CN106222880B - The processing method that waterproof refuses dirty type silk needle-punched cotton mattress - Google Patents

The processing method that waterproof refuses dirty type silk needle-punched cotton mattress Download PDF

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Publication number
CN106222880B
CN106222880B CN201610594087.9A CN201610594087A CN106222880B CN 106222880 B CN106222880 B CN 106222880B CN 201610594087 A CN201610594087 A CN 201610594087A CN 106222880 B CN106222880 B CN 106222880B
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Prior art keywords
silk
raw material
hydrophilic
solid glue
water repellent
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CN201610594087.9A
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CN106222880A (en
Inventor
席敏皓
杨佩
左臣伟
张淑芬
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Sichuan Sima Silk Technology Co.,Ltd.
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Chongqing Sima Silk Technology Co Ltd
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266Natural fibres not provided for in group D04H1/425
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01CCHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
    • D01C3/00Treatment of animal material, e.g. chemical scouring of wool
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G2009/001Anti-allergen; Anti-mite

Abstract

The invention discloses the processing methods that a kind of waterproof refuses dirty type silk needle-punched cotton mattress, include the following steps: step (1), removal of impurities solid glue, silk raw material is subjected to screening and removing impurities, solid glue processing then is carried out to silk raw material, guarantees the content and stability of fibroin;Step (2), bleaching: it after the silk raw material removal surface moisture after solid glue, puts into liquid lime chloride and is bleached, then clean, dry;It is step (3), hydrophilic --- water repellent finish: hydrophilic treated will be carried out in the silk raw material investment cationic hydrophilic agent solution after step (2) drying, put into progress water repellent processing in water repellent solution again after the silk raw material removal surface moisture by hydrophilic treated;Silk raw material combing Jing Guo hydrophilic-water repellent finish is beaten short at short-fibre silk by step (4), and product then is made by needling process.It is unique hydrophilic to assign silk --- waterproofing function prevents various spots from also assuring the original air-moisture-permeable ability of silk mattress while invasion.

Description

The processing method that waterproof refuses dirty type silk needle-punched cotton mattress
Technical field
The present invention relates to the processing methods that a kind of waterproof refuses dirty type silk needle-punched cotton mattress, belong to silk processing technology neck Domain.
Background technique
Silk is a kind of natural protein fibre.It is mainly made of fibroin albumen and sericin, wherein silk gum accounts for 10%~40% etc..18 kinds of amino acid contained in fibroin have health care, trophism to human body.In fact, silk Albumen and human skin keratin are very much like, and often contacting with fibroin can obviously improve skin, therefore silk Often it is made into non-woven fabrics for beauty product and various bedding etc..
Silk has its unrivaled advantage as mattress: moisture absorption is ventilative, antibiosis anti-acarien, but has one among these and ask It is difficult to clean up after topic, i.e. mattress contamination dirt.The cleaning procedure of mattress is troublesome, needs to place and be exposed to the sun in the sun, it is also necessary to The cleaning agent of profession removes mildew, colored drink, sweat stain, urine stain etc., and having many families can also ask the drycleaner's of profession to handle, This brings many inconvenience to our life.
Summary of the invention
Based on the deficiencies of the prior art, the technical problem to be solved in the present invention is to provide a kind of waterproofs to refuse dirty type silk needle-punched It is unique hydrophilic to assign silk for the processing method of cotton mattress --- and waterproofing function prevents various spots from also guaranteeing while invasion Silk mattress original air-moisture-permeable ability.
To achieve the goals above, the technical solution of the present invention is as follows: a kind of waterproof refuses adding for dirty type silk needle-punched cotton mattress Work method, characterized by the following steps:
Step (1), removal of impurities solid glue, carry out screening and removing impurities for silk raw material, then carry out solid glue processing to silk raw material, protect Demonstrate,prove the content and stability of fibroin;
Step (2), bleaching: it after the silk raw material removal surface moisture after solid glue, puts into liquid lime chloride and is bleached, so It cleans, dry afterwards;
It is step (3), hydrophilic --- water repellent finish: the silk raw material investment cationic hydrophilic agent after step (2) drying is molten Hydrophilic treated is carried out in liquid, puts into water repellent solution used for textiles again after the silk raw material removal surface moisture by hydrophilic treated Middle progress water repellent processing;
Step (4), by Jing Guo hydrophilic-water repellent finish silk raw material combing beat it is short at short-fibre silk, then pass through needle thorn Product is made in technique.
Above scheme, the present invention are handled by solid glue agent solid glue, guarantee the content and stability of fibroin, to guarantee The health and beauty of made mattress.First to silk carry out hydrophilic finiss, hydrophilic agent assign silk sucting wet air permeability, then into Row water repellent finish forms the cored structure of interior hydrophilic outer water repellent, so that reaching hydrone cannot pass through, and air can freely lead to The purpose crossed prevents various spots from also assuring the original air-moisture-permeable ability of silk mattress while invasion.Especially silk For fiber after cationic hydrophilic agent processing, can allow has certain repulsion between fiber, external manifestation be it is fluffy, be not easy to collapse It falls into.
It is preferred: solid glue being carried out to silk raw material in step (1) and handles the solid glue agent used as tetra methylol phosphonium salt or first Aldehyde or modified glutaraldehyde in temperature are 20-50 in the solid glue agent solution for being 0.1%-5% by silk raw material investment mass concentration DEG C, solid glue processing is carried out under pH6-7.In solid glue processing, pH is adjusted using alkali compounds sodium carbonate or sodium bicarbonate.Described four Methylol microcosmic salt is tetramethylol chloride or tetrakis hydroxymetyl phosphonium sulfuric.Preferred: the time of solid glue processing is 1-24h.
In the above scheme, in step (3), liquid lime chloride is the hydrogen peroxide solution that mass concentration is 0.1%-5%, pH control System is in 8-12, bleaching time 0.5-24h.
In the above scheme: in step (3), cationic hydrophilic agent is glycidyl dimethyl dodecyl ammonium chlorides.It should Fatty amine long-chain (dodecyl) in surfactant assigns fiber excellent softness, and it is hydrophilic that glycidyl assigns fiber Property, hygroscopicity.Azelon is handled with it, so that it is more soft, smooth, and smaller to application on human skin irritation, it will not be to people Body and environmental pollution.It is soluble easily in water, when handling protein fibre it is not necessary that organic solvent, bleeding agent and diffusant is added, Easy to operate, energy consumption is lower, and production cost is greatly saved.
Preferred: in step (3), the mass concentration of cationic hydrophilic agent solution is 0.5%-1.5%.
In the above scheme, in step (3), the waterproofing agent is ZJ-FCB1428 type waterproofing agent or organic fluoride class macromolecule Condensate waterproofing agent.ZJ-FCB1428 type waterproofing agent is produced by Guangzhou Zhuan Jie Chemical Co., Ltd..Water-proofing treatment effect is good.
In the above scheme, the mass concentration of water repellent solution is 0.3-1%.
In the above scheme: step (4), by the silk combing Jing Guo hydrophilic-water repellent finish beat it is short at average length for 2~ Then 8 centimetres of short-fibre silk is pierced into cotton sheet through cotton carding, lapping, needle according to traditional needling process, is dried at 40-100 DEG C It is dry to obtain product.
The beneficial effects of the present invention are: silk is used to make mattress by the present invention, there is natural environmental-protective, flexible, breathable, resist Bacterium is anti-mite and other effects, does silk mattress with solid glue treated silk, it is ensured that the content and stability of albumen on mattress, Guarantee the beauty treatment health care efficacy of silk mattress.It is unique hydrophilic that the present invention assigns silk mattress --- and waterproofing function prevents various Spot also assures the original air-moisture-permeable ability of silk mattress while invasion.Become so that the daily maintenance of silk mattress is cleared up It must be easier.
Specific embodiment
The present invention will be further described combined with specific embodiments below:
Embodiment 1
The processing method that waterproof refuses dirty type silk needle-punched cotton mattress, is completed by following steps:
1. removal of impurities: carrying out screening and removing impurities to husks.
2. solid glue: husks is small for immersion 6 in 0.3% tetramethylol chloride and 0.1% sodium bicarbonate solution in concentration When, adjusting PH is 6, and surface moisture is deviate from after immersion, and dehydration can be deviate from using dewaterer, with naturally dry or can also be wrung out.
3. bleaching: 12 hours will be impregnated in the solution that dewatered husks puts into PH=10, hydrogen peroxide content is 3%, clearly It washes, dries.
4. hydrophilic --- water repellent finish: by husks in 0.5% glycidyl dimethyl dodecyl ammonium chlorides solution 1h is impregnated, then removes surface moisture, then be placed in 0.3% waterproofing agent ZJ-FCB1428 (production of Guangzhou Zhuan Jie Chemical Co., Ltd.) In solution, 30min is impregnated at 25 DEG C, is then baked at 100 DEG C.
5. combing: the short short-fibre silk for being 2cm at average length is beaten in husks combing;
6. nonwoven technical process: using needled conventionally Processes and apparatus, obtained through cotton carding, lapping, needle thorn at continuous sheet, drying Product;Drying temperature is 60 DEG C.
Embodiment 2
The processing method that waterproof refuses dirty type silk needle-punched cotton mattress, is completed by following steps:
1. removal of impurities: carrying out screening and removing impurities to silk machine cotton.
2. solid glue: in concentration being to impregnate 12 in 0.5% tetrakis hydroxymetyl phosphonium sulfuric and 0.6% sodium carbonate liquor by silk machine cotton Hour.PH=7 is adjusted, deviates from surface moisture after immersion.
3. bleaching: it will be impregnated 8 hours in dewatered silk machine cotton investment PH=9, the solution that hydrogen peroxide content is 2%, Cleaning, drying;
4. hydrophilic --- water repellent finish: by husks in 1.5% glycidyl dimethyl dodecyl ammonium chlorides solution 0.5h is impregnated, is placed in 0.5% waterproofing agent ZJ-FCB1428 solution after taking out removal surface moisture, is impregnated at 25 DEG C again Then 20min is baked at 100 DEG C.
5. combing: the short short-fibre silk for being 3cm at average length is beaten in the combing of silk machine cotton;
6. nonwoven technical process: using needled conventionally Processes and apparatus, obtained through cotton carding, lapping, needle thorn at continuous sheet, drying Product;Drying temperature is 80 DEG C.
Embodiment 3
The processing method that waterproof refuses dirty type silk needle-punched cotton mattress, is completed by following steps:
1. removal of impurities: carrying out screening and removing impurities to husks.
2. solid glue: in concentration being to be impregnated 0.5 hour in 5% formaldehyde and 0.1% sodium bicarbonate solution by husks, adjust in the process Saving PH is 6, and surface moisture is deviate from after immersion, and dehydration can be deviate from using dewaterer, with naturally dry or can also be wrung out.
3. bleaching: 0.5 hour will be impregnated in the solution that dewatered husks puts into PH=12, hydrogen peroxide content is 5%, clearly It washes, dries.
4. hydrophilic --- water repellent finish: by husks in 1.5% glycidyl dimethyl dodecyl ammonium chlorides solution 1h is impregnated, then removes surface moisture, then be placed in 1% organic fluoride class high molecular polymer (fluorine-containing water repellent FUNCTEX (Fick This) F-659) in water repellent solution, 30min is impregnated at 25 DEG C, is then baked at 100 DEG C.
5. combing: the short short-fibre silk for being 5cm at average length is beaten in husks combing;
6. nonwoven technical process: using needled conventionally Processes and apparatus, obtained through cotton carding, lapping, needle thorn at continuous sheet, drying Product;Drying temperature is 60 DEG C.
Embodiment 4
The processing method that waterproof refuses dirty type silk needle-punched cotton mattress, is completed by following steps:
1. removal of impurities: carrying out screening and removing impurities to silk machine cotton.
2. solid glue: silk machine cotton is small for immersion 0.5 in 0.1% modified glutaraldehyde and 0.5% sodium carbonate liquor in concentration When.PH=7 is adjusted, deviates from surface moisture after immersion.
3. bleaching: it is small to impregnate 24 in 0.1% solution that dewatered silk machine cotton being put into PH=8, hydrogen peroxide content When, it cleans, drying;
4. hydrophilic --- water repellent finish: by husks in 1.0% glycidyl dimethyl dodecyl ammonium chlorides solution 0.5h is impregnated, is placed in 0.5% waterproofing agent ZJ-FCB1428 solution after taking out removal surface moisture, is impregnated at 25 DEG C again Then 20min is baked at 100 DEG C.
5. combing: the short short-fibre silk for being 8cm at average length is beaten in the combing of silk machine cotton;
6. nonwoven technical process: using needled conventionally Processes and apparatus, obtained through cotton carding, lapping, needle thorn at continuous sheet, drying Product;Drying temperature is 80 DEG C.
The present invention is not limited to the above embodiment, it should be understood that those skilled in the art are not necessarily to creative work It according to the present invention can conceive and make many modifications and variations.All technician in the art are under this invention's idea On the basis of existing technology by the available technical solution of logical analysis, reasoning, or a limited experiment, all should by In protection scope determined by claims.

Claims (9)

1. the processing method that a kind of waterproof refuses dirty type silk needle-punched cotton mattress, characterized by the following steps:
Step (1), removal of impurities solid glue, carry out screening and removing impurities for silk raw material, then carry out solid glue processing to silk raw material, guarantee silkworm The content and stability of silk-fibroin;
Step (2), bleaching: it after the silk raw material removal surface moisture after solid glue, puts into liquid lime chloride and is bleached, then clearly It washes, dry;
It is step (3), hydrophilic --- water repellent finish: will be in the silk raw material investment cationic hydrophilic agent solution after step (2) drying Carry out hydrophilic treated, by hydrophilic treated silk raw material removal surface moisture after put into again in water repellent solution used for textiles into The processing of row water repellent;The waterproofing agent is ZJ-FCB1428 type waterproofing agent or organic fluoride class high molecular polymer waterproofing agent;
Silk raw material combing Jing Guo hydrophilic-water repellent finish is beaten short at short-fibre silk by step (4), then passes through needling process Product is made.
2. the processing method that waterproof refuses dirty type silk needle-punched cotton mattress according to claim 1, it is characterised in that: step (1) In the solid glue agent that uses of solid glue processing is carried out for tetra methylol phosphonium salt or formaldehyde or modified glutaraldehyde to silk raw material, silk is former It is 20-50 DEG C, carries out solid glue processing under pH6-7 in temperature in the solid glue agent solution that material investment mass concentration is 0.1%-5%.
3. the processing method that waterproof refuses dirty type silk needle-punched cotton mattress according to claim 2, it is characterised in that: solid glue processing In, pH is adjusted using alkali compounds sodium carbonate or sodium bicarbonate, the tetra methylol phosphonium salt is tetramethylol chloride or four Methylol sulfuric acid phosphorus.
4. the processing method that waterproof refuses dirty type silk needle-punched cotton mattress according to claim 3, it is characterised in that: solid glue processing Time be 1-24h.
5. the processing method that waterproof refuses dirty type silk needle-punched cotton mattress according to claim 2, it is characterised in that: step (2) In, liquid lime chloride is the hydrogen peroxide solution that mass concentration is 0.1%-5%, and pH is controlled in 8-12, bleaching time 0.5-24h.
6. the processing method that any one of -5 waterproofs refuse dirty type silk needle-punched cotton mattress according to claim 1, it is characterised in that: In step (3), cationic hydrophilic agent is glycidyl dimethyl dodecyl ammonium chlorides.
7. the processing method that waterproof refuses dirty type silk needle-punched cotton mattress according to claim 6, it is characterised in that: step (3) In, the mass concentration of cationic hydrophilic agent solution is 0.5%-1.5%.
8. the processing method that waterproof refuses dirty type silk needle-punched cotton mattress according to claim 7, it is characterised in that: step (3) In, the mass concentration of water repellent solution is 0.3-1%.
9. the processing method that waterproof refuses dirty type silk needle-punched cotton mattress according to claim 8, it is characterised in that: step (4), It at average length is 2~8 centimetres of short-fibre silk that silk raw material combing Jing Guo hydrophilic-water repellent finish, which is beaten short, then according to Needling process is through cotton carding, lapping, needle thorn at cotton sheet, and drying obtains product at 40-100 DEG C.
CN201610594087.9A 2016-07-26 2016-07-26 The processing method that waterproof refuses dirty type silk needle-punched cotton mattress Active CN106222880B (en)

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111335028B (en) * 2020-03-27 2022-09-27 席敏皓 Glue-fixing production method for steam filature
CN111411518B (en) * 2020-03-27 2022-09-09 席敏皓 Antibacterial and anti-virus silk fiber filtering base cloth and application thereof
CN113604889B (en) * 2021-07-06 2022-08-19 福建省永泰县安利席业有限公司 Intelligent weaving-based water-proof and dirt-resistant silk mattress processing equipment

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CN1410623A (en) * 2001-09-27 2003-04-16 中国科学院化学研究所 Treatment method of fabric possessing ultra biphilic/ultra biphobic composite functions at same time
CN2845585Y (en) * 2005-10-08 2006-12-13 曾令福 Mattress made from silkworm velvet
CN101130898A (en) * 2007-07-25 2008-02-27 席星航 Cocoon glue producing method

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CN102162195B (en) * 2011-01-28 2013-02-20 达利(中国)有限公司 Dyeing and finishing process of washable organza fabric
CN202653669U (en) * 2012-05-04 2013-01-09 曾令福 Multi-functional washable health-care silk mattress
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CN1410623A (en) * 2001-09-27 2003-04-16 中国科学院化学研究所 Treatment method of fabric possessing ultra biphilic/ultra biphobic composite functions at same time
CN2845585Y (en) * 2005-10-08 2006-12-13 曾令福 Mattress made from silkworm velvet
CN101130898A (en) * 2007-07-25 2008-02-27 席星航 Cocoon glue producing method

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