The processing method that waterproof refuses dirty type silk needle-punched cotton mattress
Technical field
The present invention relates to the processing methods that a kind of waterproof refuses dirty type silk needle-punched cotton mattress, belong to silk processing technology neck
Domain.
Background technique
Silk is a kind of natural protein fibre.It is mainly made of fibroin albumen and sericin, wherein silk gum accounts for
10%~40% etc..18 kinds of amino acid contained in fibroin have health care, trophism to human body.In fact, silk
Albumen and human skin keratin are very much like, and often contacting with fibroin can obviously improve skin, therefore silk
Often it is made into non-woven fabrics for beauty product and various bedding etc..
Silk has its unrivaled advantage as mattress: moisture absorption is ventilative, antibiosis anti-acarien, but has one among these and ask
It is difficult to clean up after topic, i.e. mattress contamination dirt.The cleaning procedure of mattress is troublesome, needs to place and be exposed to the sun in the sun, it is also necessary to
The cleaning agent of profession removes mildew, colored drink, sweat stain, urine stain etc., and having many families can also ask the drycleaner's of profession to handle,
This brings many inconvenience to our life.
Summary of the invention
Based on the deficiencies of the prior art, the technical problem to be solved in the present invention is to provide a kind of waterproofs to refuse dirty type silk needle-punched
It is unique hydrophilic to assign silk for the processing method of cotton mattress --- and waterproofing function prevents various spots from also guaranteeing while invasion
Silk mattress original air-moisture-permeable ability.
To achieve the goals above, the technical solution of the present invention is as follows: a kind of waterproof refuses adding for dirty type silk needle-punched cotton mattress
Work method, characterized by the following steps:
Step (1), removal of impurities solid glue, carry out screening and removing impurities for silk raw material, then carry out solid glue processing to silk raw material, protect
Demonstrate,prove the content and stability of fibroin;
Step (2), bleaching: it after the silk raw material removal surface moisture after solid glue, puts into liquid lime chloride and is bleached, so
It cleans, dry afterwards;
It is step (3), hydrophilic --- water repellent finish: the silk raw material investment cationic hydrophilic agent after step (2) drying is molten
Hydrophilic treated is carried out in liquid, puts into water repellent solution used for textiles again after the silk raw material removal surface moisture by hydrophilic treated
Middle progress water repellent processing;
Step (4), by Jing Guo hydrophilic-water repellent finish silk raw material combing beat it is short at short-fibre silk, then pass through needle thorn
Product is made in technique.
Above scheme, the present invention are handled by solid glue agent solid glue, guarantee the content and stability of fibroin, to guarantee
The health and beauty of made mattress.First to silk carry out hydrophilic finiss, hydrophilic agent assign silk sucting wet air permeability, then into
Row water repellent finish forms the cored structure of interior hydrophilic outer water repellent, so that reaching hydrone cannot pass through, and air can freely lead to
The purpose crossed prevents various spots from also assuring the original air-moisture-permeable ability of silk mattress while invasion.Especially silk
For fiber after cationic hydrophilic agent processing, can allow has certain repulsion between fiber, external manifestation be it is fluffy, be not easy to collapse
It falls into.
It is preferred: solid glue being carried out to silk raw material in step (1) and handles the solid glue agent used as tetra methylol phosphonium salt or first
Aldehyde or modified glutaraldehyde in temperature are 20-50 in the solid glue agent solution for being 0.1%-5% by silk raw material investment mass concentration
DEG C, solid glue processing is carried out under pH6-7.In solid glue processing, pH is adjusted using alkali compounds sodium carbonate or sodium bicarbonate.Described four
Methylol microcosmic salt is tetramethylol chloride or tetrakis hydroxymetyl phosphonium sulfuric.Preferred: the time of solid glue processing is 1-24h.
In the above scheme, in step (3), liquid lime chloride is the hydrogen peroxide solution that mass concentration is 0.1%-5%, pH control
System is in 8-12, bleaching time 0.5-24h.
In the above scheme: in step (3), cationic hydrophilic agent is glycidyl dimethyl dodecyl ammonium chlorides.It should
Fatty amine long-chain (dodecyl) in surfactant assigns fiber excellent softness, and it is hydrophilic that glycidyl assigns fiber
Property, hygroscopicity.Azelon is handled with it, so that it is more soft, smooth, and smaller to application on human skin irritation, it will not be to people
Body and environmental pollution.It is soluble easily in water, when handling protein fibre it is not necessary that organic solvent, bleeding agent and diffusant is added,
Easy to operate, energy consumption is lower, and production cost is greatly saved.
Preferred: in step (3), the mass concentration of cationic hydrophilic agent solution is 0.5%-1.5%.
In the above scheme, in step (3), the waterproofing agent is ZJ-FCB1428 type waterproofing agent or organic fluoride class macromolecule
Condensate waterproofing agent.ZJ-FCB1428 type waterproofing agent is produced by Guangzhou Zhuan Jie Chemical Co., Ltd..Water-proofing treatment effect is good.
In the above scheme, the mass concentration of water repellent solution is 0.3-1%.
In the above scheme: step (4), by the silk combing Jing Guo hydrophilic-water repellent finish beat it is short at average length for 2~
Then 8 centimetres of short-fibre silk is pierced into cotton sheet through cotton carding, lapping, needle according to traditional needling process, is dried at 40-100 DEG C
It is dry to obtain product.
The beneficial effects of the present invention are: silk is used to make mattress by the present invention, there is natural environmental-protective, flexible, breathable, resist
Bacterium is anti-mite and other effects, does silk mattress with solid glue treated silk, it is ensured that the content and stability of albumen on mattress,
Guarantee the beauty treatment health care efficacy of silk mattress.It is unique hydrophilic that the present invention assigns silk mattress --- and waterproofing function prevents various
Spot also assures the original air-moisture-permeable ability of silk mattress while invasion.Become so that the daily maintenance of silk mattress is cleared up
It must be easier.
Specific embodiment
The present invention will be further described combined with specific embodiments below:
Embodiment 1
The processing method that waterproof refuses dirty type silk needle-punched cotton mattress, is completed by following steps:
1. removal of impurities: carrying out screening and removing impurities to husks.
2. solid glue: husks is small for immersion 6 in 0.3% tetramethylol chloride and 0.1% sodium bicarbonate solution in concentration
When, adjusting PH is 6, and surface moisture is deviate from after immersion, and dehydration can be deviate from using dewaterer, with naturally dry or can also be wrung out.
3. bleaching: 12 hours will be impregnated in the solution that dewatered husks puts into PH=10, hydrogen peroxide content is 3%, clearly
It washes, dries.
4. hydrophilic --- water repellent finish: by husks in 0.5% glycidyl dimethyl dodecyl ammonium chlorides solution
1h is impregnated, then removes surface moisture, then be placed in 0.3% waterproofing agent ZJ-FCB1428 (production of Guangzhou Zhuan Jie Chemical Co., Ltd.)
In solution, 30min is impregnated at 25 DEG C, is then baked at 100 DEG C.
5. combing: the short short-fibre silk for being 2cm at average length is beaten in husks combing;
6. nonwoven technical process: using needled conventionally Processes and apparatus, obtained through cotton carding, lapping, needle thorn at continuous sheet, drying
Product;Drying temperature is 60 DEG C.
Embodiment 2
The processing method that waterproof refuses dirty type silk needle-punched cotton mattress, is completed by following steps:
1. removal of impurities: carrying out screening and removing impurities to silk machine cotton.
2. solid glue: in concentration being to impregnate 12 in 0.5% tetrakis hydroxymetyl phosphonium sulfuric and 0.6% sodium carbonate liquor by silk machine cotton
Hour.PH=7 is adjusted, deviates from surface moisture after immersion.
3. bleaching: it will be impregnated 8 hours in dewatered silk machine cotton investment PH=9, the solution that hydrogen peroxide content is 2%,
Cleaning, drying;
4. hydrophilic --- water repellent finish: by husks in 1.5% glycidyl dimethyl dodecyl ammonium chlorides solution
0.5h is impregnated, is placed in 0.5% waterproofing agent ZJ-FCB1428 solution after taking out removal surface moisture, is impregnated at 25 DEG C again
Then 20min is baked at 100 DEG C.
5. combing: the short short-fibre silk for being 3cm at average length is beaten in the combing of silk machine cotton;
6. nonwoven technical process: using needled conventionally Processes and apparatus, obtained through cotton carding, lapping, needle thorn at continuous sheet, drying
Product;Drying temperature is 80 DEG C.
Embodiment 3
The processing method that waterproof refuses dirty type silk needle-punched cotton mattress, is completed by following steps:
1. removal of impurities: carrying out screening and removing impurities to husks.
2. solid glue: in concentration being to be impregnated 0.5 hour in 5% formaldehyde and 0.1% sodium bicarbonate solution by husks, adjust in the process
Saving PH is 6, and surface moisture is deviate from after immersion, and dehydration can be deviate from using dewaterer, with naturally dry or can also be wrung out.
3. bleaching: 0.5 hour will be impregnated in the solution that dewatered husks puts into PH=12, hydrogen peroxide content is 5%, clearly
It washes, dries.
4. hydrophilic --- water repellent finish: by husks in 1.5% glycidyl dimethyl dodecyl ammonium chlorides solution
1h is impregnated, then removes surface moisture, then be placed in 1% organic fluoride class high molecular polymer (fluorine-containing water repellent FUNCTEX (Fick
This) F-659) in water repellent solution, 30min is impregnated at 25 DEG C, is then baked at 100 DEG C.
5. combing: the short short-fibre silk for being 5cm at average length is beaten in husks combing;
6. nonwoven technical process: using needled conventionally Processes and apparatus, obtained through cotton carding, lapping, needle thorn at continuous sheet, drying
Product;Drying temperature is 60 DEG C.
Embodiment 4
The processing method that waterproof refuses dirty type silk needle-punched cotton mattress, is completed by following steps:
1. removal of impurities: carrying out screening and removing impurities to silk machine cotton.
2. solid glue: silk machine cotton is small for immersion 0.5 in 0.1% modified glutaraldehyde and 0.5% sodium carbonate liquor in concentration
When.PH=7 is adjusted, deviates from surface moisture after immersion.
3. bleaching: it is small to impregnate 24 in 0.1% solution that dewatered silk machine cotton being put into PH=8, hydrogen peroxide content
When, it cleans, drying;
4. hydrophilic --- water repellent finish: by husks in 1.0% glycidyl dimethyl dodecyl ammonium chlorides solution
0.5h is impregnated, is placed in 0.5% waterproofing agent ZJ-FCB1428 solution after taking out removal surface moisture, is impregnated at 25 DEG C again
Then 20min is baked at 100 DEG C.
5. combing: the short short-fibre silk for being 8cm at average length is beaten in the combing of silk machine cotton;
6. nonwoven technical process: using needled conventionally Processes and apparatus, obtained through cotton carding, lapping, needle thorn at continuous sheet, drying
Product;Drying temperature is 80 DEG C.
The present invention is not limited to the above embodiment, it should be understood that those skilled in the art are not necessarily to creative work
It according to the present invention can conceive and make many modifications and variations.All technician in the art are under this invention's idea
On the basis of existing technology by the available technical solution of logical analysis, reasoning, or a limited experiment, all should by
In protection scope determined by claims.