CN107195606A - A kind of silicon chip back side metallized film and preparation method thereof - Google Patents

A kind of silicon chip back side metallized film and preparation method thereof Download PDF

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Publication number
CN107195606A
CN107195606A CN201710491088.5A CN201710491088A CN107195606A CN 107195606 A CN107195606 A CN 107195606A CN 201710491088 A CN201710491088 A CN 201710491088A CN 107195606 A CN107195606 A CN 107195606A
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CN
China
Prior art keywords
silicon chip
silicon
back side
metal levels
eutectic
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Pending
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CN201710491088.5A
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Chinese (zh)
Inventor
宋忠孝
唐宁
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Kunshan Hao Sheng Tai Nanometer Technology Co Ltd
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Kunshan Hao Sheng Tai Nanometer Technology Co Ltd
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Application filed by Kunshan Hao Sheng Tai Nanometer Technology Co Ltd filed Critical Kunshan Hao Sheng Tai Nanometer Technology Co Ltd
Priority to CN201710491088.5A priority Critical patent/CN107195606A/en
Publication of CN107195606A publication Critical patent/CN107195606A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/48Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
    • H01L23/488Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of soldered or bonded constructions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/48Manufacture or treatment of parts, e.g. containers, prior to assembly of the devices, using processes not provided for in a single one of the subgroups H01L21/06 - H01L21/326
    • H01L21/4814Conductive parts
    • H01L21/4821Flat leads, e.g. lead frames with or without insulating supports
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/48Manufacture or treatment of parts, e.g. containers, prior to assembly of the devices, using processes not provided for in a single one of the subgroups H01L21/06 - H01L21/326
    • H01L21/4814Conductive parts
    • H01L21/4821Flat leads, e.g. lead frames with or without insulating supports
    • H01L21/4835Cleaning, e.g. removing of solder

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

The invention discloses a kind of silicon chip back side metallized film composition and preparation method thereof, wherein silicon chip back side metallization eutectic structure, including the Ti metal levels being arranged on silicon chip, the Ta metal levels being arranged on Ti metal levels and the Au Sn alloy eutectic metal levels that are arranged on Ta metal levels.The present invention replaces the pure Au of individual layer to be used as the coat of metal of silicon chip back side by multiple layer metal, and good Ohmic contact can be formed with silicon chip;Eutectic alloy is used as by magnetron sputtering Au Sn alloy firms simultaneously, has the advantages that nontoxic, cost is low.

Description

A kind of silicon chip back side metallized film and preparation method thereof
Technical field
The present invention relates to silicon chip back side metallized film and its manufacturing process, more particularly to a kind of silicon chip back side metallization is thin Film and preparation method thereof.
Background technology
Eutectic welding technology is used widely in Electronic Packaging industry, as chip is bonding with substrate, substrate and shell Bonding, shell sealing cap etc..Compared with traditional epoxy conductive glue sticking, eutectic welding is with thermal conductivity is high, resistance is small, heat transfer Hurry up, the big advantage of shearing force after highly reliable, bonding, it is adaptable to high frequency, high power device chips and substrate, substrate and shell Interconnection.For there is the power device of higher cooling requirements must be using eutectic welding.Eutectic weldering make use of eutectic alloy Characteristic completes welding procedure.
Eutectic alloy has following characteristic:(I) it is lower than pure constituent element fusing point, simplify melting process;(2) eutectic alloy is than pure Metal has more preferable mobility, can prevent from hindering the dendrite of liquid flowing to be formed in solidification, so as to improve casting character; (3) isothermal transformation (no solidification temperature range) reduces casting flaw, such as segregation and shrinkage cavity;(4) eutectic freezing can obtain a variety of The microscopic structure of form, especially regularly arranged stratiform or shaft-like eutectic structure can turn into the In-situ reaction material of excellent properties Material.
Eutectic refers to that the phenomenon of eutectic thing fusion occurs for eutectic solder at relatively low temperature, eutectic alloy directly from Solid-state changes to liquid, and without the plastic stage.Its fusion temperature claims eutectic temperature.
Usually used back face metalization eutectic technology is used as metal plating layer on back with proof gold, by annealing process come real The eutectic alloy of existing back metal.Proof gold price is again extremely expensive, and reliability is not high, although have patent using evaporation Ti/Ni/ The technology of Au-Sn alloys, but be due to that adhesive force is low and can not stop the diffusion of Au-Sn and silicon very well, so not being very Desirable process program.
The content of the invention
In order to overcome drawbacks described above, the invention provides a kind of silicon chip back side metallized film and preparation method thereof.
The technical scheme that is used to solve its technical problem of the present invention is:A kind of silicon chip back side metallized film and its Preparation method, including the metallization eutectic structure of silicon chip back side is arranged on, the metallization eutectic structure is by being arranged on silicon chip Ti metal levels, the Ta metal levels being arranged on Ti metal levels and the Au-Sn alloy eutectic metals being arranged on Ta metal levels Layer composition.
As a further improvement on the present invention, in addition to be arranged on Au-Sn alloy eutectics metal level (4) on Au metal levels (5)。
A kind of preparation method of silicon chip back side metallized film, it is characterised in that:Comprise the following steps:
1. will be thinned after silicon chip be put into etching tank, by silicon corrode and silicon dioxide etching method to be thinned after silicon chip Cleaned;
2. the silicon chip after cleaning is sent into and radio frequency plasma reverse sputtering cleaning is carried out in magnetic-controlled sputtering coating equipment, then successively splashed Penetrate Ti, Ta, Au-Sn and Au film.
As a further improvement on the present invention, the method for silicon corrosion and silicon dioxide etching is specially in the step:Make With passing through 1:20 HF erodes the silicon dioxide layer of presence;Finally bath is dried.
A kind of preparation method of silicon chip back side metallized film, it is characterised in that:Comprise the following steps:
1. will be thinned after silicon chip be put into etching tank, by silicon corrode and silicon dioxide etching method to be thinned after silicon chip Cleaned;
2. the silicon chip after cleaning is sent into and radio frequency plasma reverse sputtering cleaning is carried out in magnetic-controlled sputtering coating equipment, then successively splashed Penetrate Ti, Ta, Au-Sn and Au film.
The beneficial effects of the invention are as follows:The present invention replaces the gold-arsenic alloy or proof gold of individual layer to be used as by multiple layer metal The coat of metal of silicon chip back side, can form good Ohmic contact with silicon chip;Eutectic is produced by the evaporation of Sn-Au alloys simultaneously Alloy, has the advantages that nontoxic, cost is low.
Brief description of the drawings
Fig. 1 is schematic structural view of the invention;
Indicated in figure:1- silicon chips;2-Ti metal levels;3-Ta metal levels;4-Au-Sn alloy eutectic metal levels;5-Au metal levels.
Embodiment
In order to deepen the understanding of the present invention, below in conjunction with embodiment and accompanying drawing, the invention will be further described, should Embodiment is only used for explaining the present invention, is not intended to limit the scope of the present invention..
Fig. 1 shows a kind of a kind of embodiment of silicon chip back side metallized film of the invention, including is arranged on the silicon chip back of the body The metallization eutectic structure in face, the metallization eutectic structure by be arranged on silicon chip 1 Ti metal levels 2, be arranged on Ti metals Ta metal levels 3 and the Au-Sn alloy eutectics metal level 4 that is arranged on Ta metal levels 3 on layer 2 are constituted, in addition to are arranged on Au metal levels 5 on Au-Sn alloy eutectics metal 4.
Embodiment 1
The silicon chip back side metallization eutectic structure of the present embodiment, including the Ti metal levels being arranged on silicon chip I, are arranged on Ti metals Ta metal levels 3 and the Au-Sn alloy eutectics metal level 4 that is arranged on Ta metal levels 3 on layer 2.
The manufacturing process of the silicon chip back side metallization eutectic structure of the present embodiment, comprises the following steps:
1. will be thinned after silicon chip I be put into etching tank, by silicon corrode and silicon dioxide etching method to be thinned after silicon Piece I is cleaned.Silicon corrodes and the method for silicon dioxide etching is specially:Use 1:20 HF erodes what be there may exist Silicon dioxide layer
2. the silicon chip after cleaning is sent into and radio frequency plasma reverse sputtering cleaning is carried out in magnetic-controlled sputtering coating equipment, then successively splashed Ti, Ta, Au-Sn and Au film are penetrated, Au-Sn alloys there can also be the conjunction of similarity using Au-Si etc. with Au-Sn alloys Gold.
Illustrate:Using four cun of silicon wafers, the silicon chip for being thinned to 210 microns is carried out using HF-HN03 mixed acid The back side is corroded, and corrosion to silicon wafer thickness is 200 ± 20 microns, and I is used after cleaning:20 HF acid solutions are further cleaned, and bath is got rid of Magnetic-controlled sputtering coating equipment is sent into after dry.Cleaned using 500W radio frequency plasmas, magnetron sputtering skill is then used successively Art is deposited with metal membrane:First layer Ti;It is 1000 ± 80 A to control thickness;Second layer Ta, control thickness for 1500 ± 150 A;Third layer Au-Sn alloys, it is 5000 ± 500A to control thickness.
Embodiment 2
The present embodiment silicon chip back side metallization eutectic structure, including be arranged on silicon chip Ti metal levels 2, be arranged on Ti metals Ta metal levels 3, the Au-Sn alloy eutectics metal level 4 that is arranged on Ta metal levels 3 on layer 2 and it is arranged on Au-Sn alloys Au metal levels 5 on eutectic metal level 4.
The manufacturing process of the silicon chip back side metallization eutectic structure of the present embodiment, comprises the following steps:
1. will be thinned after silicon chip be put into etching tank, by silicon corrode and silicon dioxide etching method to be thinned after silicon chip I is cleaned.Silicon corrodes and the method for silicon dioxide etching is specially:Use 1:20 HF erodes there may exist two Silicon oxide layer;
2. the silicon chip after cleaning is sent into and radio frequency plasma reverse sputtering cleaning is carried out in magnetic-controlled sputtering coating equipment, then successively splashed Ti, Ta, Au-Sn and Au film are penetrated, Au-Sn alloys there can also be the conjunction of similarity using Au-Si etc. with Au-Sn alloys Gold.
Illustrate:Using six cun of silicon wafers, 230 microns of silicon chips will be thinned to and carry out the back side with HF-HN03 mixed acid Corrosion, corrosion to silicon wafer thickness is 225 ± 20 microns, and I is used after cleaning:20 HF acid solutions are further cleaned, and bath is dried After send into magnetic-controlled sputtering coating equipment.Cleaned using 500W radio frequency plasmas, magnetron sputtering technique is then used successively Deposition is with metal membrane:First layer Ti;It is 2000 ± 200 A to control thickness;Second layer Ta, it is 1000 ± 100 to control thickness A;Third layer Au-Sn alloys, it is 3000 ± 500A to control thickness.4th layer of Au, it is 1000 ± 100A to control thickness.
Particular embodiments described above, has been carried out further in detail to the purpose of the present invention, technical scheme and beneficial effect Describe in detail it is bright, should be understood that the foregoing is only the present invention specific embodiment, be not intended to limit the invention, it is all Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements done etc., should be included in the guarantor of the present invention Within the scope of shield.

Claims (5)

1. a kind of silicon chip back side metallized film, it is characterised in that:Metallization eutectic structure including being arranged on silicon chip back side, institute Metallization eutectic structure is stated by the Ti metal levels (2) being arranged on silicon chip (1), the Ta metal levels being arranged on Ti metal levels (2) (3) and be arranged on Ta metal levels (3) Au-Sn alloy eutectic metal levels (4) composition.
2. silicon chip back side metallized film according to claim 1, it is characterised in that:Also include being arranged on Au-Sn alloys Au metal levels (5) on eutectic metal (4).
3. a kind of preparation method of silicon chip back side metallized film, it is characterised in that:Comprise the following steps:
1. will be thinned after silicon chip be put into etching tank, by silicon corrode and silicon dioxide etching method to be thinned after silicon chip Cleaned;
2. the silicon chip after cleaning is sent into and radio frequency plasma reverse sputtering cleaning is carried out in magnetic-controlled sputtering coating equipment, then successively splashed Penetrate Ti, Ta, Au-Sn and Au film.
4. a kind of preparation method of silicon chip back side metallized film according to claim 3, it is characterised in that:The step Middle silicon corrosion and the method for silicon dioxide etching are specially:Using passing through 1:20 HF erodes the silicon dioxide layer of presence;Most Bath is dried afterwards.
5. a kind of preparation method of silicon chip back side metallized film, it is characterised in that:Comprise the following steps:
1. will be thinned after silicon chip be put into etching tank, by silicon corrode and silicon dioxide etching method to be thinned after silicon chip Cleaned;
2. the silicon chip after cleaning is sent into and radio frequency plasma reverse sputtering cleaning is carried out in magnetic-controlled sputtering coating equipment, then successively splashed Penetrate Ti, Ta, Au-Sn and Au film.
CN201710491088.5A 2017-06-26 2017-06-26 A kind of silicon chip back side metallized film and preparation method thereof Pending CN107195606A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108389804A (en) * 2018-02-28 2018-08-10 中国电子科技集团公司第十三研究所 The sintering method of GaN chips and GaN chips to be sintered
CN110783292A (en) * 2020-01-02 2020-02-11 南京市产品质量监督检验院 Silicon wafer back metallization structure and manufacturing process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103094170A (en) * 2011-11-07 2013-05-08 英飞凌科技股份有限公司 Method for separating a plurality of dies and a processing device for separating a plurality of dies
CN103963375A (en) * 2013-01-30 2014-08-06 苏州同冠微电子有限公司 Silicon wafer back side metallized eutectic structure and manufacturing process thereof
CN104299922A (en) * 2014-11-03 2015-01-21 苏州同冠微电子有限公司 Back metallization eutectic process method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103094170A (en) * 2011-11-07 2013-05-08 英飞凌科技股份有限公司 Method for separating a plurality of dies and a processing device for separating a plurality of dies
CN103963375A (en) * 2013-01-30 2014-08-06 苏州同冠微电子有限公司 Silicon wafer back side metallized eutectic structure and manufacturing process thereof
CN104299922A (en) * 2014-11-03 2015-01-21 苏州同冠微电子有限公司 Back metallization eutectic process method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108389804A (en) * 2018-02-28 2018-08-10 中国电子科技集团公司第十三研究所 The sintering method of GaN chips and GaN chips to be sintered
CN110783292A (en) * 2020-01-02 2020-02-11 南京市产品质量监督检验院 Silicon wafer back metallization structure and manufacturing process thereof
WO2021136222A1 (en) * 2020-01-02 2021-07-08 南京市产品质量监督检验院 Silicon wafer back metallization structure and manufacturing process therefor

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Application publication date: 20170922