CN107216158A - 一种莫来石质可塑料及其制备方法 - Google Patents
一种莫来石质可塑料及其制备方法 Download PDFInfo
- Publication number
- CN107216158A CN107216158A CN201710414268.3A CN201710414268A CN107216158A CN 107216158 A CN107216158 A CN 107216158A CN 201710414268 A CN201710414268 A CN 201710414268A CN 107216158 A CN107216158 A CN 107216158A
- Authority
- CN
- China
- Prior art keywords
- moldable
- mullite
- materials
- granularity
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052863 mullite Inorganic materials 0.000 title claims abstract description 48
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 73
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 41
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000007767 bonding agent Substances 0.000 claims abstract description 22
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 235000013312 flour Nutrition 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910010413 TiO 2 Inorganic materials 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 16
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 16
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 16
- 229940068918 polyethylene glycol 400 Drugs 0.000 claims abstract description 16
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 16
- 239000001110 calcium chloride Substances 0.000 claims abstract description 14
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 14
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 239000003595 mist Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- 239000000758 substrate Substances 0.000 claims abstract description 13
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 10
- 238000007493 shaping process Methods 0.000 claims abstract description 8
- 230000032683 aging Effects 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- 238000012216 screening Methods 0.000 claims description 6
- 229910052593 corundum Inorganic materials 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 3
- 229910052906 cristobalite Inorganic materials 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052682 stishovite Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 229910052905 tridymite Inorganic materials 0.000 claims description 3
- 239000003245 coal Substances 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 5
- 230000014759 maintenance of location Effects 0.000 abstract description 3
- 238000003756 stirring Methods 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
- C04B35/185—Mullite 3Al2O3-2SiO2
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
- C04B35/63404—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B35/63424—Polyacrylates; Polymethacrylates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
- C04B35/63404—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B35/63444—Nitrogen-containing polymers, e.g. polyacrylamides, polyacrylonitriles, polyvinylpyrrolidone [PVP], polyethylenimine [PEI]
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
- C04B35/63448—Polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B35/63488—Polyethers, e.g. alkylphenol polyglycolether, polyethylene glycol [PEG], polyethylene oxide [PEO]
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/444—Halide containing anions, e.g. bromide, iodate, chlorite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/77—Density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
本发明涉及一种莫来石质可塑料及其制备方法。其技术方案是：将聚丙烯酸钠、聚乙二醇400、聚丙烯酰胺和水搅拌，制得结合剂。再将煤矸石、γ‑氧化铝微粉和硅粉混合，制得混合料；向混合料中加入二氧化钛溶胶，混合，成型，成型后的坯体在空气气氛和1350~1400℃条件下热处理，热处理后的物料经破碎和筛分，即得粒度为3~4mm的A物料、粒度为1~2mm的B物料和粒度小于80μm的C物料。然后将所述A物料、所述B物料、所述C物料和氯化钙细粉混合，制得混合均质料；向所述混合均质料中加入所述结合剂，混合均匀，困料，制得莫来石质可塑料。本发明具有成本低廉和工艺简单的特点；所制备的莫来石质可塑料的体积密度大、耐压强度高和保存周期长。
Description
技术领域
本发明属于可塑料技术领域。具体涉及一种莫来石质可塑料及其制备方法。
背景技术
可塑料是将粒状和粉状物料按一定比例配制，并引入结合剂而制备的一类不定形耐火材料，其主要特性为长时间内保持较高的可塑性。可塑料根据硬化方式可分为气硬性和热硬性两类，根据骨料材质不同可分为硅质、镁质、莫来石质和高铝质可塑料等。
莫来石质可塑料是主晶相为莫来石的一类重要不定形耐火材料，广泛应用于高炉、垃圾焚烧炉和水泥窑等易磨损和易侵蚀的部位。
“一种含均质料的刚玉-莫来石质高强耐磨可塑料”（CN201010535348.2）专利技术，公开了一种刚玉-莫来石复相高强耐磨可塑料，所制备的可塑料虽强度高和耐磨性好，但该技术采用磷酸及磷酸盐为结合剂，一方面易形成低熔相，降低刚玉-莫来石可塑料的高温性能；另外磷酸及磷酸盐结合剂的引入也减小了可塑料的硬化时间，进而缩短了可塑料的存放周期。
发明内容
本发明旨在克服现有技术缺陷，目的在于提供一种成本低廉和工艺简单的莫来石质可塑料的制备方法；用该方法制备的莫来石质可塑料的体积密度大、耐压强度高和保存周期长。
为实现上述目的，本发明采用的技术方案的具体步骤是：
步骤一、按聚丙烯酸钠∶聚乙二醇400∶聚丙烯酰胺∶水的质量比为(0.02~0.05)∶(0.05~0.1)∶(0.05~0.08)∶1，在30~35℃水浴条件下，将聚丙烯酸钠、聚乙二醇400、聚丙烯酰胺和水置入容器中，搅拌5~8分钟，制得结合剂。
步骤二、按煤矸石︰γ-氧化铝微粉︰硅粉的质量比为1︰(0.5~0.6)︰(0.05~0.1)，将煤矸石、γ-氧化铝微粉和硅粉在行星球磨机中混合20~30分钟，制得混合料。
步骤三、按所述混合料︰二氧化钛溶胶的质量比为1︰(0.04~0.06)，向所述混合料中加入所述二氧化钛溶胶，混合5~8分钟，然后加入模具中成型，得到成型后的坯体。
步骤四、将所述成型后的坯体置于马弗炉中，在空气气氛和1350~1400℃条件下热处理1~2小时，随炉冷却，得到热处理后的物料。
步骤五、将所述热处理后的物料破碎，研磨，筛分，分别得到粒度为3~4mm的A物料、粒度为1~2mm的B物料和粒度小于80μm的C物料。
步骤六、将55~60wt%的所述A物料、14~19wt%的所述B物料、22~27wt%的所述C物料和1~3wt%的氯化钙细粉加入搅拌机中，混合5~10分钟，制得混合均质料。
步骤七、按所述混合均质料︰所述结合剂的质量比为1︰(0.05~0.08)，向所述混合均质料中加入所述结合剂，混合均匀，困料8~10小时，即得莫来石质可塑料。
所述聚丙烯酸钠、聚乙二醇400和聚丙烯酰胺均为化学纯。
所述煤矸石的主要化学成分为：Al2O3为40~50wt%，SiO2为30~40wt%，Fe2O3≤0.5wt%，（Na2O+K2O）≤0.5wt%，（MgO+CaO）≤0.5wt%；煤矸石的粒度为60~80μm。
所述γ-氧化铝微粉的Al2O3含量≥98wt%；γ-氧化铝微粉的粒度为60~80μm。
所述硅粉的Si含量≥96wt%；硅粉的粒度为60~80μm。
所述二氧化钛溶胶的TiO2含量为10~15wt%。
所述氯化钙细粉的CaCl2含量≥98wt%；CaCl2细粉的粒度为60~80μm。
由于采取上述技术方案，本发明与现有技术相比具有如下积极效果：
1、本发明采用煤矸石为主要原料，实现固体废弃物资源的有效回收利用，大幅降低了莫来石质可塑料的开发成本，制备工艺简单。
2、本发明通过预烧热处理技术，降低原料组分的二次莫来石化对可塑料体积稳定性的影响，进而增大了莫来石质可塑料的体积密度和强度。
本发明制备的莫来石质可塑料经测定：硬化时间为10~15个月；110℃×12h热处理后体积密度为2.65~2.70g/cm3；110℃×12h热处理后冷态耐压强度为35~38MPa。
因此，本发明具有成本低廉和工艺简单的特点；所制备的莫来石质可塑料的体积密度大、耐压强度高和保存周期长。
具体实施方式
下面结合具体实施方式对本发明作进一步的描述，并非对其保护范围的限制。
为避免重复，先将本具体实施方式所涉及的物料统一描述如下，实施例中不再赘述：
所述聚丙烯酸钠、聚乙二醇400和聚丙烯酰胺均为化学纯。
所述煤矸石的主要化学成分为：Al2O3为40~50wt%，SiO2为30~40wt%，Fe2O3≤0.5wt%，（Na2O+K2O）≤0.5wt%，（MgO+CaO）≤0.5wt%；煤矸石的粒度为60~80μm。
所述γ-氧化铝微粉的Al2O3含量≥98wt%；γ-氧化铝微粉的粒度为60~80μm。
所述硅粉的Si含量≥96wt%；硅粉的粒度为60~80μm。
所述二氧化钛溶胶的TiO2含量为10~15wt%。
所述氯化钙细粉的CaCl2含量≥98wt%；CaCl2细粉的粒度为60~80μm。
实施例1
一种莫来石质可塑料及其制备方法。本实施例所述制备方法的具体步骤是：
步骤一、按聚丙烯酸钠∶聚乙二醇400∶聚丙烯酰胺∶水的质量比为(0.02~0.04)∶(0.05~0.07)∶(0.05~0.07)∶1，在30~35℃水浴条件下，将聚丙烯酸钠、聚乙二醇400、聚丙烯酰胺和水置入容器中，搅拌5~8分钟，制得结合剂。
步骤二、按煤矸石︰γ-氧化铝微粉︰硅粉的质量比为1︰(0.5~0.6)︰(0.05~0.07)，将煤矸石、γ-氧化铝微粉和硅粉在行星球磨机中混合20~30分钟，制得混合料。
步骤三、按所述混合料︰二氧化钛溶胶的质量比为1︰(0.04~0.05)，向所述混合料中加入所述二氧化钛溶胶，混合5~8分钟，然后加入模具中成型，得到成型后的坯体。
步骤四、将所述成型后的坯体置于马弗炉中，在空气气氛和1350~1400℃条件下热处理1~2小时，随炉冷却，得到热处理后的物料。
步骤五、将所述热处理后的物料破碎，研磨，筛分，分别得到粒度为3~4mm的A物料、粒度为1~2mm的B物料和粒度小于80μm的C物料。
步骤六、将58~60wt%的所述A物料、14~16wt%的所述B物料、25~27wt%的所述C物料和1~2wt%的氯化钙细粉加入搅拌机中，混合5~10分钟，制得混合均质料。
步骤七、按所述混合均质料︰所述结合剂的质量比为1︰(0.05~0.07)，向所述混合均质料中加入所述结合剂，混合均匀，困料8~10小时，即得莫来石质可塑料。
本实施例制备的莫来石质可塑料经测定：硬化时间为10~12个月；110℃×12h热处理后体积密度为2.65~2.67g/cm3；110℃×12h热处理后冷态耐压强度为35~37MPa。
实施例2
一种莫来石质可塑料及其制备方法。本实施例所述制备方法的具体步骤是：
步骤一、按聚丙烯酸钠∶聚乙二醇400∶聚丙烯酰胺∶水的质量比为(0.02~0.04)∶(0.06~0.08)∶(0.05~0.07)∶1，在30~35℃水浴条件下，将聚丙烯酸钠、聚乙二醇400、聚丙烯酰胺和水置入容器中，搅拌5~8分钟，制得结合剂。
步骤二、按煤矸石︰γ-氧化铝微粉︰硅粉的质量比为1︰(0.5~0.6)︰(0.06~0.08)，将煤矸石、γ-氧化铝微粉和硅粉在行星球磨机中混合20~30分钟，制得混合料。
步骤三、按所述混合料︰二氧化钛溶胶的质量比为1︰(0.04~0.05)，向所述混合料中加入所述二氧化钛溶胶，混合5~8分钟，然后加入模具中成型，得到成型后的坯体。
步骤四、将所述成型后的坯体置于马弗炉中，在空气气氛和1350~1400℃条件下热处理1~2小时，随炉冷却，得到热处理后的物料。
步骤五、将所述热处理后的物料破碎，研磨，筛分，分别得到粒度为3~4mm的A物料、粒度为1~2mm的B物料和粒度小于80μm的C物料。
步骤六、将57~59wt%的所述A物料、15~17wt%的所述B物料、24~26wt%的所述C物料和1~2wt%的氯化钙细粉加入搅拌机中，混合5~10分钟，制得混合均质料。
步骤七、按所述混合均质料︰所述结合剂的质量比为1︰(0.05~0.07)，向所述混合均质料中加入所述结合剂，混合均匀，困料8~10小时，即得莫来石质可塑料。
本实施例制备的莫来石质可塑料经测定：硬化时间为11~13个月；110℃×12h热处理后体积密度为2.66~2.68g/cm3；110℃×12h热处理后冷态耐压强度为35~37MPa。
实施例3
一种莫来石质可塑料及其制备方法。本实施例所述制备方法的具体步骤是：
步骤一、按聚丙烯酸钠∶聚乙二醇400∶聚丙烯酰胺∶水的质量比为(0.03~0.05)∶(0.07~0.09)∶(0.06~0.08)∶1，在30~35℃水浴条件下，将聚丙烯酸钠、聚乙二醇400、聚丙烯酰胺和水置入容器中，搅拌5~8分钟，制得结合剂。
步骤二、按煤矸石︰γ-氧化铝微粉︰硅粉的质量比为1︰(0.5~0.6)︰(0.07~0.09)，将煤矸石、γ-氧化铝微粉和硅粉在行星球磨机中混合20~30分钟，制得混合料。
步骤三、按所述混合料︰二氧化钛溶胶的质量比为1︰(0.05~0.06)，向所述混合料中加入所述二氧化钛溶胶，混合5~8分钟，然后加入模具中成型，得到成型后的坯体。
步骤四、将所述成型后的坯体置于马弗炉中，在空气气氛和1350~1400℃条件下热处理1~2小时，随炉冷却，得到热处理后的物料。
步骤五、将所述热处理后的物料破碎，研磨，筛分，分别得到粒度为3~4mm的A物料、粒度为1~2mm的B物料和粒度小于80μm的C物料。
步骤六、将56~58wt%的所述A物料、16~18wt%的所述B物料、23~25wt%的所述C物料和2~3wt%的氯化钙细粉加入搅拌机中，混合5~10分钟，制得混合均质料。
步骤七、按所述混合均质料︰所述结合剂的质量比为1︰(0.06~0.08)，向所述混合均质料中加入所述结合剂，混合均匀，困料8~10小时，即得莫来石质可塑料。
本实施例制备的莫来石质可塑料经测定：硬化时间为12~14个月；110℃×12h热处理后体积密度为2.67~2.69g/cm3；110℃×12h热处理后冷态耐压强度为36~38MPa。
实施例4
一种莫来石质可塑料及其制备方法。本实施例所述制备方法的具体步骤是：
步骤一、按聚丙烯酸钠∶聚乙二醇400∶聚丙烯酰胺∶水的质量比为(0.03~0.05)∶(0.08~0.1)∶(0.06~0.08)∶1，在30~35℃水浴条件下，将聚丙烯酸钠、聚乙二醇400、聚丙烯酰胺和水置入容器中，搅拌5~8分钟，制得结合剂。
步骤二、按煤矸石︰γ-氧化铝微粉︰硅粉的质量比为1︰(0.5~0.6)︰(0.08~0.1)，将煤矸石、γ-氧化铝微粉和硅粉在行星球磨机中混合20~30分钟，制得混合料。
步骤三、按所述混合料︰二氧化钛溶胶的质量比为1︰(0.05~0.06)，向所述混合料中加入所述二氧化钛溶胶，混合5~8分钟，然后加入模具中成型，得到成型后的坯体。
步骤四、将所述成型后的坯体置于马弗炉中，在空气气氛和1350~1400℃条件下热处理1~2小时，随炉冷却，得到热处理后的物料。
步骤五、将所述热处理后的物料破碎，研磨，筛分，分别得到粒度为3~4mm的A物料、粒度为1~2mm的B物料和粒度小于80μm的C物料。
步骤六、将55~57wt%的所述A物料、17~19wt%的所述B物料、22~24wt%的所述C物料和2~3wt%的氯化钙细粉加入搅拌机中，混合5~10分钟，制得混合均质料。
步骤七、按所述混合均质料︰所述结合剂的质量比为1︰(0.06~0.08)，向所述混合均质料中加入所述结合剂，混合均匀，困料8~10小时，即得莫来石质可塑料。
本实施例制备的莫来石质可塑料经测定：硬化时间为13~15个月；110℃×12h热处理后体积密度为2.68~2.70g/cm3；110℃×12h热处理后冷态耐压强度为36~38MPa。
本具体实施方式与现有技术相比具有如下积极效果：
1、本具体实施方式采用煤矸石为主要原料，实现固体废弃物资源的有效回收利用，大幅降低了莫来石质可塑料的开发成本，制备工艺简单。
2、本具体实施方式通过预烧热处理技术，降低原料组分的二次莫来石化对可塑料体积稳定性的影响，进而增大了莫来石质可塑料的体积密度和强度。
本具体实施方式制备的莫来石质可塑料经测定：硬化时间为10~15个月；110℃×12h热处理后体积密度为2.65~2.70g/cm3；110℃×12h热处理后冷态耐压强度为35~38MPa。
因此，本具体实施方式具有成本低廉和工艺简单的特点；所制备的莫来石质可塑料的体积密度大、耐压强度高和保存周期长。
Claims (8)
1.一种莫来石质可塑料的制备方法，其特征在于所述制备方法的步骤是：
步骤一、按聚丙烯酸钠∶聚乙二醇400∶聚丙烯酰胺∶水的质量比为(0.02~0.05)∶(0.05~0.1)∶(0.05~0.08)∶1，在30~35℃水浴条件下，将聚丙烯酸钠、聚乙二醇400、聚丙烯酰胺和水置入容器中，搅拌5~8分钟，制得结合剂；
步骤二、按煤矸石︰γ-氧化铝微粉︰硅粉的质量比为1︰(0.5~0.6)︰(0.05~0.1)，将煤矸石、γ-氧化铝微粉和硅粉在行星球磨机中混合20~30分钟，制得混合料；
步骤三、按所述混合料︰二氧化钛溶胶的质量比为1︰(0.04~0.06)，向所述混合料中加入所述二氧化钛溶胶，混合5~8分钟，然后加入模具中成型，得到成型后的坯体；
步骤四、将所述成型后的坯体置于马弗炉中，在空气气氛和1350~1400℃条件下热处理1~2小时，随炉冷却，得到热处理后的物料；
步骤五、将所述热处理后的物料破碎，研磨，筛分，分别得到粒度为3~4mm的A物料、粒度为1~2mm的B物料和粒度小于80μm的C物料；
步骤六、将55~60wt%的所述A物料、14~19wt%的所述B物料、22~27wt%的所述C物料和1~3wt%的氯化钙细粉加入搅拌机中，混合5~10分钟，制得混合均质料；
步骤七、按所述混合均质料︰所述结合剂的质量比为1︰(0.05~0.08)，向所述混合均质料中加入所述结合剂，混合均匀，困料8~10小时，即得莫来石质可塑料。
2.根据权利要求1所述的莫来石质可塑料的制备方法，其特征在于所述聚丙烯酸钠、聚乙二醇400和聚丙烯酰胺均为化学纯。
3.根据权利要求1所述的莫来石质可塑料的制备方法，其特征在于所述煤矸石的主要化学成分为：Al2O3为40~50wt%，SiO2为30~40wt%，Fe2O3≤0.5wt%，（Na2O+K2O）≤0.5wt%，（MgO+CaO）≤0.5wt%；煤矸石的粒度为60~80μm。
4.根据权利要求1所述的莫来石质可塑料的制备方法，其特征在于所述γ-氧化铝微粉的Al2O3含量≥98wt%；γ-氧化铝微粉的粒度为60~80μm。
5.根据权利要求1所述的莫来石质可塑料的制备方法，其特征在于所述硅粉的Si含量≥96wt%；硅粉的粒度为60~80μm。
6.根据权利要求1所述的莫来石质可塑料的制备方法，其特征在于所述二氧化钛溶胶的TiO2含量为10~15wt%。
7.根据权利要求1所述的莫来石质可塑料的制备方法，其特征在于所述氯化钙细粉的CaCl2含量≥98wt%；CaCl2细粉的粒度为60~80μm。
8.一种莫来石质可塑料，其特征在于所述莫来石质可塑料是根据权利要求1~7项中任一项所述的莫来石质可塑料的制备方法所制备的莫来石质可塑料。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710414268.3A CN107216158B (zh) | 2017-06-05 | 2017-06-05 | 一种莫来石质可塑料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710414268.3A CN107216158B (zh) | 2017-06-05 | 2017-06-05 | 一种莫来石质可塑料及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107216158A true CN107216158A (zh) | 2017-09-29 |
| CN107216158B CN107216158B (zh) | 2020-02-14 |
Family
ID=59947077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710414268.3A Expired - Fee Related CN107216158B (zh) | 2017-06-05 | 2017-06-05 | 一种莫来石质可塑料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107216158B (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110590349A (zh) * | 2019-10-15 | 2019-12-20 | 北京中环鑫汇科技有限公司 | 低导热高温炉衬材料及其制备方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101122049A (zh) * | 2007-07-25 | 2008-02-13 | 濮阳濮耐高温材料（集团）股份有限公司 | 一种由煤矸石和氧化铝制备莫来石晶须的方法 |
| CN101857454A (zh) * | 2010-06-28 | 2010-10-13 | 通达耐火技术股份有限公司 | 一种矾土基高致密耐火合成料及生产方法 |
| CN102584289A (zh) * | 2012-02-08 | 2012-07-18 | 武汉科技大学 | 一种莫来石轻质骨料及其制备方法 |
| CN104788121A (zh) * | 2015-04-20 | 2015-07-22 | 武汉科技大学 | 一种莫来石质轻质耐火材料及其制备方法 |
| CN105272189A (zh) * | 2015-11-28 | 2016-01-27 | 郑州大学 | 一种微孔莫来石陶瓷分离膜支撑体及其制备方法 |
| CN106431371A (zh) * | 2016-09-22 | 2017-02-22 | 郑州大学 | 一种高强闭孔莫来石材料及其制备方法 |
-
2017
- 2017-06-05 CN CN201710414268.3A patent/CN107216158B/zh not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101122049A (zh) * | 2007-07-25 | 2008-02-13 | 濮阳濮耐高温材料（集团）股份有限公司 | 一种由煤矸石和氧化铝制备莫来石晶须的方法 |
| CN101857454A (zh) * | 2010-06-28 | 2010-10-13 | 通达耐火技术股份有限公司 | 一种矾土基高致密耐火合成料及生产方法 |
| CN102584289A (zh) * | 2012-02-08 | 2012-07-18 | 武汉科技大学 | 一种莫来石轻质骨料及其制备方法 |
| CN104788121A (zh) * | 2015-04-20 | 2015-07-22 | 武汉科技大学 | 一种莫来石质轻质耐火材料及其制备方法 |
| CN105272189A (zh) * | 2015-11-28 | 2016-01-27 | 郑州大学 | 一种微孔莫来石陶瓷分离膜支撑体及其制备方法 |
| CN106431371A (zh) * | 2016-09-22 | 2017-02-22 | 郑州大学 | 一种高强闭孔莫来石材料及其制备方法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110590349A (zh) * | 2019-10-15 | 2019-12-20 | 北京中环鑫汇科技有限公司 | 低导热高温炉衬材料及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107216158B (zh) | 2020-02-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108358581B (zh) | 一种含精炼渣的混凝土及其制备方法 | |
| CN107935555B (zh) | 一种镍铁渣陶瓷及其制备方法 | |
| CN102010215A (zh) | 以废弃镁碳砖为原料的中间包干式振动料及其制备方法 | |
| CN101139198A (zh) | 化工石膏建材及其制造方法 | |
| CN102690067A (zh) | 高活性水泥熟料和高活性水泥 | |
| CN106278102B (zh) | 一种利用镍渣进行石膏增韧的方法及其制品 | |
| CN102060485A (zh) | 一种水泥混凝土及其制备方法和循环利用方法 | |
| CN106588059A (zh) | 一种石灰回转窑用预制件及其制备方法 | |
| CN105731808A (zh) | 一种制备微晶玻璃的方法 | |
| CN108675657A (zh) | 一种利用废渣制备硅酸盐-硫铝酸盐复合体系熟料的方法 | |
| CN104193372B (zh) | 一种高强耐碱浇注料及其制备方法 | |
| CN107188547B (zh) | 一种高铝质可塑料及其制备方法 | |
| CN101700672A (zh) | 一种采用铝土矿选尾矿制备仿石地板砖的方法 | |
| CN103708732A (zh) | 一种钢渣制备微晶玻璃的方法 | |
| KR101205506B1 (ko) | 산업부산물을 활용한 친환경 무기결합재 조성물 | |
| CN107216158A (zh) | 一种莫来石质可塑料及其制备方法 | |
| KR100761617B1 (ko) | 항균성 및 원적외선 방사율이 높은 현무암 바이오 세라믹조성물의 제조방법 | |
| CN1982247A (zh) | 一种铝酸钙水泥 | |
| CN101337791B (zh) | 含有矿渣的复合水泥用助磨改性剂 | |
| CN104446571A (zh) | 一种镁质浇注料及其制备方法 | |
| Jiang et al. | Development of non-autoclaved aerated concrete by alkali activated phosphorus slag | |
| KR101991317B1 (ko) | 클링커 조성물 | |
| CN102910890A (zh) | 一种以水渣为原料的烧结砖及其制备工艺 | |
| CN104276761A (zh) | 废弃陶瓷石膏模制造啤酒瓶玻璃 | |
| Mamchenkov et al. | Sodium silicate manufacturing from modified silica gel as by-product of aluminum fluoride |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210902 Address after: 214200 north of Yipu Road, Dapu Industrial Park, Dingshu Town, Yixing City, Wuxi City, Jiangsu Province Patentee after: Yixing Xingbei refractory insulation engineering Co.,Ltd. Address before: 430081 No. 947 Heping Avenue, Qingshan District, Hubei, Wuhan Patentee before: WUHAN University OF SCIENCE AND TECHNOLOGY |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20200214 |