CN107217468A - A kind of wool anti-felting finishing technique - Google Patents

A kind of wool anti-felting finishing technique Download PDF

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Publication number
CN107217468A
CN107217468A CN201710519265.6A CN201710519265A CN107217468A CN 107217468 A CN107217468 A CN 107217468A CN 201710519265 A CN201710519265 A CN 201710519265A CN 107217468 A CN107217468 A CN 107217468A
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CN
China
Prior art keywords
wool
treatment
finishing technique
ferment treatment
fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710519265.6A
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Chinese (zh)
Inventor
王建
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Boao Textile Co ltd
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Nantong Boao Textile Co ltd
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Publication date
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Priority to CN201710519265.6A priority Critical patent/CN107217468A/en
Publication of CN107217468A publication Critical patent/CN107217468A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D06M10/025Corona discharge or low temperature plasma
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres
    • D06M2101/12Keratin fibres or silk
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/45Shrinking resistance, anti-felting properties

Abstract

The invention discloses a kind of wool anti-felting finishing technique, passed through pre-treatment, corona treatment and enzymatic treatment step, and completed wool anti-felting finishing technique, the advantage is that:Chitosan solution is used in pretreatment liquid of the present invention, using the viscosity of chitosan, the scale layer of wool and cortical layer is bonded, to the diffusion inside wool fiber, wool internal structure is protected so as to reduce enzyme during ferment treatment, reduces fibre damage;Low Temperature Plasma Treating is combined with albumen tissues and organs simultaneously, the felt proofing of wool fabric is effectively improved while reducing cost, and can retain the fabrics feel soft after the intrinsic strength of wool fabric, and processing;And neutral proteinase and neutral lipase are used during ferment treatment, damage of the reaction acid or alkali environment to wool is reduced, while having biocompatibility and environment friendly.

Description

A kind of wool anti-felting finishing technique
Technical field
The invention belongs to woolen finishing technique field, and in particular to a kind of wool anti-felting finishing technique.
Background technology
Wool fabric is a kind of natural fabric, with excellent performance, and wool is warming, comfortable depth is by consumers in general Like, but wool is due to the scale layer on its surface so that wool fabric has that felting property is big, and upper dye is irregular, and its scale Hydrophobic layer outside layer so that wool wetability is poor, hinders the adsorption and diffusion of dyestuff so that wool is occurred in that when dyeing The problem of being contaminated in difficulty, therefore have great importance to wool progress feld proofing.
At present, chlorinated resin method is used mostly in wool anti-felting finishing, can reach preferable anti-felting effect, but its chlorine Compound causes the organic chloride meeting of the residual do harm to huamn body in environmental pollution and wool, causes its application performance to be limited. Therefore green felt proofing method receives extensive concern, and simple Protease Treatment wool does not reach the mesh of preferable felt proofing 's.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to now provide a kind of environmental protection, wool simple to operate Feld proofing technique.
In order to solve the above technical problems, the technical solution adopted by the present invention is:A kind of wool anti-felting finishing technique, it is created New point is:By pre-treatment, Low Temperature Plasma Treating and enzymatic treatment step, wool anti-felting finishing technique is completed;It is described Comprise the following steps that:
(1)Pre-treatment:Wool fabric is immersed in pretreatment liquid, washed after taking-up, drying, standby, the pretreatment liquid is Chitosan aqueous solution, the chitosan aqueous solution concentration is 2-10g/L;
(2)Low Temperature Plasma Treating:Wool fabric after pre-treatment is subjected to Low Temperature Plasma Treating using corona discharge Cold water after hot water wash, reprocessing 5-10s is used to wash after 10-20s;
(3)Ferment treatment:Wool fabric after Low Temperature Plasma Treating is handled in ferment treatment liquid, then fabric is dried It is dry, complete wool anti-felting finishing technique.
Further, the step(1)Pretreatment liquid bath raio is 1:15-30, pretreatment liquid temperature is 50-70 DEG C, processing Time is 20-60min, and washing temperature is 25-30 DEG C, and washing times are 3-5min, and drying temperature is 60-80 DEG C, drying time For 5-10min.
Further, the step(2)Middle processing medium is air, and processing power is 100-300w, and hot water temperature is 60- 80 DEG C, the hot water wash time is 3-5min, and cold water temperature is 20-30 DEG C, and cold washing time is 5-10min.
Further, the step(3)Middle ferment treatment liquid, in parts by weight, its component are 0.1-0.5 parts of neutral protein Enzyme and 0.5-1 parts of neutral lipase, ferment treatment liquid pH are 7-8, and ferment treatment bath of liquid ratio is 1:20-30, ferment treatment liquid temperature degree is 40-70 DEG C, enzyme processing time is 30-60min, and drying temperature is 60-80 DEG C, and drying time is 5-10min.
Beneficial effects of the present invention are as follows:
(1)Pretreatment liquid of the present invention uses chitosan solution, and using the viscosity of chitosan, the scale layer and cortical layer of wool are glued Knot gets up, and, to the diffusion inside wool fiber, protects wool internal structure so as to reduce enzyme during ferment treatment, reduces Fibre damage;
(2)The present invention is combined with Low Temperature Plasma Treating with albumen tissues and organs, and wool is effectively improved while reducing cost The felt proofing of fabric, and the fabrics feel soft after the intrinsic strength of wool fabric, and processing can be retained;
(3)The present invention uses neutral proteinase and neutral lipase during ferment treatment, reduces reaction acid or alkali environment to sheep The damage of hair, while having biocompatibility and environment friendly.
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation Content disclosed by book understands other advantages and effect of the present invention easily.
Embodiment 1
A kind of wool anti-felting finishing technique, by pre-treatment, Low Temperature Plasma Treating and enzymatic treatment step, completes wool and prevents Felting finishing technique;Comprise the following steps that:
(1)Pre-treatment:Wool fabric is immersed in 2g/L chitosan solutions, bath raio is 1:Take out, use after 15, processing 20min 25 DEG C of washing 3min, then dry 5min at a temperature of 60 DEG C, standby;
(2)Low Temperature Plasma Treating:Wool fabric after pre-treatment is subjected to Low Temperature Plasma Treating using corona discharge 10s, then with 60 DEG C of hot water wash 3min, washes 3min, processing medium is air, processing power with 20 DEG C of cold water after reprocessing 5-s For 100w;
(3)Ferment treatment:In parts by weight, the ferment treatment liquid containing 0.1 part of neutral proteinase and 0.5 part of neutral lipase, enzyme are prepared Treatment fluid pH is 7, and ferment treatment bath of liquid ratio is 1:20, ferment treatment liquid temperature degree is 40 DEG C, by the wool after Low Temperature Plasma Treating Fabric carries out processing 30min in ferment treatment liquid, and fabric is then dried into 5min at a temperature of 60 DEG C, completes preventing felting and shrinking of wood fabric whole Science and engineering skill.
Embodiment 2
A kind of wool anti-felting finishing technique, by pre-treatment, Low Temperature Plasma Treating and enzymatic treatment step, completes wool and prevents Felting finishing technique;Comprise the following steps that:
(1)Pre-treatment:Wool fabric is immersed in 10g/L chitosan solutions, bath raio is 1:Take out, use after 30, processing 60min 30 DEG C of washing 5min, then dry 10min at a temperature of 80 DEG C, standby;
(2)Low Temperature Plasma Treating:Wool fabric after pre-treatment is subjected to Low Temperature Plasma Treating using corona discharge 20s, then with 80 DEG C of hot water wash 5min, washes 5min, processing medium is air, processing power with 30 DEG C of cold water after reprocessing 10s For 300w;
(3)Ferment treatment:In parts by weight, prepare at the ferment treatment liquid containing 0.5 part of neutral proteinase and 1 part of neutral lipase, enzyme It is 8 to manage liquid pH, and ferment treatment bath of liquid ratio is 30, and ferment treatment liquid temperature degree is 70 DEG C, by the wool fabric after Low Temperature Plasma Treating Processing 60min is carried out in ferment treatment liquid, fabric is then dried into 10min at a temperature of 80 DEG C, wool anti-felting finishing is completed Technique.
Embodiment 3
A kind of wool anti-felting finishing technique, by pre-treatment, Low Temperature Plasma Treating and enzymatic treatment step, completes wool and prevents Felting finishing technique;Comprise the following steps that:
(1)Pre-treatment:Wool fabric is immersed in 6g/L chitosan solutions, bath raio is 1:Take out, use after 20, processing 40min 27 DEG C of washing 4min, then dry 7min at a temperature of 70 DEG C, standby;
(2)Low Temperature Plasma Treating:Wool fabric after pre-treatment is subjected to Low Temperature Plasma Treating using corona discharge 15s, then with 70 DEG C of hot water wash 4min, washes 4min, processing medium is air, and processing power is with 25 DEG C of cold water after reprocessing 8s 200w;
(3)Ferment treatment:In parts by weight, the ferment treatment liquid containing 0.3 part of neutral proteinase and 0.7 part of neutral lipase, enzyme are prepared Treatment fluid pH is 7.5, and ferment treatment bath of liquid ratio is 1:25, ferment treatment liquid temperature degree is 60 DEG C, by the sheep after Low Temperature Plasma Treating Wool fabric carries out processing 45min in ferment treatment liquid, and fabric is then dried into 7min at a temperature of 70 DEG C, completes preventing felting and shrinking of wood fabric Finishing technique.
Pretreatment liquid of the present invention uses chitosan solution, using the viscosity of chitosan, by the scale layer and cortical layer of wool Bond, so that reducing enzyme during ferment treatment, to the diffusion inside wool fiber, protects wool internal structure, reduction Fibre damage;Low Temperature Plasma Treating is combined with albumen tissues and organs simultaneously, and wool is effectively improved while reducing cost The felt proofing of fabric, and the fabrics feel soft after the intrinsic strength of wool fabric, and processing can be retained;And in ferment treatment During use neutral proteinase and neutral lipase, damage of the reaction acid or alkali environment to wool is reduced, while having biology Compatibility and environment friendly.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as The technical scheme that can be realized without creative work on the basis of above-described embodiment, is regarded as falling into patent of the present invention Rights protection scope in.

Claims (4)

1. a kind of wool anti-felting finishing technique, it is characterised in that:Walked by pre-treatment, Low Temperature Plasma Treating and ferment treatment Suddenly, wool anti-felting finishing technique is completed;It is described to comprise the following steps that:
Pre-treatment:Wool fabric is immersed in pretreatment liquid, washed after taking-up, drying is standby, and the pretreatment liquid is poly- for shell Sugar aqueous solution, the chitosan aqueous solution concentration is 2-10g/L;
Low Temperature Plasma Treating:Wool fabric after pre-treatment is subjected to Low Temperature Plasma Treating 10- using corona discharge Cold water after hot water wash, reprocessing 5-10s is used to wash after 20s;
Ferment treatment:Wool fabric after Low Temperature Plasma Treating is handled in ferment treatment liquid, then by fabric drying, Complete wool anti-felting finishing technique.
2. a kind of wool anti-felting finishing technique according to claim, it is characterised in that:The step(1)Middle pre-treatment Bath of liquid ratio is 1:15-30, pretreatment liquid temperature is 50-70 DEG C, and processing time is 20-60min, and washing temperature is 25-30 DEG C, water Number of times is washed for 3-5min, drying temperature is 60-80 DEG C, and drying time is 5-10min.
3. a kind of wool anti-felting finishing technique according to claim 1, it is characterised in that:The step(2)Middle processing Medium is air, and processing power is 100-300w, and hot water temperature is 60-80 DEG C, and the hot water wash time is 3-5min, and cold water temperature is 20-30 DEG C, cold washing time is 5-10min.
4. a kind of wool anti-felting finishing technique according to claim 1, it is characterised in that:The step(3)At middle enzyme Liquid is managed, in parts by weight, its component is 0.1-0.5 parts of neutral proteinase and 0.5-1 parts of neutral lipase, ferment treatment liquid pH For 7-8, ferment treatment bath of liquid ratio is 1:20-30, ferment treatment liquid temperature degree is 40-70 DEG C, and enzyme processing time is 30-60min, drying temperature Spend for 60-80 DEG C, the drying time is 5-10min.
CN201710519265.6A 2017-06-30 2017-06-30 A kind of wool anti-felting finishing technique Pending CN107217468A (en)

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Application Number Priority Date Filing Date Title
CN201710519265.6A CN107217468A (en) 2017-06-30 2017-06-30 A kind of wool anti-felting finishing technique

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108149417A (en) * 2018-02-23 2018-06-12 上海嘉芮实业有限公司 The manufacture craft and its product of a kind of fulling milling method of woolen knitting ready-made clothes and the strong fulling milling knitted fabric of the wool including this method
CN109736093A (en) * 2018-11-22 2019-05-10 江阴兴吴呢绒科技有限公司 A kind of felt-proofing finishing method of machine washable wool fabric
CN111962312A (en) * 2020-08-31 2020-11-20 上海小蓝象服装有限公司 Preparation method of super-soft and smooth sweat-removing warm wool pajamas/underwear fabric without pricking

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1693575A (en) * 2005-05-18 2005-11-09 陕西省科学院酶工程研究所 Finishing method for preventing felting and shrinking of wood fabric
CN101177915A (en) * 2007-11-30 2008-05-14 东华大学 Plasma and enzyme combined anti-felting method for tidying wool knitted fabric
CN103485159A (en) * 2013-09-11 2014-01-01 昆山市万丰制衣有限责任公司 Anti-felting wool finishing process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1693575A (en) * 2005-05-18 2005-11-09 陕西省科学院酶工程研究所 Finishing method for preventing felting and shrinking of wood fabric
CN101177915A (en) * 2007-11-30 2008-05-14 东华大学 Plasma and enzyme combined anti-felting method for tidying wool knitted fabric
CN103485159A (en) * 2013-09-11 2014-01-01 昆山市万丰制衣有限责任公司 Anti-felting wool finishing process

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108149417A (en) * 2018-02-23 2018-06-12 上海嘉芮实业有限公司 The manufacture craft and its product of a kind of fulling milling method of woolen knitting ready-made clothes and the strong fulling milling knitted fabric of the wool including this method
CN109736093A (en) * 2018-11-22 2019-05-10 江阴兴吴呢绒科技有限公司 A kind of felt-proofing finishing method of machine washable wool fabric
CN111962312A (en) * 2020-08-31 2020-11-20 上海小蓝象服装有限公司 Preparation method of super-soft and smooth sweat-removing warm wool pajamas/underwear fabric without pricking

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Application publication date: 20170929