CN101280245B - Toilet-cleaning paste - Google Patents
Toilet-cleaning paste Download PDFInfo
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- CN101280245B CN101280245B CN2008100114929A CN200810011492A CN101280245B CN 101280245 B CN101280245 B CN 101280245B CN 2008100114929 A CN2008100114929 A CN 2008100114929A CN 200810011492 A CN200810011492 A CN 200810011492A CN 101280245 B CN101280245 B CN 101280245B
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- cleaning paste
- toilet cleaning
- water
- toilet
- paste
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Abstract
The invention relates to a toilet cleaning paste. The technical proposal adopted by the toilet cleaning paste includes that the toilet cleaning paste is part by weight composed of 12-17% of hydrochloric acid, 8.0-18% of thickener, 0.1-0.2% of zwitterion polyacrylamide, 1-1.5% of polyoxyethylene nonyl phenyl ether, 8-9% of sodium chloride and the residual content of water; wherein, the thickener is the silicon dioxide with the granularity of 2800-3400 mesh or the silicon dioxide with the granularity of 5-40 nm; the preparation method includes that the zwitterion polyacrylamide is melted in water according to the weight ratio; hydrochloric acid is added and stirred evenly and then the thickener is added slowly while the stirring process is conducted for 1-2 hours; finally, the polyoxyethylene nonyl phenyl ether and the sodium chloride are added and stirred for 2-3 hours. The toilet cleaning pastecannot be melted by water when the toilet cleaning paste is contacted with water and can maintain the independence in five minutes so that the high concentration dirt removal reaction is ensured for the toilet cleaning paste and is the basic reason for the less dosage; the toilet cleaning paste is very convention in application.
Description
Technical field:
The present invention relates to the daily life cleanser compositions, relate in particular to a kind of household toilet cleaner composite formula and preparation method thereof.
Background technology:
Cleaning agent in the market can be divided into liquid and block (as block cleaning toilet treasured) by state.Wherein liquid cleaning agent kind is maximum, and this type of product viscosity is lower, stays compole weak point when hanging on inclined-plane or vertical surface, and the retention amount is few, as not strengthening consumption, just is difficult to reach descale effect, not only causes waste but also polluted environment; And splash easily when using, regular meeting's corrosion clothing can cause certain injury to eyes and skin; Some dirt place is difficult to be sprayed onto, and influences descale effect; And liquid cleaning agent main component all is a hydrochloric acid, so it is very difficult to make paste.Block cleaning agent need be placed in the water box of water closet, treats just can use after it slowly is dissolved in the water, and its descale effect is not good.
Summary of the invention:
In order to address the above problem, the invention provides a kind of stay the extension time long, consumption is little and the paste toilet-cleaning paste of features high scale-removing effect.To achieve these goals, the technical solution used in the present invention is: a kind of toilet-cleaning paste, form by following compositions in weight percentage:
Hydrochloric acid 12～17%
Thickening material 8.0～18%
Amphoteric ionic polyacrylamide 0.1～0.2%
Polyoxyethylene nonylphenol ether 1～1.5%
Sodium-chlor 8～9%
Water surplus
Wherein, thickening material is that granularity is that 2800～3400 purpose silicon-dioxide or granularity are the silicon-dioxide of 5～40nm.
The preparation method of described toilet-cleaning paste is as follows: by proportioning amphoteric ionic polyacrylamide is dissolved in the water; Add hydrochloric acid and stir, slowly add thickening material then, stirred while adding 1～2 hour, add polyoxyethylene nonylphenol ether and sodium-chlor at last, stirred 2～3 hours.
The essence that can add some aldehydes or ethers among the present invention, add-on are 0.1～0.2% of composition total weight, to reconcile the fragrance of composition.
Among the present invention, hydrochloric acid is the host of removing urine dirt, incrustation scale, scale and macula lutea on urinal and the toilet.It is that 2800～3400 purpose silicon-dioxide (precipitator method) or granularity are the silicon-dioxide (vapor phase process) of 5～40nm that thickening material adopts granularity.Though silicon-dioxide and hydrochloric acid do not react, through overtesting, having only 2800～3400 purpose silicon-dioxide (precipitator method) or granularity is that the silicon-dioxide (vapor phase process) of 5～40nm can be made paste with hydrochloric acid.Therefore thickening material can be made paste with composition.Molecular-weight average is that the amphoteric ionic polyacrylamide more than 1,000 ten thousand is that composition can be guaranteed its all loose property and easy mobility after concussion.Amphoteric ionic polyacrylamide and silicon-dioxide synergy can get final product through vibration when the needs flow state.Polyoxyethylene nonylphenol ether is an excellent surfactant, can improve the clean function of composition.Sodium-chlor is density and the synergistic effect that is used for improving composition.Essence is to be used for being in harmonious proportion the taste of composition.
During use, only need toilet-cleaning paste is squeezed on the cleaning brush bristle, clean at the through above dirt of water surface place, as removing heavy dirt, Ying Zaichong dirt place smoothens toilet-cleaning paste, because the present invention is a paste, can not trickle downwards, therefore, can stop about 5 minutes at heavy dirt place, scouring gets final product then; For the following dirt of the water surface, the present invention is shaken up and down several times, make it have good flowability, squeeze the limit again along the waterside and be coated with toilet-cleaning paste, treat that it slowly flow to the following dirt of water surface place naturally, because the present invention is a paste, therefore in slowly flowing to the process of dirty place below the water surface, by water-soluble amount seldom, and on dirt, evenly stay extension, guaranteed the minimum usage quantity of toilet-cleaning paste, moments later cleaned and get final product Ex-all.
Advantage such as toilet-cleaning paste of the present invention has strong adhesion, does not run off, do not splash, consumption is few, scale removal is fast.Consumption is 1/3rd of a liquid cleaning agent, greatly reduces cost, has alleviated environmental pollution.The present invention can not keep its independence at once by water dissolution with after water contacts in 5 minutes, can guarantee its high density scale removal reaction with this, for general family is each only need 5～10g about, consumption is seldom and very easy to use.
Embodiment:
Embodiment 1
A kind of toilet-cleaning paste, form by following compositions in weight percentage:
Hydrochloric acid 12%
Silicon-dioxide granularity 5～40nm 8%
Amphoteric ionic polyacrylamide 0.1%
Polyoxyethylene nonylphenol ether 1%
Sodium-chlor 8%
Water surplus
The preparation method is as follows:
By proportioning amphoteric ionic polyacrylamide is dissolved in the water; Add hydrochloric acid and stir, slowly add the silicon-dioxide of granularity 5～40nm then, stirred while adding 1～2 hour, add polyoxyethylene nonylphenol ether and sodium-chlor at last, stirred 2～3 hours.
Embodiment 2
A kind of toilet-cleaning paste, form by following compositions in weight percentage:
Hydrochloric acid 14%
Silicon-dioxide granularity 5～40nm 8.3%
Amphoteric ionic polyacrylamide 0.15%
Polyoxyethylene nonylphenol ether 1.2%
Sodium-chlor 8.5%
Water surplus
The preparation method is as follows:
By proportioning amphoteric ionic polyacrylamide is dissolved in the water; Add hydrochloric acid and stir, slowly add the silicon-dioxide of granularity 5～40nm then, stirred while adding 1～2 hour, add polyoxyethylene nonylphenol ether and sodium-chlor at last, stirred 2～3 hours.
Embodiment 3
A kind of toilet-cleaning paste, form by following compositions in weight percentage:
Hydrochloric acid 15%
Silicon-dioxide granularity 2800～3400 orders 16.5%
Amphoteric ionic polyacrylamide 0.15%
Polyoxyethylene nonylphenol ether 1.4%
Sodium-chlor 8.5%
Water surplus
The preparation method is as follows:
By proportioning amphoteric ionic polyacrylamide is dissolved in the water; Add hydrochloric acid and stir, slowly add granularity 2800～3400 purpose silicon-dioxide then, stirred while adding 1～2 hour, add polyoxyethylene nonylphenol ether and sodium-chlor at last, stirred 2～3 hours.
Embodiment 4
A kind of toilet-cleaning paste, form by following compositions in weight percentage:
Hydrochloric acid 17%
Silicon-dioxide granularity 2800～3400 orders 18%
Amphoteric ionic polyacrylamide 0.2%
Polyoxyethylene nonylphenol ether 1.5%
Sodium-chlor 9%
Water surplus
The preparation method is as follows:
By proportioning amphoteric ionic polyacrylamide is dissolved in the water; Add hydrochloric acid and stir, slowly add granularity 2800～3400 purpose silicon-dioxide then, stirred while adding 1～2 hour, add polyoxyethylene nonylphenol ether and sodium-chlor at last, stirred 2～3 hours.
Claims (2)
1. toilet-cleaning paste is characterized in that being made up of following compositions in weight percentage:
Hydrochloric acid 12～17%
Thickening material 8.0～18%
Amphoteric ionic polyacrylamide 0.1～0.2%
Polyoxyethylene nonylphenol ether 1～1.5%
Sodium-chlor 8～9%
Water surplus
Wherein, thickening material is that granularity is that 2800～3400 purpose silicon-dioxide or granularity are the silicon-dioxide of 5～40nm;
The molecular-weight average of described amphoteric ionic polyacrylamide is more than 1,000 ten thousand.
2. the preparation method of the described toilet-cleaning paste of claim 1 is characterized in that step is as follows:
By proportioning amphoteric ionic polyacrylamide is dissolved in the water; Add hydrochloric acid and stir, slowly add thickening material then, stirred while adding 1～2 hour, add polyoxyethylene nonylphenol ether and sodium-chlor at last, stirred 2～3 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100114929A CN101280245B (en) | 2008-05-21 | 2008-05-21 | Toilet-cleaning paste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100114929A CN101280245B (en) | 2008-05-21 | 2008-05-21 | Toilet-cleaning paste |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101280245A CN101280245A (en) | 2008-10-08 |
| CN101280245B true CN101280245B (en) | 2011-01-19 |
Family
ID=40012922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008100114929A Expired - Fee Related CN101280245B (en) | 2008-05-21 | 2008-05-21 | Toilet-cleaning paste |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101280245B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102367399A (en) * | 2011-05-25 | 2012-03-07 | 王国松 | Sanitation bubbles |
| CN109370817A (en) * | 2018-11-20 | 2019-02-22 | 河南宗源环保科技有限公司 | A kind of toilet-cleaning paste |
| CN109504545A (en) * | 2018-11-20 | 2019-03-22 | 河南宗源环保科技有限公司 | A kind of paste scale remover and preparation method |
-
2008
- 2008-05-21 CN CN2008100114929A patent/CN101280245B/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN101280245A (en) | 2008-10-08 |
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| C14 | Grant of patent or utility model | ||
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110119 Termination date: 20150521 |
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| EXPY | Termination of patent right or utility model |