JPS58186428A - Foamable surfactant composition - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

DETAILED DESCRIPTION OF THE INVENTION The Technical Public Fund Book@Ming relates to a field 11/filling agent combination that provides a foamable aqueous foam. The composition of this cypress is suitable for use in fields where foam is desirable, such as human cleaning products, dishwashing, fire extinguishing (fake r・flght amount ag'), % success method, ore beneficiation, sake QJi[g (aolutIon r
It can be used for manufacturing solid structures, etc.

Alkyl/17 glycosylation agents, which are activators of the prior art, are described in U.S. Pat. No. 3,598,865;
Xie No. 3,721,633, and No. 3,772,
It is mentioned in the specification of No. 269. In addition, these hour hands are manufactured by manufacturing alkyl polyglycoside surfactants and built liquid detergent compositions containing these surfactants. l
'ft disclosed. Rice Li! Threat IIfJi143,2
No. 19,656 discloses alkyl hair noglucosides and suggests utility as foam stabilizers for other foam-occupying agents.

Taniyoko 04 Ridarakoshi)' W Dor shasha agent structures and their surface preparation methods are described in U.S. Machichin Yuko 2,974,134.

Specification No. 3,640,998, No. 3,839,318
Specification of No. II 3,314,936, No. 3,
No. 346,558, No. 4,011,389, and No. 4,223,129.

Book #4 - All parts and parts used in the book are weighted unless otherwise noted.

SUMMARY OF THE INVENTION The present invention relates to the discovery of a combination of surfactants that provides an extraordinary 1121. Evaluation [K is the present invention, (1) Formula RO(R”O) tzx C, where Zt
Residues derived from reducing sugars having 5 to 6 S carbons, preferably glucose, galactose,! lucosyl, or galactosyl residue or a mixture thereof; R is a quartzophobic selected from the group consisting of an alkyl group, an alkylphenyl group, a hydroxyalkylphenyl group or a hydroxyalkyl group or a mixture thereof; The group has about 8 to about 1 carbon atoms, preferably about 10 to about 16 carbon atoms, and preferably about 1 to about 14 carbon atoms; R1
has 2 to 4 carbon atoms, preferably ethylene, propylene and/or dalyceryl, and t is 0 to about 11
Preferably 0 to about 10. jll is also preferably 0;
I is a number from about 1.5 to about 10, preferably from 1.5 to 4, most preferably from 1.6 to 2.7], and to complete formula (2) one or more cationic groups (M)
An ion co-interfacial f8 agent which is a nalphate, sulfonate, and/or car-xylate or a mixture thereof, preferably of the formula R' (803) (COO), kl, C, where R'
41fur4, alkylphenyl, hydroxyalkylphenyl or hydroxyalkyl, or one thereof
(the alkyl group # denotes a number of about 6 to about 4 carbon atoms, preferably about 10 to about 8 carbon atoms); y is a number from θ to about 4, and 2 is a number from 0 to about 4; , y + 1 is at least
is also 1, M is a cationic group, and 9 is a formula t-
The ratio of (2) to (1) is about 1=10 to about 1.
0:1 (i.e. 0.1-10) unless the co-surfactant is an alkylbenzene sulfonate (2)
The ratio of (1) to (2) is at least about 1:2 (i.e., less (both about 0.5), and if y is O and depth is 1, then (2) to (1) The ratio of is at least about 1:
2 (i.e., at least about 0.5), and if the anionic cosurfactant does not contain sulfonate or car-xylate groups, X must be from 1.5 to 3, and the alkyl polysaccharide interface Regarding the foaming composition, the active agent must have a free fatty alcohol content of less than about 2111.

Interestingly, co-surfactants have been found to readily interact with the alkyl polyhydric active agents of the present invention to provide relatively stable foams.

The present invention also relates to a method for producing foam using a water bathing agent contained in a mixed surfactant of about 0.01 S to Kuton s1.

DESCRIPTION OF PREFERRED EMBODIMENTS The alkyl group II has a hydrophobic group having about 8 to about 8 carbon atoms, preferably about 10 to about 16 carbon atoms, and most preferably about 1 to 14 carbon atoms, and a wrapping unit (e.g., galactoside,
glucoside, fructocyto, glucosyl, fructosyl and/or I-lactosyl units) from about 1.5 to about 10
, preferably 1.5-4, most preferably 1.6-2.
It has a polysaccharide water group association of 7. Sugar Residue Temperature 9jt Can be used in alkyl polyhydric surfactants @ @x indicates the number of shield units O in a particular alkyl polyhydric surfactant.

Only in the case of specific alkyl polysaccharide molecules I can take on the integer value t. In any physical sample of an alkyl polysaccharide surfactant, there will generally be different if molecules. A true sample is characterized by the + average [K of I, and this average value can take the non-luxurious number t0. It should be understood that the hydrophobic group (R) can be attached to the 2-, 3- or 4-position (glucosy P
or glucosyl or galactosyl instead of galactoside), those linked through the 1-position, i.e., glucosyl P1 galactoside, fructocyto, etc., are preferred; in preferred products, the l a l lance unit is primarily It is attached to the 2nd position of the sugar unit. Linkages through the 3rd, 4th, and 6th positions "f:" can also occur.

If so, and less preferably, there can be a polyalkoxide residue attached to the hydrophobic group (R). A preferred alkoxide residue is ethoxide.

A typical hydrophobic group has about 8 to about 1 carbon atoms, preferably about 1 carbon number.
O to about 16 tlir saturated or unsaturated branched or unbranched alkyl groups. Preferably, the alkyl group is a diaphragm alkyl group. The alkyl 1 can contain up to 3-hydroxyl groups, and the C(or)/arykoxide can contain up to about 1,000, preferably less than 10, most preferably 0, alkoxide residues.

Suitable alkyl polymers are decyl, dodecyl, tetradecyl, hexadecyl, and octadecyl, di-, tri-, teto-2-, penta-1 and hequinaglucosy P1 galactosy IP, lactone r.

Fructosil P, fructosil, lactosyl! Lucosyl and/or galactosyl and their O? It is a l1 compound.

Alkyl monomers are relatively less soluble in water than higher alkyl monomers, and when used in a mixture with alkyl polyester 111M, the alkyl monomers become water-soluble. . The use of alkyl mono-at's in mixtures with alkyl poly-S's is a preferred method of practicing this invention. A preferred mixture includes coconut alkyl, di,
tri, tetra-1 and penta-glucoside and lutetra, penta-1 and hechtedarcoside in tallowal.

Preferred alkyl polySat's have the formula %() [where 2 is derived from glucose and R2 is selected from the group consisting of alkyl, alkyl phenyl, hydroxyalkyl, dialkylphenyl in hydro, and mixtures thereof. It is a hydrophobic group (the alkyl group has about 10 carbon atoms)
m is 2 or 3, preferably 2; t is O to about lO1, preferably O; and X is 1.5 to about 8, preferably 1.5 ~4,
most preferably 1.6 to 2.7]. To produce these compounds, long-term alcohol (R4) can be reacted with glucose in the presence of an acid shield to produce the desired darkosyl rt. Alternatively, alkyl polyglucosides can be produced by a t-2 step process in which °C is reacted with short chain alcohols (C1-6) t-glucose or polyglucosides Cx = 2-4) to form short chain alkyl glucosides (x = 1-4)? : produced, which is reacted with a long alcohol (R2oH) to substitute a short chain alcohol and obtain a t-substituted alkyl polyglucoside. This 2
When using veterinary methods, the final alkyl polyglucosyl
The short chain alkyl IJ@/; P content of the substance is alkyl poly/A/:! FI of less than 50, preferably 1011
It should be less than 51G, more preferably 51G, and most preferably 0-.

The unreacted alcohol in the desired alkyl polysaccharide surfactant steel (0*<free fatty alcohol content) is preferably less than about 2 times the total amount of alkyl polysaccharide and unreacted alcohol,
More preferably less than about 0.5 weight percent. The amount of single shield in alcohol is about 20 to 70 Jlt- of the total alkyl polysaccharide.
1, preferably (capital) to 1 mass, most preferably 30-
501 amount - 0 for some applications, about 1096
It is desirable to have an alkyl monosaccharide content of less than .

As used herein, "alkyl polyglucoside" refers to both the preferred glucose and galactose #4 surfactants and the less preferred alkyl poly-surfactants. It is used to encompass alkyl polyglucosides since the stereochemistry of the lfi group is changed during the formation reaction.

Anionic cosurfactants Anionic cosurfactants may be selected from the group consisting of sulfates, sulfonates, cal-coacylates and mixtures thereof. Co-surfactants are alkali metals such as sodium or potassium.

neutralized with one or more cationic groups selected from the group consisting of one ion of an alkaline earth metal, such as calcium or madanesium, ammonium, ammonium, such as monoethanolammonium, jetanolammonium or triethanolammonium; . Mixtures of cations are preferred. All of the anion co-world 1lti activators useful in this @mei have detergent properties, and water fI
4 sex or moisture #! This is an L note.

One of the preferred co-active 11i active agents for use in the present invention is haalkylbenzene sulfonate. The alkyl groups can be branched or straight chain in the copper phase or in the solid phase and are optionally filtered with hydroxyl groups. The central phenyl position is generally preferred for foam capacity under soil conditions.

However, under heavy soiling conditions a phenyl bond in the 1 or 2 position is preferred.

Preferred alkylbenzene sulfonates have from about 9 carbon atoms.
about 6, preferably about 10 to about 13 carbon atoms, and the cation is sodium, potassium, ammonium, diethanolammonium, jetanolammonium or triethanol. Ammonium, calcium or! Gnesicum and mixtures thereof.

-r/nesicum is a preferred cationic group. These same cations are in other ionic realms! ! Preferred for active agents and ingredients. When the polysaccharide chain averages more than about 3 shield units, the phenyl group is attached to an alkyl group near the center of the alkyl chain. Suitable alkylbenzene sulfonates, such as C1 with low 2-phenyl content
l-alkyl(benzene sulfonate).

The alkylbenzene sulfonate cosurfactant is the foam of the present invention because the foam made with it is very stable, has a large volume, rinses quickly, and does not have a "slippery" feel. Desirable in sexual compositions. These compositions are particularly desirable for the industrial and commercial processes described below. Alkylbenzene sulfonate conjugate r
Jmlli! The foam volume created using the r-active agent is greater than with any other co-surfactant.

Other co-surfactants preferred for use in soap books are carboxylate surfactants such as fatty acid soaps and grade surfactants. Soaps can be saturated or unsaturated and can have a variety of substituents, including hydroxyl groups and alpha-sulfonate groups. Preferably, the hydrophobic portion of the soap is a straight chain saturated or unsaturated carbonized, water chain. The hydrophobic portion of the soap typically has a carbon number of from about 6 to about 1, preferably from about lθ to about 18t. lim) Since it is a soap dispersant, it is especially
There is an l value.

The cationic group (M) of the cal-xylate cosurfactant is
Alkali metals, such as sodium or potassium, alkaline earth metals, such as calcium or! Danesium,
Ammonium, or a substituted ammonium, such as the cation of monoethanolammonium, jetanolammonium, or triethanolammonium. 11! A lI ion O mixture is preferred.

In addition to the preferred alkylbenzene sulfonates and soap cosurfactants, many other surfactants containing sulfonate or calxylate groups can be used in the foaming compositions of the present invention. In general, the use of these latter cosurfactants produces less foam volume than the use of the preferred cosurfactants; however, alkyl polysurfactants stabilize the resulting foam and ft!
Let At* quickly clove.

One group of co-surfactants in aS due to their superior detergency are zwitterionic detergents containing both cationic groups, i.e. ammonium, phosphonium, sulfonium or mixtures thereof and sulfonate or car-xylate groups. be. Preferably there are fewer (4 atoms) separating the cationic and anionic groups. Suitable zwitterionic surfactants are described in U.S. Pat. No. 4,159,277, No.
No. 928,251 chest #l shoe, specification No. 3,925,262, specification No. 3, 929, specification No. 678, No. 3, 2
27, 749 Specification, No. 3,539,521-
Tatami, Specification No. 3,383,321, No. 3,390,0
No. 94, and No. 3,239,560. This dan co-surfactant is extremely useful in shampoos.

Another type of co-surfactant is a bipolar surfactant which has the same structure as the zwitterionic surfactant, but has an amine group instead of a quaternary ammonium group.

The other co-surfactant preferably has about 6 to about 3 carbon atoms.
It is an alkyl (puffin or olefin) sulfonate having a central hydroxyl group in its history with Oi. Compositions containing certain of these surfactants produce a minimum volume of foam if desired. Hydrophobic groups include up to about 10 hydroxyl groups and (
or) can contain an ether bond. An example is C14,1
5 paraffin sulfonate and C14,i6 olefin sulfonate.

Still another co-surfactant has an ether bond in the chain of up to about 10 fi and an amount of carbons in the chain of from about 1 to about 41.
and has a carbon number IJ of 6 to about 30 in the terminal portion which is not ether bonded.

Glucoside units average 1.5 to 4, preferably 1 Dalkosi
1.6 to 2.7 units; less than about 50 short-alkyl noliglucosides; less than about IO, preferably less than about 296, most preferably about o,s's
Preferred alkyl polyglucosides containing less unreacted fatty alcohol than conventional sulfate detergent co-surfactants, including alkyl sal 7 ates and formula % (where 1L3 is about 8 to about 18 carbon atoms) n is 2 or 3, t can vary from O to about I, and M is the cationic group, and the cosurfactant is water bathable or water dispersible. The alkyl I ether 7 ate co-world thi with
Increases the foaming ability of the active agent.

A preferred foaming composition of the present invention has the following formula: (1) Formula RO (R10), (Z) IC formula, where z is a residue derived from a reducing sugar having 5 to 6 carbon atoms, and R is a hydrophobic group selected from the group consisting of an alkyl group, an alkylphenyl group, a hydroxyalkylphenyl group, a hydroxyalkyl group, or a mixture thereof (wherein the alkyl group has about 8 to about 18 carbon atoms), and 2R' is a carbon number 2
t is O to about 4; and X is about 1.
5 to about 10, preferably 1.5 to 4, most preferably 1
, 6 to 2.7]; and (2) (
,) an alkyl benzene sulfonate cosurfactant having a carbon number of about 1 to about 13, preferably about 10 to about 50%, and a) alkyl group having a carbon number of about 8 alkyl glyceryl ether sulfonates having from about 181 carbon atoms, α-olefin sulfonates having olefin groups having from about 10 to about 18 carbon atoms, alkyl glyceryl ether sulfonates having from about 10 to about 18 carbon atoms, and polyethoxylate groups having from about 2 to about 18 carbon atoms; A co-surfactant selected from the group consisting of alkyl polyethoxylate carboxylates containing sylate groups, and mixtures thereof, preferably from about 5 to about 99-1, preferably from about consisting of a mixture of co-surfactants neutralized with one or more of the cationic groups listed above.

Compositions of this type have a foam expansion ratio of 12 (-) compared to compositions containing only an alkylbenzene sulfonate cosurfactant and an alkyl surfactant.

Another preferred example of the foamable composition of the present invention is (1)
In the formula BD(R”o), (Z)IC formula, z is Ra number 5 to 6
and R is a hydrophobic group selected from the group consisting of an alkyl group, an alkylphenyl group, a hydroxyalkylphenyl group or a hydroxyalkyl group or mixtures thereof, wherein the alkyl group is (about 8 to about 18 carbon atoms); R1 has about 2 to about 41 carbon atoms
- an alkyl multi-surfactant having the following formula; t is about θ to about 0; and A cationic group surfactant selected from the group consisting of sulfates, sulfonates, cal-I xylates and mixtures thereof neutralized with the group M (ratio of (2) to (1) is approximately 1=10
and (3) (a) formula % formula % (8) (wherein R7 is an alkyl having a charcoal number of about W to about 14t); group, and R8 is the same or different, and hydrogen, C3 alkyl group, C1-3 alkanol group, and -(c2H4
0-) 1-411 [selected from the group consisting of groups and mixtures thereof]

(b) Formula (wherein R4 is an alkyl group having about 8 to about 18 carbon atoms, preferably about 14 carbon atoms, and %凰5 is a carbon number 2
or 3, b is from 0 to about I, %R is the same or different, c1-3 alkyl groups, C1-3 alkanol groups, and -(02H40)1-6H groups and mixtures thereof (C) an auxiliary suds enhancer selected from the group consisting of (C) an amine oxide selected from the group consisting of (selected from the group consisting of) and (C) a mixture thereof.

This lumber composition provides low grease/oil removal properties and foam build-up.

Preferred anionic co-surfactants are alkylbenzene sulfonates, alpha-olefin sulfonates, alkyl nalphates, alkyl iriethoxylate sulfonates, non-2-fin sulfonates, and mixtures thereof. Cationic groups include sodium, potassium, ammonium, monoethanolammonium, diethanolammonicum, triethanolammonicum, calcium,! selected from the group consisting of Cnesium and mixtures thereof.

A preferred composition of this embodiment of the invention is an alkyl polysaccharide surfactant in which the a;kyl group has 12 to 14 carbon atoms, (1) An alkyl penzene sulfonate or olefinic group in which the alkyl group has about 8 to about 13 carbon atoms, preferably about 10 to about 18 carbon atoms; (2) an alkyl group having about 8 to about 18 carbon atoms, preferably about 12 to 14 carbon atoms; and there are 1 to about 6 ethoxylate groups, and about 1 to about 10011, preferably about 10 to about 80, of the cationic groups are magnesium.
about 1% of an anionic cosurfactant neutralized with one or more cationic groups in a mixture with about 1% to about 95%, preferably about 5% to about 50% ~
tj5-1, preferably from about 10 Ls to about 50-1 and atrm of auxiliary whipping enhancer.

Another preferred foaming & acidic compound of the present invention has the formula (1) RO(RIO)t(Z), where ztt
A residue derived from a radical having a carbon moiety as~6, wherein 8 is a hydrophobic residue selected from the group consisting of an alkyl group, an alkylphenyl group, a hydroxyalkylphenyl group or a hydroxyalkyl group or a mixture thereof. (the alkyl group has about 8 to about 18 carbon atoms, preferably ~x4 carbons); gl has 1.2 to about 4 carbons; t is 0 to about 4; and X is about 1゛, 5 to about 10, good tL, <
is 1,5-4, most preferably 1.6-2.7C)
an alkyl multifunctional surfactant having from about 5 to about 6
(2) an alkylbenzenesulfonate cosurfactant in which the alkyl group has a carbon number of about 10 to about 13; 5) neutralized with one or more cationic groups <M)
(3) an alkyl polyethoxylate 7-ate cosurfactant in which the alkyl group has about 10 to about 16 carbon atoms and has 1 to about 6 ethoxylate groups;
-1 preferably about 1OS-4 (the alkyl polyethoxy sulfate is neutralized with one or more cations to complete the formula); (4) salts of sodium and potassium, chloride; Agglomerates containing about 5 to about 50% of water-dissolvable inorganic salts, carbonates, phlegm salts, and mixtures thereof - detergent granules! Composition/Method Rubenzene sulfonate and (or) stone co-surfactant in alcohol! li, a mixture of the agent and the alkyl multi-shield surfactant in water under stirring at a ratio of co-surfactant to alkyl polysaccharide of about 10=1 to about 1:10 of about 0.0.
It can be used in amounts of 1- to about 6-0 to provide foam.

These bubbles are relatively stable and can exist for several days if undisturbed. Additionally, the foam has structural integrity and does not spread. The foam created using the mixture of alkylbenzene sulfonate and alkyl polysaccharide is unique in that it does not have a "slippery" feel.
1 of cho pete is quickly 1 cho.

The 21i standard properties of the non-inventive foam make it ideal for use in bar soaps, non-delivery baths, shaving creams, laundry, food cleaning, and laundry odors, where the stable foam's excellent capacity and quick rinsability are desirable. (It is also valuable for use in many fields unrelated to cleaning power.)

The compositions and methods of the present invention provide a method in which the foam is water and/or
It is particularly useful for use in the "foam" or "i-st" method used to transport soil particles to the surface of the soil.

The explanation of this method of sakusei is based on the American special pestle TS3,303.
Specification No. 896, Specification No. 3.111,178, Specification No. 3,330°798, and Specification No. 3,215,2
No. 00 specification. In this fence method, the surfactant is about 0.01% to about 5%, preferably about 0.01% to about 2%, most preferably about 0.05%
~0.5 lances are present. A preferred co-surfactant is an alkylbenzene sulfonate theal.

The compositions and methods of the present invention provide stable foam #5III
Fire extinguishing methods or fire prevention methods used to extinguish flames or sludge also have considerable importance. This is US timeffj
l! No. 2,514,310, No. 3,186,9
No. 43 Specification Director, No. 3,422,011 Paulownia Specimen, Wara 3,
No. 457,172, No. 3,479,285, and No. 3,541,010. Approximately 0.1-~
Approximately ssog degrees are useful.

In addition, the composition and method of the present invention provide 4+? The foam of the present invention is suitable for resins, plastics, cellulose, etc., which solidify into stable foam structures with low density, thick walls and good structural integrity. An example of a molding method utilizing zero foam Mt that provides a thick structure is U.S. Pat. No. 3,669,898, Err. 4.907, 98.
No. 2 Akira 1ilf 111F, and No. 4,423,720
It is stated in the specification of the No.

Mineral value*1--The 4 tones (beneficiation) of minerals to refine them are:
Advantageously used in the composition and method 1 of the invention, for example in 1 form! 11! can be administered. This method is described in US Pat. Detailed book, collection 4,
No. 138,350 M.S., No. 4,090,972, and Co. 3, 640.

No. 862-#IK is described.

Particular advantages of the present compositions and methods include the use of their exceptional stability to provide temporary insulation to plants when frozen noodles are anticipated. Alkylbenzene sulfonates are preferred co-rxJ activators, and the foam can be applied to plant matter, etc. This woodcutter method is disclosed in US Pat. No. 3,649,898.

The range of practicalities possible with the compositions and methods of the present invention encompasses the areas described above and many other areas.

A typical composition for use as a light duty liquid detergent composition for tableware 1 includes a mixture of surfactants ranging from about 50 to about 50%, preferably from about 100% to about 40%
1s to about 50% S mordant selected from the group consisting of 11C alkanols, C1-3 alkalinolamines, CJ liols, and mixtures thereof.

and the remainder water. Very (concentrated Form II with only a small amount of organic solvent and without the addition of hydrotropic substances such as bird oil)
It is a particular advantage of the compositions of the present invention that it is possible to obtain up to 114 M (approximately weighted amount of the mixture of surfactants). Additional lather thickeners or pills, such as trialkylamine oxides and fatty acid amides, may also be used in amounts up to about 100%. Seven fatty alcohols should not be used.

Rumors about the combination of surfactant ~
about 95-1 preferably from about 6 to about 50%, alkanolamide from about Is to about 5-1 polymeric thickener from about 0.5 to about 3I
Consisting of II% and JAit+water. It is the special ILIJA of said shampoo that it is quick and easy to use.

Additional Ingredients The compositions 41J and methods of the present disclosure may utilize other compatible ingredients in addition to the surfactant mixtures disclosed herein, such as other surfactant A4Jt. In detergent compositions,
- The acid may contain known ingredients, such as small amounts of other IJ activators, Kapil I-1 stain clouding agent, whitening agents, abrasive agents, dyes, Shimahaku Condidi Sodium Refining Agent, Hair Conditioned Sodium It can contain bleaching agents, hydrating agents, bath mediums, lighting agents, clay, incense, and the like. A suitable ingredient is rice Li! Time tf song 4,1
Specification No. 66.039, Specification No. 4.157 Ken 78,
No. 4,056,481, Meiji No. 4,049,586
Mei #1 tatami, am 4,035,257 specification, No. 4
．． No. 019,88, M 4,000,080, and! The shampoo composition 11# of the present invention disclosed in US Pat. No. 3,983,078 can contain any additional ingredients known in the art to be suitable for use in shampoos. Examples of suitable additional ingredients, such as small amounts of other surfactants, can be found in U.S. Pat.
No. 4,089,946 Mei at No. 3,987,161 F
JA specification, and $3,962,418.

41:9? Ingredients that modify the feel of aqueous solutions containing aqueous compositions are of special interest. For example, raising the pH'1 to about 8.5 or more with an alkaline substance, or incorporating a tertiary alcohol in US Pat. No. 193,050, filed October 2, 1980. This ingredient is desirable for some consumers because the liquid has a surfactant-like feel similar to that of normal soap.

The following non-limiting examples illustrate the foamable compositions of the present invention.

Calendar'' (Pr@f@r@nee) Mu BC - Thorium C1 To13 Alkyl - -12,0 Poly! Lucosides 2-3 (11+1!ilipidemic P#: ff-, g,.

C1□, 5a, Rukiru 5,5 12.
O-I ethoxylate, remaining sodium sulfate, water 84. O) 0.0
70.0 Relative volume of foaming foam (lIj') 110 125
220(0,2) #sales) Consumer 1 Overall preference C, arrogant) 10 18
Z33 Good City Bubbly Comment) (IG) 74
S 90 Favorable rinse comment (%) 3
s t.

The foamable compositions of the present invention are superior to typical commercial products, are less expensive than typical commercial products, and can be delivered to consumers on-site in just a few minutes. [Preferred. The test involved 9 consumers washing dirty dishes in the test solution. Consumers put on five gloves during the test! The difference between the invention and the conventional product was , Mother-in-law - [Significant] at the trust level.

The relative capacity of the hawk (-) is determined by the following test method.

100 iu -i of liquid at 116"F (approx. 1℃)
Place in a 50G graduated cylinder. Continue stirring until the amount of foam in the cylinder no longer increases.
The IIL is stirred by repeated inversion of the graduated cylinder.

Subtract the southness of the bubble by the amount of liquid remaining in the cylinder.
Measure directly with a cylinder scale. Sample - Prepare a test solution by adding t-Product t7 Darren/U.S. Gallon O Hardness (Ca/Mg-3A) to water with t-.

Example I2-3 Relative capacity of darcoside 1 (Ml) 140220280300
310300240 'C Foam Example IK Using Surfactant Mixture 3001Fl in Tap Water (approximately 9 Darens/Gallon)
Generated as described. The results clearly demonstrate a synergistic effect for the foamable compositions of the present invention at ratios higher than about 1:2.

Example■ Ov4ytlf trifyh O20406080
1 o.

C12-15A MFk 100 80 60
40 20 0 poly 2-3 dulcoside foam relative each 1 (vertical) 1ω is 04I Natsuki 310
Foam was generated as in Example 1 using a 4-cm surfactant mixture 500911111. This data clearly demonstrates the foaming synergy for the foamable compositions of the present invention.

Example y Lathering with soap Glen hardness 0 2 4 6 Sodium oleate 225 10 0
0 Sodium oleate + 360 10
0 55 103:2) Surfactant mixture 500 PFI was used to generate as in 17Ga1.

Example: Increased foaming - Sodium oleate 50-76
3-[N-Coconuts Furukiru 40~
6ON, N-dimethyl-2-hydroΦ C1-sulfonate C1□15'refinsulfonate 20-4
0licum coconut alkyl sodium sulfate 10-30
Mucoconuts alkyl polyethoxylene 0-20
The above data clearly indicate that the use of sylate or sulfonate anionic detergent co-surfactants in Karoo is critical for foaming synergy with alkyl 4-liglucoside surfactants. Shown below.

Example ■ C10-15 alkylpoly which is the critical gluco 71 moiety of Dulcoside Chincho or less! Weight ratio of Lukosi P to CL2 sodium alkylbenzenesulfonate 40:60 (concentration 500 ppm)
Monoglucosibi 180 diglucoside
240p/takurcoside
260 decadarcoside 170 C-fulkylbenzenesulfone 16011.8 Sodium diglucoside, etc., has an average glucoside in the sample of 2
etc. As seen from the Iki data, significant synergy is 1.5 or more Darkosi P
units, and preferably less than about 10 (and even more preferably less than about 8!) Lukosi P units.

Example■ Alkylbenzene sulfonate (L■) 1148 body example■
Alkyl I! Lucoside + Natrif AC11LAIi, $12-21
0 phenyl sodium C,, Lm 8, similar 2- 250 phenyl sodium Cl2LAS% *'2- 225 phenyl sodium Cl2Lm S1 low% -2-225 phenyl sodium C14Lm B1 high 2- 210 Lunar Sodium C14L 8, Yu) 2-2157
As can be seen from the above data, general KCl1L (low 2-phenyl) is preferred for foaming.

Example■ Influence of foaming enhancement and staining of alkylpolyglucosibid 0.5% 1. Ol 0.2 g of the detergent composition formulated below: (C11,B Li2) 15'lk ■2- C1□, gLA830 190 140
10012 Combination; Example IO test method modified by adding a pre-dosed amount of dirt to the solution. - is the amount of electricity in the test solution.

The stain is a mixture of Fluffo and PR1eP.

Both WFi4 products are available from F.P.P.

From the above data it is clear that the benefits of the present invention are even lower in the presence of dirt.

Example )] *: Add as described in soil example ①.

Toruhonji registered trademark Crystal White is Colgate Nonorumotsui! -Can be obtained from Rikiunno 21. Registered dealer JIA
AA/Ip turtle body can be obtained from Colgate, A Lumoraiso, Kanno 21. The Explorations of the President is available from The Profter Enrol Gambling Company.

A test solution containing 0.2% by weight of the commercial product or 0.2*t of the product formulated with the surfactant mixture was used to generate as ntNl.

As can be seen from the above data, simple mixtures of representative surfactants of the present invention can be formulated to be less than or equal to the best light duty dishwashing liquids.

Example
150 190 210 220 Surfactant Mixture Used in Test 111 of Example 1 300 ppym The above data indicate that structures similar to Lurie/sp x cyto in alcohol do not provide the benefits of the present invention.

8M Shampoo coca dobrovir pemaine 5G, Goshu (added water bath liquid) Alkyl I ridarcoside of Example 1 5. OO
Arrogant polyethylene! Recoldi 1.00 Stearate preservative 0.03%
distilled water balance 100,
Go IG Examples Shampoo α-olefin insulnenate 30. G
o 嗟 (40s water 8N) SP4t's 7 ru $ ru / rig # 3,0
0% cosidohydroyaethylcellulose 0.80
Chi fragrance 1.0
01 Preservative 0.04
-S Remaining water remainder 1
00.00 11 Example 1 Sodium runenate C12,15C4-5 100 80 60 40
20 0no relative capacity (14) 185 250
275 275 m 210 Test conditions 1ii Concentration 300 nm, mixed hardness 8 grains Mizumoto” 1.!, 15C4-5 has 4 to 51 dulcoside units, and the alkyl group has 12 to 1 carbon atoms
51 alkyl polysaccharide surfactant.

Example: Composition of 0.2 Chronic Water S Solution: Example 107Jy”Fkl/k 450 150
75 Koshi I; mainly has a benzene group bonded to the center of the alkyl rhyme, and is neutralized with sodium to form an alkyl I ridal 450 200 11
0 koshi l'15 arrogant; mainly has a benzene group bonded to the center of the alkyl chain, ! Premium product neutralized with Gnesicum 350 120 75
(-ji*#411jiji) Umbrella: Dirt “voice” with test liquid Kfl added as in example ■ 4 to 4 oyh + Le multi-class II, especially alkyl I 9 / Le: l to ¥ * about 6 ~ Approximately Z70HLB” and approximately 1000
ppa! 4 (preferably less than about 500 ppm). As shown in the table below, where the alkyl group and the glucoside chain ratio are varied, short-alkyl polySs in which the alkyl group has less than about 8 carbon atoms have unacceptably high cMc
and an alkyl polysynthesis with a complement fIi greater than about 4 is an unacceptable species.

E: Approximate Book 2 Final Pease Pumak End Internacional Combres T-7 S Actevi f4-1, 42
6 (O y ry, 1957) HLB determined by K.PFI Book: PFI From the above data, it can be seen that (1): Longer pure glucosyl chain lengths increase HLB gold and the t1 surface activity of the molecule. (high CMC), and (2) alkyls shorter than two have extremely low CMCs even for monodarucids.

Example XM The following formulation was prepared.

BC Sium CI2-13 Alkyl 4 rig 149 14,9 1
4.9 Lucoside (01,7) (Free*fat Ehy Luco#<2%) 09-11 Alkoxypro-4-Pyldihydroxyethylamine oxide C12 Alkyldihydroxy-4-diethylamine oxide Ethanol 5 5 5 Water
Residue Residue Residue foam under IUI conditions under constant agitation (fats and proteins, carbohydrates and edible acids owned mixture) using 3 gallons of water in a 3 gallon OII container, 115″ PC4
6.1℃), 7Darren hardness] by generating [,
For formulation mu, l and ct-! C was collected. The dinner plates are stained with 4V against the base plate, and the foam height t'' is applied after each 565 plates.The total garden plates are washed, and the washed plates O
The sum of the foam heights taken over the number f:BT) is reported as II grade <SDW wash-foam).

This data shows that the addition of small amounts of these amine oxides dramatically increases the amount of blood that can be washed. Fatty acid At instead of at least a part of the specific A-Z-7P
l', e.g., pukonatsu fatty acids and, diemenolamide, and/or innopro-tanolua < yt
When used, KtEi1-like results are obtained.

Example: 105° of sodium dodecylbenzenesulfonate was combined with 350 g of anhydrous sodium sulfate. After pulverizing the compound 11 into powder, CI2-13I2 medium I liglucoshi P (
G2.2) (free+111fi1r fatty alcohol 2s)
70gt-mix. The alkylpolyglucosides operated in a heated 'mtma' were transferred to a moving bed Ilj, a dry rock (e.g. Aeromatic Inc. Model 8TILIA-1), and then the alkyl polyglucosides were incubated for 50 s static WL100.
g onto the powder. 1 Chronic polar blue layer liquid 7. Spout on the smi powder wood and then add a small amount of fragrance. The resulting granules t-X9! In the furnace (capital) inch Hg (approximately 7
62 mm + Hg) Remove excess water by drying for 10 hours at 1° C. in vacuum.

Similarly, 50$Al of the alkyl 49/rucoside was prepared using the O method.
Spray onto 100 g of J60gt parkite and mix with the spray onto 50 g' of sodium P-decyl penzene sulfonate flakes to give a light duty granulate.

Example C11,2M alkyl penzene sulfone ammonium CL2 alkyl I ridarcoside G3. S and about 2:
They were mixed in a ratio of 1. Mix 41 in tap water for 400P
PIII O amount used, initial m volume t+* 300
After addition of approximately 1,251 semi-grease soils per wash 11200 C4, the foam disappeared. KCl2,16 instead of 25- and 40- in the mixture
When using sodium alkyl glyceryl ether sulfonate, the foam-free point is 1.5. and 1.75g12) extended to the stain.

CI2,16 of sodium, potassium, ammonium, or monoethanolammonium in place of at least a portion of the alkyl glyceryl ether sulfonate
Similar results are obtained when using alkyl I ethoxy triacetate, also haC1←16 olefin sulfonate or mixtures thereof.

The following formulations having 49 alkyl/rucosides with 10 fatty alcohols and 1 fatty alcohol respectively were prepared.

Weight - C11,2-shaped alkylbenzene 17.5 Ammonicum sulfonate C11,2-shaped alkylbenzene 6.4 Sulfonomagnesium CL2-13 Alkyl I-liethoxy 6. Lou
(0,8)billion acid a/monyram C12-13 alkyl I ridarkosi 5do G1
．． 7 Naikura component and water remaining 80 for small amount and large amount of alcohol samples
The %V values were 12.9 and 2 (0.
L8D0.05 at 6) -11c test method see examples.

Example XX - The following formulations were prepared.

Weight - Ammonium/Madanesium Gnesicumnesate Trace components and water Balance Balance Balance Balance
B CD gDW inf ts/s 79 89 97
1107Sy index is standard commercial product 08D
5ypi grade of each product as - of w.

The following moths are examples of particularly preferred compositions.

The wide range of ingredients that can be used and the preferred Ii ranges are shown in columns 2 and 3, respectively.

Ex.
2-11 3-9 toxylate (0,8) Cast from 4-density ammonium glucose 5.0 2-11 2
~7 Ct2~13 alcohol polyglucoside (1,7) (free*fatty alcohol<O,SS) Ethanol 3,7 0~10 0~
5 Xylene sulfonate 3,0 0-10
0-5 Ni Example m1 Weight - C12-13 alkali sulfuric acid 15.7 7-ru
lO ~ Ammonicum C1 7-l Refinsul 10.4 4~19
6-13 Hong putotrichum-C12-6H205, 60-11 2-1O Coconut Emeno 5,5 2-8 3-Fluamide dulcose to C4 5.9 2-12 3-
9 C12-13 alkyl polyglycoside (1,7) (free N# alcohol (0,5%) Ecno, -l 4.0 0-10 0-10
H20 and trace components, remaining s J! ! Part A Remaining part For example, fragrance example ■I and n! The alkyl group in the surfactant can vary from about lθ to about 16, and the cation is ammonium, sodium, potassium, monoemenolammoecum, jetanolammoecum, triethanolammonium, madanesicum, or preferably can be a mixture thereof. Any preferred alkyl I glycosylation agent may be used, as well as other known adenyl oxybi and adendo foam enhancers tW disclosed in this specification #4.

Column ■ Ammonium C11,2 alkylbenzenesulfonate and C12-13 furkyl I! When rucoside (2-4)←free fatty alcohol〉2-) and O1l&compound were tested under the conditions of 1, the initial foam wave was good, but
The quality of some commercial products is not as good. When C16 alkyl dalyceryl ether sulfonate/sodium chloride, C14-16oV sodium finsulfonate, or C12-13 alkyl polyethoxylate (3) sodium acetate is used in place of 25- and 50- Dragon's first n! A standing t without excessively decreasing SIN
Increase your grade.

Known analytical techniques can be used to determine the structure of the alkyl polysaccharide surfactants of the present invention, such as determining the Darkosy r@ length, butyl Darkosi 10 weight, free fatty alcohol content, and amount of unreacted polysaccharide. More specifically, unreacted alcohol content and unreacted polysaccharide content can be determined using gas or liquid cloverfish, respectively.

Protons t>mr can be used to measure the glycoside average chain length.

Point of attachment of one water part of the molecule to the hydrophobic part of the molecule f 1
It can be measured by 3CnrBr.

The alcohol-based multi-mechanical surfactant field is a solid mixture.

The analytical standards that are useful for calibrating the analyzer for the components of alkyl polysaccharide surfactants at zero time, whose components vary depending on the nature of the starting materials and the reactions they produce, are Calbiocum Iochem ( Calblo
ah@m) φ494559], Dekuldarkosi)P
(Cal A Iochem φ252) IIS) and t-decyl maltoside (Cal A Iochem φ3243551S).

The alkyl polysaccharide surfactant OdeJ useful in this foaming composition has at as shown in 9'lXY.

CMC would be similar to the filter shown in the same example.

A polysaccharide surfactant in alcohol having a structure as described in the FIA specification and characterized by one or more standard analytical techniques will give the results shown in example # above.

Increase in cast members Boar Wk Qing procedure amendment (
Form) November 1920 (Showa Drunk) Director General of the Patent Office Kazuo Wakasugi 1, Indication of the case Showa M year patent application No. 1JllG75 2, Name of the invention Foaming surfactant composition 3, Person making the amendment Case Relationship with Patent Applicant F. Brocter, End, Gamble, Company [
Telephone Tokyo (211) 2321 main office] Applicant column of the application, W letter of appointment and specification 8, contents of amendments.

Claims (1)

[Claims] 1. (Formula 11 RO(RIO)i(Z)xC In the formula, z is a residue derived from a reducing sugar having 5 to 6 carbon atoms, and R is alkyl, an alkylphenyl, hydroxyalkylphenyl or hydroxyalkyl hydrophobic group, or a mixture thereof, wherein the alkyl group has from about 8 to about 18 carbon atoms; R1 has from 2 to about 4 carbon atoms; t is from θ to
and X is a number from about 1.5 to about 10. from about 1% to about 95% of alkylbenzene sulfonates, and (kl) alkyl glyceryl ether sulfonates in which the alkyl group has from about 8 to about 18 carbon atoms, α-olefin sulfonates in which the olefinic group has from about 1θ to about 18 carbon atoms; has about 10 to about 18 carbon atoms,
and a cosurfactant selected from the group consisting of alkyl polyethoxylate carboxylates in which the polyethoxylate chain contains from about 2 to about 6 ethoxylate groups, and mixtures thereof. A foaming composition comprising a mixture of anionic cosurfactants neutralized with one or more cationic groups as described above. 2. Co-surfactant (21(b) is an alkyl glyceryl ether sulfonate and the cationic group is selected from sodium, potassium, ammonium, monoethanolammonium, jetanolammonium, triethanolammonium, calcium, magnesium and mixtures thereof) 3. The composition according to claim 1, wherein the co-surfactant (21) is selected from the group consisting of: 4- The composition according to claim 1, wherein the co-surfactant (2) (bl) is an α-olefin sulfonate. 5. The composition according to claim 1, wherein X is a number from 1.5 to 4. Item 1~
The composition according to any of paragraph 4. 6. Claim 1 in which x is a number from 1.6 to 2.7
The composition according to any one of Items 1 to 4. 7. (1) Formula RO(R”0)t(Z)x C
In the formula, z is a residue derived from a reducing sugar having 5 to 6 carbon atoms, and R is an alkyl, alkylphenyl, hydroxyalkylphenyl, or hydroxyalkyl hydrophobic group, or a mixture thereof (the alkyl group has from about 8 to about 18 carbon atoms; iR" has from 2 to about 4 carbon atoms; Alkyl polysaccharide surfactant, (2ba) water-soluble alkylbenzene sulfonate whose alkyl group has about 10 to about 13 carbon atoms, about 1qb to about 95
H, and (bl Alkyl glyceryl ether sulfonate in which the alkyl group has about 8 to about 18 carbon atoms, α-olefin sulfonate in which the olefin group has about 10 to about 18 carbon atoms, from about 5% to about 99% of a cosurfactant selected from the group consisting of alkyl polyethoxylate carboxylates having a polyethoxylate chain containing from about 2 to about 6 ethoxylate groups, and mixtures thereof. A surfactant mixture consisting of a mixture of anionic co-surfactants neutralized with one or more cationic groups consisting essentially of from about 5% to about 50% and 01-3 alkanols, 01-3 alkanolamines 1. A light duty liquid detergent composition comprising from about 1% to about 50% of a solvent selected from the group consisting of , 02-4 polyols, and mixtures thereof, and the balance water.