CN107217469A - A kind of titania modified water-proof wool fiber - Google Patents
A kind of titania modified water-proof wool fiber Download PDFInfo
- Publication number
- CN107217469A CN107217469A CN201710616532.1A CN201710616532A CN107217469A CN 107217469 A CN107217469 A CN 107217469A CN 201710616532 A CN201710616532 A CN 201710616532A CN 107217469 A CN107217469 A CN 107217469A
- Authority
- CN
- China
- Prior art keywords
- wool fiber
- titania modified
- proof
- modified water
- water
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000835 fiber Substances 0.000 title claims abstract description 120
- 210000002268 wool Anatomy 0.000 title claims abstract description 93
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 76
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 238000004078 waterproofing Methods 0.000 claims abstract description 16
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 13
- 239000010935 stainless steel Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 30
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 15
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 15
- 241001330002 Bambuseae Species 0.000 claims description 15
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 15
- 239000011425 bamboo Substances 0.000 claims description 15
- 229940059936 lithium bromide Drugs 0.000 claims description 15
- 230000010355 oscillation Effects 0.000 claims description 15
- 239000002243 precursor Substances 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 11
- 239000012530 fluid Substances 0.000 claims description 11
- 238000000527 sonication Methods 0.000 claims description 10
- 238000007654 immersion Methods 0.000 claims description 7
- 229920000742 Cotton Polymers 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 240000005702 Galium aparine Species 0.000 claims description 3
- 235000014820 Galium aparine Nutrition 0.000 claims description 3
- 241000612118 Samolus valerandi Species 0.000 claims description 3
- 238000002242 deionisation method Methods 0.000 claims description 3
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 4
- 230000006378 damage Effects 0.000 abstract description 3
- 230000003197 catalytic effect Effects 0.000 abstract description 2
- 238000002425 crystallisation Methods 0.000 abstract description 2
- 230000008025 crystallization Effects 0.000 abstract description 2
- 239000003063 flame retardant Substances 0.000 abstract description 2
- 238000009413 insulation Methods 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 description 4
- 206010013786 Dry skin Diseases 0.000 description 3
- 239000011492 sheep wool Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004089 microcirculation Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention belongs to wool fiber technical field, more particularly to a kind of titania modified water-proof wool fiber.Titania modified water-proof wool fiber of the present invention, formed using special-shaped wool fiber, titania modified wool fiber and stainless steel fibre juxtaposed beaming, stainless steel fibre has well antistatic, fire-retardant, wear-resisting, suction sound insulation, anti electromagnetic wave effect, add the anti-shrinkage effect of wool fiber；The increase of waterproofing agent can effectively improve the water resistance of wool fiber；The titania produced inside wool fiber with the butyl titanate crystallization of surface attachment, with wool fiber strong bonded, catalytic activity is high, small to Wool Fibre Damage.
Description
Technical field
The invention belongs to wool fiber technical field, more particularly to a kind of titania modified water-proof wool fiber.
Background technology
Wool is the important source material of textile industry, the advantage that flexible good, moisture pick-up properties is strong, thermal property is good, not only
Use in winter is comfortable, and spring and autumn is suitable for use with, comfortable dry and comfortable, while wool has abundant elasticity, directly contacts skin, fur
Capillary is stimulated, is conducive to improving microcirculation in human body, meanwhile, hole one air flow of formation under hair side between fiber
Layer, makes one to feel salubriouser, comfortable soft, dispelling fatigue.But the crimpness of wool fiber is big, therefore wool fabric
Easy contraction distortion after washing, destruction of easily being damaged by worms is not easy to preserve；Existing wool fiber mostly water resistance is bad.
The content of the invention
Goal of the invention：In order to overcome problem above, it is an object of the invention to provide a kind of titania modified water-proof wool
Fiber.
Technical scheme：It is an object of the invention to provide a kind of titania modified water-proof wool fiber, including wool are fine
Body is tieed up, described wool fiber body is that different in nature wool fiber, titania modified wool fiber and stainless steel fibre are arranged side by side
Boundling is formed, and in two-sided hollow structure, bamboo fibre is filled with hollow structure inner chamber, and bamboo fibre is wrapped with cotton gauze,
Contain waterproofing agent in described bamboo fibre.
Preferably, different in nature wool fiber cross section is in polygonized structure, preferably regular hexagon structure.
Preferably, different in nature wool fiber cross section is in cross-shaped configuration.
Preferably, different in nature wool fiber cross section is in trilobal or bunge bedstraw herb shape.
Preferably, a diameter of 20-25 μm of the stainless steel fibre.
Preferably, the waterproofing agent is ADM-666 watery water-proofing agents（The mould proof fungi-proofing scientific and technological limited public affairs of Dongguan City Ai Maier
Department）.
Preferably, titania modified wool fiber its preparation method is as follows：Wool fiber is immersed in into mass concentration is
In 50-150g/L lithium-bromide solution, 3-5h is soaked in 75-85 DEG C, and uses sonic oscillation aid in treatment, processing completes to take out
After extract moisture, wool fiber must be swelled；Wool fiber will be swelled and be put into absolute ethyl alcohol and soak 30-50min, be then soaked in
In TiO 2 precursor treatment fluid, 100 DEG C of water use nothing after boiling processing 30-50min after immersion 12-24h after sonic oscillation processing
Water-ethanol soaks 8-16min, is felt with deionized water rinsing after 50-70 DEG C of drying.
Preferably, the consumption bath raio of described wool fiber and lithium-bromide solution is 1:60-80.
Preferably, sonic oscillation frequency is that 40KHz, power are 300W, and sonication treatment time is when lithium-bromide solution soaks
10-20min, sonication treatment time is 20-40min when TiO 2 precursor treatment fluid soaks.
Preferably, described TiO 2 precursor treatment fluid is butyl titanate and absolute ethyl alcohol by volume 1:15~
25 mixed liquor.
Above-mentioned technical proposal can be seen that the present invention and have the advantages that：It is of the present invention titania modified
Water-proof wool fiber, is formed, no using special-shaped wool fiber, titania modified wool fiber and stainless steel fibre juxtaposed beaming
The steel fibre that becomes rusty has good antistatic, fire-retardant, wear-resisting, suction sound insulation, anti electromagnetic wave effect, adds the anti-shrinkage of wool fiber
Effect；The increase of waterproofing agent can effectively improve the water resistance of wool fiber；With the metatitanic acid of surface attachment inside wool fiber
The titania of four butyl ester crystallization production, with wool fiber strong bonded, catalytic activity is high, small to Wool Fibre Damage.
Embodiment
With reference to specific embodiment, the present invention is furture elucidated.
Embodiment 1
A kind of titania modified water-proof wool fiber, including wool fiber body, described wool fiber body are different in nature sheep
Wool fibre, titania modified wool fiber and stainless steel fibre juxtaposed beaming are formed, and in two-sided hollow structure, hollow structure
Bamboo fibre is filled with inner chamber, and bamboo fibre is wrapped with cotton gauze, described bamboo fibre and contains waterproofing agent.
Different in nature wool fiber cross section is in polygonized structure, preferably regular hexagon.
A diameter of 20 μm of the stainless steel fibre.
The waterproofing agent is ADM-666 watery water-proofing agents（The mould proof fungi-proofing Science and Technology Ltd.s of Dongguan City Ai Maier）.
Titania modified wool fiber its preparation method is as follows：It is 50g/L's that wool fiber is immersed in into mass concentration
In lithium-bromide solution, 3h is soaked in 75 DEG C, and uses sonic oscillation aid in treatment, processing completes to extract moisture after taking out, and obtains molten
Swollen wool fiber；Wool fiber will be swelled and be put into absolute ethyl alcohol and soak 30min, TiO 2 precursor processing is then soaked in
In liquid, 100 DEG C of water use soaked in absolute ethyl alcohol 8min after boiling processing 30min after immersion 12h after sonic oscillation processing, use deionized water
Rinse and feel after 50 DEG C of dryings.
Described wool fiber and the consumption bath raio of lithium-bromide solution are 1:60.
Sonic oscillation frequency is that 40KHz, power are 300W, and sonication treatment time is 10min, two when lithium-bromide solution soaks
Sonication treatment time is 20min when titania precursor body treatment fluid soaks.
Described TiO 2 precursor treatment fluid is butyl titanate and absolute ethyl alcohol by volume 1:15 mixed liquor.
Embodiment 2
A kind of titania modified water-proof wool fiber, including wool fiber body, described wool fiber body are different in nature sheep
Wool fibre, titania modified wool fiber and stainless steel fibre juxtaposed beaming are formed, and in two-sided hollow structure, hollow structure
Bamboo fibre is filled with inner chamber, and bamboo fibre is wrapped with cotton gauze, described bamboo fibre and contains waterproofing agent.
Different in nature wool fiber cross section is in cross-shaped configuration.
A diameter of 25 μm of the stainless steel fibre.
The waterproofing agent is ADM-666 watery water-proofing agents（The mould proof fungi-proofing Science and Technology Ltd.s of Dongguan City Ai Maier）.
Titania modified wool fiber its preparation method is as follows：It is 150g/L's that wool fiber is immersed in into mass concentration
In lithium-bromide solution, 5h is soaked in 85 DEG C, and uses sonic oscillation aid in treatment, processing completes to extract moisture after taking out, and obtains molten
Swollen wool fiber；Wool fiber will be swelled and be put into absolute ethyl alcohol and soak 50min, TiO 2 precursor processing is then soaked in
In liquid, 100 DEG C of water use soaked in absolute ethyl alcohol 16min after boiling processing 50min after immersion 24h after sonic oscillation processing, use deionization
Water, which is rinsed, to be felt after 70 DEG C of dryings.
Described wool fiber and the consumption bath raio of lithium-bromide solution are 1:60.
Sonic oscillation frequency is that 40KHz, power are 300W, and sonication treatment time is 20min, two when lithium-bromide solution soaks
Sonication treatment time is 40min when titania precursor body treatment fluid soaks.
Described TiO 2 precursor treatment fluid is butyl titanate and absolute ethyl alcohol by volume 1:25 mixing
Liquid.
Embodiment 3
A kind of titania modified water-proof wool fiber, including wool fiber body, described wool fiber body are different in nature sheep
Wool fibre, titania modified wool fiber and stainless steel fibre juxtaposed beaming are formed, and in two-sided hollow structure, hollow structure
Bamboo fibre is filled with inner chamber, and bamboo fibre is wrapped with cotton gauze, described bamboo fibre and contains waterproofing agent.
Different in nature wool fiber cross section is in trilobal or bunge bedstraw herb shape structure.
A diameter of 22 μm of the stainless steel fibre.
The waterproofing agent is ADM-666 watery water-proofing agents（The mould proof fungi-proofing Science and Technology Ltd.s of Dongguan City Ai Maier）.
Titania modified wool fiber its preparation method is as follows：It is 100g/L's that wool fiber is immersed in into mass concentration
In lithium-bromide solution, 4h is soaked in 80 DEG C, and uses sonic oscillation aid in treatment, processing completes to extract moisture after taking out, and obtains molten
Swollen wool fiber；Wool fiber will be swelled and be put into absolute ethyl alcohol and soak 40min, TiO 2 precursor processing is then soaked in
In liquid, 100 DEG C of water use soaked in absolute ethyl alcohol 12min after boiling processing 40min after immersion 18h after sonic oscillation processing, use deionization
Water, which is rinsed, to be felt after 60 DEG C of dryings.
Described wool fiber and the consumption bath raio of lithium-bromide solution are 1:70.
Sonic oscillation frequency is that 40KHz, power are 300W, and sonication treatment time is 15min, two when lithium-bromide solution soaks
Sonication treatment time is 30min when titania precursor body treatment fluid soaks.
Described TiO 2 precursor treatment fluid is butyl titanate and absolute ethyl alcohol by volume 1:20 mixed liquor.
Only it is the preferred embodiment of the present invention described in upper, it is noted that for those skilled in the art
For, under the premise without departing from the principles of the invention, some improvement can also be made, these improvement also should be regarded as the guarantor of the present invention
Protect scope.
Claims (10)
1. a kind of titania modified water-proof wool fiber, it is characterised in that：Including wool fiber body, described wool fiber
Body is that different in nature wool fiber, titania modified wool fiber and stainless steel fibre juxtaposed beaming are formed, and in two-sided hollow
Bamboo fibre is filled with structure, hollow structure inner chamber, and bamboo fibre is wrapped with cotton gauze, described bamboo fibre and contains waterproof
Agent.
2. a kind of titania modified water-proof wool fiber according to claim 1, it is characterised in that：Different in nature wool fiber
Cross section is in polygonized structure, preferably regular hexagon structure.
3. a kind of titania modified water-proof wool fiber according to claim 1, it is characterised in that：Different in nature wool fiber
Cross section is in cross-shaped configuration.
4. a kind of titania modified water-proof wool fiber according to claim 1, it is characterised in that：Different in nature wool fiber
Cross section is in trilobal or bunge bedstraw herb shape.
5. a kind of titania modified water-proof wool fiber according to claim 1, it is characterised in that：The stainless steel is fine
Tie up a diameter of 20-25 μm.
6. a kind of titania modified water-proof wool fiber according to claim 1, it is characterised in that：The waterproofing agent is
ADM-666 watery water-proofing agents.
7. a kind of titania modified water-proof wool fiber according to claim 1, it is characterised in that：It is titania modified
Wool fiber its preparation method is as follows：Wool fiber is immersed in the lithium-bromide solution that mass concentration is 50-150g/L, in
75-85 DEG C of immersion 3-5h, and sonic oscillation aid in treatment is used, processing completes to extract moisture after taking out, and must be swelled wool fiber；
Wool fiber will be swelled and be put into absolute ethyl alcohol and soak 30-50min, be then soaked in TiO 2 precursor treatment fluid, surpassed
100 DEG C of water use soaked in absolute ethyl alcohol 8-16min after boiling processing 30-50min after immersion 12-24h after sound oscillation processing, use deionization
Water, which is rinsed, to be felt after 50-70 DEG C of drying.
8. a kind of titania modified water-proof wool fiber according to claim 7, it is characterised in that：Described wool is fine
The consumption bath raio of peacekeeping lithium-bromide solution is 1:60-80.
9. a kind of titania modified water-proof wool fiber according to claim 7, it is characterised in that：Sonic oscillation frequency
It is 300W for 40KHz, power, sonication treatment time is 10-20min, TiO 2 precursor processing when lithium-bromide solution soaks
Sonication treatment time is 20-40min when immersion is steeped.
10. a kind of titania modified water-proof wool fiber according to claim 7, it is characterised in that：Described dioxy
It is butyl titanate and absolute ethyl alcohol by volume 1 to change titanium precursors treatment fluids:15~25 mixed liquor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710616532.1A CN107217469A (en) | 2017-07-26 | 2017-07-26 | A kind of titania modified water-proof wool fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710616532.1A CN107217469A (en) | 2017-07-26 | 2017-07-26 | A kind of titania modified water-proof wool fiber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107217469A true CN107217469A (en) | 2017-09-29 |
Family
ID=59955051
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710616532.1A Pending CN107217469A (en) | 2017-07-26 | 2017-07-26 | A kind of titania modified water-proof wool fiber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107217469A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109137475A (en) * | 2018-08-09 | 2019-01-04 | 合肥五凡工程设计有限公司 | A kind of preparation process of waterproof and dampproof wool fiber |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105506957A (en) * | 2016-01-27 | 2016-04-20 | 西安工程大学 | Preparation method of titanium dioxide modified wool fiber |
| CN106335240A (en) * | 2016-08-23 | 2017-01-18 | 江苏协盛化纤有限公司 | Shrinkproof super soft fabric prepared from special-shaped wool fiber |
| CN106498601A (en) * | 2015-09-06 | 2017-03-15 | 江苏阳光股份有限公司 | The production technology of the radioprotective worsted fabric containing stainless steel fibre |
-
2017
- 2017-07-26 CN CN201710616532.1A patent/CN107217469A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106498601A (en) * | 2015-09-06 | 2017-03-15 | 江苏阳光股份有限公司 | The production technology of the radioprotective worsted fabric containing stainless steel fibre |
| CN105506957A (en) * | 2016-01-27 | 2016-04-20 | 西安工程大学 | Preparation method of titanium dioxide modified wool fiber |
| CN106335240A (en) * | 2016-08-23 | 2017-01-18 | 江苏协盛化纤有限公司 | Shrinkproof super soft fabric prepared from special-shaped wool fiber |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109137475A (en) * | 2018-08-09 | 2019-01-04 | 合肥五凡工程设计有限公司 | A kind of preparation process of waterproof and dampproof wool fiber |
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Application publication date: 20170929 |