CN107183085B - Preparation method of rosin mixture biological pesticide fertilizer - Google Patents
Preparation method of rosin mixture biological pesticide fertilizer Download PDFInfo
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- A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
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- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/24—Lauraceae [Laurel family], e.g. laurel, avocado, sassafras, cinnamon or camphor
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- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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Abstract
The invention relates to a preparation method of a rosin mixture biological pesticide fertilizer, which is characterized in that a rosin mixture biological pesticide is added into the fertilizer according to a certain mass ratio to obtain the rosin mixture biological pesticide fertilizer. The invention combines the fertilizer and the biological pesticide, so that the fertilizer has the effect of preventing and treating plant diseases and insect pests, and saves manpower.
Description
Technical Field
The invention relates to a preparation method of a rosin mixture biological medicinal fertilizer.
Background
In 2017, the 'central file I' refers to the improvement of the quality of agricultural products and the safety level of food comprehensively. Insist on the quality of agriculture, implement the agricultural standardization strategy, highlight the high-quality, safe and green guidance, and strengthen the quality of agricultural products and the food safety standard system.
The pesticide used in orchard all year round is acid pesticide, so the growth of plant diseases and insect pests is adapted to the acid environment, and the use of rosin (alkali) mixture can improve the acid environment of orchard, break the environment adapted by plant diseases and insect pests and reduce the drug resistance of plant diseases and insect pests. The traditional rosin mixture is a black brown strong alkaline pesticide prepared by decocting rosin (non-degreased rosin), sodium carbonate or caustic soda (namely sodium carbonate or caustic soda) with water. It has poor compatibility, and cannot be used with organic synthetic pesticide, calcium-containing Bordeaux mixture, lime sulphur mixture, etc. This limits the use of rosin compositions.
The pesticide fertilizer is a new fertilizer, and the pesticide and the fertilizer are combined, so that the fertilizer has the effect of preventing and treating plant diseases and insect pests, and the purposes of saving time and labor are achieved. At present, the pesticide fertilizer is only researched, the market application is less, and the market lacks of a satisfactory pesticide fertilizer product.
Disclosure of Invention
The invention aims to solve the technical problem of providing a preparation method of a rosin mixture biological pesticide fertilizer.
In order to solve the technical problems, the invention adopts the following technical scheme:
a preparation method of a rosin mixture biological medicine fertilizer is characterized by comprising the following steps:
adding the rosin mixture biological pesticide into a fertilizer according to the mass ratio of 0.2-5: 100 to obtain a rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizer according to the mass ratio of 20-30: 10-20: 30-50, and homogenizing at least once to obtain the rosin mixture biological medicine fertilizer;
the Chinese herbal medicine extracting solution is a composition of a derris extracting solution, a houttuynia cordata extracting solution, a garlic extracting solution, an orange peel extracting solution and a cinnamon extracting solution according to a mass ratio of 40-60: 20-40: 10-20: 5-10: 10-20; the extraction method comprises water extraction;
the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 15-30: 5-10: 25-40: 10-20;
the vegetable oil is one or more of palm oil, coconut oil, chinaberry seed oil, mandarin orange oil and litsea cubeba oil in any proportion.
The rosin mixture is prepared according to the following steps: adding rosin, organic base, a catalyst and water into a container according to a mass ratio of 10-30: 20-40: 0.5-5: 80-120, heating at 80-100 ℃ for 30-90 min, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the organic alkali is one or more than two of monoethanolamine, diethanolamine, triethanolamine and sodium ethoxide in any proportion;
the catalyst is one or more than two of sulfuric acid, hydrochloric acid, nitric acid and Lewis acid in any proportion.
The composition comprises derris extract, houttuynia cordata extract, garlic extract, orange peel extract and cinnamon extract according to the mass ratio of 50:25:15:8: 15;
the extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding the Chinese herbal medicines and water into a container according to a mass ratio of 1: 5-40, heating to 50-75 ℃, keeping the temperature for 20-90 min, cooling to 20-40 ℃, and filtering to obtain a filtrate, namely a primary solution; the obtained residue is the residue;
2) preparing a secondary liquid: adding the medicine residues and water into a container according to a mass ratio of 1: 5-40, heating to 70-120 ℃, keeping the temperature for 20-90 min under the condition that the pressure is 0-5 MPa, cooling to 20-40 ℃, and filtering to obtain a filtrate, namely a secondary liquid;
3) preparing an extracting solution: mixing the primary liquid obtained in the step 1) and the secondary liquid obtained in the step 2), and concentrating for 0-90 min at the temperature of 20-90 ℃ and under the pressure of-5 MPa-0 MPa to obtain a concentrated solution, namely an extracting solution.
The synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 20:25:8:30: 15.
The vegetable oil is litsea cubeba oil.
The organic base is triethanolamine; the catalyst is nitric acid.
The mass ratio of the rosin mixture to the Chinese herbal medicine extracting solution to the synergist to the vegetable oil is 20:30:15: 35.
Homogenizing for 2 times, wherein the first homogenizing pressure is 15-35 MPa, the homogenizing temperature is 50-70 ℃, and the homogenizing time is 10-60 min; the second homogenizing pressure is 2-8 PMa, the homogenizing temperature is 50-70 ℃, and the homogenizing time is 10-60 min.
Yuteng belongs to leguminous liana, climbs shrubs and completely removes baldness. Single feathered, compound leaves. Has the functions of eliminating blood stasis, relieving pain and killing pests. Rotenone is very toxic to insects and fishes, but is very slightly toxic to mammals, the intravenous injection lethal dose of dogs is 0.5mg/kg, and the oral administration lethal dose is 600 times larger; generally, 0.2g/kg of the composition is orally taken without causing death.
Houttuynia cordata (English name HERBA HOUTTUYNIAE) is a herb recorded in Chinese pharmacopoeia, and the herb is dried aerial part of Houttuynia cordata (Latin name: Houttuynia cordia Thunb.) of Saururaceae. Harvesting in summer when stem and leaf are flourishing and flower ear is more, removing impurities, and drying in the sun. Yu xing Cao is pungent in flavor and cold in nature and enters lung meridian. It has effects of clearing away heat and toxic materials, relieving swelling, treating sore, inducing diuresis, removing dampness, clearing away heat, relieving dysentery, invigorating stomach, and resolving food stagnation, and can be used for treating lung abscess, pyocutaneous disease, hemorrhoid hematochezia, and heat accumulation of spleen and stomach due to excess heat, heat toxin, dampness, and disease heat. Modern pharmacological experiments show that the product has antibacterial, antiviral, immunity improving, and diuretic effects.
Garlic (Garlic) is also called Garlic bulb, Garlic, calabash, single Garlic and single Garlic, and is a generic name of Garlic plants. A semiannual herb plant of the genus Allium of the family Liliaceae is used as a bulb. Collected in spring and summer, bundled, hung in a ventilated place, and dried in the shade for later use. The farm Han says "seed garlic is not in nine months and is in one end in nine months", and the seed garlic is picked up and dug in 6 months when the leaves are dry, the mud and sand are removed, and the seeds are ventilated, dried or baked until the skins are dry. Has effects of warming spleen and stomach, invigorating stomach, resolving food stagnation and regulating qi-flowing. The sulfur-containing compound in the garlic has extremely strong antibacterial and anti-inflammatory effects, has inhibition and killing effects on various cocci, bacilli, fungi, viruses and the like, and is one of the natural plants which are found at present and has the strongest antibacterial effect.
Orange peel name of traditional Chinese medicine. Is dried mature pericarp of Citrus reticulata Blanco of Rutaceae and its cultivar. The medicinal materials are classified into pericarpium citri reticulatae and pericarpium citri reticulatae. Picking mature fruit, peeling peel, and drying in the sun or at low temperature. Has the effects of regulating qi, strengthening spleen, eliminating dampness and phlegm.
Cinnamon (the scientific name of Latin: Cinnamomum cassia Presl), also called Yugui, Cinnamomum cassia, Jade Tree, Cinnamomum cassia, Pink Tree, Chinese cinnamon, is the dry bark of Cinnamomum cassia of Lauraceae. The bark is aromatic and can be used as a spice, with a flavor similar to that of cinnamon produced from cinnamon of the srilanka type, but more pungent, less delicious than cinnamon and thicker than cinnamon. Tonify primordial yang, warm spleen and stomach, remove cold accumulation, and promote blood circulation. It is indicated for decline of vital gate fire, cold limbs and pulse, yang exhaustion and collapse, abdominal pain and diarrhea, cold hernia and dolphin, cold pain in waist and knee, amenorrhea, deep rooted carbuncle, abscess, and floating yang, upper heat and lower cold. Cinnamon bark oil has a strong bactericidal effect, has a better effect on gram-staining rigid bacteria than negative bacteria, is rarely used as an antibacterial drug due to irritation, and can be used for treating stomachache, flatulence and colic by external application. It can be used as stomachic and wind-expelling agent for oral administration. Also has obvious fungicidal effect.
Colophonium is resin secreted from trunk of pine or pine tree, and contains Colophonium and oleum Terebinthinae. Also called rosin, pine extract, pine gum, pine liquid and pine fat. Can be used as materials such as emulsion paint, adhesive and the like, so that the resin has higher commercial value. It is a mixture of various high molecular compounds and therefore has different melting points. The resins can be classified into natural resins and synthetic resins. The natural resin is the only one, but with the development of chemical engineering, many of the polymers are produced by artificial synthesis, and the chemical properties and physical properties of some of the polymers are similar to those of the natural resin, so the polymers are called synthetic resins. In the air, the product is viscous liquid or solid block. The special chemical structure of the composite material can be used as materials such as emulsion paint, adhesive and the like, so that the composite material has high commercial value.
The invention has the following beneficial technical effects:
1. the invention takes the derris extract as the main material and takes other materials as the auxiliary material, the derris contains rotenone, and the rotenone has strong toxicity to insects and fishes and has light toxicity to mammals. Therefore, the method does not cause harm to people and livestock and does not destroy ecological balance.
2. The extracting solution is extracted by water, so that the problem of solvent residue is solved, wastewater and waste gas are not generated, and the environment is not damaged.
3. The invention adopts the secondary water extraction, can prevent the active substances with low molecular weight dissolved in water from decomposing in a high-temperature environment, and ensures the integrity of the extract.
4. The synergist used in the invention can obviously reduce the surface tension of liquid, has strong spreadability, permeability and moisture retention, and can obviously improve the utilization rate of pesticide.
5. The resin acid amine is synthesized by rosin and organic base under the catalytic action of the catalyst, so that the corrosivity of the rosin mixture is greatly reduced and the compatibility of the rosin mixture is improved compared with the traditional process.
6. The invention adopts the homogenizer to carry out secondary homogenization on the extract, so that the emulsion is stable and convenient to use.
7. The plant oil of the invention is preferably litsea cubeba oil, the main components of the litsea cubeba oil are citral (60-80%), methylheptenone (2.5%), citronellal (1.0%), alpha-pinene, camphene, limonene, alpha-lupinene, p-cymene, geraniol and camphor. The camphor and the alpha-pinene have the functions of killing insects and expelling insects, and the drug effect of the invention can be obviously improved.
8. The invention combines the fertilizer and the turpentine mixture biopesticide, so that the fertilizer has the effect of preventing and treating plant diseases and insect pests, and is time-saving and labor-saving.
Detailed Description
The present invention is further illustrated by the following specific examples.
Example 1
Adding the rosin mixture biological pesticide into the fertilizer according to the mass ratio of 0.5:100 to obtain the rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizing machine according to the mass ratio of 20:30:15:35, and homogenizing for 2 times, wherein the first homogenizing pressure is 25MPa, the homogenizing temperature is 65 ℃, and the homogenizing time is 20 min; and the second homogenization pressure is 4PMa, the homogenization temperature is 65 ℃, and the homogenization time is 25min, so that the rosin mixture biological medicinal fertilizer is obtained.
The rosin mixture is prepared according to the following steps: adding rosin, triethanolamine, nitric acid and water into a container according to the mass ratio of 10:25:2:100, heating for 50min at the temperature of 90 ℃, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the Chinese herbal medicine extracting solution is a composition of derris extracting solution, houttuynia cordata extracting solution, garlic extracting solution, orange peel extracting solution and cinnamon extracting solution according to a mass ratio of 50:25:15:8: 15; the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 20:25:8:30: 15; the vegetable oil is litsea cubeba oil.
The extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding one of derris, houttuynia cordata, garlic, orange peel and cinnamon and water into a container according to the mass ratio of 1:15, heating to 65 ℃, keeping the temperature for 40min, cooling to 30 ℃, and filtering to obtain a filtrate, namely a primary filtrate; the obtained residue is the residue;
2) preparing a secondary liquid: adding the residue and water into a container according to a mass ratio of 1:12, heating to 95 deg.C, maintaining the temperature at 1.5MPa for 45min, cooling to 30 deg.C, and filtering to obtain a secondary filtrate;
3) preparing an extracting solution: mixing the primary liquid obtained in step 1) and the secondary liquid obtained in step 2), and concentrating at 75 deg.C and-0.8 MPa for 30min to obtain concentrated solution, which is one of extractive solutions of caulis Seu folium Derridis Trifoliatae, herba Houttuyniae, Bulbus Allii, pericarpium Citri Tangerinae and cortex Cinnamomi.
Example 2
Adding the rosin mixture biological pesticide into the fertilizer according to the mass ratio of 1.2:100 to obtain the rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizing machine according to the mass ratio of 20:30:15:35, and homogenizing for 2 times, wherein the first homogenizing pressure is 25MPa, the homogenizing temperature is 65 ℃, and the homogenizing time is 20 min; and the second homogenization pressure is 4PMa, the homogenization temperature is 65 ℃, and the homogenization time is 25min, so that the rosin mixture biological medicinal fertilizer is obtained.
The rosin mixture is prepared according to the following steps: adding rosin, triethanolamine, nitric acid and water into a container according to the mass ratio of 10:25:2:100, heating for 50min at the temperature of 90 ℃, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the Chinese herbal medicine extracting solution is a composition of derris extracting solution, houttuynia cordata extracting solution, garlic extracting solution, orange peel extracting solution and cinnamon extracting solution according to a mass ratio of 45:30:10:5: 10; the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 20:25:8:30: 15; the vegetable oil is litsea cubeba oil.
The extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding one of derris, houttuynia cordata, garlic, orange peel and cinnamon and water into a container according to the mass ratio of 1:15, heating to 65 ℃, keeping the temperature for 40min, cooling to 30 ℃, and filtering to obtain a filtrate, namely a primary filtrate; the obtained residue is the residue;
2) preparing a secondary liquid: adding the residue and water into a container according to a mass ratio of 1:12, heating to 95 deg.C, maintaining the temperature at 1.5MPa for 45min, cooling to 30 deg.C, and filtering to obtain a secondary filtrate;
3) preparing an extracting solution: mixing the primary liquid obtained in step 1) and the secondary liquid obtained in step 2), and concentrating at 75 deg.C and-0.8 MPa for 30min to obtain concentrated solution, which is one of extractive solutions of caulis Seu folium Derridis Trifoliatae, herba Houttuyniae, Bulbus Allii, pericarpium Citri Tangerinae and cortex Cinnamomi.
Example 3
Adding the rosin mixture biological pesticide into the fertilizer according to the mass ratio of 2:100 to obtain a rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizing machine according to the mass ratio of 20:30:15:35, and homogenizing for 2 times, wherein the first homogenizing pressure is 25MPa, the homogenizing temperature is 65 ℃, and the homogenizing time is 20 min; and the second homogenization pressure is 4PMa, the homogenization temperature is 65 ℃, and the homogenization time is 25min, so that the rosin mixture biological medicinal fertilizer is obtained.
The rosin mixture is prepared according to the following steps: adding rosin, triethanolamine, nitric acid and water into a container according to the mass ratio of 10:25:2:100, heating for 50min at the temperature of 90 ℃, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the Chinese herbal medicine extracting solution is a composition of derris extracting solution, houttuynia cordata extracting solution, garlic extracting solution, orange peel extracting solution and cinnamon extracting solution according to a mass ratio of 55:20:10:5: 10; the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 20:25:8:30: 15; the vegetable oil is litsea cubeba oil.
The extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding one of derris, houttuynia cordata, garlic, orange peel and cinnamon and water into a container according to the mass ratio of 1:15, heating to 65 ℃, keeping the temperature for 40min, cooling to 30 ℃, and filtering to obtain a filtrate, namely a primary filtrate; the obtained residue is the residue;
2) preparing a secondary liquid: adding the residue and water into a container according to a mass ratio of 1:12, heating to 95 deg.C, maintaining the temperature at 1.5MPa for 45min, cooling to 30 deg.C, and filtering to obtain a secondary filtrate;
3) preparing an extracting solution: mixing the primary liquid obtained in step 1) and the secondary liquid obtained in step 2), and concentrating at 75 deg.C and-0.8 MPa for 30min to obtain concentrated solution, which is one of extractive solutions of caulis Seu folium Derridis Trifoliatae, herba Houttuyniae, Bulbus Allii, pericarpium Citri Tangerinae and cortex Cinnamomi.
Example 4
Adding the rosin mixture biological pesticide into the fertilizer according to the mass ratio of 2.5:100 to obtain a rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizing machine according to the mass ratio of 25:25:10:40, and homogenizing for 2 times, wherein the first homogenizing pressure is 25MPa, the homogenizing temperature is 65 ℃, and the homogenizing time is 20 min; and the second homogenization pressure is 4PMa, the homogenization temperature is 65 ℃, and the homogenization time is 25min, so that the rosin mixture biological medicinal fertilizer is obtained.
The rosin mixture is prepared according to the following steps: adding rosin, triethanolamine, nitric acid and water into a container according to the mass ratio of 10:25:2:100, heating for 50min at the temperature of 90 ℃, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the Chinese herbal medicine extracting solution is a composition of derris extracting solution, houttuynia cordata extracting solution, garlic extracting solution, orange peel extracting solution and cinnamon extracting solution according to a mass ratio of 50:25:15:8: 15; the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 20:25:8:30: 15; the vegetable oil is litsea cubeba oil.
The extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding one of derris, houttuynia cordata, garlic, orange peel and cinnamon and water into a container according to the mass ratio of 1:15, heating to 65 ℃, keeping the temperature for 40min, cooling to 30 ℃, and filtering to obtain a filtrate, namely a primary filtrate; the obtained residue is the residue;
2) preparing a secondary liquid: adding the residue and water into a container according to a mass ratio of 1:12, heating to 95 deg.C, maintaining the temperature at 1.5MPa for 45min, cooling to 30 deg.C, and filtering to obtain a secondary filtrate;
3) preparing an extracting solution: mixing the primary liquid obtained in step 1) and the secondary liquid obtained in step 2), and concentrating at 75 deg.C and-0.8 MPa for 30min to obtain concentrated solution, which is one of extractive solutions of caulis Seu folium Derridis Trifoliatae, herba Houttuyniae, Bulbus Allii, pericarpium Citri Tangerinae and cortex Cinnamomi.
Example 5
Adding the rosin mixture biological pesticide into the fertilizer according to the mass ratio of 3:100 to obtain a rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizing machine according to the mass ratio of 30:30:10:30, and homogenizing for 2 times, wherein the first homogenizing pressure is 25MPa, the homogenizing temperature is 65 ℃, and the homogenizing time is 20 min; and the second homogenization pressure is 4PMa, the homogenization temperature is 65 ℃, and the homogenization time is 25min, so that the rosin mixture biological medicinal fertilizer is obtained.
The rosin mixture is prepared according to the following steps: adding rosin, triethanolamine, nitric acid and water into a container according to the mass ratio of 10:25:2:100, heating for 50min at the temperature of 90 ℃, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the Chinese herbal medicine extracting solution is a composition of derris extracting solution, houttuynia cordata extracting solution, garlic extracting solution, orange peel extracting solution and cinnamon extracting solution according to a mass ratio of 50:25:15:8: 15; the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 20:25:8:30: 15; the vegetable oil is litsea cubeba oil.
The extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding one of derris, houttuynia cordata, garlic, orange peel and cinnamon and water into a container according to the mass ratio of 1:15, heating to 65 ℃, keeping the temperature for 40min, cooling to 30 ℃, and filtering to obtain a filtrate, namely a primary filtrate; the obtained residue is the residue;
2) preparing a secondary liquid: adding the residue and water into a container according to a mass ratio of 1:12, heating to 95 deg.C, maintaining the temperature at 1.5MPa for 45min, cooling to 30 deg.C, and filtering to obtain a secondary filtrate;
3) preparing an extracting solution: mixing the primary liquid obtained in step 1) and the secondary liquid obtained in step 2), and concentrating at 75 deg.C and-0.8 MPa for 30min to obtain concentrated solution, which is one of extractive solutions of caulis Seu folium Derridis Trifoliatae, herba Houttuyniae, Bulbus Allii, pericarpium Citri Tangerinae and cortex Cinnamomi.
Example 6
Adding the rosin mixture biological pesticide into the fertilizer according to the mass ratio of 3.5:100 to obtain a rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizing machine according to the mass ratio of 20:20:10:50, and homogenizing for 2 times, wherein the first homogenizing pressure is 25MPa, the homogenizing temperature is 65 ℃, and the homogenizing time is 20 min; and the second homogenization pressure is 4PMa, the homogenization temperature is 65 ℃, and the homogenization time is 25min, so that the rosin mixture biological medicinal fertilizer is obtained.
The rosin mixture is prepared according to the following steps: adding rosin, triethanolamine, nitric acid and water into a container according to the mass ratio of 10:25:2:100, heating for 50min at the temperature of 90 ℃, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the Chinese herbal medicine extracting solution is a composition of derris extracting solution, houttuynia cordata extracting solution, garlic extracting solution, orange peel extracting solution and cinnamon extracting solution according to a mass ratio of 50:25:15:8: 15; the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 20:25:8:30: 15; the vegetable oil is litsea cubeba oil.
The extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding one of derris, houttuynia cordata, garlic, orange peel and cinnamon and water into a container according to the mass ratio of 1:15, heating to 65 ℃, keeping the temperature for 40min, cooling to 30 ℃, and filtering to obtain a filtrate, namely a primary filtrate; the obtained residue is the residue;
2) preparing a secondary liquid: adding the residue and water into a container according to a mass ratio of 1:12, heating to 95 deg.C, maintaining the temperature at 1.5MPa for 45min, cooling to 30 deg.C, and filtering to obtain a secondary filtrate;
3) preparing an extracting solution: mixing the primary liquid obtained in step 1) and the secondary liquid obtained in step 2), and concentrating at 75 deg.C and-0.8 MPa for 30min to obtain concentrated solution, which is one of extractive solutions of caulis Seu folium Derridis Trifoliatae, herba Houttuyniae, Bulbus Allii, pericarpium Citri Tangerinae and cortex Cinnamomi.
Example 7
Adding the rosin mixture biological pesticide into the fertilizer according to the mass ratio of 4:100 to obtain a rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizing machine according to the mass ratio of 30:25:15:30, and homogenizing for 2 times, wherein the first homogenizing pressure is 25MPa, the homogenizing temperature is 65 ℃, and the homogenizing time is 20 min; and the second homogenization pressure is 4PMa, the homogenization temperature is 65 ℃, and the homogenization time is 25min, so that the rosin mixture biological medicinal fertilizer is obtained.
The rosin mixture is prepared according to the following steps: adding rosin, triethanolamine, nitric acid and water into a container according to the mass ratio of 10:25:2:100, heating for 50min at the temperature of 90 ℃, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the Chinese herbal medicine extracting solution is a composition of derris extracting solution, houttuynia cordata extracting solution, garlic extracting solution, orange peel extracting solution and cinnamon extracting solution according to a mass ratio of 50:25:15:8: 15; the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 30:15:7:35: 13; the vegetable oil is litsea cubeba oil.
The extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding one of derris, houttuynia cordata, garlic, orange peel and cinnamon and water into a container according to the mass ratio of 1:15, heating to 55 ℃, keeping the temperature for 50min, cooling to 32 ℃, and filtering to obtain a filtrate, namely a primary filtrate; the obtained residue is the residue;
2) preparing a secondary liquid: adding the medicine residues and water into a container according to the mass ratio of 1:12, heating to 95 ℃, keeping the temperature for 45min under the condition that the pressure is 1.5MPa, cooling to 35 ℃, and filtering to obtain a filtrate, namely a secondary solution;
3) preparing an extracting solution: mixing the primary liquid obtained in step 1) and the secondary liquid obtained in step 2), and concentrating at 75 deg.C and-0.8 MPa for 30min to obtain concentrated solution, which is one of extractive solutions of caulis Seu folium Derridis Trifoliatae, herba Houttuyniae, Bulbus Allii, pericarpium Citri Tangerinae and cortex Cinnamomi.
Example 8
Adding the rosin mixture biological pesticide into the fertilizer according to the mass ratio of 4.5:100 to obtain a rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizing machine according to the mass ratio of 20:30:15:35, homogenizing for 1 time at the homogenizing pressure of 25MPa and the homogenizing temperature of 65 ℃ for 30min to obtain the rosin mixture biological medicine fertilizer.
The rosin mixture is prepared according to the following steps: adding rosin, triethanolamine, nitric acid and water into a container according to the mass ratio of 20:40:3:120, heating at 100 ℃ for 60min, and filtering to remove impurities, wherein the obtained filtrate is a rosin mixture;
the Chinese herbal medicine extracting solution is a composition of derris extracting solution, houttuynia cordata extracting solution, garlic extracting solution, orange peel extracting solution and cinnamon extracting solution according to a mass ratio of 50:25:15:8: 15; the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 30:15:7:35: 13; the vegetable oil is a composition of litsea cubeba oil and palm oil according to the mass ratio of 1: 1.
The extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding one of derris, houttuynia cordata, garlic, orange peel and cinnamon and water into a container according to the mass ratio of 1:25, heating to 65 ℃, keeping the temperature for 40min, cooling to 30 ℃, and filtering to obtain a filtrate, namely a primary filtrate; the obtained residue is the residue;
2) preparing a secondary liquid: adding the medicine residues and water into a container according to the mass ratio of 1:15, heating to 85 ℃, keeping the temperature for 45min, cooling to 30 ℃, and filtering to obtain a filtrate, namely a secondary solution;
3) preparing a Chinese herbal medicine extracting solution: and (3) combining the primary liquid obtained in the step 1) and the secondary liquid obtained in the step 2), wherein the obtained combined liquid is one of the extract of derris, the extract of houttuynia cordata, the extract of garlic, the extract of orange peel and the extract of cinnamon.
Example 9
Adding the rosin mixture biological pesticide into the fertilizer according to the mass ratio of 0.5:100 to obtain the rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizing machine according to the mass ratio of 20:30:15:35, and homogenizing for 2 times, wherein the first homogenizing pressure is 25MPa, the homogenizing temperature is 65 ℃, and the homogenizing time is 20 min; and the second homogenization pressure is 4PMa, the homogenization temperature is 65 ℃, and the homogenization time is 25min, so that the rosin mixture biological medicinal fertilizer is obtained.
The rosin mixture is prepared according to the following steps: adding rosin, triethanolamine, nitric acid and water into a container according to the mass ratio of 10:25:2:100, heating for 50min at the temperature of 90 ℃, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the Chinese herbal medicine extracting solution is a composition of derris extracting solution, houttuynia cordata extracting solution, garlic extracting solution, orange peel extracting solution and cinnamon extracting solution according to a mass ratio of 50:25:15:8: 15; the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 15:20:6:40: 19; the vegetable oil is litsea cubeba oil.
The extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding one of derris, houttuynia cordata, garlic, orange peel and cinnamon and water into a container according to the mass ratio of 1:15, heating to 65 ℃, keeping the temperature for 40min, cooling to 30 ℃, and filtering to obtain a filtrate, namely a primary filtrate; the obtained residue is the residue;
2) preparing a secondary liquid: adding the residue and water into a container according to a mass ratio of 1:12, heating to 95 deg.C, maintaining the temperature at 1.5MPa for 45min, cooling to 30 deg.C, and filtering to obtain a secondary filtrate;
3) preparing an extracting solution: mixing the primary liquid obtained in step 1) and the secondary liquid obtained in step 2), and concentrating at 75 deg.C and-0.8 MPa for 30min to obtain concentrated solution, which is one of extractive solutions of caulis Seu folium Derridis Trifoliatae, herba Houttuyniae, Bulbus Allii, pericarpium Citri Tangerinae and cortex Cinnamomi.
Example 10
Adding the rosin mixture biological pesticide into the fertilizer according to the mass ratio of 0.5:100 to obtain the rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizing machine according to the mass ratio of 20:30:15:35, and homogenizing for 2 times, wherein the first homogenizing pressure is 25MPa, the homogenizing temperature is 65 ℃, and the homogenizing time is 20 min; and the second homogenization pressure is 4PMa, the homogenization temperature is 65 ℃, and the homogenization time is 25min, so that the rosin mixture biological medicinal fertilizer is obtained.
The rosin mixture is prepared according to the following steps: adding rosin, triethanolamine, nitric acid and water into a container according to the mass ratio of 10:25:2:100, heating for 50min at the temperature of 90 ℃, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the Chinese herbal medicine extracting solution is a composition of derris extracting solution, houttuynia cordata extracting solution, garlic extracting solution, orange peel extracting solution and cinnamon extracting solution according to a mass ratio of 50:25:15:8: 15; the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 30:25:5:30: 10; the vegetable oil is litsea cubeba oil.
The extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding one of derris, houttuynia cordata, garlic, orange peel and cinnamon and water into a container according to the mass ratio of 1:15, heating to 65 ℃, keeping the temperature for 40min, cooling to 30 ℃, and filtering to obtain a filtrate, namely a primary filtrate; the obtained residue is the residue;
2) preparing a secondary liquid: adding the residue and water into a container according to a mass ratio of 1:12, heating to 95 deg.C, maintaining the temperature at 1.5MPa for 45min, cooling to 30 deg.C, and filtering to obtain a secondary filtrate;
3) preparing an extracting solution: mixing the primary liquid obtained in step 1) and the secondary liquid obtained in step 2), and concentrating at 75 deg.C and-0.8 MPa for 30min to obtain concentrated solution, which is one of extractive solutions of caulis Seu folium Derridis Trifoliatae, herba Houttuyniae, Bulbus Allii, pericarpium Citri Tangerinae and cortex Cinnamomi.
Example 11
Adding the rosin mixture biological pesticide into the fertilizer according to the mass ratio of 0.5:100 to obtain the rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizing machine according to the mass ratio of 20:30:15:35, and homogenizing for 2 times, wherein the first homogenizing pressure is 25MPa, the homogenizing temperature is 65 ℃, and the homogenizing time is 20 min; and the second homogenization pressure is 4PMa, the homogenization temperature is 65 ℃, and the homogenization time is 25min, so that the rosin mixture biological medicinal fertilizer is obtained.
The rosin mixture is prepared according to the following steps: adding rosin, triethanolamine, nitric acid and water into a container according to the mass ratio of 10:25:2:100, heating for 50min at the temperature of 90 ℃, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the Chinese herbal medicine extracting solution is a composition of derris extracting solution, houttuynia cordata extracting solution, garlic extracting solution, orange peel extracting solution and cinnamon extracting solution according to a mass ratio of 50:25:15:8: 15; the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 15:30:10:35: 10; the vegetable oil is litsea cubeba oil.
The extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding one of derris, houttuynia cordata, garlic, orange peel and cinnamon and water into a container according to the mass ratio of 1:15, heating to 65 ℃, keeping the temperature for 40min, cooling to 30 ℃, and filtering to obtain a filtrate, namely a primary filtrate; the obtained residue is the residue;
2) preparing a secondary liquid: adding the residue and water into a container according to a mass ratio of 1:12, heating to 95 deg.C, maintaining the temperature at 1.5MPa for 45min, cooling to 30 deg.C, and filtering to obtain a secondary filtrate;
3) preparing an extracting solution: mixing the primary liquid obtained in step 1) and the secondary liquid obtained in step 2), and concentrating at 75 deg.C and-0.8 MPa for 30min to obtain concentrated solution, which is one of extractive solutions of caulis Seu folium Derridis Trifoliatae, herba Houttuyniae, Bulbus Allii, pericarpium Citri Tangerinae and cortex Cinnamomi.
The beneficial effects of the present invention are further illustrated below in conjunction with experimental data:
experiment one:
the rosin mixture produced by the conventional method and the rosin mixture of the present invention were weighed to 5g each, and added to two containers, respectively, and then 1g of calcium nitrate was added to each of the two containers, and 100ml of water was added to each of the two containers, and the phenomenon was observed.
Wherein a large amount of floccules are generated in a container of the traditional rosin mixture and sink to the bottom after 8 minutes; the container of the rosin mixture of the present invention has less floccules, which shows that the compatibility of the rosin mixture of the present invention is improved compared with the rosin mixture of the conventional method.
Experiment two:
1. experimental materials
1, materials and methods:
1.1 test site: su Jia shop town of Xixia city of tobacco station.
1.2 subjects: the 12 mu of red Fuji orchard is 10 years old.
1.3 test materials: the results were compared with those of the conventional fertilizer, treatment 1 (the preparation was identical to that of example 1 except that the conventional rosin mixture was used), example 1, example 9, example 10 and example 11.
1.4 design of test: the test was conducted in 6 treatments, 2 replicates, one treatment per acre, common fertilizer, treatment 1 (made in accordance with example 1 except using conventional rosin mixture), example 1, example 9, example 10 and example 11. Furrow application is adopted, and 150kg of fertilizer is applied to each mu. And observing the growth condition and insect pest condition of the apples after each treatment, and counting the yield of each treatment.
The experiment is consistent in other management except for different experimental treatments.
2 results and analysis
The data for the conventional fertilizer, treatment 1 (made in accordance with example 1 except that a conventional rosin mixture was used), example 1, example 9, example 10 and example 11 are shown in table 1.
TABLE 1 Effect of treatments on apple growth, insect infestation and yield
TABLE 1
As can be seen from the above data, the present invention is remarkably effective in preventing diseases and insect pests. The occurrence of the bitter pox is related to the calcium deficiency of the apples, the bitter pox occurs in the treatment 1, and the bitter pox is possibly caused because the calcium in the soil is fixed due to poor compatibility of the rosin mixture, so that the apples lack the calcium. From comparison of the data of example 1, example 9, example 10 and example 11, it can be seen that the synergistic effect of the synergist in example 1 is better than that of example 9, example 10 and example 11.
Claims (7)
1. A preparation method of a rosin mixture biological medicine fertilizer is characterized by comprising the following steps:
adding the rosin mixture biological pesticide into a fertilizer according to the mass ratio of 0.2-5: 100 to obtain a rosin mixture biological pesticide fertilizer;
the rosin mixture biological pesticide is characterized by comprising the following steps of:
adding the rosin mixture, the Chinese herbal medicine extracting solution, the synergist and the vegetable oil into a homogenizer according to the mass ratio of 20-30: 10-20: 30-50, and homogenizing at least once to obtain the rosin mixture biological medicine fertilizer;
the Chinese herbal medicine extracting solution is a composition of a derris extracting solution, a houttuynia cordata extracting solution, a garlic extracting solution, an orange peel extracting solution and a cinnamon extracting solution according to a mass ratio of 40-60: 20-40: 10-20: 5-10: 10-20; the extraction method comprises water extraction;
the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 15-30: 5-10: 25-40: 10-20;
the vegetable oil is one or more than two of palm oil, coconut oil, chinaberry seed oil, citrus oil and litsea cubeba oil in any proportion;
the rosin mixture is prepared according to the following steps: adding rosin, organic base, a catalyst and water into a container according to a mass ratio of 10-30: 20-40: 0.5-5: 80-120, heating at 80-100 ℃ for 30-90 min, and filtering out impurities to obtain filtrate, namely a rosin mixture;
the organic alkali is one or more than two of monoethanolamine, diethanolamine, triethanolamine and sodium ethoxide in any proportion;
the catalyst is one or more than two of sulfuric acid, hydrochloric acid and nitric acid in any proportion.
2. The method for preparing the rosin mixture biological medicinal fertilizer as claimed in claim 1, wherein the rosin mixture biological medicinal fertilizer comprises the following steps: the composition comprises derris extract, houttuynia cordata extract, garlic extract, orange peel extract and cinnamon extract according to the mass ratio of 50:25:15:8: 15;
the extraction method of the extracting solution is characterized by comprising the following steps of:
1) preparing a primary liquid: adding the Chinese herbal medicines and water into a container according to a mass ratio of 1: 5-40, heating to 50-75 ℃, keeping the temperature for 20-90 min, cooling to 20-40 ℃, and filtering to obtain a filtrate, namely a primary solution; the obtained residue is the residue;
2) preparing a secondary liquid: adding the medicine residues and water into a container according to a mass ratio of 1: 5-40, heating to 70-120 ℃, keeping the temperature for 20-90 min under the condition that the pressure is 0-5 MPa, cooling to 20-40 ℃, and filtering to obtain a filtrate, namely a secondary liquid;
3) preparing an extracting solution: mixing the primary liquid obtained in the step 1) and the secondary liquid obtained in the step 2), and concentrating for 0-90 min at the temperature of 20-90 ℃ and under the pressure of-5 MPa-0 MPa to obtain a concentrated solution, namely an extracting solution.
3. The method for preparing the rosin mixture biological medicinal fertilizer as claimed in claim 1, wherein the rosin mixture biological medicinal fertilizer comprises the following steps: the synergist is a composition of AEO-3, AEO-9, span-80, sorbitol and glycerol according to a mass ratio of 20:25:8:30: 15.
4. The method for preparing the rosin mixture biological medicinal fertilizer as claimed in claim 1, wherein the rosin mixture biological medicinal fertilizer comprises the following steps: the vegetable oil is litsea cubeba oil.
5. The method for preparing the rosin mixture biological medicinal fertilizer as claimed in claim 1 or 2, characterized in that: the organic base is triethanolamine; the catalyst is nitric acid.
6. The method for preparing the rosin mixture biological medicinal fertilizer as claimed in claim 1, wherein the rosin mixture biological medicinal fertilizer comprises the following steps: the mass ratio of the rosin mixture to the Chinese herbal medicine extracting solution to the synergist to the vegetable oil is 20:30:15: 35.
7. The method for preparing the rosin mixture biological medicinal fertilizer as claimed in claim 1, wherein the rosin mixture biological medicinal fertilizer comprises the following steps: homogenizing for 2 times, wherein the first homogenizing pressure is 15-35 MPa, the homogenizing temperature is 50-70 ℃, and the homogenizing time is 10-60 min; the second homogenizing pressure is 2-8 PMa, the homogenizing temperature is 50-70 ℃, and the homogenizing time is 10-60 min.
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