CN1071450A - The compound method of high viscosity transparent acid detergent - Google Patents
The compound method of high viscosity transparent acid detergent Download PDFInfo
- Publication number
- CN1071450A CN1071450A CN 92105936 CN92105936A CN1071450A CN 1071450 A CN1071450 A CN 1071450A CN 92105936 CN92105936 CN 92105936 CN 92105936 A CN92105936 A CN 92105936A CN 1071450 A CN1071450 A CN 1071450A
- Authority
- CN
- China
- Prior art keywords
- add
- polyvinyl alcohol
- high viscosity
- acid
- washing composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention is the method for preparation high viscosity transparent acid detergent, it is characterized in that adopting polyvinyl alcohol as thickening material, under 80～100 ℃ of temperature, polyvinyl alcohol is mixed with suitable quantity of water, add cats products such as nonionogenic tensides such as an amount of polyoxyethylene nonylphenol ether or dodecane trimethyl ammonium chloride then, add organic acids such as appropriate hydrochloric acid, phosphoric acid, essence, pigment etc. again and mix and form.Wherein nonionic or cats product can be added a certainly respectively, also can add two kinds simultaneously.The present invention can make high viscosity, transparent clarifying acidic liquid washing composition, and cost is low, tart flavour is little, cleaning performance and sense organ effect are good.
Description
The present invention is a kind of compound method of high viscosity transparent acid detergent, and the system that belongs to washing composition is joined technical field.
The acidic liquid washing composition is used for the surface cleaning of water closet pan, ceramic tile, mosaic etc. more.But, acidic liquid washing composition and system thereof commonly used are at present joined technology, mainly there is following several problem: in the preparation of (1) slightly acidic liquid washing agent, most with amine or sulfonamide derivatives as thickening material, though made the slightly acidic liquid washing agent that certain viscosity is arranged, make it certain adhesive power be arranged on the washings surface, increased certain washing effect, but because slightly acidic, and viscosity is not enough, and its washing effect is also not good enough; (2) the present domestic high strong acidic liquid Betengent product of viscosity that do not have as yet, do not see the hydrochloric liquid washing agent that high viscosity is arranged especially, though the acidic liquid Betengent product of viscosity higher is abroad arranged, but its compound method is not reported, though or the strong acidic liquid washing composition of certain viscosity arranged also, but, that is to say to be difficult to obtain full-bodied, transparent strong acidic liquid washing composition because of opaque, sense organ weak effect; (3) existing many acidic liquid washing composition are in order to obtain cleaning performance preferably, and content of hydrochloric acid generally reaches 5～10%, the strong impulse acid gas flavor that makes washing composition have to be difficult to hide.During use human body is stimulated greatly, be not easy to be accepted by consumers in general.
Purpose of the present invention is exactly not good enough or have the shortcomings such as strong impulse acid gas flavor that are difficult to hide for above-mentioned strong acidic liquid washing composition, washing effect and the sense organ effect that is difficult to obtain high viscosity transparent that overcomes that existing acidic liquid washing composition exists, and develops a kind of method that can prepare high viscosity, transparent, the hydrochloric acid smell is minimum, washing effect and sense organ are effective acidic liquid washing composition.
The feature of the inventive method is: adopt the thickening material of polyvinyl alcohol as the acidic liquid washing composition, in temperature is under 80～100 ℃ of conditions, polyvinyl alcohol and an amount of water are mixed, add cats products such as nonionogenic tensides such as polyoxyethylene nonylphenol ether or Dodecyl trimethyl ammonium chloride then, add mineral acid, essence, pigment etc. again and mix and form, the weight percent of its each composition is:
Polyvinyl alcohol: 1～15%
Nonionic or cats product: 0.1～10%
Hydrochloric acid or phosphoric acid: 1～15%
Essence: 0.01～0.2%
Pigment: 0.00001～0.0001%
Water: surplus
Wherein nonionic or cats product can be added wherein a kind ofly respectively, also can add these two kinds of tensio-active agents simultaneously, and its add total amount should be within 0.1～10%.Just can be mixed with the acidic liquid washing composition of high viscosity, transparent clarification, no obvious irritation hydrochloric acid smell by the invention described above method.
The inventive method is compared following advantage and effect with the technology of the acid liquid washing agent of existing preparation: 1. can utilize polyvinyl alcohol cheap and easy to get as thickening material, cost is reduced, high economic benefit is arranged; 2. owing to the hydroxyl in the polyvinyl alcohol can form with hydrochloric acid or phosphoric acid
Salt, thus make hydrochloric acid or phosphoric acid in washing composition, to stablize, tart flavour is greatly reduced, and hydrochloric acid slowly-releasing with dirt digestion the time is come out, guarantee washing effect.Thereby reduced to use the harm of acid detergent to human body; 3. can make high viscosity, transparent clarifying acidic liquid washing composition with the inventive method, this washing composition is stronger at the surface adhesion of washings, thereby, can give full play to the effect of washing composition to the long action time of dirt, make that the washing composition consumption is economized, washing effect is good; 4. owing to also be added with essence, pigment, not only the sense organ effect is good to make the acidic liquid washing composition that the inventive method makes, and, energy fresh air savory with the back, is easily accepted by the human consumer; 5. this washing composition can not only be widely used in urine dirt, the bath dirt on porcelain surfaces such as cleaning water closet pan, bathtub, can also be as the remover of its surperficial scale.
The contriver has done research and the test of long period to the inventive method, and a lot of successful embodiment are arranged, and is just preparing batch process.Be two embodiment wherein below, the method for its enforcement all is by above-mentioned the inventive method, and the character of the washing composition of the present invention of its formulation weight per-cent and preparation gained thereof is respectively as follows:
One of embodiment, its each composition weight percent is:
Polyvinyl alcohol: 2%
Trimethyllaurylammonium bromide (1227): 1.5%
Hydrochloric acid: 8%
Essence: 0.1%
Pigment: 0.00001%
Water: surplus
Prepared high viscosity, transparent acid liquid washing agent character are: smell fragrance, proportion are 1.04g/ml, and the kinematic viscosity in the time of 20 ℃ is: 45.4mm
2/ s.
Two of embodiment, its each composition weight percent is:
Polyvinyl alcohol: 10%
Polyoxyethylene nonylphenol ether: 2%
Trimethyllaurylammonium bromide: 1%
Phosphoric acid: 15%
Essence: 0.15%
Pigment: 0.00005%
Water: surplus
The character of the high viscosity transparent acid liquid washing agent of preparing is: smell fragrance, proportion are 1.00g/ml, and the kinematic viscosity in the time of 20 ℃ is 72.5mm
2/ s.
Claims (1)
1, a kind of compound method of high viscosity transparent acid detergent, it is characterized in that: adopt the thickening material of polyvinyl alcohol as the acidic liquid washing composition, in temperature is under 80～100 ℃ of conditions, polyvinyl alcohol and an amount of water are mixed, add cats products such as nonionogenic tensides such as polyoxyethylene nonylphenol ether or dodecane trimethyl ammonium chloride then, add mineral acid, essence, pigment etc. again and mix and form, the weight percent of its each composition is:
Polyvinyl alcohol: 1～15%
Nonionic or cats product: 0.1～10%
Hydrochloric acid or phosphoric acid: 1～15%
Essence: 0.01～0.2%
Pigment: 0.00001～0.0001%
Wherein, nonionic or cats product can be added wherein a kind of tensio-active agent respectively, also can add this two kinds of tensio-active agents simultaneously, and its add total amount should be within 0.1～10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN92105936A CN1042235C (en) | 1992-07-29 | 1992-07-29 | Preparation of high viscosity transparent acid detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN92105936A CN1042235C (en) | 1992-07-29 | 1992-07-29 | Preparation of high viscosity transparent acid detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1071450A true CN1071450A (en) | 1993-04-28 |
| CN1042235C CN1042235C (en) | 1999-02-24 |
Family
ID=4941670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN92105936A Expired - Fee Related CN1042235C (en) | 1992-07-29 | 1992-07-29 | Preparation of high viscosity transparent acid detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1042235C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102776084A (en) * | 2011-05-09 | 2012-11-14 | 上海丰信环保科技有限公司 | Preparation method for wall surface cleaning agent |
| CN102963869A (en) * | 2012-10-19 | 2013-03-13 | 大连碧城环保科技有限公司 | Recycling method of discarded hydrochloric acid from pickling |
| CN105567450A (en) * | 2016-01-22 | 2016-05-11 | 柳州博泽科技有限公司 | Low-cost environment-friendly ceramic purificant |
| CN107012016A (en) * | 2017-05-11 | 2017-08-04 | 江苏苏沃尚新材料科技有限公司 | A kind of lavatory descaling deodorizing bactericide |
| CN107384605A (en) * | 2017-08-31 | 2017-11-24 | 重庆尚洁日化用品有限公司 | A kind of detergent for toilet |
| CN109706001A (en) * | 2019-01-31 | 2019-05-03 | 东莞市立顿洗涤用品实业有限公司 | Prevent flat bottle cleaning toilet essence and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1003243B (en) * | 1986-10-07 | 1989-02-08 | 广西壮族自治区职业病防治研究所 | Dertergent for washing away pollutant from heavy metals |
-
1992
- 1992-07-29 CN CN92105936A patent/CN1042235C/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102776084A (en) * | 2011-05-09 | 2012-11-14 | 上海丰信环保科技有限公司 | Preparation method for wall surface cleaning agent |
| CN102963869A (en) * | 2012-10-19 | 2013-03-13 | 大连碧城环保科技有限公司 | Recycling method of discarded hydrochloric acid from pickling |
| CN105567450A (en) * | 2016-01-22 | 2016-05-11 | 柳州博泽科技有限公司 | Low-cost environment-friendly ceramic purificant |
| CN107012016A (en) * | 2017-05-11 | 2017-08-04 | 江苏苏沃尚新材料科技有限公司 | A kind of lavatory descaling deodorizing bactericide |
| CN107384605A (en) * | 2017-08-31 | 2017-11-24 | 重庆尚洁日化用品有限公司 | A kind of detergent for toilet |
| CN109706001A (en) * | 2019-01-31 | 2019-05-03 | 东莞市立顿洗涤用品实业有限公司 | Prevent flat bottle cleaning toilet essence and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1042235C (en) | 1999-02-24 |
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Legal Events
| Date | Code | Title | Description |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |