CN107136093A - A kind of composition pesticide - Google Patents

A kind of composition pesticide Download PDF

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Publication number
CN107136093A
CN107136093A CN201710435983.5A CN201710435983A CN107136093A CN 107136093 A CN107136093 A CN 107136093A CN 201710435983 A CN201710435983 A CN 201710435983A CN 107136093 A CN107136093 A CN 107136093A
Authority
CN
China
Prior art keywords
parts
composition pesticide
chlorfenapyr
etoxazole
oligosaccharide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710435983.5A
Other languages
Chinese (zh)
Inventor
刘涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Long Chemical Technology Co Ltd
Original Assignee
Hefei Long Chemical Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Long Chemical Technology Co Ltd filed Critical Hefei Long Chemical Technology Co Ltd
Priority to CN201710435983.5A priority Critical patent/CN107136093A/en
Publication of CN107136093A publication Critical patent/CN107136093A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/761,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12Powders or granules
    • A01N25/14Powders or granules wettable
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of composition pesticide, its active component is etoxazole, amino-oligosaccharide and chlorfenapyr, and the active component is calculated by weight as:1 60 parts of 1 40 parts of etoxazole, 1 50 parts of amino-oligosaccharide and chlorfenapyr.A kind of composition pesticide that the present invention is provided, the active ingredient of the different mechanisms of action is compounded, and delays disease to develop immunity to drugs.Complex role is significantly formulated, and can significantly improve preventive effect, substantially reduces the dosage of agricultural chemicals, can also expand fungicidal spectrum, improves germicidal efficiency.

Description

A kind of composition pesticide
Technical field
The present invention relates to agricultural insect pest field, and in particular to a kind of composition pesticide.
Background technology
Etoxazole (etoxazole), chemical name is (RS) -2- (2,6- difluorophenyl) -4- (tertiary fourths of 2- ethyoxyls -4- Base phenyl) -4,5- dihydro -1,3- oxazolines, be the chemical pillar commercial firm of SUMITOMO CHEMICAL in 1980s mid-term develop and in 2,4- diphenyl -1,3- oxazoline class insecticidal/acaricidal agents of commercialization in 1998.Tetranychid of the etoxazole to crops such as citruses, beginning leaf The mite class such as mite, Panonychus citri, Tetranychus urticae, Tetranychus cinnabarinus have remarkable preventive effect.Its mode of action be suppress mite ovum embry ogenesis with And from young mite to the molting process into mite, it is effective to ovum and young mite, to invalid into mite.Therefore its optimal preventing and treating time is evil mite Harm initial stage.It is environmentally safe, it is minimum to beneficial insect and beneficial mite non-hazardous or harm.
Amino-oligosaccharide (oligosaccharins), chemical name be oligomeric-D- Glucosamines, be one kind by ocean The oligomer that the degree of polymerization that the polysaccharide biological species natural products for extracting and coming in biological carapace matter is produced through enzymolysis is 2~15, it is right Phytopathogeic fungi toxicity is extremely low, but with induction plant disease-resistant function, can be used to prevent and treat grain as disease resistance of plant derivant Fungus, bacterium and the virus disease of the various plants such as food, vegetables, melon, fruit tree, Chinese medicine, wherein drawing to viruses such as TMV, CMV The viroses of plant risen, epidemic disease, white epidemic disease and gray mold caused by botrytis etc. have preferable prevention effect caused by oomycetes. 16000mg/kg is more than to rat acute toxicity LD50, belongs to micro- malicious level.
Chlorfenapyr (Chlorfenapyr) is the aryl pyrrole that American Cyanamid Company develops the late 1980s Class insecticidal/acaricidal agent is coughed up, its chemical name is 4- bromo- 2- (rubigan) -1- ethoxyl methyls -5- (trifluoromethyl) pyrroles -3- Nitrile.Universal Chinese character name chlorfenapyr.Chlorfenapyr is to transform and be able to the tool successfully developed by the chemical constitution to natural antibiotics There is a class novel insecticidal acaricide of its particular mechanism, it is as a kind of precursor insecticide, through sloughing N- second in insect bodies A kind of even agent of oxidative phosphorylation solution is changed into after epoxide ethyl, because target site is not present in uncoupler in itself, also just not There may be target site-resistance, thus there is special efficacy to the preventing and treating of many resistant insects, also therefore as the fashionable whole world in recent years New type disinsection acaricide.Chlorfenapyr is used as having for being able to successfully develop by the chemical constitution transformation to natural antibiotics One class novel insecticidal acaricide of its particular mechanism, high-efficiency broad spectrum all has excellent to chewing and sucking pest and evil mite Activity, can be for preventing and treating diamondback moth, prodenia litura, cabbage caterpillar, the agricultural pests such as vegetable aphid, especially to carbamate Class, organic phosphates and pyrethroid pesticide have produced insect and the evil mite of resistance, and such as diamondback moth, prodenia litura has spy Effect.But its use scope is have impact on because its cost is too high.The high consumption of other chlorfenapyr is to water such as honeybee, fowl, bird and fishes Raw animal toxicity is higher, its also relatively restricted use.
Either etoxazole, amino-oligosaccharide or chlorfenapyr, long-term to be used alone, and disease is produced anti-medicine Property, cause the problem of dosage increasing, preventive effect are reduced, the lasting period shortens, be unfavorable for environment sustainable development.
The content of the invention
To solve described problem, the technical problems to be solved by the invention are to provide a kind of composition pesticide, etoxazole, ammonia Base oligosaccharide is different with the chlorfenapyr mechanism of action, and mutually compounding has good synergistic effect within the specific limits.
The technical scheme that the present invention solves above-mentioned technical problem is as follows:
A kind of composition pesticide, the active component of the composition pesticide is etoxazole, amino-oligosaccharide and chlorfenapyr, institute Active component is stated to be calculated by weight as:1-60 parts of 1-40 parts of etoxazole, 1-50 parts of amino-oligosaccharide and chlorfenapyr.
Further, in addition to auxiliary agent.
Further, the auxiliary agent includes the one or more in dispersant, defoamer, wetting agent, disintegrant and filler.
Further, the parts by weight of the auxiliary agent addition are:0.1-15 parts of dispersant, 0.1-2 parts of defoamer, wetting agent 0.1-15 parts, 0.1-6 parts of disintegrant, 5-70 parts of filler.
Further, the formulation of the composition pesticide is water dispersible granules, wettable powder.
A kind of application of composition pesticide in the disease of preventing and treating citrus and vegetables.
Further, the disease is bacterium or fungal disease.
The beneficial effects of the invention are as follows:A kind of composition pesticide that the present invention is provided, the active ingredient of the different mechanisms of action Compounded, delay disease to develop immunity to drugs.Complex role is significantly formulated, and can be significantly improved preventive effect, be substantially reduced agriculture The dosage of medicine, can also expand fungicidal spectrum, improve germicidal efficiency.
Embodiment
The principle and feature of the present invention are described below in conjunction with instantiation, example is served only for explaining this hair It is bright, it is not intended to limit the scope of the present invention.
Embodiment 1
1 part of etoxazole
50 parts of amino-oligosaccharide
58 parts of chlorfenapyr
10 parts of sodium lignin sulfonate
8 parts of calcium dodecyl benzene sulfonate
1 part of succinic acid
51 parts of kaolin
The above-mentioned parts by weight such as active component etoxazole, amino-oligosaccharide and chlorfenapyr and various auxiliary agents and filler are mixed Close, after ultra-fine pulverizer disintegrating, that is, obtain wettable powder.
The embodiment is applied to preventing and treating mandarin orange canker.The wettable powder being made is diluted with water after spraying, medicine by 600 times 7-15 days, effect was notable after etoxazole, amino-oligosaccharide and chlorfenapyr are compounded.
Embodiment 2
40 parts of etoxazole
1 part of amino-oligosaccharide
2 parts of chlorfenapyr
4 parts of calcium lignosulfonate
4 parts of calcium dodecyl benzene sulfonate
3 parts of bentonite
1 part of sodium acid carbonate
5 parts of starch
28 parts of precipitated calcium carbonate
The above-mentioned parts by weight such as etoxazole and various auxiliary agents and filler are mixed, by air-flow crushing into wettable powder Agent, the amino-oligosaccharide and chlorfenapyr for adding parts by weight is well mixed, and is eventually adding a certain amount of water mixing extruding and is made material, Water dispersible granules are obtained after drying screening.
The embodiment is applied to preventing and treating cucumber downy mildew.The water dispersible granules being made are diluted with water spraying, medicine by 700 times 1-7 days afterwards, effect was notable after etoxazole, amino-oligosaccharide and chlorfenapyr are compounded.
Embodiment 3
25 parts of etoxazole
25 parts of amino-oligosaccharide
30 parts of chlorfenapyr
Calcium lignosulfonate 5g
Dodecyl polyoxyethylene sulfonic acid sodium salt 6g
Lauryl sodium sulfate 5g
Ammonium sulfate 4g
Kaolin 15g
The above-mentioned parts by weight such as etoxazole and various auxiliary agents and filler are mixed, by air-flow crushing into wettable powder Agent, the amino-oligosaccharide and chlorfenapyr for adding parts by weight is well mixed, and is eventually adding a certain amount of water mixing extruding and is made material, Water dispersible granules are obtained after drying screening.
The embodiment is applied to the preventing and treating white rot of paddy rice.The water dispersible granules 800g/hm2 being made is watered after 225L, medicine 7-15 days, effect was notable after etoxazole, amino-oligosaccharide and chlorfenapyr are compounded.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.

Claims (7)

1. a kind of composition pesticide, it is characterised in that the active component of the composition pesticide be etoxazole, amino-oligosaccharide and Chlorfenapyr, the active component is calculated by weight as:1-40 parts of etoxazole, 1-50 parts of amino-oligosaccharide and chlorfenapyr 1-60 Part.
2. composition pesticide according to claim 1, it is characterised in that the agricultural chemicals also includes auxiliary agent.
3. composition pesticide according to claim 2, it is characterised in that the auxiliary agent includes dispersant, defoamer, wetting One or more in agent, disintegrant and filler.
4. composition pesticide according to claim 3, it is characterised in that the parts by weight of the auxiliary agent addition are: 0.1-15 parts of dispersant, 0.1-2 parts of defoamer, 0.1-15 parts of wetting agent, 0.1-6 parts of disintegrant, 5-70 parts of filler.
5. the composition pesticide according to claim any one of 1-4, it is characterised in that the formulation of the composition pesticide is Water dispersible granules, wettable powder.
6. a kind of application of composition pesticide as described in claim any one of 1-5 in the disease of preventing and treating citrus and vegetables.
7. application according to claim 6, it is characterised in that the disease is bacterium or fungal disease.
CN201710435983.5A 2017-06-08 2017-06-08 A kind of composition pesticide Pending CN107136093A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710435983.5A CN107136093A (en) 2017-06-08 2017-06-08 A kind of composition pesticide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710435983.5A CN107136093A (en) 2017-06-08 2017-06-08 A kind of composition pesticide

Publications (1)

Publication Number Publication Date
CN107136093A true CN107136093A (en) 2017-09-08

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710435983.5A Pending CN107136093A (en) 2017-06-08 2017-06-08 A kind of composition pesticide

Country Status (1)

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CN (1) CN107136093A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113598180A (en) * 2021-07-13 2021-11-05 河北禾润生物科技有限公司 Insecticidal and bactericidal composition and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101836630A (en) * 2010-05-14 2010-09-22 深圳市朗钛生物科技有限公司 Pesticide composition containing amino-oligosaccharide and kresoxim-methyl and use method and application thereof
CN102696631A (en) * 2012-05-09 2012-10-03 广东中迅农科股份有限公司 Synergistic acaricidal composition containing etoxazole and chlorfenapyr

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101836630A (en) * 2010-05-14 2010-09-22 深圳市朗钛生物科技有限公司 Pesticide composition containing amino-oligosaccharide and kresoxim-methyl and use method and application thereof
CN102696631A (en) * 2012-05-09 2012-10-03 广东中迅农科股份有限公司 Synergistic acaricidal composition containing etoxazole and chlorfenapyr

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
安楠等: "乙螨唑防治棉花叶螨药效试验", 《植物保护》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113598180A (en) * 2021-07-13 2021-11-05 河北禾润生物科技有限公司 Insecticidal and bactericidal composition and application thereof

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Application publication date: 20170908