CN107197869A - A kind of containing copper rosinate and suspending agent of azoles alcohol and preparation method thereof - Google Patents
A kind of containing copper rosinate and suspending agent of azoles alcohol and preparation method thereof Download PDFInfo
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- CN107197869A CN107197869A CN201710472906.7A CN201710472906A CN107197869A CN 107197869 A CN107197869 A CN 107197869A CN 201710472906 A CN201710472906 A CN 201710472906A CN 107197869 A CN107197869 A CN 107197869A
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- Prior art keywords
- agent
- suspending agent
- copper rosinate
- azoles alcohol
- mixture
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
Abstract
The invention discloses a kind of containing copper rosinate and suspending agent of azoles alcohol, belong to agricultural bacteriocide technical field, its composition and percentage by weight are as follows：Copper rosinate active compound 5~30%, hexaconazole 3~30%, dispersant 1~5%, wetting agent 1~5%, thickener 0.1~1.5%, antifreezing agent 1~5%, defoamer 0.1~0.4%, surplus is water.Containing the copper rosinate and suspending agent of azoles alcohol of the present invention has protection and therapeutic action, belongs to environmental protection low nuisanceless sterilization formulation, a variety of fungies, bacteriosis to paddy rice have protect well, therapeutic action.
Description
Technical field
The present invention relates to a kind of copper rosinate compounding suspending agent and preparation method thereof, and in particular to one kind containing copper rosinate and
Suspending agent of azoles alcohol and preparation method thereof, belongs to agricultural bacteriocide technical field.
Background technology
The wide spectrum copper fungicide agriculturally commonly used at present is generally inorganic copper fungicide, such as common Bordeaux mixture, with
And Kocide SD, copper oxychloride, cuprous oxide etc..The shortcoming of these inorganic copper fungicides is：Security is poor, it is unsuitable and its
Its combined use of pesticides, is otherwise also easy to produce poisoning；Mite class outburst etc. is easily caused after use；Copper ion utilization rate is low, and the lasting period is short.
And copper rosinate is then a kind of new copper agent sterilization pesticide of high-efficiency low-toxicity wide spectrum, with lasting period length, use
Convenient new feature.Copper rosinate has prevention ＆ protection and treatment double action, available for preventing and treating caused by a variety of fungies and bacterium
Frequently seen plants disease, there is obvious stimulating growth to act on to vegetables, can be mixed with other bactericide, spray effect is good.For
Prevent and treat a variety of vegetables such as downy mildew of cucurbits, epidemic disease, scab, anthracnose, bacterial angular leaf spot, eggplant damping-off, tomato late blight
Dish disease.And as a kind of organic copper agent, it preferably solves the safety issue of product and easily causes mite class to break out
Defect.
But it is due to that production technology is limited, all copper rosinate bactericide are cream preparation in the market, and this makes
Its cost is higher, cost performance is relatively low, and the organic solvent such as its turpentine oil, the dimethylbenzene that largely use also bring it is substantial amounts of
Pollution.
Disclosed in 20 days December in 2000, number of patent application is 99116238.2, and entitled " one kind contains organic copper
Bactericidal composition " Chinese invention patent disclose a kind of bactericidal composition containing organic copper, disclosed in embodiment
The preparation method of bactericidal composition containing organic copper, is directed to following steps：(1) rosin+heavy oil+sodium hydroxide, plus
Heat, stirring；(2) copper sulphate, stirring are added；(3) emulsifying agent is added again；(4) azone is added, what is obtained is killing containing organic copper
Bacteria composition.Its shortcoming is exactly that it employs substantial amounts of heavy oil first so that the cost of product is significantly raised (it is expected that obtaining phase
With the copper rosinate of content, its cost is more than 3 times using Aqueous phase cost), reduce the cost performance of product；Secondly it is exactly
Heavy oil has very serious pollution to environment as a kind of organic solvent, and current country has had timed out new missible oil product in agriculture
Handling in medicine registration.
Meanwhile, number of patent application discloses a kind of resin acid copper water for 200510043522.0 Chinese invention patent application
Emulsion and preparation method thereof, but its solvent falls within organic solvent, it is inreal to solve what is brought using organic solvent yet
The problem of environmental pollution and higher cost.
Number of patent application is 201310472875.7, entitled a kind of copper rosinate suspending agent and preparation method thereof
Chinese invention patent discloses a kind of copper rosinate suspending agent and preparation method thereof, the composition and weight hundred of copper rosinate suspending agent
Divide ratio as follows：Copper rosinate original powder 10%-50%, dispersant 3-10%, thickener 0.1-1.5%, antifreezing agent 2-5%,
Surplus is water.The inventor of the application for a patent for invention is also the present inventor, and the present inventor has found in actual use, above-mentioned
Copper rosinate suspending agent has special efficacy for bacterial diseases such as rice streak, bacterial leaf-blight, basal stem rots, to rice sheath blight disease,
The fungal diseases such as rice blast, damping-off have certain preventive effect, but much can not meet modern to efficient requirement.Even if
It is efficient bactericide, it is long-term to be used alone, also easily disease is developed immunity to drugs, so as to cause dosage to increase, preventive effect drops
The problems such as low, lasting period shortens, Reusability will also result in agricultural chemicals and largely be remained in soil, and this is unsatisfactory for continuity of environment hair
The requirement of exhibition.Rational chemical bactericide compounding, which has, expands fungicidal spectrum, improves preventive effect, reduce dosage, extension dispenser period,
Reduction poisoning, reduction remain, delay the advantages of resistance to the action of a drug occurs.
Hexaconazole belongs to triazole bactericidal agent, sterol demethylation inhibitors, to fungi especially Basidiomycota and ascus
Disease caused by bacterium door has the protection and therapeutic action of broad spectrum activity, there is good prevention effect to rice sheath blight disease.
Present inventors have surprisingly found that azoles alcohol is compounded by copper rosinate and, there is good synergy to make in certain scope
With expanding fungicidal spectrum significantly, improve germicidal efficiency, fungi and the bacterial disease of paddy rice can be prevented and treated comprehensively, is reduced
Dosage.
The content of the invention
An object of the present invention is to provide a kind of copper rosinate prevented and treated for rice disease and the compounding of hexaconazole is hanged
Floating agent.
The foregoing invention purpose of the present invention reaches by the following technical programs：
A kind of containing copper rosinate and suspending agent of azoles alcohol, its composition and percentage by weight are as follows：Copper rosinate active compound 5~
30%, hexaconazole 3~30%, dispersant 1~5%, wetting agent 1~5%, thickener 0.1~1.5%, antifreezing agent 1~5% disappears
Infusion 0.1~0.4%, surplus is water.
Preferably, the composition and weight percentage of the suspending agent are：Copper rosinate active compound 15%, hexaconazole 5%, point
Powder 3%, wetting agent 3%, thickener 0.2%, antifreezing agent 4%, defoamer 0.15%, surplus is water.
Preferably, described dispersant is alkylnaphthalene sulfonate condensation polymer, NPE, naphthalenesulfonateformaldehyde formaldehyde contracting
Compound, ethoxylated castor oil, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether or lignin sulfonic acid
The mixture of one or more of arbitrary proportions in sodium.
Preferably, described wetting agent is alkylnaphthalene sulfonate condensation polymer, polyoxyethylene aliphatic alcohol ether, polyoxyethylene nonyl phenyl second
Alkene ether phosphoric acid monoesters, polyoxyethylated alkyl phenol, castor oil Succinate sodium sulfonate or one kind or several in benzyl sodium naphthalene sulfonate
Plant the mixture of arbitrary proportion.
Preferably, described thickener be xanthans, carboxylic first (second) base sodium cellulosate, methylcellulose, polyvinyl alcohol or
The mixture of one or more of arbitrary proportions in aluminium-magnesium silicate.
Preferably, described antifreezing agent is the one or more in ethylene glycol, propane diols, glycerine or polyethylene glycol 400
The mixture of arbitrary proportion.
Preferably, described defoamer is silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8-10
The mixture of one or more of arbitrary proportions of fatty alcohol.
It is a further object of the present invention to provide above-mentioned containing the copper rosinate and preparation method of the suspending agent of azoles alcohol.
The foregoing invention purpose of the present invention reaches by the following technical programs：
Scheme one：
A kind of preparation method of the compounding suspending agent of containing copper rosinate and azoles alcohol, its step is as follows：
First by copper rosinate active compound 5~30%, azoles alcohol 3~30%, dispersant 1~5% and wetting agent 1~5% are mixed,
Add suitable quantity of water；Through milling treatment of colloid into thinner slurry, then put this slurry into sand mill and be ground, until particle is straight
When footpath reaches about 4 microns, thickener 0.1~1.5% and antifreezing agent 1~5% are added；Grind again, whole process of lapping is according to tool
Body situation adds defoamer 0.1~0.4%, and adds water to 100%, that is, copper rosinate and the compounding suspending agent of azoles alcohol is made.
Scheme two：
A kind of preparation method of the compounding suspending agent of containing copper rosinate and azoles alcohol, its step is as follows：One-step method is taken to be made
Copper rosinate suspending agent (10%~50%), inside add hexaconazole 3~30%, dispersant 1~5%, wetting agent 1~
5%, put sand mill into after being well mixed and be ground, until when particle diameter reaches about 4 microns, addition thickener 0.1~
1.5% and antifreezing agent 1~5%, then grind, whole process of lapping adds defoamer 0.1~0.4% as the case may be；And add
Water is quantitative to 100%, that is, is made and contains the sour copper of loose ester and the suspending agent of azoles alcohol.
Preferably, described dispersant is alkylnaphthalene sulfonate condensation polymer, NPE, naphthalenesulfonateformaldehyde formaldehyde contracting
Compound, ethoxylated castor oil, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether or lignin sulfonic acid
The mixture of one or more of arbitrary proportions in sodium.
Preferably, described wetting agent is alkylnaphthalene sulfonate condensation polymer, polyoxyethylene aliphatic alcohol ether, polyoxyethylene nonyl phenyl second
Alkene ether phosphoric acid monoesters, polyoxyethylated alkyl phenol, castor oil Succinate sodium sulfonate or one kind or several in benzyl sodium naphthalene sulfonate
Plant the mixture of arbitrary proportion.
Preferably, described thickener be xanthans, carboxylic first (second) base sodium cellulosate, methylcellulose, polyvinyl alcohol or
The mixture of one or more of arbitrary proportions in aluminium-magnesium silicate.
Preferably, described antifreezing agent is the one or more in ethylene glycol, propane diols, glycerine or polyethylene glycol 400
The mixture of arbitrary proportion.
Preferably, described defoamer is silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8-10
The mixture of one or more of arbitrary proportions of fatty alcohol.
Containing the copper rosinate and suspending agent of azoles alcohol of the present invention, which has, to be protected and therapeutic action, belongs to the low public affairs of environmental protection
Evil sterilization formulation, and both are mixed, can expand the fungicidal spectrum of product, fungi, bacteriosis (such as rice banded sclerotial blight to paddy rice
Disease, false smut, rice blast, bacterial leaf-blight etc.) there are protection, therapeutic action well.
Simultaneously present inventors have surprisingly found that, azoles alcohol has been applied in combination by copper rosinate and, the preventing and treating for rice disease
There is super addition.
The copper rosinate of the present invention and the complex preparation of azoles alcohol, have good synergistic effect, greatly in certain scope
Fungicidal spectrum is expanded greatly, germicidal efficiency is improved, fungi and the bacterial disease of paddy rice can be prevented and treated comprehensively, medication is reduced
Amount.This active response《To the year two thousand twenty Pesticide use amount zero growth rate action scheme》.
Below by embodiment, the present invention is described in detail.It should be understood that described embodiment is only
It is related to the preferred embodiments of the invention, in the case of the spirit and scope of the present invention are not departed from, the change of various composition and content
It is all possible to change and improve.
Embodiment
Embodiment 1：A kind of containing copper rosinate and suspending agent 1 (hexaconazole of 10% copper rosinate active compound+10%) of azoles alcohol
Preparation
A kind of containing copper rosinate and suspending agent of azoles alcohol, its composition and percentage by weight are as follows：Copper rosinate active compound 100
Kilogram, hexaconazole double centner, 40 kilograms of dispersant alkylnaphthalene sulfonate condensation polymer, wetting agent polyoxyethylene aliphatic alcohol ether 30,000
Gram, 2 kilograms of thickener xanthans, 30 kilograms of antifreeze glycol, 1 kilogram of defoamer silicone oil adds water to 1000 kilograms.
Preparation method is：
Its step is as follows：
First by commercially available copper rosinate active compound double centner, commercially available hexaconazole double centner, commercially available alkylnaphthalene sulfonate condensation polymer
40 kilograms, commercially available 30 kilograms of polyoxyethylene aliphatic alcohol ether adds suitable quantity of water, through milling treatment of colloid into thinner slurry, then will
This slurry is put sand mill into and is ground, until when particle diameter reaches about 4 microns, 2 kilograms of the commercially available xanthans of addition and second two
30 kilograms of alcohol, then grind, 1 kilogram of organic silicon defoamer is added, and it is quantitative to 1000 kilograms to add water, that is, is made containing the sour copper of loose ester
The suspending agent 1 of azoles alcohol.
Embodiment 2：It is a kind of containing copper rosinate and the preparation of the suspending agent 2 (hexaconazole of 15% copper rosinate+5%) of azoles alcohol
A kind of containing copper rosinate and suspending agent of azoles alcohol, its composition and percentage by weight are as follows：Copper rosinate active compound 150
Kilogram, 50 kilograms of hexaconazole, 50 kilograms of dispersant NPE, wetting agent alkylnaphthalene sulfonate condensation polymer 40,000
Gram, 10 kilograms of thickener aluminium-magnesium silicate, 30 kilograms of antifreezing agent propane diols, 2.5 kilograms of defoamer C8-10 fatty alcohols are added water to
1000 kilograms.
Preparation method is：
Its step is as follows：
First by 150 kilograms commercially available of copper rosinate active compound, commercially available 50 kilograms of hexaconazole, commercially available NPE 50
Kilogram, commercially available 40 kilograms of alkylnaphthalene sulfonate condensation polymer adds suitable quantity of water, through milling treatment of colloid into thinner slurry, then will
This slurry is put sand mill into and is ground, until particle diameter is when reaching about 4 microns, adds 10 kilograms of commercially available aluminium-magnesium silicate and third
30 kilograms of glycol, then grind, 2.5 kilograms of defoamer C8-10 fatty alcohols are added, and it is quantitative to 1000 kilograms to add water, that is, is made and contains
There are the sour copper of loose ester and the suspending agent 2 of azoles alcohol.
Embodiment 3：It is a kind of containing copper rosinate and the preparation of the suspending agent 2 (hexaconazole of 15% copper rosinate+5%) of azoles alcohol
A kind of containing copper rosinate and suspending agent of azoles alcohol, its composition and percentage by weight are as follows：Made from one-step method
20% 750 kilograms of copper rosinate suspending agent, 50 kilograms of hexaconazole, 50 kilograms of dispersant NPE, wetting agent alkane
40 kilograms of base naphthalene sulphonate, 10 kilograms of thickener aluminium-magnesium silicate, 30 kilograms of antifreezing agent propane diols, defoamer C8-10 fat
2.5 kilograms of fat alcohol, adds water to 1000 kilograms.
The suspending agent can also be prepared by the following：Take 20% copper rosinate suspending agent 750,000 made from one-step method
Gram, inside add 50 kilograms of hexaconazole active compound, commercially available 50 kilograms of NPE, commercially available alkylnaphthalene sulfonate polycondensation
40 kilograms of thing, puts sand mill into after being well mixed and is ground, until when particle diameter reaches about 4 microns, adding commercially available silicic acid
10 kilograms of magnalium is ground again, 30 kilograms of antifreezing agent propane diols, 2.5 kilograms of defoamer C8-10 fatty alcohols, and it is quantitative to 1000 to add water
Kilogram, that is, it is made and contains the sour copper of loose ester and the suspending agent 3 of azoles alcohol.
Comparative examples and the embodiment of the present invention 2 the application test effect on paddy rice：
Subjects：Paddy rice
Test method：According to medicine inspecting institute of the Ministry of Agriculture " GB/T 17980.20-2000 pesticide field efficacy medicine tests criterions (one)
Bactericidal agent for preventing and treating rice sheath blight disease " and " GB/T 17980.19-2000 pesticide field efficacy medicine tests criterion (one) bactericidal agent for preventing and treating
The regulation of paddy rice leaf diseases ", test medicine, comparison medicament and the processing of the cell of blank control are small using the arrangement of random district's groups
Area area 16m2, 4 repetitions, this experiment amount to dispenser twice.First is carried out in rice sheath blight disease and bacterial leaf-blight early stage
Secondary dispenser, carries out second of dispenser after 10 days.This experiment, which amounts to, to be investigated twice, is investigated within 10 days after administration respectively.Root
According to rice leaf sheath and blade damage symptom grading, in units of strain, sampled per experimental plot using diagonal five-spot, line
Every investigation of rot is connected 5 clumps, totally 25 clumps, and bacterial leaf-blight every takes 50 plants, and every plant is investigated boot leaf and the following two panels leaf of boot leaf, note
Record disease grade.
Banded sclerotial blight disease scale standard is as follows：
0 grade：Complete stool is disease-free；
1 grade：Quaterfoil and its following leaf sheath, blade morbidity are (using sword-like leave as first leaf)；
3 grades：Third blade and its following leaf sheath, blade morbidity；
5 grades：Second blade and its following leaf sheath, blade morbidity；
7 grades：Sword-like leave blade and its following leaf sheath, blade morbidity；
9 grades：Complete stool falls ill, withered ahead of time.
Bacterial leaf-blight disease scale standard is as follows：
0 grade：It is disease-free；
1 grade：Lesion area is leaf area below 10%；
3 grades：Lesion area is leaf area 11%~25%；
5 grades：Lesion area is leaf area 26%~45%；
7 grades：Lesion area is leaf area 46%~65%；
9 grades：Lesion area is leaf area more than 65%.
Drug effect computational methods：
Disease index and preventive effect are calculated by formula (1), formula (2)：
In formula：The disease index of CK-blank district；
The disease index of PT-chemicals treatment district.
Result of the test：
Table 1 is applied to the prevention effect of rice sheath blight disease
Table 2 is applied to the prevention effect of bacterial blight of rice
It can be seen from Table 1 that：By products application of the present invention in the preventing and treating of rice sheath blight disease, compound product preventing and treating paddy rice
Banded sclerotial blight has a significant effect, and preventive effect has reached 80.46~89.87% after second of dispenser 10 days, under same amount, effect
Two kinds of single doses are significantly better than, are had significant synergies.
It can be seen from Table 2 that：5% hexaconazole suspending agent to bacterial blight of rice almost without prevention effect, and rosin
Sour copper and hexaconazole compounding suspending agent prevent and treat bacterial blight of rice and have significant effect, under same amount, prevention effect
It is markedly superior to copper rosinate single dose, preventive effect has reached 75.34~85.47% after second of dispenser 10 days.
Found by Tables 1 and 2：Containing the copper rosinate and suspending agent pair of azoles alcohol that copper rosinate and hexaconazole compounding are obtained
The preventing and treating of rice disease serves the effect of super plus sum；Also, rice sheath blight disease can be both prevented and treated, the white leaf of paddy rice can also be prevented and treated
Rot, can comprehensively prevent and treat fungi and the bacteriosis of paddy rice, and the medicament adhesion is strong, resistance of rainwater washing against, Neng Gouming
It is aobvious to extend protective period.
It is described above, only it is highly preferred embodiment of the present invention and control case study on implementation, other forms not is made to the present invention
Limitation, any those skilled in the art are changed or are modified as equivalent change using the technology contents of the disclosure above
The equivalent embodiment of change.In every case it is that, without departing from technical solution of the present invention content, the technical spirit according to the present invention is implemented to more than
Any modification, equivalent variations and remodeling that example is made, still fall within the protection domain of technical solution of the present invention.
Claims (10)
1. a kind of containing copper rosinate and suspending agent of azoles alcohol, its composition and percentage by weight are as follows：Copper rosinate active compound 5~
30%, hexaconazole 3~30%, dispersant 1~5%, wetting agent 1~5%, thickener 0.1~1.5%, antifreezing agent 1~5% disappears
Infusion 0.1~0.4%, surplus is water.
2. the suspending agent as claimed in claim 1 containing copper rosinate and hexaconazole, it is characterised in that：The composition of the suspending agent
It is with percentage by weight：It is copper rosinate active compound 15%, hexaconazole 5%, dispersant 3%, wetting agent 3%, thickener 0.2%, anti-
Freeze agent 4%, defoamer 0.15%, surplus is water.
3. containing the copper rosinate and suspending agent of azoles alcohol as claimed in claim 1 or 2, it is characterised in that：Described dispersant
For alkylnaphthalene sulfonate condensation polymer, NPE, naphthalene sulfonic acid-formaldehyde condensation product, ethoxylated castor oil, phenethyl
One or more of arbitrary proportions in phenol polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether or sodium lignin sulfonate
Mixture.
4. containing the copper rosinate and suspending agent of azoles alcohol as claimed in claim 1 or 2, it is characterised in that：Described wetting agent
For alkylnaphthalene sulfonate condensation polymer, polyoxyethylene aliphatic alcohol ether, NPE phosphate monoester, polyoxyethylene alkylphenol
The mixture of one or more of arbitrary proportions in ether, castor oil Succinate sodium sulfonate or benzyl sodium naphthalene sulfonate.
5. containing the copper rosinate and suspending agent of azoles alcohol as claimed in claim 1 or 2, it is characterised in that：Described thickener
For any ratio of the one or more in xanthans, carboxylic first (second) base sodium cellulosate, methylcellulose, polyvinyl alcohol or aluminium-magnesium silicate
The mixture of example.
6. containing the copper rosinate and suspending agent of azoles alcohol as claimed in claim 1 or 2, it is characterised in that：Described antifreezing agent
For the mixture of one or more of arbitrary proportions in ethylene glycol, propane diols, glycerine or polyethylene glycol 400；Described froth breaking
Agent is silicone oil, silicone compound, C10-20 saturated fat acid compounds, any ratio of one or more of C8-10 fatty alcohols
The mixture of example.
7. containing the copper rosinate and preparation method of the suspending agent of azoles alcohol any one of claim 1-6, its step is such as
Under：
First by copper rosinate active compound 5~30%, azoles alcohol 3~30%, dispersant 1~5%, wetting agent 1~5%, are added appropriate
Water, through milling treatment of colloid into thinner slurry, then puts this slurry into sand mill and is ground, until particle diameter reaches about
At 4 microns, thickener 0.1~1.5% and antifreezing agent 1~5% are added, then is ground, defoamer 0.1~0.4% is added, and add water
To 100%, that is, it is made containing the sour copper of loose ester and the suspending agent agent of azoles alcohol.
8. containing the copper rosinate and preparation method of the suspending agent of azoles alcohol any one of claim 1-6, its step is such as
Under：
Copper rosinate suspending agent made from 10%~50% one-step method is taken, hexaconazole 3~30%, dispersant 1 is inside added
~5%, wetting agent 1~5% is put sand mill into after being well mixed and is ground, until when particle diameter reaches about 4 microns, plus
Enter thickener 0.1~1.5% and antifreezing agent 1~5%, then grind, add defoamer 0.1~0.4%；And add water quantitatively extremely
100%, that is, it is made and contains the sour copper of loose ester and the suspending agent of azoles alcohol.
9. containing the copper rosinate and preparation method of the suspending agent of azoles alcohol as claimed in claim 7 or 8, it is characterised in that：Institute
The dispersant stated is alkylnaphthalene sulfonate condensation polymer, NPE, naphthalene sulfonic acid-formaldehyde condensation product, ethoxylation castor-oil plant
One or more in oil, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether or sodium lignin sulfonate
Arbitrary proportion mixture；Described wetting agent is alkylnaphthalene sulfonate condensation polymer, polyoxyethylene aliphatic alcohol ether, nonyl phenol gather
One kind in oxygen vinethene phosphate monoester, polyoxyethylated alkyl phenol, castor oil Succinate sodium sulfonate or benzyl sodium naphthalene sulfonate
Or the mixture of several arbitrary proportions；Described thickener be xanthans, carboxylic first (second) base sodium cellulosate, methylcellulose,
The mixture of one or more of arbitrary proportions in polyvinyl alcohol or aluminium-magnesium silicate；Described antifreezing agent be ethylene glycol, propane diols,
The mixture of one or more of arbitrary proportions in glycerine or polyethylene glycol 400；Described defoamer is silicone oil, silicone
Compound, C10-20 saturated fat acid compounds, the mixture of one or more of arbitrary proportions of C8-10 fatty alcohols.
10. application of the suspending agent containing copper rosinate and hexaconazole in rice disease is prevented and treated as described in claim 1-6.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1505932A (en) * | 2002-12-12 | 2004-06-23 | 河北省农林科学院植物保护研究所 | Plant viral disease preventing and controlling agent and its prepn process |
| CN101671207A (en) * | 2009-09-23 | 2010-03-17 | 湖南大方农化有限公司 | Bactericidal yield-increase medicine fertilizer and use method thereof |
| CN101935275A (en) * | 2009-06-29 | 2011-01-05 | 孔波 | Preparation method and application of gum rosin acid copper |
| CN102405911A (en) * | 2011-10-21 | 2012-04-11 | 海利尔药业集团股份有限公司 | Sterilizing composition comrpising cyproconazole and abietic acid copper |
| CN103493805A (en) * | 2013-10-11 | 2014-01-08 | 广东植物龙生物技术有限公司 | Copper rosinate suspending agent and preparation method thereof |
-
2017
- 2017-06-21 CN CN201710472906.7A patent/CN107197869A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1505932A (en) * | 2002-12-12 | 2004-06-23 | 河北省农林科学院植物保护研究所 | Plant viral disease preventing and controlling agent and its prepn process |
| CN101935275A (en) * | 2009-06-29 | 2011-01-05 | 孔波 | Preparation method and application of gum rosin acid copper |
| CN101671207A (en) * | 2009-09-23 | 2010-03-17 | 湖南大方农化有限公司 | Bactericidal yield-increase medicine fertilizer and use method thereof |
| CN102405911A (en) * | 2011-10-21 | 2012-04-11 | 海利尔药业集团股份有限公司 | Sterilizing composition comrpising cyproconazole and abietic acid copper |
| CN103493805A (en) * | 2013-10-11 | 2014-01-08 | 广东植物龙生物技术有限公司 | Copper rosinate suspending agent and preparation method thereof |
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