CN107226550A - Efficiently catalyzing and oxidizing device - Google Patents

Efficiently catalyzing and oxidizing device Download PDF

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Publication number
CN107226550A
CN107226550A CN201710488239.1A CN201710488239A CN107226550A CN 107226550 A CN107226550 A CN 107226550A CN 201710488239 A CN201710488239 A CN 201710488239A CN 107226550 A CN107226550 A CN 107226550A
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CN
China
Prior art keywords
zone
area
efficiently catalyzing
oxidizing
coagulation floatation
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CN201710488239.1A
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Chinese (zh)
Inventor
刘耀中
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Sichuan Austrian Environmental Protection Technology Co Ltd
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Sichuan Austrian Environmental Protection Technology Co Ltd
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Filing date
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Priority to CN201710488239.1A priority Critical patent/CN107226550A/en
Publication of CN107226550A publication Critical patent/CN107226550A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/343Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the pharmaceutical industry, e.g. containing antibiotics
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]

Abstract

The invention discloses a kind of efficiently catalyzing and oxidizing device, including the coagulation floatation being sequentially communicated, intermediate water tank, O3 contacted oxidation tower, efficiently catalyzing and oxidizing groove and efficient sedimentation tank, the inside of coagulation floatation is mixed zone and air flotation zone by vertical divides, the bottom leaving certain gaps uncovered by the economic plan of demarcation strip and coagulation floatation, wastewater inlet is provided with the side wall of mixed zone, dosing mouth is provided with the top of mixed zone, air flotation zone is divided into first area and second area by netted filter, it is provided with above first area in J-shaped scum silica frost collecting pit, the bottom of first area is provided with aeration head, second area connects intermediate water tank by pipeline.By mixed zone and air flotation zone subregion in coagulation floatation in the present invention, and agitating device is set in mixed zone, aerator is set in air flotation zone, accelerates air supporting reaction, waste water is moved quickly through coagulation floatation and remove suspended particulate substance, improve the speed and effect of catalysis oxidation.

Description

Efficiently catalyzing and oxidizing device
Technical field
The present invention relates to industrial waste water treatment, and in particular to a kind of efficiently catalyzing and oxidizing device.
Background technology
At present, the main process of China's medicine producing wastewater processing is micro-organism treatment process, and micro-organism treatment process is The organic pollution in waste water is decomposed by the metabolism of microbe colony, microorganism therefrom absorb sugar, protein, Fat, starch and other low molecular compounds, and in aerobic environment by low molecule organic matter oxidation Decomposition into CO2And H2O's Process.But a certain amount of Biostatic pollutant, the particularly life of bactericidal antiphlogistic class medicine are commonly present in medicine producing wastewater Enterprise is produced, Biostatic pollutant inhibits the microbe colony played a crucial role in Waste Water Treatment to grow, so that It significantly have impact on the treatment effect of micro-organism treatment process.Efficiently catalyzing and oxidizing equipment as medication chemistry class waste water at The pre-processing device of reason, the Biostatic pollutant structure that can be destroyed in waste water improves the biodegradability of waste water.
The content of the invention
It is an object of the invention to provide a kind of efficiently catalyzing and oxidizing device, solve in current efficiently catalyzing and oxidizing device Not to the carry out dissolved air flotation of waste water so that during catalytic oxidation, the problem of catalytic oxidation is insufficient.
To solve above-mentioned technical problem, the present invention uses following technical scheme:
A kind of efficiently catalyzing and oxidizing device, including coagulation floatation, intermediate water tank, O3 contacted oxidation tower, the height being sequentially communicated Catalysis oxidation groove, pipe-line mixer and efficient sedimentation tank are imitated, O3 contacted oxidation tower is connected with ozone generator, coagulation floatation Inside by vertical divides be mixed zone and air flotation zone, the bottom leaving certain gaps uncovered by the economic plan of demarcation strip and coagulation floatation, It is provided with the side wall of mixed zone at the top of wastewater inlet, mixed zone and is provided with dosing mouth, the bottom of mixed zone is provided with by electricity The spiral agitator of machine driving, air flotation zone is divided into first area and second area, first area by netted filter Top be provided with J-shaped scum silica frost collecting pit, the bottom of first area is provided with aeration head, and aeration head is connected by connecting tube Have and be provided with valve in air blower, the connecting tube, second area connects intermediate water tank by pipeline.Waste water of the present invention is by carrying Rise to enter and coagulation air-float reaction is carried out in coagulation floatation, adding decoction by dosing mouth is reacted, and passes through air-dissolving air-float The suspended material in waste water is separated in effect, and air-flotation scum is transported outward after entering the processing of Waste Water Treatment sludge dehydrating and drying Harmless treatment is done, the water outlet gravity flow of coagulation floatation supplies elevator pump to be lifted into O3 contacted oxidation into intermediate water tank is temporary Tower.Ozone of the waste water after suspending by reflux type with special ozone generator generation in O3 contacted oxidation tower is removed to fill Divide haptoreaction, pass through the pollutant in the strong oxidizing property Decomposition Wastewater of ozone.O3 contacted oxidation tower water outlet gravity flow enters high Imitate catalysis oxidation groove.Substantial amounts of iron filings slag is set in efficiently catalyzing and oxidizing groove, and waste water gravity flow enters efficiently catalyzing and oxidizing groove, in acid Under the conditions of property and add quantitative H in efficiently catalyzing and oxidizing groove certain depth2O2, the pollutant in waste water is urged in Fe2+ Under agent effect, by H2O2The active hydroxyl free radical produced triggers and propagated radical chain reaction, accelerates organic matter and reproducibility The oxidation of material.Efficiently catalyzing and oxidizing groove water outlet gravity flow enters in efficient sedimentation tank, certain by being added in pipe-line mixer The Ca (OH) of amount2Solution is precipitated after waste water is neutralized, and precipitating sludge is periodically emitted at Waste Water Treatment sludge dehydrating and drying Outer operation harmless treatment after reason.By mixed zone and air flotation zone subregion in coagulation floatation in the present invention, and in mixed zone Agitating device is set, the speed of dosing reaction is improved, while setting aerator in air flotation zone, accelerates air supporting reaction, makes to give up Water moves quickly through coagulation floatation and removes suspended particulate substance, can make efficiently catalyzing and oxidizing reaction not by various suspended particulate substances Influence, improves the speed and effect of catalysis oxidation.
Preferably, the bottom of first area is in inverted trapezoidal shape, the lower end of filter is fixed on first area inverted trapezoidal At the upper end-face edge of bottom.The bottom of first area is in inverted trapezoidal shape, is conducive to the sludgd deposition in coagulation floatation, is easy to sludge Discharge.
Preferably, spiral agitator includes rotating shaft and the spiral plate set along rotating shaft, spiral agitator has two More than, the rotation direction of adjacent spiral agitator is opposite.The structure of spiral agitator is limited, passes through the agitation of spiral plate More preferably, faster, while set more than two spiral agitators, and adjacent spiral is stirred dosing reaction speed mixing effect The rotation direction of device is mixed on the contrary, decoction mixing velocity can be increased, the effect of dosing reaction is improved.
Preferably, being provided with tube settling layer in efficient sedimentation tank, efficient sedimentation tank is divided into position by tube settling layer Clear water output is provided with clear water zone and underlying settling zone in top, the side wall of clear water zone, settling zone is with efficiently urging Change oxidation trough to be connected.Efficient sedimentation tank is precipitated using tube settling layer to the waste water after catalysis oxidation, and inclined tube sinks Shallow lake layer can be effectively by sludge barrier in settling zone, and clear water flows into clear water zone discharge utilization naturally.
Preferably, being additionally provided with flocculant concentration pipeline in settling zone, flocculant speculates pipeline connection flocculant concentration Device.Flocculant is added in settling zone by flocculant concentration device to be reacted.
Preferably, the both sides of settling zone are tiltedly installed with the cleaning shoe being provided with baffle plate, baffle plate along barrier slides, scrape Mud plate is connected with the power set for sliding cleaning shoe.Due to that can have sludgd deposition on baffle plate, cleaning shoe can be by baffle plate The sludge scraping of deposition enters settling zone bottom.
Preferably, the bottom of settling zone is provided with sludge pump, sludge pump connection sludge dewatering device.Settling zone bottom is set Sludge pump, is conveyed into sludge dewatering device by sludge by sludge pump, does harmless treatment.
Compared with prior art, beneficial effects of the present invention are at least one of following:
By mixed zone and air flotation zone subregion in coagulation floatation in the present invention, and agitating device is set in mixed zone, improved The speed of dosing reaction, while setting aerator in air flotation zone, accelerates air supporting reaction, waste water is moved quickly through coagulation air-float Pond removes suspended particulate substance, and efficiently catalyzing and oxidizing reaction can be made not influenceed by various suspended particulate substances, catalysis oxidation is improved Speed and effect.
The present invention by the agitation mixing effect of spiral plate more preferably, dosing reaction speed faster, while setting two or more Spiral agitator, and adjacent spiral agitator rotation direction on the contrary, decoction mixing velocity can be increased, improve The effect of dosing reaction.
Efficient sedimentation tank of the present invention is precipitated using tube settling layer to the waste water after catalysis oxidation, tube settling Layer can be effectively by sludge barrier in settling zone, and clear water flows into clear water zone discharge utilization naturally.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and It is not used in the restriction present invention.
Embodiment 1:
A kind of efficiently catalyzing and oxidizing device, as shown in figure 1, being connect including the coagulation floatation 1, intermediate water tank 2, ozone being sequentially communicated Oxidizing tower 3, efficiently catalyzing and oxidizing groove 4, pipe-line mixer 7 and efficient sedimentation tank 5 are touched, O3 contacted oxidation tower 3 is connected with ozone Generator 6, the inside of coagulation floatation 1 is divided into mixed zone 12 and air flotation zone 13, demarcation strip 11 by vertical demarcation strip 11 With the bottom leaving certain gaps uncovered by the economic plan of coagulation floatation 1, wastewater inlet 14 is provided with the side wall of mixed zone 12, the top of mixed zone 12 is set Dosing mouth 15 is equipped with, the bottom of mixed zone 12 is provided with by motor-driven spiral agitator, and air flotation zone 13 is by netted Filter 16, which is divided into, to be provided with above first area and second area, first area in J-shaped scum silica frost collecting pit 18, the The bottom in one region is provided with aeration head 19, and aeration head 19 is connected with air blower 20, the connecting tube by connecting tube and is provided with Valve 21, second area connects intermediate water tank 2 by pipeline.
Waste water is added by being lifted into progress coagulation air-float reaction in coagulation floatation by dosing mouth in the present embodiment Decoction is reacted, and is separated the suspended material in waste water by air-dissolving air-float effect, and air-flotation scum enters at waste water Outer operation harmless treatment after the processing of system sludge dehydration and drying is managed, the water outlet gravity flow of coagulation floatation enters intermediate water tank and kept in O3 contacted oxidation tower is lifted into for elevator pump.Waste water after removal suspension is by reflux type in O3 contacted oxidation tower The abundant haptoreaction of ozone produced with special ozone generator, passes through the pollutant in the strong oxidizing property Decomposition Wastewater of ozone. O3 contacted oxidation tower water outlet gravity flow enters efficiently catalyzing and oxidizing groove.Substantial amounts of iron filings slag is set in efficiently catalyzing and oxidizing groove, given up Water gravity flow enters efficiently catalyzing and oxidizing groove, adds in acid condition and in efficiently catalyzing and oxidizing groove certain depth quantitative H2O2, make the pollutant in waste water under Fe2+ catalyst actions, by H2O2The active hydroxyl free radical produced triggers and propagated certainly By base chain reaction, accelerate the oxidation of organic matter and reducing substances.Efficiently catalyzing and oxidizing groove water outlet gravity flow enters efficient sedimentation tank In, by adding a certain amount of CaOH in pipe-line mixer2Solution is precipitated after waste water is neutralized, and precipitating sludge is periodically emitted into Outer operation harmless treatment after the processing of Waste Water Treatment sludge dehydrating and drying.
By mixed zone and air flotation zone subregion in coagulation floatation in the present embodiment, and stirring is set to fill in mixed zone Put, improve the speed of dosing reaction, while setting aerator in air flotation zone, accelerate air supporting reaction, move quickly through waste water Coagulation floatation removes suspended particulate substance, and efficiently catalyzing and oxidizing reaction can be made not influenceed by various suspended particulate substances, improved The speed and effect of catalysis oxidation.
Embodiment 2:
Optimized on the basis of embodiment 1, the bottom of first area is in inverted trapezoidal shape, the lower end of filter 16 is fixed on the At the bottom upper end-face edge of one region inverted trapezoidal.
The bottom of first area in the present embodiment is in inverted trapezoidal shape, is conducive to the sludgd deposition in coagulation floatation, just In sludge discharge.
Embodiment 3:
Optimized on the basis of embodiment 2, spiral agitator includes rotating shaft 23 and the spiral plate 24 set along rotating shaft 23, Spiral agitator has two or more, and the rotation direction of adjacent spiral agitator is opposite.
The present embodiment limits the structure of spiral agitator, more preferable by the agitation mixing effect of spiral plate, dosing reaction Speed faster, while set more than two spiral agitators, and adjacent spiral agitator rotation direction on the contrary, Decoction mixing velocity can be increased, the effect of dosing reaction is improved.
Embodiment 4:
Optimized on the basis of embodiment 3, tube settling layer 51 is provided with efficient sedimentation tank 5, tube settling layer 51 will Efficient sedimentation tank 5, which is divided on clear water zone 52 and underlying settling zone 53 above, the side wall of clear water zone 52, to be set There is clear water output 54, settling zone 53 is connected with efficiently catalyzing and oxidizing groove 4.
In the present embodiment, efficient sedimentation tank is precipitated using tube settling layer to the waste water after catalysis oxidation, tiltedly The pipe beds of precipitation can be effectively by sludge barrier in settling zone, and clear water flows into clear water zone discharge utilization naturally.
Embodiment 5:
Optimized on the basis of embodiment 4, flocculant concentration pipeline 55 is additionally provided with settling zone 53, flocculant speculates pipe The connection flocculant concentration device of road 55 56.Flocculant is added in settling zone by flocculant concentration device to be reacted.
Embodiment 6:
Optimized on the basis of embodiment 5, the both sides of settling zone 53, which are tiltedly installed with baffle plate 57, baffle plate 57, is provided with edge The cleaning shoe 58 that baffle plate 57 is slided, cleaning shoe 58 is connected with the power set for sliding cleaning shoe 58.
In the present embodiment, due to that can have sludgd deposition on baffle plate, cleaning shoe can enter the sludge scraping deposited on baffle plate Settling zone bottom.
Embodiment 7:
Optimized on the basis of embodiment 6, the bottom of settling zone 53 is provided with sludge pump 59, and the sludge pump 59 connects dirt Mud dehydrator 8.
In the present embodiment, settling zone bottom sets sludge pump, and sludge is conveyed into sludge dewatering device by sludge pump, nothing is done Evilization processing.
Although reference be made herein to invention has been described for multiple explanatory embodiments of the invention, however, it is to be understood that Those skilled in the art can be designed that a lot of other modification and embodiment, and these modifications and embodiment will fall in this Shen Please be within disclosed spirit and spirit.More specifically, can in the range of disclosure, drawings and claims A variety of variations and modifications are carried out with the building block to theme composite configuration and/or layout.Except to building block and/or layout Outside the modification and improvement of progress, to those skilled in the art, other purposes also will be apparent.

Claims (7)

1. a kind of efficiently catalyzing and oxidizing device, including the coagulation floatation being sequentially communicated(1), intermediate water tank(2), ozone contact oxygen Change tower(3), efficiently catalyzing and oxidizing groove(4), pipe-line mixer(7)And efficient sedimentation tank(5), the O3 contacted oxidation tower(3) It is connected with ozone generator(6), it is characterised in that:
The coagulation floatation(1)Inside pass through vertical demarcation strip(11)It is divided into mixed zone(12)And air flotation zone(13), The demarcation strip(11)With coagulation floatation(1)Bottom leaving certain gaps uncovered by the economic plan, the mixed zone(12)Side wall on be provided with sewage Import(14), the mixed zone(12)Top be provided with dosing mouth(15), the mixed zone(12)Bottom be provided with by electricity The spiral agitator of machine driving,
The air flotation zone(13)Pass through netted filter(16)It is divided into first area and second area, the first area Top is provided with J-shaped scum silica frost collecting pit(18), the bottom of the first area is provided with aeration head(19), the aeration Head(19)Air blower is connected with by connecting tube(20), valve is provided with the connecting tube(21),
The second area connects intermediate water tank by pipeline(2).
2. efficiently catalyzing and oxidizing device according to claim 1, it is characterised in that:The bottom of the first area is terraced in falling Shape, the filter(16)Lower end be fixed at the bottom upper end-face edge of first area inverted trapezoidal.
3. efficiently catalyzing and oxidizing device according to claim 1, it is characterised in that:The spiral agitator includes rotating shaft (23)With along rotating shaft(23)The spiral plate of setting(24), the spiral agitator has two or more, and the adjacent spiral is stirred The rotation direction for mixing device is opposite.
4. efficiently catalyzing and oxidizing device according to claim 1, it is characterised in that:The efficient sedimentation tank(5)It is interior to set There is tube settling layer(51), the tube settling layer(51)By efficient sedimentation tank(5)It is divided into clear water zone above(52) With underlying settling zone(53), the clear water zone(52)Side wall on be provided with clear water output(54), the settling zone (53)With efficiently catalyzing and oxidizing groove(4)It is connected.
5. efficiently catalyzing and oxidizing device according to claim 4, it is characterised in that:The settling zone(53)Inside it is additionally provided with Flocculant concentration pipeline(55), the flocculant speculates pipeline(55)Connect flocculant concentration device(56).
6. efficiently catalyzing and oxidizing device according to claim 4, it is characterised in that:The settling zone(53)Both sides tilt It is provided with baffle plate(57), the baffle plate(57)On be provided with along baffle plate(57)The cleaning shoe of slip(58), the cleaning shoe(58) Being connected with makes cleaning shoe(58)The power set of slip.
7. efficiently catalyzing and oxidizing device according to claim 4, it is characterised in that:The settling zone(53)Bottom set There is sludge pump(59), the sludge pump(59)Connect sludge dewatering device(8).
CN201710488239.1A 2017-06-23 2017-06-23 Efficiently catalyzing and oxidizing device Pending CN107226550A (en)

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CN201710488239.1A CN107226550A (en) 2017-06-23 2017-06-23 Efficiently catalyzing and oxidizing device

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Application Number Priority Date Filing Date Title
CN201710488239.1A CN107226550A (en) 2017-06-23 2017-06-23 Efficiently catalyzing and oxidizing device

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CN110885146A (en) * 2019-11-22 2020-03-17 中石化南京工程有限公司 Circulating water sewage treatment device and method
CN113680151A (en) * 2020-05-19 2021-11-23 中国石油天然气集团有限公司 Device and method for dedusting and desulfurizing tail gas of thermal desorption system

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CN113680151A (en) * 2020-05-19 2021-11-23 中国石油天然气集团有限公司 Device and method for dedusting and desulfurizing tail gas of thermal desorption system

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Application publication date: 20171003