CN107129308A - Ceramic Tiles adobe that a kind of anti-hollowing comes off and its preparation method and application - Google Patents

Ceramic Tiles adobe that a kind of anti-hollowing comes off and its preparation method and application Download PDF

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Publication number
CN107129308A
CN107129308A CN201710225181.1A CN201710225181A CN107129308A CN 107129308 A CN107129308 A CN 107129308A CN 201710225181 A CN201710225181 A CN 201710225181A CN 107129308 A CN107129308 A CN 107129308A
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China
Prior art keywords
adobe
ceramic tiles
comes
base powder
base substrate
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CN201710225181.1A
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Inventor
马超
汪乾
柯善军
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Foshan Oceano Ceramics Co Ltd
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Foshan Oceano Ceramics Co Ltd
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Priority to CN201710225181.1A priority Critical patent/CN107129308A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/6269Curing of mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62695Granulation or pelletising
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063Preparing or treating the raw materials individually or as batches
    • C04B38/0635Compounding ingredients
    • C04B38/0645Burnable, meltable, sublimable materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063Preparing or treating the raw materials individually or as batches
    • C04B38/0635Compounding ingredients
    • C04B38/0645Burnable, meltable, sublimable materials
    • C04B38/067Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063Preparing or treating the raw materials individually or as batches
    • C04B38/0635Compounding ingredients
    • C04B38/0645Burnable, meltable, sublimable materials
    • C04B38/068Carbonaceous materials, e.g. coal, carbon, graphite, hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Finishing Walls (AREA)

Abstract

The invention discloses the Ceramic Tiles adobe that a kind of anti-hollowing comes off, it has by billet surface layer and the compressing double-decker of base substrate backing layer, and the billet surface layer is compacted zone, and the base substrate backing layer is open-pored porous layer.The Ceramic Tiles adobe of the present invention is the double-decker with gradient, its base substrate backing layer is open-pored porous layer, the adhesion strength of Ceramic Tiles base substrate bottom surface and cement mortar is improved by increasing specific surface area and pinning effect, so as to realize that high-strength interfaces are combined, hollowing and the problem that comes off that Ceramic Tiles occur during paving and use are improved.The invention also discloses the preparation method of the Ceramic Tiles adobe, its technical process is simple, it is easy to accomplish industrialization, and reproducible, high yield rate.The present invention is applied to the adobe of a variety of Ceramic Tiles with decorative effect.

Description

Ceramic Tiles adobe that a kind of anti-hollowing comes off and its preparation method and application
Technical field
The present invention relates to architectural pottery field, Ceramic Tiles adobe that more particularly to a kind of anti-hollowing comes off and preparation method thereof And application.
Background technology
In recent years, with the development of Real estate industry, and the income groups of the general public of middle class's representative expand, Requirement more and more higher of the people to hardware conditions such as houses;Also turn into important selection as the Ceramic Tiles of home decorating, and it is right In ceramic tile in itself except in addition to its ornamental expansion attractive in appearance, also needing to ensure and improve the practicality of Ceramic Tiles.Hollowing phenomenon one It is directly building ceramic tiles quotidian quality problems during paving use, its presence causes Ceramic Tiles core the most Decoration, using effect are had a greatly reduced quality, it is also possible to as potential potential safety hazard.And when hollowing phenomenon occurs in kitchen, bathroom etc. Region then easily forms ponding at Ceramic Tiles bottom and produces stench, has a strong impact on people and occupies experience.Between building ceramic tiles and cement mortar Bond strength deficiency be to cause one of basic reason of hollowing.At present, in architectural ceramic industry, mainly by increasing Ceramic Tiles back end The specific surface area of line(Such as concave and convex stripe, crossed square concave and convex stripe, hexagon concave and convex stripe)To improve Ceramic Tiles and cement Contact area, reach the purpose of increase Ceramic Tiles and cement bond strength.But porcelain still can not effectively be solved using this kind of method The problem of wall hollowing comes off on matter brick.In order to solve the hollowing of Ceramic Tiles and the problem that comes off is, it is necessary to increase Ceramic Tiles and binding agent Bond strength, to increase service life, reduce maintenance cost.In increase Ceramic Tiles and the intensity of binding agent, tile bonding Agent is a kind of mode often used, but its cost is often several times or even several times of ordinary mortar, and this can increase construction cost.
The content of the invention
It is an object of the invention to for above-mentioned the deficiencies in the prior art, there is provided the Ceramic Tiles adobe that a kind of anti-hollowing comes off And preparation method thereof, the Ceramic Tiles adobe that emptying drum comes off has gradient-structure and can apply to the ceramics of a variety of decorative effects The preparation of brick.
The technical solution used in the present invention is:The Ceramic Tiles adobe that a kind of anti-hollowing comes off, it has by billet surface Layer and the compressing double-decker of base substrate backing layer, the billet surface layer are compacted zone, and the base substrate backing layer is perforate Porous layer.
As the further improvement of such scheme, the open cell porous structure of the base substrate backing layer is by pore creating material foam process It is made.
Specifically, the compacted zone is used in subsequent machining technology the traditional decoration for realizing Ceramic Tiles, such as billet surface Decorative pattern needed for layer is obtained after the charity of the glaze such as cover-coat enamel, color glaze, throwing glaze, can be prepared into decorative effect by burning till Ceramic Tiles.The base substrate backing layer has open cell porous structure, can improve
A kind of preparation method for the Ceramic Tiles adobe that anti-hollowing as described above comes off, it is comprised the technical steps that:
1)It is prepared by base powder:The different base powder of two kinds of moisture content, i.e. low-water-content is made by mist projection granulating in conventional ceramic slurry Two kinds of base powder and high-moisture percentage base powder, are mixed after then high-moisture percentage base powder is handled through sieving with a certain amount of pore creating material Even, must be foamed base powder, and the foaming base powder and low-water-content base powder are carried out into old processing respectively;
2)Shaping:With step 1)In low-water-content base powder be base substrate fabric, step 1)In foaming base powder be base substrate bed material, adopt It is dry-pressing formed with secondary material distributing, the double-deck knot that it is compacted zone to be formed with billet surface layer and base substrate backing layer is open-pored porous layer The adobe of structure;
3)Post processing:By step 2)The adobe of gained is placed in dry kiln and dried, and adobe surface is entered by mill blank machine after drying Row throws flat processing, obtains adobe finished product.
It is used as the further improvement of such scheme, step 1)Described in low-water-content base powder moisture content be 4 ~ 5%, institute The moisture content for stating high-moisture percentage base powder is 7 ~ 9%.
It is used as the further improvement of such scheme, step 1)Described in sieving processing sieve mesh number be 20 mesh.
It is used as the further improvement of such scheme, step 1)Described in pore creating material be selected from carbon dust, it is starch, carborundum, poly- At least one of styrene, polymethyl methacrylate, polypropylene and polyethylene, its addition are the foaming total matter of base powder The 0.5 ~ 15% of amount.
It is used as the further improvement of such scheme, step 1)Described in the old time be not less than 7 days.
It is used as the further improvement of such scheme, step 2)Described in base substrate fabric and base substrate bed material mass ratio for 5 ~ 10:1。
It is used as the further improvement of such scheme, step 2)Described in drying temperature be 150 ~ 180 DEG C, drying time is 45~60min。
It is used as the further improvement of such scheme, step 2)Described in the mill blank thickness of the flat processing of throwing be 0.3 ~ 0.5mm.
The Ceramic Tiles adobe that the anti-hollowing of the present invention comes off, it is adaptable to the adobe of a variety of Ceramic Tiles with decorative effect.
The beneficial effects of the invention are as follows:The Ceramic Tiles adobe of the present invention is the double-decker with gradient, its base substrate back end Layer is open-pored porous layer, strong by the bonding for increasing specific surface area and pinning effect raising Ceramic Tiles base substrate bottom surface and cement mortar Degree, so as to realize that high-strength interfaces are combined, improves hollowing and the problem that comes off that Ceramic Tiles occur during paving and use. Present invention process process is simple, it is easy to accomplish industrialization, and reproducible, high yield rate.The present invention is applied to a variety of with dress Adorn the adobe of the Ceramic Tiles of effect.
Brief description of the drawings
Accompanying drawing 1 is the photo in the section of the Ceramic Tiles adobe prepared by the embodiment of the present invention 1;
Accompanying drawing 2 is the actual effect figure of the base substrate backing layer of the Ceramic Tiles adobe prepared by the embodiment of the present invention 1.
Embodiment
The present invention is specifically described with reference to embodiment, in order to art personnel to the present invention Understand.It is necessary that herein the present invention will be further described it is emphasized that embodiment is only intended to, it is impossible to be interpreted as to this The limitation of invention protection domain, art person skilled in the art, the non-intrinsically safe made according to foregoing invention content to the present invention The modifications and adaptations of property, should still fall within protection scope of the present invention.Simultaneously following mentioned raw materials are unspecified, are Commercially available prod;The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or Preparation method.
Embodiment 1
The Ceramic Tiles adobe that a kind of anti-hollowing comes off, it has by the compressing double-deck knot of billet surface layer and base substrate backing layer Structure, the billet surface layer is compacted zone, and the base substrate backing layer is open-pored porous layer, and its preparation method is as follows:
1)It is prepared by blank:Conventional ceramic slurry is prepared into by mist projection granulating respectively low-water-content base powder that moisture content is 4% and Moisture content is 7% high-moisture percentage base powder, is uniformly mixed with carbon dust and starch after high-moisture percentage base powder then is crossed into the processing of 20 mesh sieves Close, must foam base powder, wherein the total amount of adding of carbon dust and starch is 0.5% of gross mass in foaming base powder, then low-water-content base powder Distinguish old 9 days with foaming base powder;
2)Shaping:With step 1)In low-water-content base powder be base substrate fabric, step 1)In foaming base powder be base substrate bed material, and The mass ratio of base substrate fabric and base substrate bed material is 10:1, dry-pressing formed using secondary material distributing, i.e. formation is with billet surface layer Compacted zone and base substrate backing layer are the adobe of the double-decker of open-pored porous layer;
3)Post processing:By step 2)The adobe of gained is placed in dry kiln and dried, and drying temperature is 180 DEG C, and drying time is 45min, to adobe surface throw and puts down processing, wherein mill blank thickness is 0.3mm, obtains adobe finished product after drying by mill blank machine.
Embodiment 1 it is prepared anti-hollowing come off Ceramic Tiles adobe, it has double-decker as shown in Figure 1, its The actual effect of the open cell porous structure of base substrate backing layer is as shown in Figure 2.
Embodiment 2
The Ceramic Tiles adobe that a kind of anti-hollowing comes off, it has by the compressing double-deck knot of billet surface layer and base substrate backing layer Structure, the billet surface layer is compacted zone, and the base substrate backing layer is open-pored porous layer, and its preparation method is as follows:
1)It is prepared by blank:Conventional ceramic slurry is prepared into by mist projection granulating respectively low-water-content base powder that moisture content is 5% and Moisture content is 8% high-moisture percentage base powder, and high-moisture percentage base powder then is crossed into equal with polymethyl methacrylate after the processing of 20 mesh sieves Even mixing, must foam base powder, and wherein the addition of polymethyl methacrylate is 10% of gross mass in foaming base powder, then low is contained Water rate base powder and foaming base powder are distinguished old 7 days;
2)Shaping:With step 1)In low-water-content base powder be base substrate fabric, step 1)In foaming base powder be base substrate bed material, and The mass ratio of base substrate fabric and base substrate bed material is 5:1, dry-pressing formed using secondary material distributing, that is, being formed has billet surface layer to cause Close layer and base substrate backing layer is the adobe of the double-decker of open-pored porous layer;
3)Post processing:By step 2)The adobe of gained is placed in dry kiln and dried, and drying temperature is 150 DEG C, and drying time is 60min, to adobe surface throw and puts down processing, wherein mill blank thickness is 0.5mm, obtains adobe finished product after drying by mill blank machine.
Embodiment 3
The Ceramic Tiles adobe that a kind of anti-hollowing comes off, it has by the compressing double-deck knot of billet surface layer and base substrate backing layer Structure, the billet surface layer is compacted zone, and the base substrate backing layer is open-pored porous layer, and its preparation method is as follows:
1)It is prepared by blank:Conventional ceramic slurry is prepared into the low-water-content base powder that moisture content is 4.5% respectively by mist projection granulating With moisture content be 9% high-moisture percentage base powder, then by high-moisture percentage base powder cross 20 mesh sieves processing after with carborundum, polystyrene, Polypropylene and polyethylene are uniformly mixed, and must foam base powder, and the addition of wherein carborundum, polystyrene, polypropylene and polyethylene is total Measure as 15% of gross mass in foaming base powder, then low-water-content base powder and foaming base powder are distinguished old 12 days;
2)Shaping:With step 1)In low-water-content base powder be base substrate fabric, step 1)In foaming base powder be base substrate bed material, and The mass ratio of base substrate fabric and base substrate bed material is 7:1, dry-pressing formed using secondary material distributing, that is, being formed has billet surface layer to cause Close layer and base substrate backing layer is the adobe of the double-decker of open-pored porous layer;
3)Post processing:By step 2)The adobe of gained is placed in dry kiln and dried, and drying temperature is 170 DEG C, and drying time is 50min, to adobe surface throw and puts down processing, wherein mill blank thickness is 0.4mm, obtains adobe finished product after drying by mill blank machine.
Above-described embodiment is the preferred embodiments of the present invention, all with similar technique of the invention and the equivalence changes made, The protection category of the present invention all should be belonged to.

Claims (10)

1. the Ceramic Tiles adobe that a kind of anti-hollowing comes off, it is characterised in that:With by billet surface layer and the compacting of base substrate backing layer The double-decker of shaping, the billet surface layer is compacted zone, and the base substrate backing layer is open-pored porous layer.
2. the Ceramic Tiles adobe that a kind of anti-hollowing according to claim 1 comes off, it is characterised in that:The base substrate backing layer Open cell porous structure be made up of pore creating material foam process.
3. a kind of preparation method for the Ceramic Tiles adobe that anti-hollowing as claimed in claim 1 or 2 comes off, it is characterised in that bag Include following processing step:
1)It is prepared by base powder:The different base powder of two kinds of moisture content, i.e. low-water-content is made by mist projection granulating in conventional ceramic slurry Two kinds of base powder and high-moisture percentage base powder, are mixed after then high-moisture percentage base powder is handled through sieving with a certain amount of pore creating material Even, must be foamed base powder, and the foaming base powder and low-water-content base powder are carried out into old processing respectively;
2)Shaping:With step 1)In low-water-content base powder be base substrate fabric, step 1)In foaming base powder be base substrate bed material, adopt It is dry-pressing formed with secondary material distributing, the double-deck knot that it is compacted zone to be formed with billet surface layer and base substrate backing layer is open-pored porous layer The adobe of structure;
3)Post processing:By step 2)The adobe of gained is placed in dry kiln and dried, and adobe surface is entered by mill blank machine after drying Row throws flat processing, obtains adobe finished product.
4. the preparation method for the Ceramic Tiles adobe that a kind of anti-hollowing according to claim 3 comes off, it is characterised in that:Step 1)Described in the moisture content of low-water-content base powder be 4 ~ 5%, the moisture content of the high-moisture percentage base powder is 7 ~ 9%.
5. the preparation method for the Ceramic Tiles adobe that a kind of anti-hollowing according to claim 3 comes off, it is characterised in that:Step 1)Described in sieving processing sieve mesh number be 20 mesh.
6. the preparation method for the Ceramic Tiles adobe that a kind of anti-hollowing according to claim 3 comes off, it is characterised in that:Step 1)Described in pore creating material be selected from carbon dust, starch, carborundum, polystyrene, polymethyl methacrylate, polypropylene and polyethylene At least one of, its addition is the 0.5 ~ 15% of the foaming base powder gross mass.
7. the preparation method for the Ceramic Tiles adobe that a kind of anti-hollowing according to claim 3 comes off, it is characterised in that:Step 1)Described in the old time be not less than 7 days.
8. the preparation method for the Ceramic Tiles adobe that a kind of anti-hollowing according to claim 3 comes off, it is characterised in that:Step 2)Described in the mass ratio of base substrate fabric and base substrate bed material be 5 ~ 10:1.
9. the preparation method for the Ceramic Tiles adobe that a kind of anti-hollowing according to claim 3 comes off, it is characterised in that:Step 2)Described in drying temperature be 150 ~ 180 DEG C, drying time be 45 ~ 60min.
10. a kind of application for the Ceramic Tiles adobe that anti-hollowing as claimed in claim 1 or 2 comes off, it is characterised in that:It is applied to The adobe of a variety of Ceramic Tiles with decorative effect.
CN201710225181.1A 2017-06-26 2017-06-26 Ceramic Tiles adobe that a kind of anti-hollowing comes off and its preparation method and application Pending CN107129308A (en)

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Cited By (10)

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Publication number Priority date Publication date Assignee Title
CN107651966A (en) * 2017-09-30 2018-02-02 佛山欧神诺陶瓷股份有限公司 A kind of decorative light temperature preservation ceramic tile and preparation method thereof
CN109534760A (en) * 2018-11-22 2019-03-29 河南创新复合材料科技有限责任公司 A kind of light ceramics composite exterior wall tapestry brick and preparation method thereof
CN110054475A (en) * 2019-04-09 2019-07-26 广东金意陶陶瓷集团有限公司 A kind of bottom has the Ceramic Tiles and preparation method thereof of porous structure
CN111605043A (en) * 2020-05-14 2020-09-01 东莞市唯美陶瓷工业园有限公司 Porous gradient ceramic tile and manufacturing method thereof
CN112624771A (en) * 2020-12-11 2021-04-09 佛山欧神诺陶瓷有限公司 Hollowing-proof ceramic tile with gradient porous structure and preparation method and application thereof
CN112979298A (en) * 2021-05-19 2021-06-18 蒙娜丽莎集团股份有限公司 Spread and pasted ceramic tile green body easy to bond, ceramic tile comprising green body and preparation method
CN114014686A (en) * 2021-10-29 2022-02-08 佛山欧神诺陶瓷有限公司 Porcelain tile blank with hollowing prevention function and preparation method thereof
CN114477982A (en) * 2021-12-30 2022-05-13 佛山欧神诺陶瓷有限公司 Preparation method of ceramic tile back texture
CN114853445A (en) * 2022-05-06 2022-08-05 蒙娜丽莎集团股份有限公司 Easy-to-bond green body for improving bonding strength of ceramic tile, ceramic tile comprising easy-to-bond green body and preparation method
CN115894088A (en) * 2022-12-19 2023-04-04 佛山欧神诺陶瓷有限公司 Preparation method of ceramic tile, ceramic tile and application of ceramic tile

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107651966A (en) * 2017-09-30 2018-02-02 佛山欧神诺陶瓷股份有限公司 A kind of decorative light temperature preservation ceramic tile and preparation method thereof
CN109534760A (en) * 2018-11-22 2019-03-29 河南创新复合材料科技有限责任公司 A kind of light ceramics composite exterior wall tapestry brick and preparation method thereof
CN110054475A (en) * 2019-04-09 2019-07-26 广东金意陶陶瓷集团有限公司 A kind of bottom has the Ceramic Tiles and preparation method thereof of porous structure
CN110054475B (en) * 2019-04-09 2022-03-22 广东金意陶陶瓷集团有限公司 Ceramic tile with porous structure at bottom and preparation method thereof
CN111605043A (en) * 2020-05-14 2020-09-01 东莞市唯美陶瓷工业园有限公司 Porous gradient ceramic tile and manufacturing method thereof
CN112624771A (en) * 2020-12-11 2021-04-09 佛山欧神诺陶瓷有限公司 Hollowing-proof ceramic tile with gradient porous structure and preparation method and application thereof
CN112979298B (en) * 2021-05-19 2021-09-10 蒙娜丽莎集团股份有限公司 Spread and pasted ceramic tile green body easy to bond, ceramic tile comprising green body and preparation method
CN112979298A (en) * 2021-05-19 2021-06-18 蒙娜丽莎集团股份有限公司 Spread and pasted ceramic tile green body easy to bond, ceramic tile comprising green body and preparation method
CN114014686A (en) * 2021-10-29 2022-02-08 佛山欧神诺陶瓷有限公司 Porcelain tile blank with hollowing prevention function and preparation method thereof
CN114477982A (en) * 2021-12-30 2022-05-13 佛山欧神诺陶瓷有限公司 Preparation method of ceramic tile back texture
CN114477982B (en) * 2021-12-30 2022-11-15 佛山欧神诺陶瓷有限公司 Preparation method of ceramic tile back texture
CN114853445A (en) * 2022-05-06 2022-08-05 蒙娜丽莎集团股份有限公司 Easy-to-bond green body for improving bonding strength of ceramic tile, ceramic tile comprising easy-to-bond green body and preparation method
CN115894088A (en) * 2022-12-19 2023-04-04 佛山欧神诺陶瓷有限公司 Preparation method of ceramic tile, ceramic tile and application of ceramic tile

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Application publication date: 20170905