CN107164967A - A kind of preparation method of the processed down fiber of antibacterial deodourizing eider down - Google Patents

A kind of preparation method of the processed down fiber of antibacterial deodourizing eider down Download PDF

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Publication number
CN107164967A
CN107164967A CN201710403883.4A CN201710403883A CN107164967A CN 107164967 A CN107164967 A CN 107164967A CN 201710403883 A CN201710403883 A CN 201710403883A CN 107164967 A CN107164967 A CN 107164967A
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antibacterial deodourizing
gained
parts
eider down
preparation
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李林刚
汪锐
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Anhui Three Auspicious Feather Ltd By Share Ltd
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Anhui Three Auspicious Feather Ltd By Share Ltd
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    • D06M2101/12—Keratin fibres or silk

Abstract

The invention discloses a kind of preparation method of the processed down fiber of antibacterial deodourizing eider down, it is related to eiderdown quilt processing technique field, comprises the following steps：(1) prepared by eider down ungrease treatment, (2) antibacterial deodourizing treatment fluid, the processing of (3) eider down antibacterial deodourizing, the shaping of (4) antibacterial deodourizing down fiber.The made antibacterial deodourizing down fiber of the present invention has excellent antibacterial deodourizing effect, more than 99% is reached to the average bacteriostasis rate of gold-coloured staphylococci, candida albicanses and Escherichia coli, and by made antibacterial deodourizing down fiber be made eiderdown quilt normally using after 1 year to the average bacteriostasis rates of gold-coloured staphylococci, candida albicanses and Escherichia coli more than 97%, it is normal using after 3 years to the average bacteriostasis rates of gold-coloured staphylococci, candida albicanses and Escherichia coli more than 95%.

Description

A kind of preparation method of the processed down fiber of antibacterial deodourizing eider down
Technical field：
The present invention relates to eiderdown quilt processing technique field, and in particular to a kind of processed down fiber of antibacterial deodourizing eider down Preparation method.
Background technology：
Eider down is good natural heat insulating material, has the advantages that light weight, softness, good heat preservation performance, therefore eiderdown quilt is to disappear Expense person warming bedding are preferably selected.But, the chemical composition of eider down is a kind of protein, and with animal fat, Even across degreasing and matting in preprocessing process, impurity and bacterium can not be still completely eliminated.Also, using process In if irregularly dried, it is easy to breed bacteria, while being produced with peculiar smell.
At present, the mould proof method for deodorizing of eider down reported is mainly using inorganic antiseptic and natural antibacterial agent to eider down Fiber is handled, and wherein inorganic antiseptic is using silver-based inorganic antibacterial agent as representative, although its antibacterial deodourizing effect is notable, but with The Percentage bound of down fiber is low, and processing cost is higher.Natural antibacterial agent is using chitin as representative, although processing cost is low, But the binding strength with down fiber is poor, antibacterial deodourizing action time is short.
The content of the invention：
The technical problems to be solved by the invention are to provide a kind of anti-bacteium deodorization finishing agent Percentage bound height, binding strength By force, the preparation method of the processed down fiber of antibacterial deodourizing eider down of long action time.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of preparation method of the processed down fiber of antibacterial deodourizing eider down, comprises the following steps：
(1) eider down ungrease treatment：Degreasing agent is warming up to 35-40 DEG C of insulation mixing 3-5min, added through HTHP Eider down after disinfecting, makes eider down be totally submerged in degreasing agent, pulls eider down out after 5-10min, washes twice, and in Dried under the conditions of 70-75 DEG C；
(2) prepared by antibacterial deodourizing treatment fluid：Boiling water is added under stirring into anti-bacteium deodorization finishing agent, makes gained antibacterial deodourizing The weight water content for the treatment of fluid reaches 65-70%, and naturally cools to room temperature；
(3) eider down antibacterial deodourizing is handled：Eider down after ungrease treatment is ground into coarse powder, 100 mesh sieves are crossed, then spray into anti- Bacterium deodorization treatment fluid, is sufficiently mixed, and is warming up to 65-70 DEG C of insulation mixing 10-15min with 2-3 DEG C/min programming rate, so 15-20 DEG C of water is added dropwise with 2-3ml/min rate of addition under stirring afterwards, the weight water content of gained mixture is reached 55- 60%, finally send into freeze drier, dry the gained size-reduced machine of solid and fine powder is made, cross 200 mesh sieves；
(4) antibacterial deodourizing down fiber is molded：Gained down fiber powder is mixed with water after being handled through above-mentioned antibacterial deodourizing After be made mixed liquor, mixed liquor is sprayed under pressure pumping action by nozzle in pencil form, crin is formed after solidification, and pass through Gained down fiber is cut into 15-20mm length after three stretchings, once curling.
The mass ratio of eider down and antibacterial deodourizing treatment fluid is 20-30 in the step (3):1-2.
The mass ratio of down fiber powder and water is 1-2 in the step (4):5-10.
The degreasing agent is made up of the raw material of following parts by weight：Polyvinyl alcohol/10-15 parts of microcrystalline cellulose, carboxymethyl 2-3 parts of sodium starch, 1-2 parts of allyl polyethenoxy ether, 0.5-1 parts of super fine magnesia, N, N- caprolactams 0.5-1 Part, 0.5-1 parts of saleratus power, double trifluoromethanesulfonimide 0.1-0.3 parts, 50-100 parts of water, its preparation method is：To carboxylic first Allyl polyethenoxy ether and N, N- caprolactam are added in base sodium starch, 110-115 DEG C of insulation grinding is warming up to 15min, adds saleratus power and double trifluoromethanesulfonimides, continues to be incubated grinding 10min, produces modified carboxy methyl starch Sodium, after naturally cool to polyvinyl alcohol/microcrystalline cellulose, super fine magnesia and water is added after 45-50 DEG C, gained mixed liquor is sent into In ball mill, discharging-material size is milled to less than 30 μm, degreasing agent is produced.
Polyvinyl alcohol/the microcrystalline cellulose is composited by polyvinyl alcohol and microcrystalline cellulose, its specific preparation side Method is：Boiling water is added dropwise until being completely dissolved with 5ml/min rate of addition into polyvinyl alcohol, and adds N- methylol acryloyls Amine and allyl glycidyl ether, flow back insulated and stirred 10min, adds microcrystalline cellulose, continues the insulated and stirred that flows back 30min, gained mixed liquor naturally cools to room temperature, finally sends into freeze drier, dries gained solid through micronizer Micro mist is made, polyvinyl alcohol/microcrystalline cellulose is produced.
The polyvinyl alcohol, N hydroxymethyl acrylamide, the mass ratio of allyl glycidyl ether and microcrystalline cellulose are 5-10:0.5-1:0.3-0.5:5-10。
The anti-bacteium deodorization finishing agent is made up of the raw material of following parts by weight：5-10 parts of polyglutamic acid, sodium alginate 3-5 parts, 2-3 parts of Tea Saponin, 1-2 parts of HPMA, 0.5-1 parts of sodium gluconate, hexamethylolmelamine pregnancy 0.5-1 parts of ether, 0.3-0.5 parts of nanometer titanium dioxide, 0.05-0.1 parts of Nano Silver, 0.05-0.1 parts of ferrocene, its preparation method is： Sodium alginate and HPMA are added into polyglutamic acid, gained powder is warming up to 50-55 DEG C of insulation grinding 10min, then boiling water is added dropwise with 5ml/min rate of addition under agitation, until powder all dissolves, then add Tea Saponin, Nanometer titanium dioxide, Nano Silver and ferrocene, utilize microwave treater microwave 5min after being sufficiently mixed, stand micro- again after 30min Ripple 5min, is subsequently added sodium gluconate and hexamethylolmelamine pregnancy ether, sends into gained mixed liquor after being well mixed In spray dryer, dry gained particle and micro mist is made through micronizer, produce anti-bacteium deodorization finishing agent.
The condition of work of the microwave treater is microwave frequency 2450MHz, power output 700W.
The beneficial effects of the invention are as follows：
(1) ungrease treatment is carried out to eider down using the degreasing agent, effectively removes the fatty impurity adhered on eider down, make Eider down Oil and Fat Content is reduced to less than 0.2%；
(2) it is fine by contained carboxyl and eider down using polyglutamic acid, sodium alginate and HPMA as carrier The sterol reaction generation ester bond in most cells of superficial layer film is tieed up, makes antibacterial deodourizing composition by carrier strong bonded in down fiber On, strengthen binding strength while improving Percentage bound；And using sodium gluconate and hexamethylolmelamine pregnancy ether as Load auxiliary agent, load factor of the enhancing antibacterial deodourizing composition on carrier；
(3) there is excellent antibacterial deodourizing effect through the made antibacterial deodourizing down fiber of the method for the invention, to gold The average bacteriostasis rate of staphylococcus, candida albicanses and Escherichia coli reaches more than 99%, and by made antibacterial deodourizing eider down The average bacteriostasis rate to gold-coloured staphylococci, candida albicanses and Escherichia coli after eiderdown quilt is normally used 1 year is made in fiber More than 97%, the average bacteriostasis rate of gold-coloured staphylococci, candida albicanses and Escherichia coli is existed after normally using 3 years More than 95%.
Embodiment：
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
(1) eider down ungrease treatment：Degreasing agent is warming up to 35-40 DEG C of insulation mixing 5min, adds and disappears through HTHP Eider down after poison processing, makes eider down be totally submerged in degreasing agent, pulls eider down out after 10min, washes twice, and in 70-75 Dried under the conditions of DEG C；
(2) prepared by antibacterial deodourizing treatment fluid：Boiling water is added under stirring into anti-bacteium deodorization finishing agent, makes gained antibacterial deodourizing The weight water content for the treatment of fluid reaches 65-70%, and naturally cools to room temperature；
(3) eider down antibacterial deodourizing is handled：Eider downs of the 1kg after ungrease treatment is ground into coarse powder, 100 mesh sieves are crossed, then spray Enter 0.05kg antibacterial deodourizing treatment fluids, be sufficiently mixed, and 65-70 DEG C of insulation mixing is warming up to 2-3 DEG C/min programming rate 15min, 15-20 DEG C of water is added dropwise under then stirring with 2-3ml/min rate of addition, reaches the weight water content of gained mixture To 55-60%, finally send into freeze drier, dry the gained size-reduced machine of solid and fine powder is made, cross 200 mesh sieves；
(4) antibacterial deodourizing down fiber is molded：Gained 1kg down fibers powder and 5kg after being handled through above-mentioned antibacterial deodourizing Mixed liquor is made after water mixing, mixed liquor is sprayed under pressure pumping action by nozzle in pencil form, forms thick after solidification Silk, and through three stretchings, once crimp after gained down fiber is cut into 15-20mm length.
The preparation of degreasing agent：1kg allyl polyethenoxy ethers and 0.5kg N, N- second are added into 3kg sodium carboxymethyl starches Alkenyl caprolactam, is warming up to 110-115 DEG C of insulation grinding 15min, adds 0.5kg saleratus powers and the double fluoroforms of 0.1kg Alkane sulfimide, continues to be incubated grinding 10min, produces modified carboxy methyl sodium starch, added after naturally cool to after 45-50 DEG C In 10kg polyvinyl alcohol/microcrystalline cellulose, 0.5kg super fine magnesias and 100kg water, gained mixed liquor feeding ball mill, ball milling It is less than 30 μm to discharging-material size, produces degreasing agent.
The preparation of polyvinyl alcohol/microcrystalline cellulose：Boiling water is added dropwise with 5ml/min rate of addition into 10kg polyvinyl alcohol Until being completely dissolved, and 1kgN- NMAs and 0.3kg allyl glycidyl ethers are added, flow back insulated and stirred 10min, adds 10kg microcrystalline celluloses, continues the insulated and stirred 30min that flows back, and gained mixed liquor naturally cools to room temperature, most Afterwards in feeding freeze drier, dry gained solid and micro mist is made through micronizer, produce polyvinyl alcohol/microcrystalline cellulose.
The preparation of anti-bacteium deodorization finishing agent：30g sodium alginates are added into 100g polyglutamic acids and 10g hydrolyzes poly- Malaysia Acid anhydrides, gained powder is warming up to 50-55 DEG C of insulation grinding 10min, then under agitation with 5ml/min rate of addition dropwise addition boiling Water, until powder all dissolves, then adds 20g Tea Saponins, 3g nanometer titanium dioxides, 0.5g Nano Silvers and 0.5g ferrocene, fills Divide and microwave frequency 2450MHz, power output 700W microwave treater microwave 5min are utilized after mixing, stand after 30min again Microwave 5min, is subsequently added 5g sodium gluconates and 5g hexamethylolmelamine pregnancy ethers, mixes gained after being well mixed In liquid feeding spray dryer, dry gained particle and micro mist is made through micronizer, produce anti-bacteium deodorization finishing agent.
Embodiment 2
(1) eider down ungrease treatment：Degreasing agent is warming up to 35-40 DEG C of insulation mixing 5min, adds and disappears through HTHP Eider down after poison processing, makes eider down be totally submerged in degreasing agent, pulls eider down out after 10min, washes twice, and in 70-75 Dried under the conditions of DEG C；
(2) prepared by antibacterial deodourizing treatment fluid：Boiling water is added under stirring into anti-bacteium deodorization finishing agent, makes gained antibacterial deodourizing The weight water content for the treatment of fluid reaches 65-70%, and naturally cools to room temperature；
(3) eider down antibacterial deodourizing is handled：Eider downs of the 1.5kg after ungrease treatment is ground into coarse powder, 100 mesh sieves are crossed, then 0.1kg antibacterial deodourizing treatment fluids are sprayed into, are sufficiently mixed, and 65-70 DEG C of insulation mixing is warming up to 2-3 DEG C/min programming rate 15min, 15-20 DEG C of water is added dropwise under then stirring with 2-3ml/min rate of addition, reaches the weight water content of gained mixture To 55-60%, finally send into freeze drier, dry the gained size-reduced machine of solid and fine powder is made, cross 200 mesh sieves；
(4) antibacterial deodourizing down fiber is molded：Gained 1kg down fibers powder and 5kg after being handled through above-mentioned antibacterial deodourizing Mixed liquor is made after water mixing, mixed liquor is sprayed under pressure pumping action by nozzle in pencil form, forms thick after solidification Silk, and through three stretchings, once crimp after gained down fiber is cut into 15-20mm length.
The preparation of degreasing agent：1kg allyl polyethenoxy ethers and 0.5kg N, N- second are added into 3kg sodium carboxymethyl starches Alkenyl caprolactam, is warming up to 110-115 DEG C of insulation grinding 15min, adds 0.5kg saleratus powers and the double fluoroforms of 0.1kg Alkane sulfimide, continues to be incubated grinding 10min, produces modified carboxy methyl sodium starch, added after naturally cool to after 45-50 DEG C In 15kg polyvinyl alcohol/microcrystalline cellulose, 0.5kg super fine magnesias and 100kg water, gained mixed liquor feeding ball mill, ball milling It is less than 30 μm to discharging-material size, produces degreasing agent.
The preparation of polyvinyl alcohol/microcrystalline cellulose：Boiling water is added dropwise with 5ml/min rate of addition into 8kg polyvinyl alcohol Until being completely dissolved, and 0.5kgN- NMAs and 0.5kg allyl glycidyl ethers are added, flow back insulated and stirred 10min, adds 10kg microcrystalline celluloses, continues the insulated and stirred 30min that flows back, and gained mixed liquor naturally cools to room temperature, most Afterwards in feeding freeze drier, dry gained solid and micro mist is made through micronizer, produce polyvinyl alcohol/microcrystalline cellulose.
The preparation of anti-bacteium deodorization finishing agent：30g sodium alginates are added into 100g polyglutamic acids and 10g hydrolyzes poly- Malaysia Acid anhydrides, gained powder is warming up to 50-55 DEG C of insulation grinding 10min, then under agitation with 5ml/min rate of addition dropwise addition boiling Water, until powder all dissolves, then adds 30g Tea Saponins, 5g nanometer titanium dioxides, 0.5g Nano Silvers and 0.5g ferrocene, fills Divide and microwave frequency 2450MHz, power output 700W microwave treater microwave 5min are utilized after mixing, stand after 30min again Microwave 5min, is subsequently added 8g sodium gluconates and 5g hexamethylolmelamine pregnancy ethers, mixes gained after being well mixed In liquid feeding spray dryer, dry gained particle and micro mist is made through micronizer, produce anti-bacteium deodorization finishing agent.
Reference examples 1
(1) eider down ungrease treatment：Degreasing agent is warming up to 35-40 DEG C of insulation mixing 5min, adds and disappears through HTHP Eider down after poison processing, makes eider down be totally submerged in degreasing agent, pulls eider down out after 10min, washes twice, and in 70-75 Dried under the conditions of DEG C；
(2) prepared by antibacterial deodourizing treatment fluid：Boiling water is added under stirring into anti-bacteium deodorization finishing agent, makes gained antibacterial deodourizing The weight water content for the treatment of fluid reaches 65-70%, and naturally cools to room temperature；
(3) eider down antibacterial deodourizing is handled：Eider downs of the 1.5kg after ungrease treatment is ground into coarse powder, 100 mesh sieves are crossed, then 0.1kg antibacterial deodourizing treatment fluids are sprayed into, are sufficiently mixed, and 65-70 DEG C of insulation mixing is warming up to 2-3 DEG C/min programming rate 15min, 15-20 DEG C of water is added dropwise under then stirring with 2-3ml/min rate of addition, reaches the weight water content of gained mixture To 55-60%, finally send into freeze drier, dry the gained size-reduced machine of solid and fine powder is made, cross 200 mesh sieves；
(4) antibacterial deodourizing down fiber is molded：Gained 1kg down fibers powder and 5kg after being handled through above-mentioned antibacterial deodourizing Mixed liquor is made after water mixing, mixed liquor is sprayed under pressure pumping action by nozzle in pencil form, forms thick after solidification Silk, and through three stretchings, once crimp after gained down fiber is cut into 15-20mm length.
The preparation of degreasing agent：1kg allyl polyethenoxy ethers and 0.5kg N, N- second are added into 3kg sodium carboxymethyl starches Alkenyl caprolactam, is warming up to 110-115 DEG C of insulation grinding 15min, adds 0.5kg saleratus powers and the double fluoroforms of 0.1kg Alkane sulfimide, continues to be incubated grinding 10min, produces modified carboxy methyl sodium starch, added after naturally cool to after 45-50 DEG C In 15kg polyvinyl alcohol/microcrystalline cellulose, 0.5kg super fine magnesias and 100kg water, gained mixed liquor feeding ball mill, ball milling It is less than 30 μm to discharging-material size, produces degreasing agent.
The preparation of polyvinyl alcohol/microcrystalline cellulose：Boiling water is added dropwise with 5ml/min rate of addition into 8kg polyvinyl alcohol Until being completely dissolved, flow back insulated and stirred 10min, adds 10kg microcrystalline celluloses, continues flow back insulated and stirred 30min, institute Obtain mixed liquor and naturally cool to room temperature, finally send into freeze drier, dry gained solid and micro mist is made through micronizer, Produce polyvinyl alcohol/microcrystalline cellulose.
The preparation of anti-bacteium deodorization finishing agent：30g sodium alginates are added into 100g polyglutamic acids and 10g hydrolyzes poly- Malaysia Acid anhydrides, gained powder is warming up to 50-55 DEG C of insulation grinding 10min, then under agitation with 5ml/min rate of addition dropwise addition boiling Water, until powder all dissolves, then adds 30g Tea Saponins, 5g nanometer titanium dioxides, 0.5g Nano Silvers and 0.5g ferrocene, fills Divide and microwave frequency 2450MHz, power output 700W microwave treater microwave 5min are utilized after mixing, stand after 30min again Microwave 5min, is subsequently added 8g sodium gluconates and 5g hexamethylolmelamine pregnancy ethers, mixes gained after being well mixed In liquid feeding spray dryer, dry gained particle and micro mist is made through micronizer, produce anti-bacteium deodorization finishing agent.
Reference examples 2
(1) eider down ungrease treatment：Degreasing agent is warming up to 35-40 DEG C of insulation mixing 5min, adds and disappears through HTHP Eider down after poison processing, makes eider down be totally submerged in degreasing agent, pulls eider down out after 10min, washes twice, and in 70-75 Dried under the conditions of DEG C；
(2) prepared by antibacterial deodourizing treatment fluid：Boiling water is added under stirring into anti-bacteium deodorization finishing agent, makes gained antibacterial deodourizing The weight water content for the treatment of fluid reaches 65-70%, and naturally cools to room temperature；
(3) eider down antibacterial deodourizing is handled：Eider downs of the 1.5kg after ungrease treatment is ground into coarse powder, 100 mesh sieves are crossed, then 0.1kg antibacterial deodourizing treatment fluids are sprayed into, are sufficiently mixed, and 65-70 DEG C of insulation mixing is warming up to 2-3 DEG C/min programming rate 15min, 15-20 DEG C of water is added dropwise under then stirring with 2-3ml/min rate of addition, reaches the weight water content of gained mixture To 55-60%, finally send into freeze drier, dry the gained size-reduced machine of solid and fine powder is made, cross 200 mesh sieves；
(4) antibacterial deodourizing down fiber is molded：Gained 1kg down fibers powder and 5kg after being handled through above-mentioned antibacterial deodourizing Mixed liquor is made after water mixing, mixed liquor is sprayed under pressure pumping action by nozzle in pencil form, forms thick after solidification Silk, and through three stretchings, once crimp after gained down fiber is cut into 15-20mm length.
The preparation of degreasing agent：3kg sodium carboxymethyl starches are warming up to after 45-50 DEG C and add 15kg polyvinyl alcohol/crystallite fibre In dimension element, 0.5kg super fine magnesias and 100kg water, gained mixed liquor feeding ball mill, discharging-material size is milled to less than 30 μm, Produce degreasing agent.
The preparation of polyvinyl alcohol/microcrystalline cellulose：Boiling water is added dropwise with 5ml/min rate of addition into 8kg polyvinyl alcohol Until being completely dissolved, and 0.5kgN- NMAs and 0.5kg allyl glycidyl ethers are added, flow back insulated and stirred 10min, adds 10kg microcrystalline celluloses, continues the insulated and stirred 30min that flows back, and gained mixed liquor naturally cools to room temperature, most Afterwards in feeding freeze drier, dry gained solid and micro mist is made through micronizer, produce polyvinyl alcohol/microcrystalline cellulose.
The preparation of anti-bacteium deodorization finishing agent：30g sodium alginates are added into 100g polyglutamic acids and 10g hydrolyzes poly- Malaysia Acid anhydrides, gained powder is warming up to 50-55 DEG C of insulation grinding 10min, then under agitation with 5ml/min rate of addition dropwise addition boiling Water, until powder all dissolves, then adds 30g Tea Saponins, 5g nanometer titanium dioxides, 0.5g Nano Silvers and 0.5g ferrocene, fills Divide and microwave frequency 2450MHz, power output 700W microwave treater microwave 5min are utilized after mixing, stand after 30min again Microwave 5min, is subsequently added 8g sodium gluconates and 5g hexamethylolmelamine pregnancy ethers, mixes gained after being well mixed In liquid feeding spray dryer, dry gained particle and micro mist is made through micronizer, produce anti-bacteium deodorization finishing agent.
Reference examples 3
(1) eider down ungrease treatment：Degreasing agent is warming up to 35-40 DEG C of insulation mixing 5min, adds and disappears through HTHP Eider down after poison processing, makes eider down be totally submerged in degreasing agent, pulls eider down out after 10min, washes twice, and in 70-75 Dried under the conditions of DEG C；
(2) prepared by antibacterial deodourizing treatment fluid：Boiling water is added under stirring into anti-bacteium deodorization finishing agent, makes gained antibacterial deodourizing The weight water content for the treatment of fluid reaches 65-70%, and naturally cools to room temperature；
(3) eider down antibacterial deodourizing is handled：Eider downs of the 1.5kg after ungrease treatment is ground into coarse powder, 100 mesh sieves are crossed, then 0.1kg antibacterial deodourizing treatment fluids are sprayed into, are sufficiently mixed, and 65-70 DEG C of insulation mixing is warming up to 2-3 DEG C/min programming rate 15min, 15-20 DEG C of water is added dropwise under then stirring with 2-3ml/min rate of addition, reaches the weight water content of gained mixture To 55-60%, finally send into freeze drier, dry the gained size-reduced machine of solid and fine powder is made, cross 200 mesh sieves；
(4) antibacterial deodourizing down fiber is molded：Gained 1kg down fibers powder and 5kg after being handled through above-mentioned antibacterial deodourizing Mixed liquor is made after water mixing, mixed liquor is sprayed under pressure pumping action by nozzle in pencil form, forms thick after solidification Silk, and through three stretchings, once crimp after gained down fiber is cut into 15-20mm length.
The preparation of degreasing agent：1kg allyl polyethenoxy ethers and 0.5kg N, N- second are added into 3kg sodium carboxymethyl starches Alkenyl caprolactam, is warming up to 110-115 DEG C of insulation grinding 15min, adds 0.5kg saleratus powers and the double fluoroforms of 0.1kg Alkane sulfimide, continues to be incubated grinding 10min, produces modified carboxy methyl sodium starch, added after naturally cool to after 45-50 DEG C In 15kg polyvinyl alcohol/microcrystalline cellulose, 0.5kg super fine magnesias and 100kg water, gained mixed liquor feeding ball mill, ball milling It is less than 30 μm to discharging-material size, produces degreasing agent.
The preparation of polyvinyl alcohol/microcrystalline cellulose：Boiling water is added dropwise with 5ml/min rate of addition into 8kg polyvinyl alcohol Until being completely dissolved, and 0.5kgN- NMAs and 0.5kg allyl glycidyl ethers are added, flow back insulated and stirred 10min, adds 10kg microcrystalline celluloses, continues the insulated and stirred 30min that flows back, and gained mixed liquor naturally cools to room temperature, most Afterwards in feeding freeze drier, dry gained solid and micro mist is made through micronizer, produce polyvinyl alcohol/microcrystalline cellulose.
The preparation of anti-bacteium deodorization finishing agent：30g sodium alginates are added into 100g polyglutamic acids and 10g hydrolyzes poly- Malaysia Acid anhydrides, gained powder is warming up to 50-55 DEG C of insulation grinding 10min, then under agitation with 5ml/min rate of addition dropwise addition boiling Water, until powder all dissolves, then adds 30g Tea Saponins, 5g nanometer titanium dioxides, 0.5g Nano Silvers and 0.5g ferrocene, fills Divide and microwave frequency 2450MHz, power output 700W microwave treater microwave 5min are utilized after mixing, stand after 30min again In microwave 5min, gained mixed liquor feeding spray dryer, dry gained particle and micro mist is made through micronizer, produce antibacterial Deodorization finishing agent.
Reference examples 4
(1) eider down ungrease treatment：Degreasing agent is warming up to 35-40 DEG C of insulation mixing 5min, adds and disappears through HTHP Eider down after poison processing, makes eider down be totally submerged in degreasing agent, pulls eider down out after 10min, washes twice, and in 70-75 Dried under the conditions of DEG C；
(2) prepared by antibacterial deodourizing treatment fluid：Boiling water is added under stirring into anti-bacteium deodorization finishing agent, makes gained antibacterial deodourizing The weight water content for the treatment of fluid reaches 65-70%, and naturally cools to room temperature；
(3) eider down antibacterial deodourizing is handled：Eider downs of the 1.5kg after ungrease treatment is ground into coarse powder, 100 mesh sieves are crossed, then 0.1kg antibacterial deodourizing treatment fluids are sprayed into, are sufficiently mixed, and 65-70 DEG C of insulation mixing is warming up to 2-3 DEG C/min programming rate 15min, 15-20 DEG C of water is added dropwise under then stirring with 2-3ml/min rate of addition, reaches the weight water content of gained mixture To 55-60%, finally send into freeze drier, dry the gained size-reduced machine of solid and fine powder is made, cross 200 mesh sieves；
(4) antibacterial deodourizing down fiber is molded：Gained 1kg down fibers powder and 5kg after being handled through above-mentioned antibacterial deodourizing Mixed liquor is made after water mixing, mixed liquor is sprayed under pressure pumping action by nozzle in pencil form, forms thick after solidification Silk, and through three stretchings, once crimp after gained down fiber is cut into 15-20mm length.
The preparation of degreasing agent：1kg allyl polyethenoxy ethers and 0.5kg N, N- second are added into 3kg sodium carboxymethyl starches Alkenyl caprolactam, is warming up to 110-115 DEG C of insulation grinding 15min, adds 0.5kg saleratus powers and the double fluoroforms of 0.1kg Alkane sulfimide, continues to be incubated grinding 10min, produces modified carboxy methyl sodium starch, added after naturally cool to after 45-50 DEG C In 15kg polyvinyl alcohol/microcrystalline cellulose, 0.5kg super fine magnesias and 100kg water, gained mixed liquor feeding ball mill, ball milling It is less than 30 μm to discharging-material size, produces degreasing agent.
The preparation of polyvinyl alcohol/microcrystalline cellulose：Boiling water is added dropwise with 5ml/min rate of addition into 8kg polyvinyl alcohol Until being completely dissolved, and 0.5kgN- NMAs and 0.5kg allyl glycidyl ethers are added, flow back insulated and stirred 10min, adds 10kg microcrystalline celluloses, continues the insulated and stirred 30min that flows back, and gained mixed liquor naturally cools to room temperature, most Afterwards in feeding freeze drier, dry gained solid and micro mist is made through micronizer, produce polyvinyl alcohol/microcrystalline cellulose.
The preparation of anti-bacteium deodorization finishing agent：Calculate the Tea Saponin contained in embodiment 2 in anti-bacteium deodorization finishing agent used, receive The quality of rice titanium dioxide, Nano Silver and ferrocene, then the Tea Saponin of equivalent, nanometer titanium dioxide, Nano Silver and ferrocene are disperseed In Yu Shuizhong, gained mixed liquor feeding spray dryer, dry gained particle and micro mist is made through micronizer, produce antibacterial and prevent Smelly finishing agent.
Embodiment 3
Eider down Oil and Fat Content measure is carried out to embodiment 1, embodiment 2, reference examples 1, the made down fiber of reference examples 2 respectively, And embodiment 1, embodiment 2, reference examples 1, reference examples 2, reference examples 3 and the made down fiber of reference examples 4 are determined to golden grape The bacteriostasis rate of coccus, candida albicanses and Escherichia coli, and made down fiber is made after eider down core normally uses 1 Year and after 3 years to gold-coloured staphylococci, candida albicanses and the bacteriostasis rate of Escherichia coli, as a result as shown in table 1.
The eider down Oil and Fat Content and bacteriostasis rate of the made down fiber of the invention of table 1
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (8)

1. a kind of preparation method of the processed down fiber of antibacterial deodourizing eider down, it is characterised in that comprise the following steps：
(1) eider down ungrease treatment：Degreasing agent is warming up to 35-40 DEG C of insulation mixing 3-5min, added through autoclave sterilization Eider down after processing, makes eider down be totally submerged in degreasing agent, pulls eider down out after 5-10min, washes twice, and in 70-75 Dried under the conditions of DEG C；
(2) prepared by antibacterial deodourizing treatment fluid：Boiling water is added under stirring into anti-bacteium deodorization finishing agent, makes gained antibacterial deodourizing processing The weight water content of liquid reaches 65-70%, and naturally cools to room temperature；
(3) eider down antibacterial deodourizing is handled：Eider down after ungrease treatment is ground into coarse powder, 100 mesh sieves is crossed, then sprays into antibacterial and prevent Smelly treatment fluid, is sufficiently mixed, and is warming up to 65-70 DEG C of insulation mixing 10-15min with 2-3 DEG C/min programming rate, then stirs Mix down and 15-20 DEG C of water is added dropwise with 2-3ml/min rate of addition, the weight water content of gained mixture is reached 55-60%, most Afterwards in feeding freeze drier, dry the gained size-reduced machine of solid and fine powder is made, cross 200 mesh sieves；
(4) antibacterial deodourizing down fiber is molded：Gained down fiber powder is made after being mixed with water after being handled through above-mentioned antibacterial deodourizing Into mixed liquor, mixed liquor is sprayed under pressure pumping action by nozzle in pencil form, and crin is formed after solidification, and through three times Gained down fiber is cut into 15-20mm length after stretching, once curling.
2. the preparation method of the processed down fiber of antibacterial deodourizing eider down according to claim 1, it is characterised in that：Institute The mass ratio for stating eider down and antibacterial deodourizing treatment fluid in step (3) is 20-30:1-2.
3. the preparation method of the processed down fiber of antibacterial deodourizing eider down according to claim 1, it is characterised in that：Institute The mass ratio for stating down fiber powder and water in step (4) is 1-2:5-10.
4. the preparation method of the processed down fiber of antibacterial deodourizing eider down according to claim 1, it is characterised in that：Institute Degreasing agent is stated to be made up of the raw material of following parts by weight：Polyvinyl alcohol/10-15 parts of microcrystalline cellulose, sodium carboxymethyl starch 2-3 Part, 1-2 parts of allyl polyethenoxy ether, 0.5-1 parts of super fine magnesia, N, 0.5-1 parts of N- caprolactams, saleratus power 0.5-1 parts, double trifluoromethanesulfonimide 0.1-0.3 parts, 50-100 parts of water, its preparation method is：Into sodium carboxymethyl starch Allyl polyethenoxy ether and N, N- caprolactam are added, 110-115 DEG C of insulation grinding 15min is warming up to, adds Saleratus power and double trifluoromethanesulfonimides, continue to be incubated grinding 10min, produce modified carboxy methyl sodium starch, treat that nature is cold But to addition polyvinyl alcohol/microcrystalline cellulose, super fine magnesia and water after 45-50 DEG C, in gained mixed liquor feeding ball mill, ball Discharging-material size is milled to less than 30 μm, degreasing agent is produced.
5. the preparation method of the processed down fiber of antibacterial deodourizing eider down according to claim 4, it is characterised in that：Institute Stating polyvinyl alcohol/microcrystalline cellulose is composited by polyvinyl alcohol and microcrystalline cellulose, and its specific preparation method is：Xiang Juyi Boiling water is added dropwise until being completely dissolved with 5ml/min rate of addition in enol, and adds N hydroxymethyl acrylamide and pi-allyl Glycidol ether, flow back insulated and stirred 10min, adds microcrystalline cellulose, continues the insulated and stirred 30min that flows back, gained mixing Liquid naturally cools to room temperature, finally sends into freeze drier, dries gained solid and micro mist is made through micronizer, produce poly- Vinyl alcohol/microcrystalline cellulose.
6. the preparation method of the processed down fiber of antibacterial deodourizing eider down according to claim 5, it is characterised in that：Institute The mass ratio for stating polyvinyl alcohol, N hydroxymethyl acrylamide, allyl glycidyl ether and microcrystalline cellulose is 5-10:0.5-1: 0.3-0.5:5-10。
7. the preparation method of the processed down fiber of antibacterial deodourizing eider down according to claim 1, it is characterised in that：Institute Anti-bacteium deodorization finishing agent is stated to be made up of the raw material of following parts by weight：5-10 parts of polyglutamic acid, 3-5 parts of sodium alginate, tea soap Plain 2-3 parts, 1-2 parts of HPMA, 0.5-1 parts of sodium gluconate, 0.5-1 parts of hexamethylolmelamine pregnancy ether, 0.3-0.5 parts of nanometer titanium dioxide, 0.05-0.1 parts of Nano Silver, 0.05-0.1 parts of ferrocene, its preparation method is：To many polyglutamics Sodium alginate and HPMA are added in acid, gained powder is warming up to 50-55 DEG C of insulation grinding 10min, then in stirring Under boiling water is added dropwise with 5ml/min rate of addition, until powder all dissolves, then add Tea Saponin, nanometer titanium dioxide, nanometer Silver and ferrocene, utilize microwave treater microwave 5min after being sufficiently mixed, stand microwave 5min again after 30min, be subsequently added Sodium gluconate and hexamethylolmelamine pregnancy ether, send into gained mixed liquor in spray dryer after being well mixed, and do Micro mist is made through micronizer in dry gained particle, produces anti-bacteium deodorization finishing agent.
8. the preparation method of the processed down fiber of antibacterial deodourizing eider down according to claim 7, it is characterised in that：Institute The condition of work for stating microwave treater is microwave frequency 2450MHz, power output 700W.
CN201710403883.4A 2017-06-01 2017-06-01 A kind of preparation method of the processed down fiber of antibacterial deodourizing eider down Pending CN107164967A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107660440A (en) * 2017-11-05 2018-02-06 茆莉娟 A kind of urban landscaping nursery stock transplanting trunk fixator
CN109610181A (en) * 2018-12-19 2019-04-12 东莞亿达服装科技有限公司 A kind of antibacterial deodourizing eider down outerwear
CN109853251A (en) * 2019-04-04 2019-06-07 六安市海洋羽毛有限公司 A kind of preparation method of flame-retardant waterproof natural feather
CN111498789A (en) * 2020-04-26 2020-08-07 安徽华英新塘羽绒有限公司 Antibacterial and antiseptic down and preparation method thereof
CN112792871A (en) * 2020-12-22 2021-05-14 蒋爱玉 Feather sequencing and shearing device
CN112853765A (en) * 2021-02-03 2021-05-28 百事基材料（青岛）股份有限公司 Down feather macrofiber containing active ingredients of tangerine peel, orange and pomelo and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103266022A (en) * 2013-05-11 2013-08-28 安徽三祥羽毛有限公司 Washing and deodorizing agent for washing feather
CN104947233A (en) * 2015-06-02 2015-09-30 安徽省含山县富强羽绒制品有限公司 Antistatic ecological bacteriostatic down fiber and making method thereof
CN104947223A (en) * 2015-06-02 2015-09-30 安徽省含山县富强羽绒制品有限公司 Low-damage green ecological bacteriostatic down fiber and making method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103266022A (en) * 2013-05-11 2013-08-28 安徽三祥羽毛有限公司 Washing and deodorizing agent for washing feather
CN104947233A (en) * 2015-06-02 2015-09-30 安徽省含山县富强羽绒制品有限公司 Antistatic ecological bacteriostatic down fiber and making method thereof
CN104947223A (en) * 2015-06-02 2015-09-30 安徽省含山县富强羽绒制品有限公司 Low-damage green ecological bacteriostatic down fiber and making method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107660440A (en) * 2017-11-05 2018-02-06 茆莉娟 A kind of urban landscaping nursery stock transplanting trunk fixator
CN109610181A (en) * 2018-12-19 2019-04-12 东莞亿达服装科技有限公司 A kind of antibacterial deodourizing eider down outerwear
CN109853251A (en) * 2019-04-04 2019-06-07 六安市海洋羽毛有限公司 A kind of preparation method of flame-retardant waterproof natural feather
CN111498789A (en) * 2020-04-26 2020-08-07 安徽华英新塘羽绒有限公司 Antibacterial and antiseptic down and preparation method thereof
CN111498789B (en) * 2020-04-26 2022-04-08 安徽华英新塘羽绒有限公司 Antibacterial and antiseptic down and preparation method thereof
CN112792871A (en) * 2020-12-22 2021-05-14 蒋爱玉 Feather sequencing and shearing device
CN112853765A (en) * 2021-02-03 2021-05-28 百事基材料（青岛）股份有限公司 Down feather macrofiber containing active ingredients of tangerine peel, orange and pomelo and preparation method thereof

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Application publication date: 20170915