CN107190399A - 一种纳米银纺织面料的制造方法 - Google Patents

一种纳米银纺织面料的制造方法 Download PDF

Info

Publication number
CN107190399A
CN107190399A CN201710629249.2A CN201710629249A CN107190399A CN 107190399 A CN107190399 A CN 107190399A CN 201710629249 A CN201710629249 A CN 201710629249A CN 107190399 A CN107190399 A CN 107190399A
Authority
CN
China
Prior art keywords
weaving face
face fabric
fabric
nano silver
manufacture method
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710629249.2A
Other languages
English (en)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
According To Hefei Clothing Trade Co Ltd
Original Assignee
According To Hefei Clothing Trade Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by According To Hefei Clothing Trade Co Ltd filed Critical According To Hefei Clothing Trade Co Ltd
Priority to CN201710629249.2A priority Critical patent/CN107190399A/zh
Publication of CN107190399A publication Critical patent/CN107190399A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D11/00—Double or multi-ply fabrics not otherwise provided for
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/56—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B19/00—Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
    • D06B19/0005—Fixing of chemicals, e.g. dyestuffs, on textile materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00—Heating or cooling textile fabrics
    • D06C7/02—Setting
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65—Salts of oxyacids of nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

本发明公开了一种纳米银纺织面料的制造方法，包括如下步骤：步骤1：纺纱；步骤2：织造；步骤3：制备纳米银织物，将硝酸银加入到蒸馏水中，均匀搅拌得到硝酸银溶液，再将步骤2处理得到的坯布浸泡在硝酸银溶液中，进行微波加热50~100min，加热温度为60~120℃，每隔5~10min取出至少翻动一次；步骤4：纺织面料后处理，将双层结构的坯布进行退浆、丝光、拉幅定型、预缩工序，所述退浆工序采用3~5g/L的淀粉酶，并使用80~90℃的水洗；所述丝光工序采用15~20%质量浓度的氢氧化钠溶液；所述拉幅定型工序预烘温度为80~100℃，焙烘温度为100~160℃；所述预缩工序制成幅宽100~160mm，克重120~180g/m2的纺织面料。该方法工艺简单，成本低，能够在纺织面料表面形成均匀、牢度高的抗菌、拒水性功能涂层。

Description

一种纳米银纺织面料的制造方法
技术领域
本发明属于纺织技术领域，具体涉及一种纳米银纺织面料的制造方法。
背景技术
纺织面料，按织造方法分，有纬编针织面料和经编针织面料两类。纬编针织面料常以低弹涤纶丝或异型涤纶丝、锦纶丝、棉纱、毛纱等为原料，采用平针组织，变化平针组织，罗纹平针组织，双罗纹平针组织、提花组织，毛圈组织等，在各种纬编机上编织而成。随着现代科技的进步及生活水平的提高，人们对于服装面料的功能性要求越来越
高，这使得功能性面料成为新的热点，各种功能性面料的开发随之产生。
银纳米粒子除了具备一般纳米材料的表面效应、小尺寸效应、催化效率强和宏观量子隧道效应等许多优于常规固体物质的特殊化学和物理性质的性质外，还具有独特的催化性质、优异的生物相容性和较好的传感性等，其中最为优异的性能是纳米银的抗菌性。随着科技发展和人们生活水平不断提高，纳米银纺织面料受到人们青睐，纳米银材料在低温超导、防静电、抗菌等方面应用前景非常广阔。通过简单、环保的方法将纳米银材料施加到纺织面料表面成为纺织面料功能整理研究的热点。
发明内容
针对上述问题，本发明要解决的技术问题是提供一种纳米银纺织面料的制造方法。
为实现上述目的，本发明的技术方案为：一种纳米银纺织面料的制造方法，包括如下步骤：
步骤1：纺纱，将天丝和氨纶布混合纺织为第一纱线，将丙纶短纤维和竹炭纤维混合纺织为第二纱线，再放入有机溶剂超声处理30~90min去除杂质，然后水洗去除杂质，干燥备用；
步骤2：织造，将第一纱线和第二纱线浸渍到浆液中，50-60分钟后取出，放入50-60℃旋转干燥箱中干燥20-30分钟，将第一纱线和第二纱线采用穿纱方式织造出双层结构的坯布，坯布用粘合剂连接；
步骤3：制备纳米银织物，将硝酸银加入到蒸馏水中，均匀搅拌得到硝酸银溶液，再将步骤2处理得到的坯布浸泡在硝酸银溶液中，进行微波加热50~100min，加热温度为60~120℃，每隔5~10min取出至少翻动一次；
步骤4：纺织面料后处理，将双层结构的坯布进行退浆、丝光、拉幅定型、预缩工序，所述退浆工序采用3~5g/L的淀粉酶，并使用80~90℃的水洗；所述丝光工序采用15~20%质量浓度的氢氧化钠溶液；所述拉幅定型工序预烘温度为80~100℃，焙烘温度为100~160℃；所述预缩工序制成幅宽100~160mm，克重120~180g/m2的纺织面料。
优选地，所述纺织面料的缩布率为5~10%。
优选地，所述第一纺纱的穿纱张力为3.0~3.5N，所述第二纺纱的穿纱张力为5.5~8.5N。
优选地，所述步骤1中的有机溶剂选自苯乙烯、全氯乙烯、三氯乙烯、乙烯乙二醇醚和三乙醇胺中的任一一种。
优选地，所述粘合剂为环氧树脂、酚醛树脂、脲醛树脂、三聚氰-甲醛树脂、有机硅树脂或丙烯酸树脂。
优选地，所述步骤1中有机溶剂为丙酮和乙醇，其体积比为1～3:1。
优选地，所述纺织面料为为竹纤维、棉、毛、麻、丝、涤纶、粘胶、聚酯或腈纶中的至少一种。
优选地，所述步骤3中硝酸银溶液的浓度为20~40%。
本发明的有益效果在于：本发明提供一种纳米银纺织面料的制造方法，再通过微波加热方法原位还原纳米银颗粒在纺织面料上，形成具有优异性能的纳米银面料，它将同时具有抗紫外、导电性、抗菌性、拒水性和纳米效应。竹炭纤维是取毛竹为原料，采用了纯氧高温及氮气阻隔延时的煅烧新工艺，使得竹炭天生具有的微孔更细化和蜂窝化，然后再与具有蜂窝状微孔结构趋势的聚酯改性切片熔融纺丝而制成的。这种独特的纤维结构设计，具有吸湿透气、抑菌抗菌、冬暖夏凉、绿色环保等特点。
该方法工艺简单，成本低，能够在纺织面料表面形成均匀、牢度高的抗菌、拒水性功能涂层。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合实施例，对本发明进行进一步的详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不限定本发明。
实施例1
一种纳米银纺织面料的制造方法，包括如下步骤：
步骤1：纺纱，将天丝和氨纶布混合纺织为第一纱线，将丙纶短纤维和竹炭纤维混合纺织为第二纱线，再放入有机溶剂超声处理30min去除杂质，然后水洗去除杂质，干燥备用；
步骤2：织造，将第一纱线和第二纱线浸渍到浆液中，50分钟后取出，放入50℃旋转干燥箱中干燥20分钟，将第一纱线和第二纱线采用穿纱方式织造出双层结构的坯布，坯布用粘合剂连接；
步骤3：制备纳米银织物，将硝酸银加入到蒸馏水中，均匀搅拌得到硝酸银溶液，再将步骤2处理得到的坯布浸泡在硝酸银溶液中，进行微波加热50~100min，加热温度为60℃，每隔5min取出至少翻动一次；
步骤4：纺织面料后处理，将双层结构的坯布进行退浆、丝光、拉幅定型、预缩工序，所述退浆工序采用3g/L的淀粉酶，并使用80℃的水洗；所述丝光工序采用15%质量浓度的氢氧化钠溶液；所述拉幅定型工序预烘温度为80℃，焙烘温度为100℃；所述预缩工序制成幅宽100mm，克重120g/m2的纺织面料。
所述纺织面料的缩布率为5%。
所述第一纺纱的穿纱张力为3.0N，所述第二纺纱的穿纱张力为5.5N。
所述步骤1中的有机溶剂选自苯乙烯、全氯乙烯、三氯乙烯、乙烯乙二醇醚和三乙醇胺中的任一一种。
所述粘合剂为环氧树脂、酚醛树脂、脲醛树脂、三聚氰-甲醛树脂、有机硅树脂或丙烯酸树脂。
所述步骤1中有机溶剂为丙酮和乙醇，其体积比为1:1。
所述纺织面料为为竹纤维、棉、毛、麻、丝、涤纶、粘胶、聚酯或腈纶中的至少一种。
所述步骤3中硝酸银溶液的浓度为20%。
实施例2
一种纳米银纺织面料的制造方法，包括如下步骤：
步骤1：纺纱，将天丝和氨纶布混合纺织为第一纱线，将丙纶短纤维和竹炭纤维混合纺织为第二纱线，再放入有机溶剂超声处理60min去除杂质，然后水洗去除杂质，干燥备用；
步骤2：织造，将第一纱线和第二纱线浸渍到浆液中，55分钟后取出，放入55℃旋转干燥箱中干燥25分钟，将第一纱线和第二纱线采用穿纱方式织造出双层结构的坯布，坯布用粘合剂连接；
步骤3：制备纳米银织物，将硝酸银加入到蒸馏水中，均匀搅拌得到硝酸银溶液，再将步骤2处理得到的坯布浸泡在硝酸银溶液中，进行微波加热80min，加热温度为80℃，每隔7min取出至少翻动一次；
步骤4：纺织面料后处理，将双层结构的坯布进行退浆、丝光、拉幅定型、预缩工序，所述退浆工序采用4g/L的淀粉酶，并使用85℃的水洗；所述丝光工序采用18%质量浓度的氢氧化钠溶液；所述拉幅定型工序预烘温度为90℃，焙烘温度为120℃；所述预缩工序制成幅宽140mm，克重160g/m2的纺织面料。
所述纺织面料的缩布率为7%。
所述第一纺纱的穿纱张力为3.2N，所述第二纺纱的穿纱张力为6.5N。
所述步骤1中的有机溶剂选自苯乙烯、全氯乙烯、三氯乙烯、乙烯乙二醇醚和三乙醇胺中的任一一种。
所述粘合剂为环氧树脂、酚醛树脂、脲醛树脂、三聚氰-甲醛树脂、有机硅树脂或丙烯酸树脂。
所述步骤1中有机溶剂为丙酮和乙醇，其体积比为2:1。
所述纺织面料为为竹纤维、棉、毛、麻、丝、涤纶、粘胶、聚酯或腈纶中的至少一种。
所述步骤3中硝酸银溶液的浓度为30%。
实施例3
一种纳米银纺织面料的制造方法，包括如下步骤：
步骤1：纺纱，将天丝和氨纶布混合纺织为第一纱线，将丙纶短纤维和竹炭纤维混合纺织为第二纱线，再放入有机溶剂超声处理90min去除杂质，然后水洗去除杂质，干燥备用；
步骤2：织造，将第一纱线和第二纱线浸渍到浆液中， 60分钟后取出，放入60℃旋转干燥箱中干燥30分钟，将第一纱线和第二纱线采用穿纱方式织造出双层结构的坯布，坯布用粘合剂连接；
步骤3：制备纳米银织物，将硝酸银加入到蒸馏水中，均匀搅拌得到硝酸银溶液，再将步骤2处理得到的坯布浸泡在硝酸银溶液中，进行微波加热100min，加热温度为120℃，每隔10min取出至少翻动一次；
步骤4：纺织面料后处理，将双层结构的坯布进行退浆、丝光、拉幅定型、预缩工序，所述退浆工序采用5g/L的淀粉酶，并使用90℃的水洗；所述丝光工序采用20%质量浓度的氢氧化钠溶液；所述拉幅定型工序预烘温度为100℃，焙烘温度为160℃；所述预缩工序制成幅宽160mm，克重180g/m2的纺织面料。
所述纺织面料的缩布率为10%。
所述第一纺纱的穿纱张力为3.5N，所述第二纺纱的穿纱张力为8.5N。
所述步骤1中的有机溶剂选自苯乙烯、全氯乙烯、三氯乙烯、乙烯乙二醇醚和三乙醇胺中的任一一种。
所述粘合剂为环氧树脂、酚醛树脂、脲醛树脂、三聚氰-甲醛树脂、有机硅树脂或丙烯酸树脂。
所述步骤1中有机溶剂为丙酮和乙醇，其体积比为3:1。
所述纺织面料为为竹纤维、棉、毛、麻、丝、涤纶、粘胶、聚酯或腈纶中的至少一种。
所述步骤3中硝酸银溶液的浓度为40%。
以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (8)

1.一种纳米银纺织面料的制造方法，其特征在于，包括如下步骤：
步骤1：纺纱，将天丝和氨纶布混合纺织为第一纱线，将丙纶短纤维和竹炭纤维混合纺织为第二纱线，再放入有机溶剂超声处理30~90min去除杂质，然后水洗去除杂质，干燥备用；
步骤2：织造，将第一纱线和第二纱线浸渍到浆液中，50-60分钟后取出，放入50-60℃旋转干燥箱中干燥20-30分钟，将第一纱线和第二纱线采用穿纱方式织造出双层结构的坯布，坯布用粘合剂连接；
步骤3：制备纳米银织物，将硝酸银加入到蒸馏水中，均匀搅拌得到硝酸银溶液，再将步骤2处理得到的坯布浸泡在硝酸银溶液中，进行微波加热50~100min，加热温度为60~120℃，每隔5~10min取出至少翻动一次；
步骤4：纺织面料后处理，将双层结构的坯布进行退浆、丝光、拉幅定型、预缩工序，所述退浆工序采用3~5g/L的淀粉酶，并使用80~90℃的水洗；所述丝光工序采用15~20%质量浓度的氢氧化钠溶液；所述拉幅定型工序预烘温度为80~100℃，焙烘温度为100~160℃；所述预缩工序制成幅宽100~160mm，克重120~180g/m2的纺织面料。
2.根据权利要求1所述的一种纳米银纺织面料的制造方法，其特征在于，所述纺织面料的缩布率为5~10%。
3.根据权利要求1所述的一种纳米银纺织面料的制造方法，其特征在于，所述第一纺纱的穿纱张力为3.0~3.5N，所述第二纺纱的穿纱张力为5.5~8.5N。
4.根据权利要求1所述的一种纳米银纺织面料的制造方法，其特征在于，所述步骤1中的有机溶剂选自苯乙烯、全氯乙烯、三氯乙烯、乙烯乙二醇醚和三乙醇胺中的任一一种。
5.根据权利要求1所述的一种纳米银纺织面料的制造方法，其特征在于，所述粘合剂为环氧树脂、酚醛树脂、脲醛树脂、三聚氰-甲醛树脂、有机硅树脂或丙烯酸树脂。
6.根据权利要求1所述的一种纳米银纺织面料的制造方法，其特征在于，所述步骤1中有机溶剂为丙酮和乙醇，其体积比为1～3:1。
7.根据权利要求1所述的一种纳米银纺织面料的制造方法，其特征在于，所述纺织面料为为竹纤维、棉、毛、麻、丝、涤纶、粘胶、聚酯或腈纶中的至少一种。
8.根据权利要求1所述的一种纳米银纺织面料的制造方法，其特征在于，所述步骤3中硝酸银溶液的浓度为20~40%。
CN201710629249.2A 2017-07-28 2017-07-28 一种纳米银纺织面料的制造方法 Pending CN107190399A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710629249.2A CN107190399A (zh) 2017-07-28 2017-07-28 一种纳米银纺织面料的制造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710629249.2A CN107190399A (zh) 2017-07-28 2017-07-28 一种纳米银纺织面料的制造方法

Publications (1)

Publication Number Publication Date
CN107190399A true CN107190399A (zh) 2017-09-22

Family

ID=59884895

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710629249.2A Pending CN107190399A (zh) 2017-07-28 2017-07-28 一种纳米银纺织面料的制造方法

Country Status (1)

Country Link
CN (1) CN107190399A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112626667A (zh) * 2020-12-28 2021-04-09 江苏全球康功能纺织品有限公司 一种纳米银防电磁辐射功能面料的制造方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102717094A (zh) * 2012-06-11 2012-10-10 无锡市顺业科技有限公司 原位合成纳米银的方法
CN104404707A (zh) * 2014-12-02 2015-03-11 常熟市新达纬编厂 一种多功能纺织面料的制备方法
CN104878587A (zh) * 2015-05-08 2015-09-02 四川大学 一种超临界流体纳米银纺织面料前处理及其微波制备方法
CN105040241A (zh) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 一种抗菌混纺面料的制备方法
CN105040240A (zh) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 一种抗菌混纺面料及其制备方法
CN105040404A (zh) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 一种原位生成抗菌混纺织物的方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102717094A (zh) * 2012-06-11 2012-10-10 无锡市顺业科技有限公司 原位合成纳米银的方法
CN104404707A (zh) * 2014-12-02 2015-03-11 常熟市新达纬编厂 一种多功能纺织面料的制备方法
CN104878587A (zh) * 2015-05-08 2015-09-02 四川大学 一种超临界流体纳米银纺织面料前处理及其微波制备方法
CN105040241A (zh) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 一种抗菌混纺面料的制备方法
CN105040240A (zh) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 一种抗菌混纺面料及其制备方法
CN105040404A (zh) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 一种原位生成抗菌混纺织物的方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112626667A (zh) * 2020-12-28 2021-04-09 江苏全球康功能纺织品有限公司 一种纳米银防电磁辐射功能面料的制造方法

Similar Documents

Publication Publication Date Title
CN103352293B (zh) 一种阻燃防火面料、加工工艺及其应用
CN107119372A (zh) 高效长久石墨烯抗紫外面料及其制备方法
CN105088373A (zh) 一种抗菌面料及其制备方法
CN104131382A (zh) 一种玉石纤维和椰炭纤维的混纺纱线及其面料
CN102605609B (zh) 竹纤维和涤纶交织面料的制造方法及面料
WO2021243941A1 (zh) 抗起球石墨烯混纺纱纤维复合面料及其制造方法
CN107700020A (zh) 一种纳米银纺织面料的制造方法
CN107190399A (zh) 一种纳米银纺织面料的制造方法
CN105040243A (zh) 一种玉米纤维毛巾制作工艺
CN101818401A (zh) 柔软抑菌吸湿抗紫外线面料及制备工艺
CN114182414B (zh) 一种抗菌布料的生产工艺
CN104420042A (zh) 一种玉石纤维、椰炭纤维和Coolmax纤维的混纺纱线及其面料
CN202989436U (zh) 一种含镀银长丝的双层毛精纺面料
CN102587124B (zh) 竹纤维和涤锦纤维交织面料的制造方法及面料
CN106985471A (zh) 一种清爽透气的纺织面料及其制备方法
CN114941195A (zh) 一种持久抗菌型纺织面料及制备方法
CN110468478B (zh) 一种轻薄保暖的兔绒与涤纶纤维的混纺织物
CN102505268A (zh) 一种透湿保暖面料生产工艺
CN106400358A (zh) 一种麻棉色织面料超柔软生产方法
CN104818554A (zh) 玉石纤维、椰炭纤维和Coolmax纤维的混纺纱线及其面料
CN107956130B (zh) 一种棉羊毛水洗面料的染整加工方法
CN110682617A (zh) 一种透湿抑菌抗紫外线竹纤维面料
CN104358000A (zh) 一种竹炭纤维纺织面料的加工方法
CN104775220A (zh) 一种毯子及其加工方法
CN113584888B (zh) 光热转换可变色织物及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170922

RJ01 Rejection of invention patent application after publication