750r/
Min rotating speeds stir 3h, dry to constant weight, ground 50 mesh sieve is cooled to room temperature and obtains filler.
Modified sustained release agent is prepared by following technique：By weight by 10 parts of bentonites, 4.5 parts of cetyl trimethyls
Ammonium chloride and 6.5 parts of water are well mixed, and with 3050r/min speed oscillation 4h in 60 DEG C of thermostatic control oscillator vibrations, are then added
3.5 parts of phoxims are well mixed, and with 200r/min speed oscillation 3h in 25 DEG C of thermostatic control oscillator vibrations, are cooled to room temperature and are obtained
Material a；2.5 parts of lactic acid are warming up to 120 DEG C, 2h is incubated, nitrogen is then passed through, 4.5 parts of stannous chlorides is added and is well mixed, rise
Temperature is incubated 2h to 150 DEG C in 0.1MPa, is then cooled to 45 DEG C, separates out and is washed after precipitation, is dried in 40 DEG C to constant weight and obtains thing
Expect b；By 3.5 parts of dichloromethane under nitrogen protection, 37 DEG C are warming up to, 10min is incubated, 2.5 parts of phosphorus pentachlorides is subsequently added into and mixes
Close uniform, 4 parts of hexamethylene diamines are added after centrifugation and are well mixed, 4 parts of triethylamines are added in ice-water bath and are well mixed, are stirred at room temperature
7h, washes after 40 DEG C of dry 12h, is cooled to room temperature and obtains material b；Material a and material b are well mixed, 130 are warming up to
DEG C, 15min is incubated, then 2h is stirred in 750r/min rotating speeds, is cooled to room temperature and obtains being modified sustained release agent.
Soil conditioner is by C12AESA and C12AEO is by weight 4：
1.5 mix.
Embodiment 2
A kind of improving yield of wheat organic slow-release fertilizer resistant to lodging proposed by the present invention, its raw material includes by weight：Cow dung 35
Part, 20 parts of chicken manure, 5 parts of pig manure, 6 parts of Erucic acid, 2 parts of rice hull ash, 4 parts of yeast powder, 1 part of stalk fermentation microbial inoculum, potassium ore deposit
5 parts of powder, 3 parts of potassium chloride, 6 parts of potassium sulfate, 1 part of potassium nitrate, 5 parts of ammonium nitrate, 6 parts of ammonium molybdate, 3 parts of calcium carbonate, 2 parts of calcium phosphate,
8 parts of calcium monohydrogen phosphate, 2 parts of cerous nitrate, 6 parts of borax, 1 part of manganese sulfate, 3 parts of zinc sulfate, 4 parts of filler, modified 15 parts of sustained release agent, soil
2 parts of conditioner.
Filler is prepared by following technique：By weight by 1 part of medical stone, 5 parts of montmorillonite powders, 3 parts of attapulgites, 5
Accumulated after part chitosan, 2 parts of talcum powder, 6 parts of land plasters, 3 parts of cake-shaped rape seed dregs, 4 parts of seawood meals, 1 part of diatomite mixing, room temperature
5d, then adds 2 parts of polypropylene, 6 parts of amide waxes, 4 parts of urea, 5 parts of lignin and 1 part of calcium sulfate land plaster and is well mixed, rise
Temperature is incubated 1h to 150 DEG C, is subsequently added into 6 parts of silane resin acceptor kh-550s and is well mixed, 4h is stirred in 650r/min rotating speeds, does
It is dry to constant weight, ground 40 mesh sieve is cooled to room temperature and obtains filler.
Modified sustained release agent is prepared by following technique：By weight by 5 parts of bentonites, 6 parts of cetyl trimethyl chlorine
Change ammonium and 4 parts of water are well mixed, with 250r/min speed oscillation 5h in 65 DEG C of thermostatic control oscillator vibrations, then 2 parts of addition is pungent
Sulphur phosphorus is well mixed, and with 150r/min speed oscillation 4h in 30 DEG C of thermostatic control oscillator vibrations, is cooled to room temperature and is obtained material a；
1 part of lactic acid is warming up to 130 DEG C, 1h is incubated, nitrogen is then passed through, 6 parts of stannous chlorides is added and is well mixed, be warming up to 170 DEG C,
1h is incubated in 0.12MPa, 50 DEG C are then cooled to, separates out and is washed after precipitation, is dried in 35 DEG C to constant weight and obtains material b；By 5 parts
Dichloromethane is warming up to 35 DEG C under nitrogen protection, is incubated 15min, is subsequently added into 1 part of phosphorus pentachloride and is well mixed, after centrifugation
Add 5 parts of hexamethylene diamines to be well mixed, 2 parts of triethylamines are added in ice-water bath and are well mixed, 8h is stirred at room temperature, are washed after 35
DEG C dry 14h, be cooled to room temperature and obtain material b；Material a and material b are well mixed, 120 DEG C are warming up to, 20min is incubated, connects
And stir 3h in 650r/min rotating speeds, be cooled to room temperature and obtain being modified sustained release agent.
Soil conditioner is by C12AESA and C12AEO is by weight 3：2
Mix.
Embodiment 3
A kind of improving yield of wheat organic slow-release fertilizer resistant to lodging proposed by the present invention, its raw material includes by weight：Cow dung 45
Part, 10 parts of chicken manure, 15 parts of pig manure, 3 parts of Erucic acid, 8 parts of rice hull ash, 2 parts of yeast powder, 3 parts of stalk fermentation microbial inoculum, potassium ore deposit
1 part of powder, 9 parts of potassium chloride, 2 parts of potassium sulfate, 4 parts of potassium nitrate, 3 parts of ammonium nitrate, 12 parts of ammonium molybdate, 1 part of calcium carbonate, 4 parts of calcium phosphate,
4 parts of calcium monohydrogen phosphate, 5 parts of cerous nitrate, 3 parts of borax, 3 parts of manganese sulfate, 1 part of zinc sulfate, 9 parts of filler, modified 5 parts of sustained release agent, soil
5 parts of conditioner.
Filler is prepared by following technique：By weight by 5 parts of medical stones, 2 parts of montmorillonite powders, 6 parts of attapulgites, 3
Accumulated after part chitosan, 5 parts of talcum powder, 1 part of land plaster, 6 parts of cake-shaped rape seed dregs, 2 parts of seawood meals, 4 parts of diatomite mixing, room temperature
3d, then adds 5 parts of polypropylene, 3 parts of amide waxes, 6 parts of urea, 2 parts of lignin and 5 parts of calcium sulfate land plasters and is well mixed, rise
Temperature is incubated 3h to 130 DEG C, is subsequently added into 4 parts of silane resin acceptor kh-550s and is well mixed, 2h is stirred in 850r/min rotating speeds, does
It is dry to constant weight, ground 60 mesh sieve is cooled to room temperature and obtains filler.
Modified sustained release agent is prepared by following technique：By weight by 15 parts of bentonites, 3 parts of cetyl trimethyl chlorine
Change ammonium and 9 parts of water are well mixed, with 350r/min speed oscillation 3h in 55 DEG C of thermostatic control oscillator vibrations, then 5 parts of addition is pungent
Sulphur phosphorus is well mixed, and with 250r/min speed oscillation 2h in 20 DEG C of thermostatic control oscillator vibrations, is cooled to room temperature and is obtained material a；
4 parts of lactic acid are warming up to 110 DEG C, 3h is incubated, nitrogen is then passed through, 3 parts of stannous chlorides is added and is well mixed, be warming up to 190 DEG C,
3h is incubated in 0.08MPa, 40 DEG C are then cooled to, separates out and is washed after precipitation, is dried in 45 DEG C to constant weight and obtains material b；By 2 parts
Dichloromethane is warming up to 39 DEG C under nitrogen protection, is incubated 5min, is subsequently added into 4 parts of phosphorus pentachlorides and is well mixed, adds after centrifugation
Enter 3 parts of hexamethylene diamines to be well mixed, 6 parts of triethylamines are added in ice-water bath and are well mixed, 6h is stirred at room temperature, are washed after 45 DEG C
10h is dried, room temperature is cooled to and obtains material b；Material a and material b are well mixed, 140 DEG C are warming up to, 10min is incubated, then
1h is stirred in 850r/min rotating speeds, room temperature is cooled to and obtains being modified sustained release agent.
Soil conditioner is by C12AESA and C12AEO is by weight 5：1
Mix.
Embodiment 4
A kind of improving yield of wheat organic slow-release fertilizer resistant to lodging proposed by the present invention, its raw material includes by weight：Cow dung 38
Part, 18 parts of chicken manure, 8 parts of pig manure, 5 parts of Erucic acid, 3 parts of rice hull ash, 3.5 parts of yeast powder, 1.5 parts of stalk fermentation microbial inoculum,
4 parts of potassium breeze, 4 parts of potassium chloride, 5 parts of potassium sulfate, 2 parts of potassium nitrate, 4.5 parts of ammonium nitrate, 7 parts of ammonium molybdate, 2.5 parts of calcium carbonate, phosphorus
Sour 2.5 parts of calcium, 7 parts of calcium monohydrogen phosphate, 3 parts of cerous nitrate, 5 parts of borax, 1.5 parts of manganese sulfate, 2.5 parts of zinc sulfate, 5 parts of filler, modification
12 parts of sustained release agent, 3 parts of soil conditioner.
Filler is prepared by following technique：By weight by 4 parts of medical stones, 3 parts of montmorillonite powders, 5 parts of attapulgites,
Accumulated after 3.5 parts of chitosans, 4 parts of talcum powder, 2 parts of land plasters, 5 parts of cake-shaped rape seed dregs, 2.5 parts of seawood meals, 3 parts of diatomite mixing, normal temperature
3.5d is placed, 4 parts of polypropylene, 4 parts of amide waxes, 5.5 parts of urea, 3 parts of lignin and 4 parts of calcium sulfate land plaster mixing are then added
Uniformly, 135 DEG C are warming up to, 2.5h is incubated, 4.5 parts of silane resin acceptor kh-550s is subsequently added into and is well mixed, turn in 820r/min
Speed stirring 2.5h, is dried to constant weight, ground 55 mesh sieve is cooled to room temperature and obtains filler.
Modified sustained release agent is prepared by following technique：By weight by 12 parts of bentonites, 4 parts of cetyl trimethyl chlorine
Change ammonium and 8 parts of water are well mixed, with 320r/min speed oscillation 3.5h in 58 DEG C of thermostatic control oscillator vibrations, then add 4 parts
Phoxim is well mixed, and with 220r/min speed oscillation 2.5h in 22 DEG C of thermostatic control oscillator vibrations, is cooled to room temperature and is obtained thing
Expect a；3 parts of lactic acid are warming up to 115 DEG C, 2.5h is incubated, nitrogen is then passed through, 4 parts of stannous chlorides is added and is well mixed, be warming up to
185 DEG C, 2.5h is incubated in 0.09MPa, 42 DEG C are then cooled to, separates out and is washed after precipitation, is dried in 42 DEG C to constant weight and obtains thing
Expect b；By 3 parts of dichloromethane under nitrogen protection, 38 DEG C are warming up to, 8min is incubated, 3 parts of phosphorus pentachloride mixing are subsequently added into equal
It is even, 3.5 parts of hexamethylene diamines are added after centrifugation and are well mixed, 5 parts of triethylamines are added in ice-water bath and are well mixed, are stirred at room temperature
6.5h, washes after 42 DEG C of dry 11h, is cooled to room temperature and obtains material b；Material a and material b are well mixed, 135 are warming up to
DEG C, 12min is incubated, then 1.5h is stirred in 820r/min rotating speeds, is cooled to room temperature and obtains being modified sustained release agent.
Soil conditioner is by C12AESA and C12AEO is by weight 3.5：
1.8 mix.
Embodiment 5
A kind of improving yield of wheat organic slow-release fertilizer resistant to lodging proposed by the present invention, its raw material includes by weight：Cow dung 42
Part, 12 parts of chicken manure, 12 parts of pig manure, 4 parts of Erucic acid, 7 parts of rice hull ash, 2.5 parts of yeast powder, 2.5 parts of stalk fermentation microbial inoculum,
2 parts of potassium breeze, 8 parts of potassium chloride, 3 parts of potassium sulfate, 3 parts of potassium nitrate, 3.5 parts of ammonium nitrate, 11 parts of ammonium molybdate, 1.5 parts of calcium carbonate, phosphorus
Sour 3.5 parts of calcium, 5 parts of calcium monohydrogen phosphate, 4 parts of cerous nitrate, 4 parts of borax, 2.5 parts of manganese sulfate, 1.5 parts of zinc sulfate, 8 parts of filler, modification
8 parts of sustained release agent, 4 parts of soil conditioner.
Filler is prepared by following technique：By weight by 4 parts of medical stones, 3 parts of montmorillonite powders, 5 parts of attapulgites,
Accumulated after 3.5 parts of chitosans, 4 parts of talcum powder, 2 parts of land plasters, 5 parts of cake-shaped rape seed dregs, 2.5 parts of seawood meals, 3 parts of diatomite mixing, normal temperature
3.5d is placed, 4 parts of polypropylene, 4 parts of amide waxes, 5.5 parts of urea, 3 parts of lignin and 4 parts of calcium sulfate land plaster mixing are then added
Uniformly, 135 DEG C are warming up to, 2.5h is incubated, 4.5 parts of silane resin acceptor kh-550s is subsequently added into and is well mixed, turn in 820r/min
Speed stirring 2.5h, is dried to constant weight, ground 55 mesh sieve is cooled to room temperature and obtains filler.
Modified sustained release agent is prepared by following technique：By weight by 12 parts of bentonites, 4 parts of cetyl trimethyl chlorine
Change ammonium and 8 parts of water are well mixed, with 320r/min speed oscillation 3.5h in 58 DEG C of thermostatic control oscillator vibrations, then add 4 parts
Phoxim is well mixed, and with 220r/min speed oscillation 2.5h in 22 DEG C of thermostatic control oscillator vibrations, is cooled to room temperature and is obtained thing
Expect a；3 parts of lactic acid are warming up to 115 DEG C, 2.5h is incubated, nitrogen is then passed through, 4 parts of stannous chlorides is added and is well mixed, be warming up to
185 DEG C, 2.5h is incubated in 0.09MPa, 42 DEG C are then cooled to, separates out and is washed after precipitation, is dried in 42 DEG C to constant weight and obtains thing
Expect b；By 3 parts of dichloromethane under nitrogen protection, 38 DEG C are warming up to, 8min is incubated, 3 parts of phosphorus pentachloride mixing are subsequently added into equal
It is even, 3.5 parts of hexamethylene diamines are added after centrifugation and are well mixed, 5 parts of triethylamines are added in ice-water bath and are well mixed, are stirred at room temperature
6.5h, washes after 42 DEG C of dry 11h, is cooled to room temperature and obtains material b；Material a and material b are well mixed, 135 are warming up to
DEG C, 12min is incubated, then 1.5h is stirred in 820r/min rotating speeds, is cooled to room temperature and obtains being modified sustained release agent.
Soil conditioner is by C12AESA and C12AEO is by weight 4.5：
1.2 mix.
By the improving yield of wheat organic slow-release fertilizer resistant to lodging in embodiment 1- embodiments 5 before wheat transplanting, by every 53kg/
667m2Amount disposably apply, contrast groups basal dressing and are topdressed according to a conventional method, and total fertilization amount is 70kg/667m2, fertilizer is nitrogen
Phosphorus potassium complex fertilizer, wherein, nitrogenous fertilizer and potash fertilizer spread fertilizer over the fields in two times；
Yield-increasing efficiency=(experimental group yield/contrast groups yield -1) * 100%
Obtained wheat increase yield efficiency and rate resistant to lodging is as shown in table 1.
Table 1：
The wheat increase yield efficiency and rate data resistant to lodging obtained according to table 1, obtaining the improving yield of wheat of the present invention resistant to lodging has
Machine slow release fertilizer can be prevented effectively from Wheat lodging, improve the yield and quality of wheat.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of improving yield of wheat organic slow-release fertilizer resistant to lodging, it is characterised in that its raw material includes by weight：Cow dung 35-45
Part, 10-20 parts of chicken manure, 5-15 parts of pig manure, 3-6 parts of Erucic acid, 2-8 parts of rice hull ash, 2-4 parts of yeast powder, stalk fermentation
1-3 parts of microbial inoculum, 1-5 parts of potassium breeze, 3-9 parts of potassium chloride, 2-6 parts of potassium sulfate, 1-4 parts of potassium nitrate, 3-5 parts of ammonium nitrate, ammonium molybdate
6-12 parts, 1-3 parts of calcium carbonate, 2-4 parts of calcium phosphate, 4-8 parts of calcium monohydrogen phosphate, 2-5 parts of cerous nitrate, 3-6 parts of borax, manganese sulfate 1-3
Part, 1-3 parts of zinc sulfate, 4-9 parts of filler, modified 5-15 parts of sustained release agent, 2-5 parts of soil conditioner.
2. improving yield of wheat organic slow-release fertilizer resistant to lodging according to claim 1, it is characterised in that the raw material of filler is by weight
Amount part includes：1-5 parts of medical stone, 2-5 parts of montmorillonite powder, 3-6 parts of attapulgite, 3-5 parts of chitosan, 2-5 parts of talcum powder, gypsum
1-6 parts of powder, 3-6 parts of cake-shaped rape seed dregs, 2-4 parts of seawood meal, 1-4 parts of diatomite, 2-5 parts of polypropylene, 3-6 parts of amide waxe, 4-6 parts of urea,
2-5 parts of lignin, 1-5 parts of calcium sulfate land plaster, 4-6 parts of silane resin acceptor kh-550.
3. improving yield of wheat organic slow-release fertilizer resistant to lodging according to claim 1 or 2, it is characterised in that filler is by as follows
It is prepared by technique：By medical stone, montmorillonite powder, attapulgite, chitosan, talcum powder, land plaster, cake-shaped rape seed dregs, seawood meal, diatom
Accumulated after soil mixing, room temperature 3-5d, then add polypropylene, amide waxe, urea, lignin and the mixing of calcium sulfate land plaster
Uniformly, 130-150 DEG C is warming up to, 1-3h is incubated, silane resin acceptor kh-550 is subsequently added into and is well mixed, in 650-850r/min
Rotating speed stirs 2-4h, dries to constant weight, ground 40-60 mesh sieves are cooled to room temperature and obtain filler.
4. the improving yield of wheat organic slow-release fertilizer resistant to lodging according to claim any one of 1-3, it is characterised in that modified slow
Release the raw material of agent includes by weight：5-15 parts of bentonite, 3-6 parts of hexadecyltrimethylammonium chloride, 4-9 parts of water, phoxim
2-5 parts, 1-4 parts of lactic acid, 3-6 parts of stannous chloride, 2-5 parts of dichloromethane, 1-4 parts of phosphorus pentachloride, 3-5 parts of hexamethylene diamine, triethylamine
2-6 parts.
5. the improving yield of wheat organic slow-release fertilizer resistant to lodging according to claim any one of 1-4, it is characterised in that modified slow
Agent is released to be prepared by following technique：Bentonite, hexadecyltrimethylammonium chloride and water are well mixed, shaken in water bath with thermostatic control
Swing in device and vibrate, then add phoxim and be well mixed, vibrated in thermostatic control oscillator vibration, be cooled to room temperature and obtain material a；Will
Lactic acid heats up, insulation, is then passed through nitrogen, adds stannous chloride and is well mixed, heats up, and insulation then cools, and separates out after precipitation
Washing, dries to constant weight and obtains material b；By dichloromethane under nitrogen protection, heat up, insulation is subsequently added into phosphorus pentachloride and mixed
Close uniform, hexamethylene diamine is added after centrifugation and is well mixed, triethylamine is added in ice-water bath and is well mixed, is stirred at room temperature, is washed
After dry, be cooled to room temperature and obtain material b；Material a and material b are well mixed, heated up, insulation is followed by stirring for, is cooled to room
Temperature obtains being modified sustained release agent.
6. the improving yield of wheat organic slow-release fertilizer resistant to lodging according to claim any one of 1-5, it is characterised in that modified slow
Agent is released to be prepared by following technique：Bentonite, hexadecyltrimethylammonium chloride and water are well mixed, in 55-65 DEG C of perseverance
With 250-350r/min speed oscillation 3-5h in tepidarium oscillator, then add phoxim and be well mixed, in 20-30 DEG C of constant temperature
With 150-250r/min speed oscillation 2-4h in water bath chader, it is cooled to room temperature and obtains material a；Lactic acid is warming up to 110-
130 DEG C, 1-3h is incubated, nitrogen is then passed through, stannous chloride is added and is well mixed, 170-190 DEG C is warming up to, in 0.08-
0.12MPa is incubated 1-3h, is then cooled to 40-50 DEG C, separates out and is washed after precipitation, is dried in 35-45 DEG C to constant weight and obtains material
b；By dichloromethane under nitrogen protection, 35-39 DEG C is warming up to, 5-15min is incubated, phosphorus pentachloride is subsequently added into and is well mixed,
Add hexamethylene diamine after centrifugation to be well mixed, triethylamine added in ice-water bath and is well mixed, 6-8h is stirred at room temperature, washing after
35-45 DEG C of dry 10-14h, is cooled to room temperature and obtains material b；Material a and material b are well mixed, 120-140 DEG C is warming up to,
10-20min is incubated, then 1-3h is stirred in 650-850r/min rotating speeds, is cooled to room temperature and obtains being modified sustained release agent.
7. the improving yield of wheat organic slow-release fertilizer resistant to lodging according to claim any one of 1-6, it is characterised in that soil is adjusted
Agent is managed by C12AESA and C12AEO is by weight 3-5：1-2 is mixed.
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| CN107652081A (en) * | 2017-11-16 | 2018-02-02 | 来安县薜必英家庭农场 | A kind of wheat composite fertilizer for improving soil hardening situation |
| CN108476891A (en) * | 2018-04-03 | 2018-09-04 | 山东黎昊源生物工程有限公司 | A kind of Wheat in Northern high yield implantation methods resistant to lodging |
| CN109122122A (en) * | 2018-08-03 | 2019-01-04 | 内蒙古朔河禾农业发展有限公司 | It increases percent protein the processing method of novel wheat implantation methods and Highly elastic friction clutch |
| RU2819756C1 (en) * | 2023-01-09 | 2024-05-23 | Федеральное Государственное Бюджетное Образовательное Учреждения Высшего Образования "Уральский Государственный Аграрный Университет" (ФГБОУ ВО Уральский ГАУ) | Organo-mineral fertilizer and method for its production |
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