CN107191943A - Incineration disposal draff processing method - Google Patents

Incineration disposal draff processing method Download PDF

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Publication number
CN107191943A
CN107191943A CN201710283327.8A CN201710283327A CN107191943A CN 107191943 A CN107191943 A CN 107191943A CN 201710283327 A CN201710283327 A CN 201710283327A CN 107191943 A CN107191943 A CN 107191943A
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China
Prior art keywords
incineration disposal
zinc
slag
waste
processing method
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CN201710283327.8A
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CN107191943B (en
Inventor
张海云
宋玉林
黄博
廖庭
廖一庭
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Shaoguan Green Renewable Resources Development Co Ltd
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Shaoguan Green Renewable Resources Development Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00Obtaining zinc or zinc oxide
    • C22B19/20Obtaining zinc otherwise than by distilling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/001Dry processes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/30Solid combustion residues, e.g. bottom or flyash
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Engineering & Computer Science (AREA)
  • Processing Of Solid Wastes (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention provides a kind of incineration disposal draff processing method, pending incineration disposal residue is mixed to prepare baking mixes with processing auxiliary agent, containing any one or a few element in iron, three kinds of elements of silicon and calcium in the processing auxiliary agent, make the ratio of weight and number of iron in the baking mixes, three kinds of elements of silicon and calcium as follows:Iron:Silicon:Calcium=(11~43):(11~22):(3.5~18);The baking mixes are put into high-temperature roasting reduction volatilization processing is carried out in rotary kiln, glassy solids kiln slag is made in slag cooling.Above-mentioned incineration disposal draff processing method, iron, three kinds of elements of silicon and calcium are in certain ratio range in baking mixes, so that after roasting reduction processing obtains slag cooling, glassy solids kiln slag is made, the glassy solids belong to general discarded object, can be directly as cement producting material.The cement raw material using high price is avoided, the processing cost of incineration disposal residue is greatly reduced.

Description

Incineration disposal draff processing method
Technical field
The present invention relates to hazardous waste innoxious process for treating field, more particularly to incineration disposal draff processing method.
Background technology
Incineration disposal residue exists《National dangerous waste register》Dangerous waste classification is HW18 in (the Environmental Protection Department portion of order makes No. 39), The bottom ash that the disposal process such as domestic garbage incineration flyash, danger from environmental improvement industry are burned, pyrolysis are produced was waited The non-glass state material and flying dust produced in journey, dangerous special efficacy is:Toxicity.
The processing method of traditional incineration disposal residue mainly passes through cement solidification-dangerous waste landfill yard.At this burning Put draff processing method and need to consume substantial amounts of cement and it is solidified, landfill needs to take the larger space of landfill yard after solidification, Processing cost and maintenance cost are high.
The content of the invention
Based on this, it is necessary to which for the high technical problem of traditional incineration disposal residue treatment process costs, there is provided one Plant incineration disposal draff processing method.
A kind of incineration disposal draff processing method that the present invention is provided, wherein, it the treating method comprises following steps:
Pending incineration disposal residue is mixed to prepare in baking mixes, the processing auxiliary agent with processing auxiliary agent and contained Any one or a few element in iron, three kinds of elements of silicon and calcium, makes iron in the baking mixes, three kinds of elements of silicon and calcium Ratio of weight and number is as follows:Iron:Silicon:Calcium=(11~43):(11~22):(3.5~18);
The baking mixes are put into rotary kiln and carry out being made molten after roasting reduction volatilization processing, reduction volatilization metal Slag;
The slag is cooled and solidified, glassy solids kiln slag is made.
In one of the embodiments, iron described in the baking mixes, the total content of three kinds of elements of silicon and calcium are 25.5~83%.
In one of the embodiments, the processing auxiliary agent includes steel mill gas ash, steel mill sack dust, zinc abstraction mistake Goethite slag, the lead-zinc smelting produced in the iron vitriol slag that is produced in the leached mud that is produced in journey, zinc metallurgical process, zinc metallurgical process Fuel treatment thing that Water Quenching Slag that treatment of sewage slag in production process, lead-zinc smelting are produced, lead-zinc smelting are produced,《Country is useless Name is recorded》Waste classification for HW17 surface treatment waste,《National waste register》Waste classification for HW23 waste containing zinc with And《National waste register》Waste classification is any one or a few in HW48 non-ferrous metal waste.
In one of the embodiments, the surface treatment waste is utilising zinc containing waste residue and wastewater treatment sludge;
The non-ferrous metal waste is containing iron, three kinds of elements of silicon and calcium any one or a few non-ferrous metal wastes;
The zinc-containing dust that the waste containing zinc is collected for the sack cleaner in Treatment of Metal Surface and heat treatment process.
In one of the embodiments, the baking mixes also include material containing zinc.
In one of the embodiments, roasting reduction agent is also included in the baking mixes.
In one of the embodiments, the roasting reduction agent includes any one or a few in carbon dust, coal, coke.
In one of the embodiments, the roasting reduction processing includes roasting preheating band, calcination band and is calcined cold But band;The temperature of the calcination band is 1100~1250 DEG C.
In one of the embodiments, it is further comprising the steps of:
The flue gas that roasting reduction processing is produced is handled by collection, obtains rich metal oxide products.
In one of the embodiments, it is further comprising the steps of:
The glassy solids are handled by ore dressing, rich metal product is obtained.
Above-mentioned incineration disposal draff processing method, using existing rotary kiln, by by incineration disposal residue with containing iron, The processing auxiliary agent mixing of any one or a few element in three kinds of elements of silicon and calcium so that iron, silicon and calcium in baking mixes Three kinds of elements are in certain ratio range, so that after roasting reduction processing obtains slag cooling, glassy solids are made Kiln slag, the glassy solids belong to general discarded object, can be directly as cement producting material.Avoid the cement raw using high price Material, greatly reduces the processing cost of incineration disposal residue.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, by the following examples, to the present invention Incineration disposal draff processing method be further elaborated.It should be appreciated that specific embodiment described herein is only used To explain the present invention, it is not intended to limit the present invention.
The incineration disposal draff processing method that the present invention is provided, comprises the following steps:
Step one:Pending incineration disposal residue is mixed to prepare baking mixes with processing auxiliary agent, wherein, handle auxiliary agent In containing any one or a few element in iron, three kinds of elements of silicon and calcium, make iron in baking mixes, three kinds of elements of silicon and calcium Parts by weight it is as follows:
Iron:Silicon:Calcium=(11~43):(11~22):(3.5~18);
Step 2:Baking mixes are put into rotary kiln and made after roasting reduction volatilization processing, reduction volatilization metal Obtain slag;
Step 3:Slag is cooled and solidified, glassy solids kiln slag is made.
The incineration disposal draff processing method of the present invention, property and treatment characteristic based on Chinese incineration disposal residue, from Incineration disposal residue treatment, using being taken in terms of the recycling and effect on environment of technology, both in view of burning The feasibility that disposal residue as resources is utilized is burnt, and optimal equalization point is have found in financial cost and environmental protection, is utilized Existing rotary kiln handles incineration disposal residue, it is to avoid using the cement raw material of high price, greatly reduce incineration disposal residue Processing cost;Limited standard can not only be reached by making the environmental characteristics of incineration disposal residue treatment product, additionally it is possible to right Processing product is used, and greatly reduces processing cost and improves the utilization rate of product.
Using existing rotary kiln, by by incineration disposal residue with containing any one in iron, three kinds of elements of silicon and calcium Plant or the processing auxiliary agent of several elements is mixed so that iron, three kinds of elements of silicon and calcium are in certain ratio range in baking mixes It is interior, so as to obtain slag by roasting reduction volatilization processing.Slag is the product of roasting reduction processing, is various oxides and gold Category formation compound, eutectic, melt of solid solution under the conditions of certain temperature, its component main source treating material, i.e., Incineration disposal residue and processing auxiliary agent.The property of slag is often depending on the component for the treatment of material, the thawing for the treatment of material Speed, metal ingredient and slag separation degree are production technology economic indicators.
After slag cooling, glassy solids kiln slag is made, glassy solids (being similar to fayalite) belong to general discarded Thing, can directly be discharged, and reach innoxious requirement.Heavy metal (such as copper, iron, lead, cadmium, chromium) in incineration disposal residue can be It is stabilized for a long time in glassy solids, can also avoids the secondary pollution to environment from destroying.In addition, glassy solids can be with As cement producting material, its recycling can be realized.
Further, by make iron in baking mixes, three kinds of elements of silicon and calcium ratio of weight and number be iron:Silicon:Calcium= (11~43):(11~22):(3.5~18), can make the slag fusing point after calcination process be less than 1150 DEG C, relatively low fusing point can To reduce the consumption of roasting reduction agent and provide suitable processing speed.
Further, CaO-FeO-SiO is formed after roasting2Ternary system slag type, the physicochemical properties of the ternary system slag type, Viscosity, density, melting temperature, surface tension etc. can be adapted to the enriching and recovering of heavy metal and form stabilized glass State solid, and stabilized glassy solids can be such that heavy metal therein is stable in the presence of wherein, it is to avoid and its release is caused Secondary pollution.For example, the viscosity that CaO-FeO-SiO2 ternary system slag types are formed after roasting is preferably 1~2PaS, the viscosity model Enclose and ensure that the good mobility of slag, slag is smoothly discharged from rotary kiln and be easy to cooling and solidifying.Alternatively, cool down Solidification can be using water cooling solidification.
As a kind of optional embodiment, iron in baking mixes, the total content of three kinds of elements of silicon and calcium for 25.5~ 83%.
Iron, three kinds of constituent contents of silicon and calcium and ratio are that influence incineration disposal draff processing method is every in baking mixes The shape of the important parameter of technology, economic indicator, such as rate of recovery of influence metal, the consumption of roasting reduction agent and glassy solids Into.When the total content of iron in baking mixes, three kinds of elements of silicon and calcium is 25.5~83%, it can be ensured that glassy solids The rate of recovery of metal, the consumption of roasting reduction agent are formed and controlled in suitable scope.
As a kind of optional embodiment, above-mentioned processing auxiliary agent can be selected from steel mill gas ash, steel mill sack dust, zinc Goethite slag, the lead produced in the iron vitriol slag that is produced in the leached mud that is produced in smelting process, zinc metallurgical process, zinc metallurgical process The fuel treatment thing that treatment of sewage slag, the Water Quenching Slag of lead-zinc smelting generation, lead-zinc smelting are produced in zinc abstraction production process, 《National waste register》Waste classification for HW17 surface treatment waste,《National waste register》Waste classification is coloured for HW48's Metal waste and《National waste register》Waste classification is any one or a few in HW23 waste containing zinc.
Further, surface treatment waste is utilising zinc containing waste residue and wastewater treatment sludge;Non-ferrous metal waste is to contain iron, silicon And three kinds of elements of calcium any one or a few non-ferrous metal wastes;Waste containing zinc is in Treatment of Metal Surface and heat treatment process Sack cleaner collect zinc-containing dust.
Wherein, in the leached mud that is produced in steel mill gas ash, steel mill sack dust, zinc metallurgical process, zinc metallurgical process Treatment of sewage slag, lead zinc smelting in the goethite slag that is produced in the iron vitriol slag of generation, zinc metallurgical process, lead-zinc smelting production process Refine fuel treatment thing and non-ferrous metal waste that the Water Quenching Slag produced, lead-zinc smelting produce be pending discarded object, it is necessary to Further it could discharge or fill after processing.On the one hand the incineration disposal draff processing method of the present invention can handle incineration disposal Residue, on the one hand using elements such as the iron in above-mentioned discarded object, silicon, calcium, on the other hand can also be assisted to above-mentioned discarded object With processing, treatment effeciency and value are substantially increased.
As a kind of optional embodiment, the baking mixes also include material containing zinc.Further, material containing zinc can To be solid containing zinc, dangerous waste containing zinc.
Zinc reduction volatilization method handling process, is widely used in the various solids containing zinc of processing, dangerous waste containing zinc.Its technical process is to contain In zinc material match somebody with somebody powdered carbon, into rotary kiln in high-temperature roasting reduction treatment.Metal oxide in material containing zinc, is such as aoxidized Zinc, lead oxide etc. are contacted with powdered carbon, are reduced into metal vapors and are entered gas phase, are oxidized to metal oxidation again in the gas phase Thing, and be together captured down with flue gas into dust collecting system.
Solid containing zinc, often there is the oxidations of the multiple elements such as zinc, lead, tin, indium, iron, calcium, silicon in dangerous waste containing zinc simultaneously Thing, the metal oxide such as zinc therein, lead, tin, indium is reduced into metallic vapour in roasting reduction processing and enters gas phase, in gas Metal oxide is oxidized in phase again, and is captured down with the logical dust collecting system that enters of flue gas one;Iron therein, calcium, silicon, Sulfonium, other not volatile heavy metals (silver, copper etc.) and corresponding oxide are stayed in slag.
The incineration disposal draff processing method of the present invention cooperates with progress with zinc reduction volatilization method handling process, can be simultaneously real The recovery of processing and the zinc reduction volatilization of existing incineration disposal residue, does not influence therebetween its original processing or reclaims effect Really, in addition, zinc reduction volatilization again can there is provided institute as the processing auxiliary agent of incineration disposal residue treatment using the composition as slag Part heavy metal in iron, silicon and the calcium constituent needed, incineration disposal residue can be also collected by reduction volatilization method is subject to resource Change and utilize, it is to avoid the influence that heavy metal long-term existence is likely to result in environment.By incineration disposal draff processing method and zinc also The collaboration of former volatility process handling process is carried out, and can greatly improve the treatment effeciency of the two, reduces processing cost, and realize zinc also The comprehensive utilization of former volatility process handling process kiln slag.
Alternatively, the kiln slag fusing point after calcination process is less than 1150 DEG C, can provide suitable for zinc reduction volatilization handling process Suitable reduction volatilization speed, is conducive to the recovery of zinc.
As a kind of optional embodiment, also include roasting reduction agent in baking mixes.Alternatively, roasting reduction agent can With the one or more in carbon dust, coal, coke.Roasting reduction agent provides reducing material for roasting reduction processing, can make roasting Reduction reaction is smoothed out.
In other embodiments, roasting reduction agent can also be put into rotary kiln respectively with baking mixes.
As a kind of optional embodiment, pending incineration disposal residue, according to material proportion, passes through machine with processing auxiliary agent Tool batch mixing puts into baking mixes in rotary kiln after belt bed of material cloth.
As a kind of optional embodiment, roasting reduction processing includes roasting preheating band, calcination band and roasting cooling Band, the wherein temperature of calcination band are 1100~1250 DEG C.The temperature of calcination band is able to ensure that the smooth of calcination Carry out, the metal oxide in baking mixes is reduced into metallic vapour and enter gas phase, and can ensure that various oxygen in kiln slag Compound and metal form compound, eutectic, the melt of solid solution under the temperature conditionss.Alternatively, by adjusting roasting also The additive of former agent, the total amount of baking mixes and its roasting preheating band, calcination band and be calcined cooling zone delay Time-controllable roasting reduction volatilization treatment progress.Alternatively, it is mainly anti-according to material lagging time, calcination band temperature control Answer process.
As a kind of optional embodiment, incineration disposal draff processing method of the invention is further comprising the steps of:It is described The flue gas that roasting reduction processing is produced is handled by collection, obtains rich metal oxide products.To realize to incineration disposal residue And the volatile metal recovery in processing auxiliary agent is utilized.Rich metal oxide products mainly include volatile in baking mixes Metal, such as zinc, lead, tin, antimony, indium.Rich metal oxide products mainly include volatile metal quilt in baking mixes Carbon reduction volatilization is in gas phase flue gas.Flue gas is collected by cooling down collection and sack cleaner or electric cleaner and obtains containing for enrichment Zinc product, available for zinc and the raw material of other Metal Productions.Tail gas is after desulfurization and electric demisting eliminate Organic aerosol processing Qualified discharge.
As a kind of optional embodiment, incineration disposal draff processing method of the invention is further comprising the steps of:By institute State glassy solids to handle by ore dressing, obtain rich metal product.Rich metal product is mainly included and derived from baking mixes Not volatile metal, such as iron, copper, available for iron, the raw materials for production of copper or auxiliary material slag former.It is residual to incineration disposal to realize Not volatile metal recovery is utilized in slag and processing auxiliary agent.Further, the tailings of ore dressing processing can act on production silicate The raw material of cement.
Embodiment 1
Pending incineration disposal in constituent analysis, the present embodiment is carried out to pending incineration disposal residue and processing auxiliary agent residual Slag is flying ash, the processing auxiliary agent of selection be the Water Quenching Slag that leached mud, the lead-zinc smelting produced in zinc metallurgical process is produced and Steel mill gas ash;The charge ratio of incineration disposal residue and each processing auxiliary agent is calculated according to composition analysis result, will by charge ratio With processing auxiliary agent, by mechanical mixture, baking mixes are made in pending flying ash, in the present embodiment composition analysis result and Charge ratio is as shown in table 1.
Turned round after baking mixes are mixed with roasting reduction agent by putting into baking mixes after belt bed of material cloth Roasting reduction processing is carried out in kiln.The total length of the rotary kiln of the present embodiment is 48 meters, and wherein roasting preheating strip length is 12 meters, Residence time of material is 15~30 minutes;Calcination strip length be 32 meters, temperature be 1250 DEG C, residence time of material be 40~ 80 minutes;Cooling zone, roasting cooling strip length is 4 meters, and residence time of material is 4~8 minutes, and slag is made.Baking mixes In volatile metal-zinc, lead, tin, antimony, indium etc. by carbon reduction volatilization in gas phase flue gas.Flue gas is collected and cloth by cooling down What bag dust collector or electric cleaner collection acquisition were enriched with contains zinc product, available for zinc and the raw material of other Metal Productions, wherein containing The composition of zinc product is as shown in table 1.Tail gas qualified discharge after desulfurization and electric demisting eliminate Organic aerosol processing.Roasting is mixed Difficult volatilized metal-iron, silver, copper etc. form simple substance or sulfonium in compound and oxidation state is present in slag.
By the slag discharge rotary kiln cooling by water solidification of molten state, glassy solids kiln slag is made.Wherein,
The composition of glassy solids kiln slag is as shown in table 1.
The input and output component list of the embodiment 1 of table 1
Wherein, middle product are that high-temperature flue gas enters the precipitum in cooling procedure before sack cleaner, alternatively, are first settled Middle product containing zinc it is relatively low, can return to dispensing processing.
Embodiment 2
To handle incineration disposal residue with embodiment identical processing method, difference is different in the material of supplying, The pending incineration disposal residue selected in the present embodiment be bottom ash, processing auxiliary agent be zinc metallurgical process in produce leached mud, The iron vitriol slag and treatment of sewage slag produced in zinc metallurgical process, goes back crude fuel coke;The input and output composition of embodiment 2 Table is as shown in table 2.
The input and output component list of the embodiment 2 of table 2
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed, but simultaneously Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention Protect scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (10)

1. a kind of incineration disposal draff processing method, it is characterised in that the treating method comprises following steps:
Pending incineration disposal residue is mixed to prepare in baking mixes, the processing auxiliary agent with processing auxiliary agent and contains iron, silicon And any one or a few element in three kinds of elements of calcium, make iron in the baking mixes, the weight of three kinds of elements of silicon and calcium Portion rate is as follows:
Iron:Silicon:Calcium=(11~43):(11~22):(3.5~18);
The baking mixes are put into rotary kiln and carry out that slag is made after roasting reduction volatilization processing, reduction volatilization metal;
The slag is cooled and solidified, glassy solids kiln slag is made.
2. incineration disposal draff processing method according to claim 1, it is characterised in that described in the baking mixes Iron, the total content of three kinds of elements of silicon and calcium are 25.5~83%.
3. incineration disposal draff processing method according to claim 1, it is characterised in that the processing auxiliary agent includes steel-making The iron vitriol slag that is produced in the leached mud that is produced in factory's gas ash, steel mill sack dust, zinc metallurgical process, zinc metallurgical process, zinc smelting Treatment of sewage slag, lead-zinc smelting are produced in the goethite slag that is produced during refining, lead-zinc smelting production process Water Quenching Slag, lead The fuel treatment thing of zinc abstraction generation,《National waste register》Waste classification for HW17 surface treatment waste,《National waste name Record》Waste classification for HW23 waste containing zinc in and《National waste register》Waste classification is in HW48 non-ferrous metal waste Any one or a few.
4. incineration disposal draff processing method according to claim 3, it is characterised in that the surface treatment waste be containing Zinc waste residue and wastewater treatment sludge;
The non-ferrous metal waste is containing iron, three kinds of elements of silicon and calcium any one or a few non-ferrous metal wastes;
The zinc-containing dust that the waste containing zinc is collected for the sack cleaner in Treatment of Metal Surface and heat treatment process.
5. incineration disposal draff processing method according to claim 1, it is characterised in that the baking mixes also include Material containing zinc.
6. incineration disposal draff processing method according to claim 1, it is characterised in that also wrapped in the baking mixes Include roasting reduction agent.
7. incineration disposal draff processing method according to claim 6, it is characterised in that the roasting reduction agent includes carbon Any one or a few in powder, coal, coke.
8. the incineration disposal draff processing method according to claim 1 to 7 any one, it is characterised in that the roasting Reduction treatment includes roasting preheating band, calcination band and roasting cooling zone;The temperature of the calcination band be 1100~ 1250℃。
9. incineration disposal draff processing method according to claim 8, it is characterised in that further comprising the steps of:
The flue gas that roasting reduction processing is produced is handled by collection, obtains rich metal oxide products.
10. incineration disposal draff processing method according to claim 8, it is characterised in that further comprising the steps of:
The glassy solids are handled by ore dressing, rich metal product is obtained.
CN201710283327.8A 2017-04-26 2017-04-26 Incineration disposal draff processing method Active CN107191943B (en)

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CN108043859A (en) * 2017-12-01 2018-05-18 中广核研究院有限公司 A kind of domestic garbage incineration flyash innocuity disposal system and method
CN108411113A (en) * 2018-03-01 2018-08-17 浙江申联环保集团有限公司 A kind of resource regeneration method of hazardous waste
CN109706327A (en) * 2018-12-28 2019-05-03 焱鑫环保科技有限公司 A kind of method of harmlessness disposing beryllium slag
CN112439492A (en) * 2020-11-04 2021-03-05 大江环境股份有限公司 Residue solidification stabilizing method and equipment

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CN105817459A (en) * 2016-01-08 2016-08-03 上海市固体废物处置中心 Method for treating hazardous waste incineration bottom ash by using plasma technology
CN105921483A (en) * 2016-04-29 2016-09-07 义马环保电力有限公司 Environment-friendly treatment system and method for fly ash of household garbage power generating station
CN106396410A (en) * 2016-08-29 2017-02-15 中国恩菲工程技术有限公司 Production method of microcrystalline glass

Cited By (5)

* Cited by examiner, † Cited by third party
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CN108043859A (en) * 2017-12-01 2018-05-18 中广核研究院有限公司 A kind of domestic garbage incineration flyash innocuity disposal system and method
CN108411113A (en) * 2018-03-01 2018-08-17 浙江申联环保集团有限公司 A kind of resource regeneration method of hazardous waste
CN109706327A (en) * 2018-12-28 2019-05-03 焱鑫环保科技有限公司 A kind of method of harmlessness disposing beryllium slag
CN109706327B (en) * 2018-12-28 2021-06-11 焱鑫环保科技有限公司 Method for harmlessly treating beryllium slag
CN112439492A (en) * 2020-11-04 2021-03-05 大江环境股份有限公司 Residue solidification stabilizing method and equipment

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