CN107216739A - A kind of water soluble acrylic acid paint added with titanium dioxide and preparation method thereof - Google Patents
A kind of water soluble acrylic acid paint added with titanium dioxide and preparation method thereof Download PDFInfo
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- CN107216739A CN107216739A CN201610160653.5A CN201610160653A CN107216739A CN 107216739 A CN107216739 A CN 107216739A CN 201610160653 A CN201610160653 A CN 201610160653A CN 107216739 A CN107216739 A CN 107216739A
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- acrylic acid
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
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Abstract
It is an object of the invention to provide a kind of high-weatherability, the water soluble acrylic acid paint added with titanium dioxide of energy heat-insulation and heat-preservation and preparation method thereof.The water soluble acrylic acid enamel-cover includes acrylic resin, dispersant, wetting agent, film forming agent, defoamer, filler and solvent;Film forming agent includes amino resins;Defoamer includes four heptanone of fluorination;Filler includes rutile type titanium white.Its preparation method comprises the following steps:S1, the progress of acrylic resin, dispersant, wetting agent, filler and solvent is pre-dispersed, obtain pre-dispersed system;S2, the pre-dispersed system milled processed that step S1 is obtained, in being wherein sequentially added into film forming agent, defoamer and solvent, stirs, produces.After the water soluble acrylic acid paint of the application is spread in painting, it can effectively reflect infrared ray, therefore at a temperature below the temperature of other materials, be cooled in the high solar term of temperature also without by cooling devices such as air-conditionings, and then reach the purpose of energy-conservation.
Description
Technical field
The present invention relates to paint field, more specifically, it relates to a kind of water soluble acrylic acid paint added with titanium dioxide and
Its preparation method.
Background technology
Coating, is commonly called as " painting ", be it is a kind of can be coated in body surface by different construction technologies, form adhesion jail
Gu, the continuous solid-state film substrate with some strength, object can be played protection, decoration and characteristic functions effect.Tradition
Coating can discharge a large amount of volatile organic matters (VOC) after use, cause air quality to be deteriorated, human body is in the short time
The VOC of the interior a large amount of high concentrations of suction can make lung tissue forever be damaged, and Long Term Contact more damages respiratory system, liver, kidney
The function such as dirty, triggers organ failure.When these traditional coating are used as being applied to the paint on wall, these coating need
It can just volatilize completely for a long time, this will influence the health of user.With the enhancing of environmental consciousness, countries in the world are all made in succession
The limit standard and regulation of volatile organic matter (VOC) discharge are ordered.
At present, in each kind of environmental protection paint, water soluble acrylic acid paint is with its green (low VOC emission), energy-conservation
The features such as, developed rapidly in countries in the world.Application publication number discloses for CN104745028A Chinese patent
A kind of water soluble acrylic acid paint and preparation method thereof, this water soluble acrylic acid enamel-cover includes 40~60 parts of acrylic resin, dispersant
3~6 parts, 1~2 part of wetting agent, 10~20 parts of film forming agent, 1~5 part of preservative, 0.5~1.5 part of defoamer, thickening
30~40 parts of 2~6 parts of agent, 10~25 parts of filler and water, and it is filler from titanium dioxide.In water soluble acrylic acid paint,
The main purpose for adding filler is the filling power and reduction production cost of increase paint;And titanium dioxide is as conventional filler, its
It is widely used with advantages such as preferable chemical stability and covering powers into water soluble acrylic acid paint.But send out in actual applications
It is existing, there are many photoactivation because titanium dioxide (principal component of titanium dioxide) itself is present on some lattice defects, its surface
Point, has slight absorption to visible ray ultraviolet light spectral coverage;In the presence of the catalyst such as ultraviolet light and water, titanium dioxide can
The continuous redox reaction of generation, generation hydroxyl and hydroperoxyl free radical;Hydroxyl and hydroperoxyl free radical have height
Activity, can aoxidize the organic polymer in coating, occur macromolecular chain chain rupture and degraded, destroy the continuity of coating,
Make coating weatherability (i.e. coating be exposed to outdoor weathering environments under, resistance daylight and air effect, it is to avoid occur discoloration,
Efflorescence, the ability of loss of gloss) reduction.This will cause this kind of water soluble acrylic acid paint can not meet the demand of some high standard industries.
Therefore, developing a kind of water soluble acrylic acid paint added with titanium dioxide that can improve weatherability has preferable application
Value.
The content of the invention
In view of the deficienciess of the prior art, it is an object of the invention to provide it is a kind of can improve weatherability be added with titanium
The water soluble acrylic acid paint of white powder, after the water soluble acrylic acid paint added with titanium dioxide of the application is spread in painting, it can effectively reflect
Infrared ray, therefore at a temperature below the temperature of other materials, also without cold by air-conditioning etc. in the high solar term of temperature
But equipment is cooled, and then reaches the purpose of energy-conservation..
To achieve the above object, the invention provides following technical scheme:
A kind of water soluble acrylic acid paint added with titanium dioxide, includes the component of following parts by weight:
10~30 parts of acrylic resin;
0.1~1 part of dispersant;
1~5 part of wetting agent;
2~10 parts of film forming agent;
0.1~1 part of defoamer;
20~100 parts of filler;
20~40 parts of solvent;
Wherein, the film forming agent includes 90~95wt% of amino resins;
The defoamer includes four 50~100wt% of heptanone of fluorination;
The filler includes 10~100wt% of rutile type titanium white.
Each component in this application is interpreted respectively as:
Dispersant, refers to a kind of chemicals, and it, which is added in solvent, increases the ability of its degranulation;
Wetting agent, referring to can make solid material be more easy to the material being soaked in water;
Film forming agent, the polymer of continuous film can be formed by referring to;
Defoamer, surface tension can be reduced by referring to, suppressed foam and produced or eliminate the additive for having produced foam;
Filler, refers to the material being filled in other objects.
Dispersant and wetting agent are mainly used in dispersion, make each component with or be swelled or the state that dissolves uniformly is divided
It is dispersed in emulsion, to improve the possibility being had an effect between each component;Film forming agent can be acted on acrylic resin, in propylene
The surface of acid resin forms one layer and sticked together firmly, with certain flexibility, extensibility and elasticity, wearability, water resistance etc.
Continuous uniform film, reduces water soluble acrylic acid paint and comes off, and preferable waterproof is played to it and is born dirty and other effects;Add in formula
Enter defoamer, it is possible to reduce or foam is further eliminated, make dispersion stable homogeneous and influence its scribble effect without bubbling,
Reduce the later stage and smear uneven situation;The crystal structure of rutile titanium dioxide (titanium dioxide) is stable and its crystal structure
Fine and close and refractive index is above anatase titanium dioxide, and it can play preferable covering, colour killing to water soluble acrylic acid paint, disperse
Deng effect.
Using above-mentioned technical proposal, whole system is entered by dispersant, wetting agent, rutile type titanium white and solvent
Row is scattered, amino resins and the quick continuous uniform film forming of acrylic resin energy, there will be the rutile type titanium white of lattice defect
In being wrapped in, the rutile type titanium white that there is lattice defect is set to isolate with external environment, the light for reducing the surface of titanium dioxide is lived
Change the possibility that point reacts with external environment;Four heptanone of fluorination are added in finely dispersed system, it can be in solvent and dispersant
In the presence of fill into the lattice of rutile type titanium white, reduce titanium dioxide surface photoactivation point;Meanwhile, fluorination
Four heptanone can be used for the influences of the factor to titanium dioxide such as the air carried in elimination bubble, reduction bubble;By combinations thereof,
The weatherability of water soluble acrylic acid paint can be improved.
Preferably, the dispersant is non-ionic polyalcohol.
Using above-mentioned technical proposal, non-ionic polyalcohol is not dissociated in aqueous, and it is to being fluorinated four heptanone only
There is physics peptizaiton, and because it has preferable acid-fast alkali-proof and keeps living in the system for carrying four heptanone of fluorination
Property.
Preferably, the wetting agent is aqueous moistening flatting agent.
Using above-mentioned technical proposal, aqueous moistening flatting agent can reduce the dynamic surface tension of coating system, without bright
It is aobvious to reduce static surface tension, therefore its recoatability influence on coating is smaller;Meanwhile, there is the work(of froth breaking and anti-shrinkage cavity in it
Can, it can further reduce the influences of the factor to titanium dioxide such as the air that is carried in bubble;In addition, it can form one with water
One stable solution system, can further improve effect of impregnation, improve the possibility of system effect in homogeneous.
Preferably, the film forming agent includes 5~10wt% of 90~95wt% of amino resins and drier.
Using above-mentioned technical proposal, amino resins and acrylic resin can quick continuous uniform film forming, except can obtaining property
The water soluble acrylic acid paint that can be improved, the rutile type titanium white that also can there will be lattice defect is isolated with external environment, reduces dioxy
Change the possibility that the photoactivation point on the surface of titanium reacts with external environment;Using drier, amino resins and acrylic acid tree can be accelerated
Reaction between fat, the machine that may be reacted between the photoactivation point and external environment that further reduce the surface of titanium dioxide
Meeting.
Preferably, the rutile type titanium white is through zirconium, aluminium inorganic surface treatment and organic surface treatment.
Using above-mentioned technical proposal, through the rutile type titanium white after zirconium, aluminium inorganic surface treatment and organic surface treatment
Compatibility with color spreading agent is strong, can improve its dispersiveness in dispersion, improves rutile type titanium white and continuous film forming
Amino resins and acrylic resin afterwards, the possibility for the effect being fluorinated between four heptanone, further reduce the table of titanium dioxide
The possibility that the photoactivation point in face and the photoactivation point on the surface of reduction titanium dioxide react with external environment.
Preferably, the filler includes rutile type titanium white and/or barium sulfate.
Using above-mentioned technical proposal, the combination of barium sulfate and rutile type titanium white in this application can basically reach proof gold
The filling effect of red stone-type titanium dioxide, and the presence of barium sulfate can reduce the consumption of rutile type titanium white accordingly, can enter one
Step reduces the possibility that the photoactivation point on the surface of rutile type titanium white reacts with external environment.
Preferably, the solvent includes 5~10wt% of 90~95wt% of water and ethanol.
Using above-mentioned technical proposal, water and ethanol are nontoxic, and the application water soluble acrylic acid paint in water and ethanol
In solubility much larger than its solubility in pure water or straight alcohol;The water soluble acrylic acid paint of the application is answered water and ethanol
With having preferable solubility in solution, it is uniformly dispersed.
Research finds that the granularity of the filler is 0.01~0.05 μm, and the ability that it improves weatherability is optimal.
Another object of the present invention is to provide a kind of preparation side of the described water soluble acrylic acid paint added with titanium dioxide
Method, it comprises the following steps:
S1, the solvent progress of the acrylic resin of formula ratio, dispersant, wetting agent, filler and part formulation amount is pre-dispersed,
Obtain pre-dispersed system;
S2, the pre-dispersed system milled processed that step S1 is obtained is matched somebody with somebody in being wherein sequentially added into film forming agent, defoamer and part
The solvent of side's amount, stirs;The solvent of remaining formula ratio is added, is stirred, is produced.
Preferably, the preparation method comprises the following steps:
S1, by 10~30 parts of acrylic resins, 0.1~1 part of dispersant, 1~5 part of wetting agent, 20~100 parts of fillers and 9~
Carried out under 400~600r/min of rotating speed pre-dispersed after the mixing of 19 parts of water, obtain pre-dispersed system;
S2, the pre-dispersed system milled processed that step S1 is obtained, in being wherein sequentially added into 2~10 parts of film forming agents, 0.1~1
Part defoamer and 2~5 parts of ethanol, stir;9~19 parts of water are added, stir equal under 400~600r/min of rotating speed
It is even, produce;
Wherein, the dispersant is non-ionic polyalcohol;The wetting agent is aqueous moistening flatting agent;The filler includes golden red
0~90wt% of 10~100wt% of stone-type titanium dioxide and barium sulfate, the granularity of the filler is 0.01~0.05 μm, and institute
Rutile type titanium white is stated through zirconium, aluminium inorganic surface treatment and organic surface treatment;The film forming agent include amino resins 90~
5~10wt% of 95wt% and drier;The defoamer includes four 50~100wt% of heptanone of fluorination.
Using above-mentioned technical proposal, first acrylic resin and filler are entered by dispersant, wetting agent and partial solvent
Row is pre-dispersed, it is obtained relatively uniform system;Then at wherein sequentially adding film forming agent, defoamer, partial solvent, into
Film effect full and uniform can be carried out, moreover it is possible to which reducing early stage is largely caused in course of reaction foam more using solvent and influence behaviour
The situation of work;The water soluble acrylic acid paint obtained by the preparation method has preferable technology stability, with preferable big work
Skill application prospect.
By using above-mentioned technical proposal, have the advantages that:
Whole system is disperseed by dispersant, wetting agent, rutile type titanium white and solvent, amino resins and acrylic acid tree
Fat can quick continuous uniform film forming, there will be lattice defect rutile type titanium white be wrapped in, make the presence of lattice defect
Rutile type titanium white is isolated with external environment, reduces the possibility that the photoactivation point on the surface of titanium dioxide reacts with external environment;
Four heptanone of fluorination are added in finely dispersed system, it can be filled in the presence of solvent and dispersant to rutile titanium dioxide
In the lattice of powder, the photoactivation point on the surface of titanium dioxide is reduced;Meanwhile, four heptanone of fluorination can be used for eliminating bubble, reduce
Influence of the factors such as the air carried in bubble to titanium dioxide;By combinations thereof, the weatherability of water soluble acrylic acid paint can be improved;
Study and find in weatherability contrast test, compared with control sample, the water soluble acrylic acid paint added with titanium dioxide of the application exists
Operate loss of gloss in formula A, B, C, D, discoloration, efflorescence, general gold, spot, contamination, cracking, foaming, mildew,
It is 0 grade or 1 grade to peel off and get rusty, and it has preferable weatherability;
Non-ionic polyalcohol is not dissociated in aqueous, and it only exists physical dispersion effect to four heptanone of fluorination, and because of its tool
There is preferable acid-fast alkali-proof and activity is kept in the system for carrying four heptanone of fluorination;Aqueous moistening flatting agent can have froth breaking
With the function of anti-shrinkage cavity, the influences of the factor to titanium dioxide such as the air that is carried in bubble can be further reduced, it can be formed with water
The solution system of one stable homogeneous, can further improve effect of impregnation, improve the possibility of system effect in homogeneous;Through
The compatibility of rutile type titanium white and color spreading agent after zirconium, aluminium inorganic surface treatment and organic surface treatment is strong, can improve it
Dispersiveness in dispersion, improves rutile type titanium white and the amino resins after continuous film forming and acrylic resin, fluorine
Change the possibility of the effect between four heptanone;The combination of barium sulfate and rutile type titanium white can basically reach pure in this application
The filling effect of rutile type titanium white, and the presence of barium sulfate can reduce the consumption of rutile type titanium white accordingly;This Shen
Water soluble acrylic acid paint please has preferable solubility in the combination solution of water and ethanol, and it is uniformly dispersed;Pass through above-mentioned skill
The photoactivation point on art scheme, the photoactivation point that can further reduce the surface of titanium dioxide and the surface for reducing titanium dioxide with it is outer
The possibility of environment reaction;Study and find in weatherability contrast test, compared with control sample, the application's is added with titanium white
The prioritization scheme (embodiment 1-5) of the water soluble acrylic acid paint of powder operation formula A, B, C, D in loss of gloss, discoloration,
Efflorescence, general gold, spot, contamination, cracking, foaming, mildew, peel off and get rusty be 0 grade of probability be up to 93% with
On, its weatherability is further enhanced;
Study and find in comprehensive contrast test, compared with control sample, in the water soluble acrylic acid paint added with titanium dioxide of the application
The material of addition is less, but its adhesive force, pencil hardness, impact strength, pliability, water resistance, acid resistance, alkaline-resisting
Property, VOC meet national standard;
After the water soluble acrylic acid paint added with titanium dioxide of the application is spread in painting, it can effectively reflect infrared ray, therefore its temperature is low
In the temperature of other materials, cooled in the high solar term of temperature also without by cooling devices such as air-conditionings, entered
And reach the purpose of energy-conservation.
Embodiment
Embodiment 1-5
A kind of water soluble acrylic acid paint added with titanium dioxide, its specific preparation method comprises the following steps:
S1, in rotating speed after the water of the acrylic resin of formula ratio, dispersant, wetting agent, filler and 50wt% formula ratios is mixed
Carry out pre-dispersed under 400~600r/min, obtain pre-dispersed system;
S2, the pre-dispersed system milled processed that step S1 is obtained, in the film forming agent, the defoamer that are wherein sequentially added into formula ratio
And ethanol, stir;The water of remaining formula ratio is added, stirs, produces under 400~600r/min of rotating speed.
Wherein, each component and its consumption of the embodiment 1-5 water soluble acrylic acid paint added with titanium dioxide be as shown in tables 1 to 5.
The formula of the water soluble acrylic acid paint added with titanium dioxide of the embodiment 1 of table 1
The formula of the water soluble acrylic acid paint added with titanium dioxide of the embodiment 2 of table 2
The formula of the water soluble acrylic acid paint added with titanium dioxide of the embodiment 3 of table 3
The formula of the water soluble acrylic acid paint added with titanium dioxide of the embodiment 4 of table 4
The formula of the water soluble acrylic acid paint added with titanium dioxide of the embodiment 5 of table 5
Embodiment 6-10
A kind of water soluble acrylic acid paint added with titanium dioxide, its specific preparation method comprises the following steps:
S1, in rotating speed after the water of the acrylic resin of formula ratio, dispersant, wetting agent, filler and 50wt% formula ratios is mixed
Carry out pre-dispersed under 400~600r/min, obtain pre-dispersed system;
S2, the pre-dispersed system milled processed that step S1 is obtained, in the film forming agent, the defoamer that are wherein sequentially added into formula ratio,
Addition ethanol that can be appropriate, stirs;The water of remaining formula ratio is added, is stirred under 400~600r/min of rotating speed,
Produce.
Wherein, each component and its consumption of the embodiment 6-8 water soluble acrylic acid paint added with titanium dioxide are as shown in table 6-8.
The formula of the water soluble acrylic acid paint added with titanium dioxide of the embodiment 6 of table 6
The formula of the water soluble acrylic acid paint added with titanium dioxide of the embodiment 7 of table 7
The formula of the water soluble acrylic acid paint added with titanium dioxide of the embodiment 8 of table 8
Comparative example
1. the preparation of control sample
Application reference publication No. prepares control sample 1-5 for the embodiment 1-5 of CN104745028A Chinese patent, its specific preparation
Method comprises the following steps:
(1) raw material of corresponding weight is weighed according to formula ratio, it is standby;
(2) at normal temperatures and pressures, by acrylic resin, dispersant, wetting agent, preservative, defoamer, filler and 50%
Water latting drown simultaneously stirs, and is then slowly added into above solution, stirs well 10-15 minutes, obtains in 400-600r/min speed
The control sample of the application;
Each component and its consumption in wherein control sample 1-5 formulas is as shown in table 9.
The each component and its consumption information of the control sample of table 9
2. weatherability contrast test
(1) subjects:Using control sample 1-5 as control, sample prepared by embodiment 1-8 is test sample.
(2) content of the test:Weatherability contrast test is carried out with reference to GB/T 1865-1997 and combines GB/T 1766-2008
Aging grading is carried out, its specific experimental condition is as shown in table 10.
The weatherability contrast test parameter of table 10
(3) result of the test:Result of the test is as shown in table 11-14, in weatherability contrast test, and embodiment 1-8 exists
Operate loss of gloss in formula A, B, C, D, discoloration, efflorescence, general gold, spot, contamination, cracking, foaming, mildew,
It is that 0 grade in 0 grade or 1 grade, and embodiment 1-5 accounts for more than 93% to peel off and get rusty;And control sample 1-5 weatherability
Result of the test is uneven, and its weatherability is compared with a certain distance with embodiment 1-8.
Atmospheric exposure test result statistics (unit under the operation formula of table 11 A:Level)
Atmospheric exposure test result statistics (unit under the operation formula of table 12 B:Level)
Atmospheric exposure test result statistics (unit under the operation formula of table 13 C:Level)
Atmospheric exposure test result statistics (unit under the operation formula of table 14 D:Level)
3. comprehensive contrast test
(1) subjects:Using control sample 1-5 as control, sample prepared by embodiment 1-8 is test sample.
(2) content of the test:With reference to GB/T9286-1998, GB/T6769-1996, GB/T1732-1993,
It is hard that GB/T1731-1993, GB/T1733-1993 and GB/T1763-1979 carry out adhesive force, pencil to subjects respectively
Degree, impact strength, pliability, water resistance, acid resistance, alkali resistance test and VOC tests.
(3) result of the test:Result of the test is as shown in Table 15, in comprehensive contrast test, embodiment 1-8 attachment
Power, pencil hardness, impact strength, pliability, water resistance, acid resistance, alkali resistance, VOC meet national standard.
The comprehensive comparative test result of table 15 is counted
Described above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that being led for this technology
For the those of ordinary skill in domain, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications
Also it should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of water soluble acrylic acid paint added with titanium dioxide, it is characterised in that include the component of following parts by weight:
10~30 parts of acrylic resin;
0.1~1 part of dispersant;
1~5 part of wetting agent;
2~10 parts of film forming agent;
0.1~1 part of defoamer;
20~100 parts of filler;
20~40 parts of solvent;
Wherein, the film forming agent includes 90~95wt% of amino resins;
The defoamer includes four 50~100wt% of heptanone of fluorination;
The filler includes 10~100wt% of rutile type titanium white.
2. the water soluble acrylic acid paint according to claim 1 added with titanium dioxide, it is characterised in that the dispersant is non-ionic polyalcohol.
3. the water soluble acrylic acid paint according to claim 1 added with titanium dioxide, it is characterised in that the wetting agent is aqueous moistening flatting agent.
4. the water soluble acrylic acid paint according to claim 1 added with titanium dioxide, it is characterised in that the film forming agent includes 5~10wt% of 90~95wt% of amino resins and drier.
5. the water soluble acrylic acid paint according to claim 1 added with titanium dioxide, it is characterised in that the rutile type titanium white is through zirconium, aluminium inorganic surface treatment and organic surface treatment.
6. the water soluble acrylic acid paint according to claim 1 added with titanium dioxide, it is characterised in that the filler includes rutile type titanium white and/or barium sulfate.
7. the water soluble acrylic acid paint according to claim 1 added with titanium dioxide, it is characterised in that the solvent includes 5~10wt% of 90~95wt% of water and ethanol.
8. the water soluble acrylic acid paint according to claim 1 added with titanium dioxide, it is characterised in that the granularity of the filler is 0.01~0.05 μm.
9. the preparation method of a kind of water soluble acrylic acid paint added with titanium dioxide as described in claim any one of 1-8, it is characterised in that comprise the following steps:
S1, the solvent progress of the acrylic resin of formula ratio, dispersant, wetting agent, filler and part formulation amount is pre-dispersed, obtain pre-dispersed system;
S2, the pre-dispersed system milled processed that step S1 is obtained, in the solvent for being wherein sequentially added into film forming agent, defoamer and part formulation amount, stirs;The solvent of remaining formula ratio is added, is stirred, is produced.
10. preparation method according to claim 9, it is characterised in that comprise the following steps:
S1, will 10~30 parts of acrylic resins, 0.1~1 part of dispersant, 1~5 part of wetting agent, 20~100 parts of fillers and 9~19 parts of water mix after carried out under 400~600r/min of rotating speed pre-dispersed, obtain pre-dispersed system;
S2, the pre-dispersed system milled processed that step S1 is obtained, in being wherein sequentially added into 2~10 parts of film forming agents, 0.1~1 part of defoamer and 2~5 parts of ethanol, stirs;9~19 parts of water are added, stirs, produces under 400~600r/min of rotating speed;
Wherein, the dispersant is non-ionic polyalcohol;The wetting agent is aqueous moistening flatting agent;The filler includes 0~90wt% of 10~100wt% of rutile type titanium white and barium sulfate, and the granularity of the filler is 0.01~0.05 μm, and the rutile type titanium white is through zirconium, aluminium inorganic surface treatment and organic surface treatment;The film forming agent includes 5~10wt% of 90~95wt% of amino resins and drier;The defoamer includes four 50~100wt% of heptanone of fluorination.
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CN101987936A (en) * | 2010-12-09 | 2011-03-23 | 上海电动工具研究所 | Single-component water-soluble insulated enamel paint and preparation method thereof |
CN104164145A (en) * | 2014-07-15 | 2014-11-26 | 合肥科润节能建材有限公司 | Water-based baked industrial paint |
CN104559555A (en) * | 2014-11-29 | 2015-04-29 | 上海国谷化工科技有限公司 | Method for preparing boiling-resistant waterborne acrylic paint |
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