CN107126378B - 表面活性剂组合物及由其制成的清洁剂 - Google Patents
表面活性剂组合物及由其制成的清洁剂 Download PDFInfo
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- CN107126378B CN107126378B CN201610145987.5A CN201610145987A CN107126378B CN 107126378 B CN107126378 B CN 107126378B CN 201610145987 A CN201610145987 A CN 201610145987A CN 107126378 B CN107126378 B CN 107126378B
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- 239000000203 mixture Substances 0.000 title claims abstract description 108
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 83
- 239000003599 detergent Substances 0.000 title description 9
- 229920006318 anionic polymer Polymers 0.000 claims abstract description 32
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 21
- 239000002453 shampoo Substances 0.000 claims abstract description 10
- -1 alkyl ether sulfate Chemical class 0.000 claims description 28
- 229920002635 polyurethane Polymers 0.000 claims description 21
- 239000004814 polyurethane Substances 0.000 claims description 21
- OWEGWHBOCFMBLP-UHFFFAOYSA-N 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethylbutan-2-one Chemical compound C1=CN=CN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 OWEGWHBOCFMBLP-UHFFFAOYSA-N 0.000 claims description 19
- 229960003344 climbazole Drugs 0.000 claims description 17
- 239000004480 active ingredient Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
- 239000012459 cleaning agent Substances 0.000 claims description 6
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 6
- 150000001768 cations Chemical class 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 4
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 4
- 229950001046 piroctone Drugs 0.000 claims description 4
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 claims description 4
- XMAYWYJOQHXEEK-OZXSUGGESA-N (2R,4S)-ketoconazole Chemical compound C1CN(C(=O)C)CCN1C(C=C1)=CC=C1OC[C@@H]1O[C@@](CN2C=NC=C2)(C=2C(=CC(Cl)=CC=2)Cl)OC1 XMAYWYJOQHXEEK-OZXSUGGESA-N 0.000 claims description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 3
- 229960003237 betaine Drugs 0.000 claims description 3
- 229960004125 ketoconazole Drugs 0.000 claims description 3
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims 3
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- 239000007787 solid Substances 0.000 description 11
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000000654 additive Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
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- 230000003750 conditioning effect Effects 0.000 description 6
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- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
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- 239000013543 active substance Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
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- 239000000126 substance Substances 0.000 description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 150000004985 diamines Chemical class 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 4
- 125000003010 ionic group Chemical group 0.000 description 4
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- 229920001296 polysiloxane Polymers 0.000 description 4
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 150000003141 primary amines Chemical class 0.000 description 3
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- PRBXPAHXMGDVNQ-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethoxy]acetic acid Chemical compound OCCOCCOCC(O)=O PRBXPAHXMGDVNQ-UHFFFAOYSA-N 0.000 description 2
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 2
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- PJWWRFATQTVXHA-UHFFFAOYSA-N Cyclohexylaminopropanesulfonic acid Chemical compound OS(=O)(=O)CCCNC1CCCCC1 PJWWRFATQTVXHA-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- VZWGRQBCURJOMT-UHFFFAOYSA-N Dodecyl acetate Chemical compound CCCCCCCCCCCCOC(C)=O VZWGRQBCURJOMT-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 239000005700 Putrescine Substances 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 2
- QVBODZPPYSSMEL-UHFFFAOYSA-N dodecyl sulfate;2-hydroxyethylazanium Chemical compound NCCO.CCCCCCCCCCCCOS(O)(=O)=O QVBODZPPYSSMEL-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical class CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
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- CBFCDTFDPHXCNY-UHFFFAOYSA-N icosane Chemical class CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
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- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
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- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 2
- 229940116985 potassium lauryl sulfate Drugs 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
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- 150000003335 secondary amines Chemical class 0.000 description 2
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- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 1
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- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
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- QGLRLXLDMZCFBP-UHFFFAOYSA-N 1,6-diisocyanato-2,4,4-trimethylhexane Chemical compound O=C=NCC(C)CC(C)(C)CCN=C=O QGLRLXLDMZCFBP-UHFFFAOYSA-N 0.000 description 1
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- DPQHRXRAZHNGRU-UHFFFAOYSA-N 2,4,4-trimethylhexane-1,6-diamine Chemical compound NCC(C)CC(C)(C)CCN DPQHRXRAZHNGRU-UHFFFAOYSA-N 0.000 description 1
- RRLKOZCPQXMIIJ-UHFFFAOYSA-N 2,4,4-trimethylnonane Chemical compound CCCCCC(C)(C)CC(C)C RRLKOZCPQXMIIJ-UHFFFAOYSA-N 0.000 description 1
- RWBHOLZDSPWSPK-UHFFFAOYSA-N 2,4,4-trimethylundecane Chemical compound CCCCCCCC(C)(C)CC(C)C RWBHOLZDSPWSPK-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- IVGRSQBDVIJNDA-UHFFFAOYSA-M 2-(2-aminoethylamino)ethanesulfonate Chemical compound NCCNCCS([O-])(=O)=O IVGRSQBDVIJNDA-UHFFFAOYSA-M 0.000 description 1
- IVGRSQBDVIJNDA-UHFFFAOYSA-N 2-(2-aminoethylamino)ethanesulfonic acid Chemical compound NCCNCCS(O)(=O)=O IVGRSQBDVIJNDA-UHFFFAOYSA-N 0.000 description 1
- CYPKANIKIWLVMF-UHFFFAOYSA-N 2-[(2-oxo-3,4-dihydro-1h-quinolin-5-yl)oxy]acetic acid Chemical compound N1C(=O)CCC2=C1C=CC=C2OCC(=O)O CYPKANIKIWLVMF-UHFFFAOYSA-N 0.000 description 1
- FZZMTSNZRBFGGU-UHFFFAOYSA-N 2-chloro-7-fluoroquinazolin-4-amine Chemical compound FC1=CC=C2C(N)=NC(Cl)=NC2=C1 FZZMTSNZRBFGGU-UHFFFAOYSA-N 0.000 description 1
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明涉及一种表面活性剂组合物,包含:阴离子聚合物和两性表面活性剂,其中阴离子聚合物与两性表面活性剂的重量比为1∶25‑25∶1。本发明的表面活性剂组合物能够提高活性物质在待清洁物体上的沉积,且当用于洗发水时,还有助于头发保持卷曲。本发明还涉及一种清洁剂,特别是涉及一种洗发水,其由本发明的表面活性剂组合物制成。
Description
技术领域
本发明涉及一种表面活性剂组合物,具体而言,涉及一种用于清洁剂的组合物;以及涉及由所述表面活性剂组合物制成的清洁剂。
背景技术
日常清洁剂,特别是洗发水,除了需要满足基本的清洁功能之外,还期望其具有更多的功能,例如营养头发并保持头皮和头发健康。为了满足日益增加的消费者的需求,生产商向洗发水中添加越来越多的活性物质以实现上述功能。然而,所添加的活性物质大多在冲洗头发时被冲走,仅有极少量保留在头发上并发挥效果。
发明内容
本发明旨在解决上述问题,提高清洁剂、特别是洗发水中活性物质的沉积。
因此,本发明一方面提供一种表面活性剂组合物,包含:阴离子聚合物和两性表面活性剂,其中阴离子聚合物与两性表面活性剂的重量比为1∶25-25∶1。
在本发明表面活性剂组合物的一个优选实施方案中,阴离子聚合物的量为至少0.2重量%,基于组合物为100重量%计。
在本发明的另一个优选实施方案中,两性表面活性剂的量为1-20重量%,基于组合物为100重量%计。
在本发明表面活性剂组合物的一个更优选的实施方案中,阴离子聚合物选自聚氨酯阴离子聚合物或聚丙烯酸酯聚合物。所述聚氨酯阴离子聚合物包含至少一个磺酸盐基团。聚氨酯阴离子聚合物进一步优选自C1000、C1001、C1003、C1004、C1005、C1008和C2000中的一种或多种。
在本发明表面活性剂组合物的另一个更优选的实施方案中,两性表面活性剂的选自十二烷基氨氧化物、椰油二甲基磺基丙基甜菜碱、十二烷甜菜碱和椰油酰胺基丙基甜菜碱中的一种或多种。
在本发明表面活性剂组合物的一个优选实施方案中,还包含活性成分,所述活性成分的量为0.1-5重量%,基于组合物为100重量%计。
在本发明表面活性剂组合物的一个更优选的实施方案中,活性成分选自羟甲辛吡酮(octopirox)、氯咪巴唑(climbazole,化学名称为1-(4-氯代苯氧基)-1-(1H-咪唑-1-基)-3,3-二甲基-2-丁酮,俗称甘宝素)和酮康唑中的一种或多种。
在本发明表面活性剂组合物的一个优选实施方案中,还包含阴离子表面活性剂,所述阴离子表面活性剂的量为0.1-30重量%,基于组合物为100重量%计。
本发明另一方面涉及一种清洁剂,所述清洁剂由本发明的表面活性剂组合物制成。
在本发明清洁剂的一个优选实施方案中,所述清洁剂为洗发水。
本发明另一方面涉及将本发明的清洁剂施加到待清洁物体上的应用。
本发明的另一方面涉及本发明的清洁剂的沉积方法,包含:a)将本发明的包含表面活性剂组合物的清洁剂施加到待清洁物体上,b)用水去除所述清洁剂。
本发明的表面活性剂组合物能够提高活性物质在待清洁物体上的沉积。特别地,对于洗发水而言,本发明的表面活性剂组合物还有助于头发保持卷曲。
附图说明
图1示出使用本发明表面活性剂组合物与比较表面活性剂组合物后头发的卷曲效果,其中,图1a示出用对比实施例2的组合物洗涤头发后的效果,图1b示出用本发明实施例3的组合物洗涤头发后的明显卷曲的效果。
图2示出本发明表面活性剂组合物与比较表面活性剂组合物中活性物质的沉积效果,其中,图2a示出对比实施例2的化合物的沉积效果,图2a-1示出干燥后头发的质量为15.7823克,图2a-2示出摇动后头发的质量为15.7141克且对比实施例2的化合物无残留;图2b示出本发明实施例3的化合物的沉积效果,图2b-1示出干燥后的头发的质量为16.1822克,图2b-2示出摇动后头发的质量为16.1671克且本发明实施例3的化合物有明显残留。
具体实施方式
本发明中所有百分比均为重量百分比,且均以本发明表面活性剂组合物为100%重量计,另有说明的除外。
本发明中所指的重量均为有效物质的重量。对于呈分散体形式的物质,本发明所指的重量为物质的实际重量,而不包括载体的重量,也就是说,本发明中所指分散体形式的物质的重量=分散体的重量×分散体的固含量。对于含结晶水的固体物质,本发明中所指的物质的重量为除去结晶水的重量。
本发明一方面提供一种表面活性剂组合物,包含:
阴离子聚合物和两性表面活性剂,其中阴离子聚合物与两性表面活性剂的重量比为1∶25-25∶1,优选为1∶15-15∶1,更优选为1∶12-12∶1,最优选为1∶1-12∶1,例如为10∶1。
阴离子聚合物
本发明表面活性剂组合物中可使用的聚氨酯阴离子聚合物可通过一种或多种水不溶性、非水分散性的异氰酸酯官能化聚氨酯预聚物A1)与一种或多种氨基官能化合物A2)反应来获得。
在本发明的范围内,术语″水不溶性、非水分散性的聚氨酯预聚物″指,该预聚物在23℃下在水中的溶解度是低于10g/升,优选低于5g/升,并且预聚物在23℃下在水(尤其指去离子水)中无法产生沉降稳定的分散体。换句话说,在将它分散在水中的实验中,预聚物沉淀出来。
在本发明一个优选的实施方案中,聚氨酯预聚物A1)具有末端异氰酸酯基团,即异氰酸酯基团位于预聚物链末端,优选地,聚氨酯预聚物的所有链末端均具有异氰酸酯基团。
在本发明一个优选的实施方案中,可用于本发明的非水溶性和非水分散性的异氰酸酯官能化聚氨酯预聚物A1)基本上不含有离子基团和/或离子源基团,即离子基团和/或离子源基团的含量合适地是低于15毫克当量(Milli equivalent)/100g的聚氨酯预聚物A1),优选低于5毫克当量,更优选低于1毫克当量,特别优选低于0.1毫克当量/100g的聚氨酯预聚物A1)。本发明优选实施方案中的水指没有添加表面活性剂的去离子水。
在本发明一些实施方案中,可用于本发明的聚氨酯预聚物可以含有酸性离子基团和/或离子源基团,这些聚氨酯预聚物的酸值合适地是低于30mg KOH/g,优选低于10mgKOH/g。该酸值表示为了中和1g的研究样品所需要的氢氧化钾质量(mg)(根据DIN EN ISO211测量)。被中和的酸(即相应盐)自然不具有酸值或具有较低的酸值。
在本发明一些实施方案中,聚氨酯预聚物可通过有机多异氰酸酯制备。合适的有机多异氰酸酯是所属技术领域的技术人员已知的NCO官能度大于或等于2的脂肪族、芳族或脂环族多异氰酸酯。
有机多异氰酸酯非限制性的实例包括1,4-亚丁基二异氰酸酯,1,6-六亚甲基二异氰酸酯(HDI),异佛尔酮二异氰酸酯(IPDI),2,2,4-和/或2,4,4-三甲基六亚甲基二异氰酸酯,双(4,4,-异氰酸根环己基)甲烷异构体或这些异构体的混合物,1,4-亚环已基二异氰酸酯,4-异氰酸根甲基-1,8-辛烷二异氰酸酯(壬烷三异氰酸酯),1,4-苯二异氰酸酯,2,4-和/或2,6-甲苯二异氰酸酯,1,5-亚萘基二异氰酸酯,2,2′-和/或2,4′-和/或4,4′-二苯甲烷二异氰酸酯,1,3-和/或1,4-双(2-异氰酸根丙-2-基)苯(TMXDI),1,3-双(异氰酸根甲基)苯(XDI),和具有C1-C8-烷基的2,6-二异氰酸根己酸烷基酯(赖氨酸二异氰酸酯)。
除上述多异氰酸酯之外,还有可能使用具有脲二酮、异氰脲酸酯、脲烷、脲基甲酸酯、缩二脲、亚氨基噁二嗪二酮或噁二嗪三酮结构的官能度≥2的改性二异氰酸酯,以及这些成分按比例的混合物。
在本发明一个优选的实施方案中,有机多异氰酸酯选自六亚甲基二异氰酸酯、异佛尔酮二异氰酸酯或其组合。
用于制备聚氨酯阴离子聚合物的组分还包括组分A2)一种或多种氨基官能化合物,优选是伯胺、仲胺、二胺或其组合,特别优选二胺。
在本发明一些优选的实施方案中,组分A2)包含:
A2a)不具有离子基团或离子源基团的氨基官能化合物;和
A2b)具有离子基团或离子源基团的氨基官能化合物。
可用作组分A2a)的实例包括但不限于有机二胺或多胺,如1,2-乙二胺,1,2-和1,3-二氨基丙烷,1,4-二氨基丁烷,1,6-二氨基己烷,异佛尔酮二胺,2,2,4-和2,4,4-三甲基六亚甲基二胺的异构体混合物,2-甲基五亚甲基二胺,二亚乙基三胺,4,4-二氨基二环己基甲烷,水合肼,二甲基乙二胺或其组合。
此外,包含伯氨基和仲氨基的化合物,以及包含氨基(伯或仲)和羟基的化合物也能够用作组分A2a)。这些化合物的实例包括伯/仲胺,如二乙醇胺,3-氨基-1-甲基氨基丙烷,3-氨基-1-乙基氨基丙烷,3-氨基-1-环己基氨基丙烷,3-氨基-1-甲基氨基丁烷,链烷醇胺,如N-氨基乙基乙醇胺,乙醇胺,3-氨丙醇,新戊醇胺。
另外,单官能的异氰酸酯反应活性的胺化合物也能够用作组分A2a),例如甲基胺,乙基胺,丙基胺,丁基胺,辛基胺,月桂基胺,硬脂基胺,异壬基氧基丙基胺,二甲基胺,二乙基胺,二丙基胺,二丁基胺,N-甲基氨基丙基胺,二乙基(甲基)氨基丙基胺,吗啉,哌啶,和它们的合适的取代衍生物;由二伯胺和单羧酸形成的酰胺-胺;二伯胺的单酮亚胺(Monoketim);伯/叔胺,如N,N-二甲基氨基丙基胺。
优选地,组分A2a)选自1,2-乙二胺,双(4-氨基环己基)甲烷,1,4-二氨基丁烷,异佛尔酮二胺,乙醇胺,二乙醇胺,二亚乙基三胺或其组合。
组分A2)特别优选包括至少一种组分A2b)。作为组分A2b)是一种阴离子亲水化化合物,优选含有磺酸或磺酸盐基团,特别优选磺酸钠基团。此类阴离子亲水化试剂的实例包括2-(2-氨基乙基氨基)乙烷磺酸、乙二胺-丙基-或-丁基-磺酸、1,2-或1,3-丙二胺-β-乙基磺酸或牛磺酸及其盐类。在WO-A 01/88006公开的环己基氨基丙磺酸(CAPS)的盐也可以用作本发明的组分A2b)。
特别优选的阴离子亲水化试剂A2b)是含有磺酸盐基团作为离子基团和含有两个氨基的那些,如2-(2-氨基乙基氨基)乙基磺酸盐和1,3-丙二胺-β-乙基磺酸盐。
本发明中的聚氨酯特别优选包括至少一个磺酸盐基团。
在本发明一些实施方案中,也可以使用聚合物多元醇来制备聚氨酯阴离子聚合物,此类聚合物多元醇是在聚氨酯涂料技术中已知的聚酯多元醇,聚丙烯酸酯多元醇,聚氨酯多元醇,聚碳酸酯多元醇,聚醚多元醇,聚酯聚丙烯酸酯多元醇,聚氨酯聚丙烯酸酯多元醇,聚氨酯聚酯多元醇,聚氨酯聚醚多元醇,聚氨酯聚碳酸酯多元醇和聚酯聚碳酸酯多元醇。它们能够单独或以混合的形式用于制备本发明的聚氨酯阴离子聚合物。
本发明中的聚合物多元醇优选是聚四亚甲基二醇聚醚、聚碳酸酯多元醇和它们的混合物,特别优选聚四亚甲基二醇聚醚多元醇。
可用于本发明的聚氨酯阴离子聚合物优选是线型分子,但也可是支化的。可用于本发明的聚氨酯阴离子聚合物的数均分子量是,例如,约1000-200000,优选5000到150000。
在本发明中,所用的聚氨酯阴离子聚合物可以是固体形式或分散体形式的,优选使用呈分散体形式的聚氨酯阴离子聚合物。
根据本发明所用的优选聚氨酯阴离子聚合物或聚氨酯阴离子聚合物分散体可通过现有技术中已知的方法,使用已知的组分获得,例如美国专利公开US 2011/0027211,将该文献的全部内容以引用的方式合并入本文。
在本发明一个优选的实施方案中,聚氨酯阴离子聚合物分散体的固体含量为10-70重量%,优选30-65重量%,特别优选40-60重量%。固体含量是通过将称量样品在125℃下加热至恒重来确定的。在恒重下,通过再称量样品来计算固体含量。
本发明表面活性剂组合物中可使用的聚丙烯酸酯聚合物选自丙烯酸脂或聚丙烯酸酯和烷基丙烯酸酯交联嵌段聚合物,此聚合物是空间网状分子。其中烷基的链长为1-45个碳原子,优选10-30个碳原子。为市售可得产品,例如由Lubrizol公司出售的产品:ETD 2020、ETD 2050、Ultrez10、Ultrez20、Ultrez21、Ultrez30、Aqua SF-1、Aqua SF-2、Silk 100等。在本发明表面活性剂组合物中,阴离子聚合物的量为至少0.2重量%,优选为0.5-30重量%,更优选为5-25重量%,基于组合物为100重量%计。
两性表面活性剂
本发明的表面活性剂组合物中使用的两性表面活性剂无特别限制,可以是清洁剂领域常用的两性表面活性剂中的任何一种或多种。
两性表面活性剂的实例包括:烷基氨氧化物、烷基甜菜碱、烷基氨基丙基甜菜碱、烷基磺基甜菜碱、烷基甘氨酸盐、烷基羧基甘氨酸盐、烷基氨基丙基羟基、酰基牛磺酸盐和酰基谷氨酸盐,其中烷基和酰基具有8-19个碳原子。优选的两性表面活性剂为例如十二烷基氨氧化物、椰油二甲基磺基丙基甜菜碱、十二烷甜菜碱和椰油酰胺基丙基甜菜碱。上述提及的两性表面活性物质均为市售可得的。
在本发明的表面活性剂组合物中,两性表面活性剂的量为1-20重量%,优选为2-15重量%,基于表面活性剂组合物为100重量%计。
在本发明的表面活性剂组合物中,所用的两性表面活性剂可以是固体形式或分散体形式的。
在本发明表面活性剂组合物中,还可以包含活性成分。
活性成分
本发明表面活性剂组合物中可以使用的活性成分不作特别限制,可以是例如清洁剂领域常用的活性成分的任何一种或多种。清洁剂中的活性成分通常用于实现某种功能,例如对于洗发水而言,实现去屑效果。
在本发明的表面活性剂组合物中,活性成分优选为去屑剂。去屑剂的实例包括羟甲辛吡酮(octopirox)、例如氯咪巴唑(climbazole,化学名称为1-(4-氯代苯氧基)-1-(1H-咪唑-1-基)-3,3-二甲基-2-丁酮,俗称甘宝素)和酮康唑。在本发明的表面活性剂组合物中,活性成分优选氯咪巴唑。
在本发明的表面活性剂组合物中,活性成分的量可以为0.1-5重量%,优选为0.2-3重量%,基于表面活性剂组合物为100重量%计。
本发明的表面活性剂组合物中,还可以包含阴离子表面活性剂。
阴离子表面活性剂
本发明的表面活性剂组合物中可以使用的阴离子表面活性剂不作特别限制,可以是例如清洁剂领域常用的阴离子表面活性剂的任何一种或多种。
适用于本发明表面活性剂组合物中的阴离子表面活性剂可以为由ROSO3M和RO(C2H4O)xSO3M表示的烷基硫酸盐和烷基醚硫酸盐,其中,R为含有8-18个碳原子的烷基或链烯基;x为1-10的整数;M为阳离子,如铵离子、一价金属阳离子(如钠和钾)以及多价金属阳离子(如镁和钙)。可用于本发明表面活性剂组合物中的烷基硫酸盐和烷基醚硫酸盐的非限制性实例包括牛油烷基六环氧乙烷硫酸的钠盐和铵盐以及椰油烷基三甘醇醚硫酸和牛油烷基三甘醇醚硫酸的钠盐和铵盐。
适用于本发明表面活性剂组合物的其他阴离子去污表面活性剂是琥珀酸盐,实例包括N-十八烷基磺基琥珀酸二钠、十二烷基磺基琥珀酸二钠、十二烷基磺基琥珀酸二铵、N-(1,2-二羧基乙基)-N-十八烷基磺基琥珀酸四钠、磺基琥珀酸钠的二戊酯、磺基琥珀酸钠的二己酯和磺基琥珀酸钠的二辛酯。
优选用于本发明表面活性剂组合物的阴离子表面活性剂包括十二烷基硫酸铵、十二烷基聚氧乙烯醚硫酸铵、十二烷基硫酸三乙基胺、十二烷基聚氧乙烯醚硫酸三乙基胺、十二烷基硫酸三乙醇胺、十二烷基聚氧乙烯醚硫酸三乙醇胺、十二烷基硫酸单乙醇胺、十二烷基聚氧乙烯醚硫酸单乙醇胺、十二烷基硫酸二乙醇胺、十二烷基聚氧乙烯醚硫酸二乙醇胺、十二烷基甘油单酯硫酸钠、十二烷基硫酸钠、十二烷基聚氧乙烯醚硫酸钠、十二烷基硫酸钾、十二烷基聚氧乙烯醚硫酸钾、十二烷基肌氨酸钠、月桂酰肌氨酸钠、肌氨酸月桂酯、椰油基肌氨酸、椰油基硫酸铵、月桂酰基硫酸铵、椰油基硫酸钠、月桂酰基硫酸钠、椰油基硫酸钾、十二烷基硫酸钾、十二烷基硫酸三乙醇胺、十二烷基硫酸三乙醇胺、椰油基硫酸一乙醇胺、十二烷基硫酸一乙醇胺、十三烷基苯磺酸钠、十二烷基苯磺酸钠及其结合物。
在本发明的表面活性剂组合物中,阴离子表面活性剂的量通常为0.1-30重量%,优选为约5-25重量%,更优选为10-22重量%,甚至更优选为12-20重量%,基于表面活性剂组合物为100重量%计。
在本发明的表面活性剂组合物中,还可以包含水性载体。
水性载体
本发明的表面活性剂组合物包含的含水载体的含量和种类根据与其他组分的相容性和产品所需的其他特性选择。
在本发明的表面活性剂组合物中,可以使用的水性载体包括水和低级烷醇的水溶液。本发明表面活性剂组合物中可以使用的低级烷醇为含有1至6个碳原子的一元醇,优选乙醇和异丙醇。优选地,含水载体基本上是水。优选使用去离子水。
在本发明的表面活性剂组合物中,水性载体的含量可以为20-98重量%,优选为30-90重量%,更优选为40-80重量%,基于表面活性剂组合物为100重量%计。
在本发明的表面活性剂组合物中,还可以包括清洁剂中常用的一种或多种添加剂,条件是添加剂与本发明表面活性剂组合物中的各组分在物理和化学上相容,或不会不适当地损害产品的稳定性、美观性或性能。
本发明的表面活性剂组合物中可以使用的添加剂包括调理剂(硅氧烷和有机调理油)、悬浮剂、粘度改性剂、染料、非挥发性溶剂或稀释剂、珠光助剂、泡沫促进剂、附加表面活性剂或非离子助表面活性剂、杀虱剂、pH调节剂、香料、防腐剂、螯合剂、蛋白质、皮肤活性剂、防晒剂、紫外线吸收剂和维生素。
硅氧烷的实例包括聚二甲基硅氧烷、聚二乙基硅氧烷和聚甲基苯基硅氧烷、(聚二甲基硅氧烷)(甲基乙烯基硅氧烷)共聚物,聚(二甲基硅氧烷)(二苯基硅氧烷)(甲基乙烯基硅氧烷)共聚物及其混合物,但不限于此。
有机调理油优选选自烃油、聚烯烃和脂族酯及其混合物。在本发明的清洁剂中,作为调理剂的有机调理油可单独使用,也可与其他调理剂如硅氧烷结合使用。
烃油的实例包括石蜡油、矿物油、饱和和不饱和十二烷、饱和和不饱和十三烷、饱和和不饱和十四烷、饱和和不饱和十五烷、饱和和不饱和十六烷、聚丁烯、聚癸烯及其混合物。也可以使用这些化合物的支链异构体以及更高级链长的烃,实例包括高度支化的饱和或不饱和烷烃,如高甲基取代的异构体,例如十六烷和二十碳烷的高甲基取代的异构体,如2,2,4,4,6,6,8,8-二甲基-10-甲基十一烷和2,2,4,4,6,6-二甲基-8-甲基壬烷(购自Permethyl Corporation)。
聚烯烃的实例包括乙烯、丙烯、1-丁烯、1-戊烯、1-己烯、1-辛烯、1-癸烯、1-十二碳烯、1-十四烯、支链异构体如4-甲基-1-戊烯,以及它们的混合物。优选的氢化α-烯烃单体包括但不限于1-己烯至1-十六碳烯、1-辛烯至1-十四烯,以及它们的混合物。
脂肪酯的实例包括但不限于:脂族链含有10-22个碳原子的脂肪酸烷基酯,如异硬脂酸异丙酯、月桂酸己酯、月桂酸异己酯、十六烷酸异己酯、十六烷酸异丙酯、油酸癸酯、油酸异癸酯、硬脂酸十六烷基酯、硬脂酸癸酯、异硬脂酸异丙酯、己二酸二己基癸酯、乳酸月桂酯、乳酸十四烷酯、乳酸鲸蜡酯、硬脂酸油基酯、油酸油基酯、十四烷酸油基酯、乙酸月桂酯、丙酸鲸蜡酯和己二酸油基酯;单羧酸酯,如肉豆蔻酸异丙酯、硬脂酸乙二醇酯和月桂酸异丙酯;羧酸的二烷基酯和三烷基酯,如硬脂酰基硬脂酸异十六烷基酯、己二酸二异丙酯和柠檬酸三硬脂醇酯;其他脂族酯,如包括甘油一酯、甘油二酯和甘油三酯。
上述添加剂均为市售可得的。
此外,本发明的表面活性剂组合物中包含的其他添加剂的种类和含量可以根据清洁剂领域中的为实现的功能确定,在此不再赘述。
本发明的表面活性剂组合物中如包含添加剂,则添加剂的重量基于本发明的组合物的量为100重量%计。
下面通过以下实施例更详细地说明本发明。应理解,以下实施例仅在于说明本发明,而非对本发明范围的限制。
实施例
原料
椰油酰胺基丙基甜菜碱,CAB-35,两性表面活性剂,固含量为35重量%,购自Rhodia,分散体。
氯咪巴唑,活性化合物,无水白色粉末,活性物含量为98重量%,购自LKTLaboratories,Inc.。
十二烷基聚氧乙烯醚硫酸钠,ROKER SLES-70,分散体,固含量为70重量%,购自诺可(上海)化工有限公司。
十二烷基硫酸钠,无水白色粉末,购自Aladdin(阿拉丁)公司。
硅氧烷,PMX200,购自DOW CORNING(道康宁)公司。
表面活性剂组合物
表1列出了本发明实施例的表面活性剂组合物和对比实施例的表面活性剂组合物的组成和含量,其中的含量均为重量%,基于表面活性剂组合物为100重量%计。
表1本发明实施例的表面活性剂组合物和对比实施例的表面活性剂组合物的组成和含量
*呈分散体形式,所列重量为分散体中固形物的重量。
性能测试
1.沉积率测定
将表1所列的本发明实施例的表面活性剂组合物和对比实施例的表面活性剂组合物使用于经过清水冲洗30秒的头发,每个发束使用2g/次,并揉搓25次,然后用清水冲洗头发30秒。室温下干燥后,将头发置于甲醇(40ml)中浸泡10秒钟,以溶解氯咪巴唑。随后,用紫外超声仪(08891-26,购自Cole-Parmer)处理溶解有氯咪巴唑的甲醇。用紫外分光光度计(NanoDrop Lite,购自ThermoFisher Scientific)测量氯咪巴唑的残留率,氯咪巴唑的特征峰位于223nm,测得的峰高数值A*6*40即为该发束上残留的氯咪巴唑含量,沉积率=发束上残留的氯咪巴唑含量/使用的洗发水含量。结果示于表2。
2.弯曲度测试
分别使用表1所列的本发明实施例的表面活性剂组合物和对比实施例的表面活性剂组合物清洗头发5分钟,并用卷棒使头发卷曲,然后使卷曲的于室温下头发干燥过夜,用肉眼观察头发的弯曲程度,观察的状态如图1所示,其结果示于表2。
本发明实施例的表面活性剂组合物的沉积率与对比实施例的表面活性剂组合物的沉积率相比有明显的提高。表面活性剂组合物的沉积率越高,表面活性剂组合物在头发上的残留越多,组合物在头发上的使用效果越好,在本发明的一个实施例中表现为头发的弯曲程度保持的更好。
表2弯曲度和沉积率的测试结果
肉眼观察的弯曲度 | 沉积率 | |
本发明1 | 弯曲 | 高34.25% |
本发明2 | 弯曲 | 高36.47% |
本发明3 | 弯曲 | 高31.12% |
本发明4 | 弯曲 | 高40.59% |
本发明5 | 弯曲 | 高45.18% |
对比1 | 不弯曲 | 低25.31% |
对比2 | 不弯曲 | 低24.38% |
3.阴离子聚合物对活性物质的固定作用
分别将10克本发明实施例3的表面活性剂组合物和对比实施例2的表面活性剂组合物使用于头发上并涂抹均匀。室温下干燥后,用摇动设备(IKA WERKE Digital Mixer)模拟头发的自然甩动,将氯咪巴唑用圆圈标记,将摇动前后的头发称重,结果如图2所示。
使用本发明实施例3的表面活性剂组合物的头发摇动前后质量差小于使用对比实施例2的表面活性剂组合物的头发摇动前后质量差,由此表明,本发明实施例3的表面活性剂组合物在头发上的沉积效果好于对比实施例2的表面活性剂组合物。使用本发明实施例3的表面活性剂组合物的头发在摇动后,残留的氯咪巴唑明显多于使用对比实施例2的表面活性剂组合物的头发。
Claims (6)
1.一种清洁剂,由一表面活性剂组合物制成,所述表面活性剂组合物包含:阴离子聚合物、两性表面活性剂和阴离子表面活性剂,其中阴离子聚合物与两性表面活性剂的重量比为1∶15-15∶1,所述阴离子聚合物是包含至少一个磺酸盐基团的聚氨酯阴离子聚合物;所述阴离子表面活性剂的量为0.1-30重量%,基于组合物为100重量%计;所述两性表面活性剂是下列的一种或多种:烷基甜菜碱、烷基氨基丙基甜菜碱和烷基磺基甜菜碱,其中,烷基具有8-19个碳原子;所述阴离子表面活性剂是下列的一种或多种:由ROSO3M表示的烷基硫酸盐和由RO(C2H4O)xSO3M表示的烷基醚硫酸盐,其中,R为含有8-18个碳原子的烷基或链烯基,x为1-10的整数,M为阳离子;所述包含至少一个磺酸盐基团的聚氨酯阴离子聚合物选自C1000、C1001、C1004和C1008中的一种或多种;所述两性表面活性剂选自椰油二甲基磺基丙基甜菜碱、十二烷甜菜碱和椰油酰胺基丙基甜菜碱中的一种或多种。
2.根据权利要求1所述的清洁剂,其中所述清洁剂为洗发水。
3.根据权利要求1所述的清洁剂,其中,阴离子聚合物的量为至少0.2重量%,基于组合物为100重量%计。
4.根据权利要求1-3任一项所述的清洁剂,其中,两性表面活性剂的量为1-20重量%,基于组合物为100重量%计。
5.根据权利要求1所述的清洁剂,其中,还包含活性成分,其量为0.1-5重量%,基于组合物为100重量%计。
6.根据权利要求5所述的清洁剂,其中,活性成分选自羟甲辛吡酮、氯咪巴唑和酮康唑中的一种或多种。
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