CN107190500A - 一种柔软击剑运动金属衣面料用导电纱制备方法 - Google Patents

一种柔软击剑运动金属衣面料用导电纱制备方法 Download PDF

Info

Publication number
CN107190500A
CN107190500A CN201710423101.3A CN201710423101A CN107190500A CN 107190500 A CN107190500 A CN 107190500A CN 201710423101 A CN201710423101 A CN 201710423101A CN 107190500 A CN107190500 A CN 107190500A
Authority
CN
China
Prior art keywords
copper wire
yarn
fasciated yarn
copper
soft
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710423101.3A
Other languages
English (en)
Inventor
袁明富
刘若华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Danyang Sporting Goods Co Ltd
Original Assignee
Danyang Sporting Goods Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Danyang Sporting Goods Co Ltd filed Critical Danyang Sporting Goods Co Ltd
Priority to CN201710423101.3A priority Critical patent/CN107190500A/zh
Publication of CN107190500A publication Critical patent/CN107190500A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/12—Threads containing metallic filaments or strips
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/38—Threads in which fibres, filaments, or yarns are wound with other yarns or filaments, e.g. wrap yarns, i.e. strands of filaments or staple fibres are wrapped by a helically wound binder yarn
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

本发明公开了一种柔软击剑运动金属衣面料用导电纱制备方法，涉及纺织材料技术领域，包括如下步骤：以直径为50μm的紫铜丝为导电丝原料；以80D涤纶长丝纱为芯纱，通过并捻机将紫铜丝包缠在芯纱外层；将包缠纱放入铜减量溶液中浸泡处理，控制紫铜丝直径减少至30μm为止；用去离子水清洗；清洗后进行紫铜丝表面的化学镀银或锡处理；烘干后沿轴向滚压压扁，制成的细度小、柔软性良好的导电包缠纱。本发明制成的导电包缠纱可用于织造击剑运动金属衣导电面料，可降低其厚度，改善其柔软性。

Description

一种柔软击剑运动金属衣面料用导电纱制备方法
技术领域
本发明涉及纺织材料技术领域，具体涉及一种柔软击剑运动金属衣面料用导电纱制备方法。
背景技术
自从1896年击剑运动成为奥运会比赛项目以来，击剑运动的普及性越来越广，参与人数近年来更是呈现出爆发式增长。为此，针对击剑防护金属衣的研发工作也得到越来越多的关注。与此同时，击剑防护金属衣技术的进步也成为击剑这项高危险、强对抗的竞技运动稳步发展的重要助力。
目前金属丝型击剑导电运动金属衣面料使用的导电材料为镀锡磷铜丝，将镀锡后的磷铜丝与非导电芯纱如棉纱，锦纶纱或涤纶纱缠绕后，制成导电纱，再将这种导电纱与非导电纱线作为经纬纱线，以一定的间隔进行织造，制成导电的击剑运动金属衣面料。
磷铜丝为铜/锡合金，锡的含量为10～15％，这种铜合金延展性较好，所以在各种铜及其合金中，磷铜丝可以做的最细，紫铜丝最低可做到50微米，但由于磷铜含10～15％的锡，相比紫铜(纯铜)，磷铜导电率下降，丝的硬度也提高。
市场上击剑运动金属衣使用的磷铜丝直径最细的一般为35微米，大多为40微米及以上，硬度较大；使得最终制成的导电包缠纱柔软性差，导电性也不及同样细度的紫铜丝。最终制成的面料手感柔软性不理想，穿着时变形能力差，影响运动灵活性。
发明内容
为解决上述技术问题，本发明提供一种柔软击剑运动金属衣面料用导电纱制备方法，本发明制成的导电包缠纱可用于织造击剑运动金属衣导电面料，可降低其厚度，改善其柔软性。
为了解决上述技术问题，本发明采用如下技术方案：
一种柔软击剑运动金属衣面料用导电纱制备方法，以直径为50μm的紫铜丝为导电丝原料，包括下列步骤：
a、以80D涤纶长丝纱为芯纱，通过并捻机将紫铜丝包缠在芯纱外层，获得包缠纱；
b、将包缠纱放入铜减量溶液中浸泡处理，控制紫铜丝直径减少至30μm为止；
c、用去离子水将包缠纱上残留的铜减量溶液清洗干净；
d、将清洗干净的包缠纱进行紫铜丝表面的化学镀处理；
e、将化学镀处理的包缠纱烘干后沿轴向滚压压扁，制成的细度小、柔软性良好的导电包缠纱。
优选的，步骤a中紫铜丝的包缠密度为18～20转/cm。
优选的，步骤b中铜减量溶液由过氧水和硫酸组成，浓度分别为10％和30％，
优选的，步骤d中对包缠纱进行紫铜丝表面的化学镀银处理，将清洗干净的包缠纱浸置于化学镀银溶液中，在紫铜丝表面获得镀银层。
优选的，步骤d中对包缠纱进行紫铜丝表面的化学镀锡处理，将清洗干净的包缠纱浸置于化学镀锡溶液中，在紫铜丝表面获得镀锡层。
相比于现有技术，本发明具有如下有益效果：
相比传统击剑运动金属衣导电面料所用导电纱，本发明通过采用紫铜丝做导电材料，并用化学减量法，减少紫铜丝的直径，改善导电纱的柔软性，并保持和提高导电纱的导电性，以用于生产轻薄柔软性和良好导电性的击剑运动金属衣面料。
这种导电纱由于导电材料的柔软性和导电性好，因此相对传统导电纱柔软性和导电性都有很大的改善，使得面料更轻薄，柔软性也大幅提升，可提高金属衣的运动舒适性，有助于运动员减少体力消耗并提升成绩。
具体实施方式
以下将结合具体实施例以对本发明做进一步详细说明，但不应将其理解为对本发明保护范围的限制。对于实施例中未具体描述的工艺参数，可遵照本领域中的常规条件或者按照设备规范要求进行。
紫铜为纯铜，对比各种铜合金，紫铜丝的柔软性和导电性都最好，但由于材料和工艺限制，目前最细的紫铜丝实际生产中可做直径50微米，在这个直径下，紫铜丝弯曲刚度较大。
本发明采用一种对紫铜进行化学减量处理的方法，可使其直径减少，并控制到所需要大小，由于线材的弯曲刚度与其半径成4次方关系，因此直径减少可以使其弯曲刚度大幅下降，又由于紫铜的导电性好于磷铜，所以在紫铜丝直径下降，仍然可以使导电纱有较好的导电性。
实施例1
一种柔软击剑运动金属衣面料用导电纱制备方法，以直径为50μm的紫铜丝为导电丝原料，包括下列步骤：
a、以80D涤纶长丝纱为芯纱，通过并捻机将紫铜丝包缠在芯纱外层，包缠密度为18～20转/cm，获得包缠纱；
b、将包缠纱放入铜减量溶液中浸泡处理，铜减量溶液由过氧水和硫酸组成，浓度分别为10％和30％，控制紫铜丝直径减少至30μm为止；
c、用去离子水将包缠纱上残留的铜减量溶液清洗干净；
d、将清洗干净的包缠纱浸置于化学镀银溶液中，进行紫铜丝表面的化学镀银处理，在紫铜丝表面获得镀银层；
e、将化学镀处理的包缠纱烘干后沿轴向滚压压扁，制成的细度小、柔软性良好的导电包缠纱。
实施例2
一种柔软击剑运动金属衣面料用导电纱制备方法，以直径为50μm的紫铜丝为导电丝原料，包括下列步骤：
a、以80D涤纶长丝纱为芯纱，通过并捻机将紫铜丝包缠在芯纱外层，包缠密度为18～20转/cm，获得包缠纱；
b、将包缠纱放入铜减量溶液中浸泡处理，铜减量溶液由过氧水和硫酸组成，浓度分别为10％和30％，控制紫铜丝直径减少至30μm为止；
c、用去离子水将包缠纱上残留的铜减量溶液清洗干净；
d、将清洗干净的包缠纱浸置于化学镀锡溶液中，进行紫铜丝表面的化学镀锡处理，在紫铜丝表面获得镀锡层；
e、将化学镀处理的包缠纱烘干后沿轴向滚压压扁，制成的细度小、柔软性良好的导电包缠纱。
本发明针对现有产品采用的镀锡磷铜丝较粗、较硬及导电性差而导致导电纱柔软性较差，导电性有待提高的问题，通过本发明方法制成柔软性更好的导电纱。
相比传统击剑运动金属衣导电面料所用导电纱，本发明通过采用紫铜丝做导电材料，并用化学减量法，减少紫铜丝的直径，改善导电纱的柔软性，并保持和提高导电纱的导电性，以用于生产轻薄柔软性和良好导电性的击剑运动金属衣面料。
这种导电纱由于导电材料的柔软性和导电性好，因此相对传统导电纱柔软性和导电性都有很大的改善，使得面料更轻薄，柔软性也大幅提升，可提高金属衣的运动舒适性，有助于运动员减少体力消耗并提升成绩。
综合这些特点表明，本发明制成的导电包缠纱可用于织造击剑运动金属衣导电面料，可降低其厚度，改善其柔软性。
以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (5)

1.一种柔软击剑运动金属衣面料用导电纱制备方法，以直径为50μm的紫铜丝为导电丝原料，包括下列步骤：
S1、以80D涤纶长丝纱为芯纱，通过并捻机将紫铜丝包缠在芯纱外层，获得包缠纱；
S2、将包缠纱放入铜减量溶液中浸泡处理，控制紫铜丝直径减少至30μm为止；
S3、用去离子水将包缠纱上残留的铜减量溶液清洗干净；
S4、将清洗干净的包缠纱进行紫铜丝表面的化学镀处理；
S5、将化学镀处理的包缠纱烘干后沿轴向滚压压扁，制成的细度小、柔软性良好的导电包缠纱。
2.根据权利要求1所述的一种柔软击剑运动金属衣面料用导电纱制备方法，其特征在于，所述步骤S1中紫铜丝的包缠密度为18～20转/cm。
3.根据权利要求1所述的一种柔软击剑运动金属衣面料用导电纱制备方法，其特征在于，所述步骤S2中铜减量溶液由过氧水和硫酸组成，浓度分别为10％和30％。
4.根据权利要求1所述的一种柔软击剑运动金属衣面料用导电纱制备方法，其特征在于，所述步骤S4中对包缠纱进行紫铜丝表面的化学镀银处理，将清洗干净的包缠纱浸置于化学镀银溶液中，在紫铜丝表面获得镀银层。
5.根据权利要求1所述的一种柔软击剑运动金属衣面料用导电纱制备方法，其特征在于，步骤S4中对包缠纱进行紫铜丝表面的化学镀锡处理，将清洗干净的包缠纱浸置于化学镀锡溶液中，在紫铜丝表面获得镀锡层。
CN201710423101.3A 2017-06-07 2017-06-07 一种柔软击剑运动金属衣面料用导电纱制备方法 Pending CN107190500A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710423101.3A CN107190500A (zh) 2017-06-07 2017-06-07 一种柔软击剑运动金属衣面料用导电纱制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710423101.3A CN107190500A (zh) 2017-06-07 2017-06-07 一种柔软击剑运动金属衣面料用导电纱制备方法

Publications (1)

Publication Number Publication Date
CN107190500A true CN107190500A (zh) 2017-09-22

Family

ID=59877223

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710423101.3A Pending CN107190500A (zh) 2017-06-07 2017-06-07 一种柔软击剑运动金属衣面料用导电纱制备方法

Country Status (1)

Country Link
CN (1) CN107190500A (zh)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1671901A (zh) * 2002-09-14 2005-09-21 W·齐默尔曼两合公司 导电纱线
US20060218778A1 (en) * 2005-04-04 2006-10-05 Govindaraj Jawahar Flexible conducting thread
CN200981909Y (zh) * 2006-05-23 2007-11-28 卜凡刚 镀银纤维复合纱
CN202530225U (zh) * 2012-03-22 2012-11-14 浙江国远纱线有限公司 一种导电纤维包覆纱

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1671901A (zh) * 2002-09-14 2005-09-21 W·齐默尔曼两合公司 导电纱线
US20060218778A1 (en) * 2005-04-04 2006-10-05 Govindaraj Jawahar Flexible conducting thread
CN200981909Y (zh) * 2006-05-23 2007-11-28 卜凡刚 镀银纤维复合纱
CN202530225U (zh) * 2012-03-22 2012-11-14 浙江国远纱线有限公司 一种导电纤维包覆纱

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
周邦娜等: "铜在硫酸及过氧化氢溶液中溶解过程研究", 《有色金属(冶炼部分)》 *

Similar Documents

Publication Publication Date Title
CN107201585A (zh) 一种击剑运动金属衣面料用扁丝包缠纱及其制备方法
US9388514B2 (en) Method of producing electrically conductive metal composite yarn having increased yield strength, composite yarn produced by the method and embroidered circuit produced using the composite yarn
US7984604B2 (en) Manufacturing method and apparatus for producing digital yarns using hybrid metal for high speed communication and digital yarns thereof
TW567077B (en) Wearable electrode apparatus and manufacture thereof
KR20120086462A (ko) 이중구조의 금속사와 그 제조방법, 이를 이용한 합연사 및 합연방법, 및 이 합연사를 이용하여 제조된 원단
DE10242785A1 (de) Elektrisch leitfähiges Garn
CN107268214A (zh) 一种浸渍法制备导电击剑运动金属衣面料的方法
CN104814552B (zh) 一种击剑服用导电面料及其制备方法
CN107190500A (zh) 一种柔软击剑运动金属衣面料用导电纱制备方法
CN112251869B (zh) 一种制备柔性可穿戴导电氨纶纱线的方法
KR20210112268A (ko) 탄소섬유 발열선의 제조방법 및 이에 따라 제조된 탄소섬유 발열선
CN105336445B (zh) 一种应用于穿戴设备的电线制造方法
CN104131467A (zh) 一种腈纶导电长丝的制备方法
CN107151921A (zh) 一种纳米银涂层导电击剑运动金属衣面料的制备方法
JP2016212960A (ja) ポリマー繊維導電線およびその製造方法
CN108588942A (zh) 一种腈纶镀铜-硼合金导电长丝及其制备方法
KR100895092B1 (ko) 전력 공급 및 데이터 전송선으로 적용할 수 있는 스마트직물용 전기전도성 재봉사
CN208368189U (zh) 一种耐摇摆的导电线
CN107268144A (zh) 一种不锈钢纤维混纺击剑运动金属衣面料及其制备工艺
CN108589275A (zh) 一种腈纶导电长丝及其化学镀银制备的方法
RU182617U1 (ru) Нить мишурная
KR101617835B1 (ko) 전기전도성 합사 및 전기전도성 피복품
CN115559036B (zh) 纤维包芯金属长丝包缠复合纱线、制备方法和用途
CN113699646A (zh) 一种击剑布及其制备方法
CN107268131A (zh) 一种击剑运动金属衣面料用导电银纤维捻线

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170922

RJ01 Rejection of invention patent application after publication