CN107119472A - Pretreating process before yarn dyeing - Google Patents
Pretreating process before yarn dyeing Download PDFInfo
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- CN107119472A CN107119472A CN201710482116.7A CN201710482116A CN107119472A CN 107119472 A CN107119472 A CN 107119472A CN 201710482116 A CN201710482116 A CN 201710482116A CN 107119472 A CN107119472 A CN 107119472A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/13—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
Abstract
The present invention relates to the pretreating process before a kind of yarn dyeing, comprise the following steps：(1) yarn is taken, chelated dispersants, refining agent, alkali, graft modification agent and water, stirring mixing is added；Wherein, the graft modification agent is quaternary ammonium salt polymer composite, and consumption is the 2%~5% of the yarn weight；(2) bleaching agent is added, 70 DEG C~90 DEG C are warming up to, 30min~60min is incubated；(3) clean, you can.Pretreating process before the yarn dyeing of the present invention, by using specific graft modification agent and with reference to specific pretreating process, can be under relatively low temperature conditionss, it is synchronous that dye and bleaching pretreatment are carried out to yarn, the dye-uptake and glossiness of yarn are improved, and color fastness is good, power consumption is few, environment-friendly, cost is low.
Description
Technical field
The present invention relates to field of textiles, the pretreating process before more particularly to a kind of yarn dyeing.
Background technology
With industrial expansion, environmental problem is increasingly severe, and energy-saving and environmental protection, cost-effective technique are increasingly obtained
The favor of the producer.
In field of textiles, yarn is before pulp before being dyed, it is necessary to pre-processed, it is main such as bleaching, it is concise, with
Improve the glossiness of yarn.And conventional pretreatment technique need to use higher temperature (generally 105~110 DEG C) and pretreatment
Dye-uptake is poor afterwards, causes follow-up yarn dyeing step to waste more dyestuff, and higher temperature consumes energy, unnecessary dyestuff
Processing to sewage also brings burden.
At present, to increase the dye-uptake of yarn, some cation-modified methods can be used, although this method can be in dyeing
It is helpful in depth, but the fastness after dyeing, especially dry fastness and fastness to wet rubbing, and do not improve can be reduced
The problem of pre-treatment step high temperature consumes energy.In addition, cation-modified step and remaining pre-treatment step of yarn are in view of technique bar
The difference of part, to avoid the influence to treatment effect, is generally carried out separately, i.e., first carry out it is cation-modified after, dry yarn
Line, then carry out remaining pre-treatment step.The time is so not only wasted, source chemicals, water, energy etc. is also further wasted,
Increase production cost.
The content of the invention
Based on this, it is necessary to which providing one kind can be while carries out a variety of yarn pretreatments, and raising yarn dye-uptake, color are firm
The qualities such as degree, glossiness, and power consumption is few, the pretreating process before the low yarn dyeing of cost.
A kind of pretreating process before yarn dyeing, comprises the following steps：
(1) yarn is taken, chelated dispersants, refining agent, alkali, graft modification agent and water, stirring mixing is added；Wherein, it is described
Graft modification agent is quaternary ammonium salt polymer composite, and consumption is the 2%~5% of the yarn weight；
(2) bleaching agent is added, 70 DEG C~90 DEG C are warming up to, 30min~60min is incubated；
(3) clean, you can.
Pretreating process before the yarn dyeing of the present invention：
First, graft modification technique is added before dyeing：Table is carried out to yarn using the specific graft modification agent
Face handle, in yarn fibers, add colouring functional group, allow yarn can more effectively in follow-up dyeing course with dyestuff
Molecule is combined, reaction, is improved dye-uptake, is reduced the waste of dyestuff, and the color fastness of yarn can be also obviously improved；Meanwhile, because
Preferably to adsorb dyestuff by the yarn after above-mentioned graft modification, so needed for during follow-up yarn dyeing can be reduced
Raw material dosage, such as glauber salt, soda ash, have both saved cost, and environmentally friendly.
Secondly, the pretreatment such as modification and bleaching of yarn is carried out with process：By substantial amounts of experimental exploring, by reasonable
The temperature and time of pretreating process is controlled, being modified to yarn for the graft modification agent used can be promoted, is contaminated in raising
While rate, additionally it is possible to the synchronous bleaching for carrying out yarn, and dye and the effect of bleaching in guarantee, pretreatment institute has been saved again
The time of cost and source chemicals.And compared with traditional handicraft, pretreating process temperature is reduced 15~40 DEG C by the present invention,
Pretreatment can be completed at 70~90 DEG C, energy consumption is reduced.
Again, the alkali and bleaching agent needed for bleaching are added separately to, it is to avoid high concentration directly mixing causes bleaching
The possibility that agent is decomposed, further optimizes the bleaching effect to yarn.
To sum up, the pretreating process before yarn dyeing of the invention, by using specific graft modification agent and combination spy
Fixed pretreating process, can be synchronous that dye and bleaching pretreatment are carried out to yarn under relatively low temperature conditionss, improves yarn
Dye-uptake and glossiness, and color fastness is good, and power consumption is few, and environment-friendly, cost is low, and technological operation is simple, both can be in intelligence
Chemical plant is applied, and manually operated can also be carried out.
In one of the embodiments, in step (1), the molecular weight of the graft modification agent is 7000~10000.
In one of the embodiments, in step (2), 70 DEG C~80 DEG C are warming up to, 40~60min is incubated.
In one of the embodiments, in step (2), the speed of the heating is 1~3 DEG C/min.
Heated up, can preferably be controlled in graft modification agent and the combination of yarn, optimization with specific heating rate
The uniformity of dye, while ensureing the abundant activation of bleaching agent, improves its bleachability.
In one of the embodiments, in step (2), the bleaching agent includes hydrogen peroxide and Activation of Hydrogen Peroxide Solution agent；Institute
State in water, the concentration of the hydrogen peroxide is 1~3g/L；The consumption of the Activation of Hydrogen Peroxide Solution agent is 0.8~3g/L.Made with hydrogen peroxide
For main bleaching agent, and coordinate using Activation of Hydrogen Peroxide Solution agent, can be further ensured that under the conditions of relatively low pretreatment temperature, hydrogen peroxide
Advantageous bleachability is maintained to, the requirement of glossiness is provided for follow-up Color.
In one of the embodiments, the Activation of Hydrogen Peroxide Solution agent is anionic activator.
In one of the embodiments, by weight percentage, the Activation of Hydrogen Peroxide Solution agent includes：Epoxyethane derivative
Polymer 1~10%, sodium salt 1~5%, surplus is water.
In one of the embodiments, in step (3), the cleaning step is：First add aqueous acetic acid cleaning 5min
~15min；Add washing 2~3 times, each 5min~15min；In the aqueous acetic acid concentration of acetic acid be 0.5g/L~
1g/L。
In one of the embodiments, in step (1), the yarn of the pretreatment and the mass ratio of water are 1：5~1：20；
In the water, the concentration of the chelated dispersants is 0.5~1.5g/L；The concentration of refining agent is 0.5~1.5g/L；The alkali
For sodium hydroxide (caustic soda), concentration is 1~5g/L.
In one of the embodiments, the chelated dispersants are methylene condensation polymer.
In one of the embodiments, the refining agent is morpholine type amido silicon oil.
In one of the embodiments, the material of the yarn is pure cotton.Above-mentioned pretreating process is particularly suitable for use in pure cotton
The pretreatment of yarn.
The present invention also provides a kind of dyeing of yarn, comprises the following steps：
Yarn is pre-processed according to described pretreating process；
Dyestuff and dyeing assistant, water are added in pretreated yarn, is dyed, you can.
Above-mentioned dyeing, high to the dye-uptake of yarn by using specific pretreating process, the yarn color after dyeing
Fastness and glossiness are good, and process energy consumption is few, environment-friendly, and cost is low.
In one of the embodiments, in addition to post-processing step：Carry out after the dyeing, under the conditions of 90~110 DEG C
Soaped, fixation is then carried out under the conditions of 50~60 DEG C.
In one of the embodiments, carry out after the pretreatment, prior to adding water and deoxyenzyme, mixing in the yarn
Waste water after 1~10min, then processing of draining, then carries out the dyeing again.
In one of the embodiments, the dyeing assistant includes sodium sulphate (glauber salt) and sodium carbonate (soda ash).
The present invention also provides the yarn that the dyeing is prepared.
Brief description of the drawings
Fig. 1 is that step (1)-(3) in the embodiment of the present invention 1 add the process chart that reagent is pre-processed；
The process chart that Fig. 2 cleans for the step (4) in the embodiment of the present invention 1.
Embodiment
The pretreating process before the yarn dyeing of the present invention is described in further detail below in conjunction with specific embodiment.
Chelated dispersants described in the embodiment of the present invention are methylene condensation polymer, and specially purchased from opening up, to receive trade (Shanghai) limited
The chelated dispersants AVOLAN IS of company.
The refining agent is morpholine type amido silicon oil, specially purchased from the KF-110 of Hangzhou Ke Feng Chemical Co., Ltd.s.
The graft modification agent is quaternary ammonium salt polymer composite, and molecular weight is 7000~10000, non-/ cationic,
Yellow liquid, 125 DEG C of boiling point ＞, pH6~8 (1% aqueous solution)；Specially it is purchased from the mordant dyeing body DB of Yuan Na Chemical Co., Ltd.s.
The Activation of Hydrogen Peroxide Solution agent is anionic activator, is the mixture of inorganic matter and organic matter, with weight percent
Than meter, including：Epoxyethane derivative polymer 1~10%, sodium salt 1~5%, surplus is water；Viscosity (dynamic) ＜
50mPa.s, 100 DEG C of boiling point, (20 DEG C) of pH6~8 are specially the Prestogen LTB liq purchased from Ang Gao Chemical Co., Ltd.s.
Embodiment 1
Pretreating process and colouring method before the present embodiment yarn dyeing, comprise the following steps that (process chart is as schemed
Shown in 1-2)：
(1) by the traditional thread binding cage of Quality Pure Cotton Yarn Production, it is placed in dye vat, adds chelated dispersants AVOLAN IS, refining agent KF-110, burns
Alkali, graft modification agent mordant dyeing body DB, water, turn on pump are run 2~3 minutes；
Wherein, graft modification agent mordant dyeing body DB consumptions are the 3% of the yarn weight；The mass ratio of yarn and water is 1：
11；Chelated dispersants AVOLAN IS concentration is 0.8g/L；Refining agent KF-110 concentration is 0.8g/L；The concentration of caustic soda is
2g/L；
(2) hydrogen peroxide (27.5%) and Activation of Hydrogen Peroxide Solution agent Prestogen LTB liq, in water, hydrogen peroxide are added
(27.5%) concentration is 4.5g/L；The consumption of Activation of Hydrogen Peroxide Solution agent is 1.5g/L；
(3) 80 DEG C are warming up to 2 DEG C/min of heating rate, are incubated 30 minutes, liquid in discharge dye vat washes 2 with clear water
It is secondary, continue 3 minutes every time；
(4) 1 time is washed with aqueous acetic acid, 5 minutes, clear water washed 2 times, 10 minutes every time, water or aqueous acetic acid used
Consumption is yarn weight：Water or aqueous acetic acid weight=1：8, the concentration of acetic acid is 0.8g/L in the aqueous acetic acid；
(5) deoxyenzyme is added, after adding water running 5 minutes, is drained；
(6) dyed according to standard recipe, dyestuff total concentration is 5%, glauber salt consumption 90g/L；Soda ash consumption is 20g/L；
(7) soaped according to common process in 105 DEG C, 55 DEG C of fixation.
(8) sampling gives colorist to color, gives physical testing portion testing friction fastness after dehydration, drying.
The step of the present embodiment (1)~(4) are the pretreating process before yarn dyeing, and step (5)~(8) are follow-up dye
Color and post-processing step.
Embodiment 2
Pretreating process and colouring method before the present embodiment yarn dyeing, comprise the following steps：
(1) by the traditional thread binding cage of Quality Pure Cotton Yarn Production, it is placed in dye vat, adds chelated dispersants AVOLAN IS, refining agent KF-110, burns
Alkali, graft modification agent mordant dyeing body DB, water, turn on pump are run 2~3 minutes；
Wherein, graft modification agent mordant dyeing body DB consumptions are the 2% of the yarn weight；The mass ratio of yarn and water is 1：5；
Chelated dispersants AVOLAN IS concentration is 1.0g/L；Refining agent KF-110 concentration is 1.0g/L；The concentration of caustic soda is 2g/
L；
(2) hydrogen peroxide (27.5%) and Activation of Hydrogen Peroxide Solution agent Prestogen LTB liq, in water, hydrogen peroxide are added
(27.5%) concentration is 8g/L；The consumption of Activation of Hydrogen Peroxide Solution agent is 3g/L；
(3) 70 DEG C are warming up to 3 DEG C/min of heating rate, are incubated 60 minutes, liquid in discharge dye vat washes 2 with clear water
It is secondary, continue 3 minutes every time；
(4) 1 time is washed with aqueous acetic acid, 5 minutes, clear water washed 2 times, 15 minutes every time, water or aqueous acetic acid used
Consumption is yarn weight：Water or aqueous acetic acid weight=1：8, the concentration of acetic acid is 1g/L in the aqueous acetic acid；
(5) deoxyenzyme is added, after adding water running 5 minutes, is drained；
(6) dyed according to standard recipe, dyestuff total concentration is 5%, glauber salt consumption 90g/L；Soda ash consumption is 20g/L；
(7) soaped according to common process in 105 DEG C, 55 DEG C of fixation.
(8) sampling gives colorist to color, gives physical testing portion testing friction fastness after dehydration, drying.
The step of the present embodiment (1)~(4) are the pretreating process before yarn dyeing, and step (5)~(8) are follow-up dye
Color and post-processing step.
Embodiment 3
Pretreating process and colouring method before the present embodiment yarn dyeing, comprise the following steps：
(1) by the traditional thread binding cage of Quality Pure Cotton Yarn Production, it is placed in dye vat, adds chelated dispersants AVOLAN IS, refining agent KF-110, burns
Alkali, graft modification agent mordant dyeing body DB, water, turn on pump are run 2 minutes；
Wherein, graft modification agent mordant dyeing body DB consumptions are the 5% of the yarn weight；The mass ratio of yarn and water is 1：
20；Chelated dispersants AVOLAN IS concentration is 0.7g/L；Refining agent KF-110 concentration is 0.7g/L；The concentration of caustic soda is
2g/L；
(2) hydrogen peroxide (27.5%) and Activation of Hydrogen Peroxide Solution agent Prestogen LTB liq, in water, hydrogen peroxide are added
(27.5%) concentration is 5g/L；The consumption of Activation of Hydrogen Peroxide Solution agent is 0.8g/L；
(3) 90 DEG C are warming up to 2 DEG C/min of heating rate, are incubated 30 minutes, liquid in discharge dye vat washes 2 with clear water
It is secondary, continue 3 minutes every time；
(4) 1 time is washed with aqueous acetic acid, 5 minutes, clear water washed 2 times, 15 minutes every time, water or aqueous acetic acid used
Consumption is yarn weight：Water or aqueous acetic acid weight=1：8, the concentration of acetic acid is 1g/L in the aqueous acetic acid；
(5) deoxyenzyme is added, after adding water running 5 minutes, is drained；
(6) dyed according to standard recipe, dyestuff total concentration is 5%, glauber salt consumption 90g/L；Soda ash consumption is 20g/L；
(7) soaped according to common process in 105 DEG C, 55 DEG C of fixation.
(8) sampling gives colorist to color, gives physical testing portion testing friction fastness after dehydration, drying.
The step of the present embodiment (1)~(4) are the pretreating process before yarn dyeing, and step (5)~(8) are follow-up dye
Color and post-processing step.
Comparative example 1
This comparative example is the high temperature pretreating process and colouring method before yarn dyeing, is comprised the following steps：
(1) by the traditional thread binding cage of Quality Pure Cotton Yarn Production, it is placed in dye vat, adds chelated dispersants AVOLAN IS, refining agent KF-110, burns
Alkali, water, turn on pump are run 2 minutes；
Wherein, the quality of yarn and water is 1：11；Chelated dispersants AVOLAN IS concentration is 0.8g/L；Refining agent KF-
110 concentration is 0.8g/L；The concentration of caustic soda is 1.5g/L；
(2) hydrogen peroxide (27.5%) is added, concentration is 4.5g/L.
(3) 110 DEG C are warming up to 2 DEG C/min of heating rate, are incubated 30 minutes, liquid in discharge dye vat is washed with clear water
2 times, continue 3 minutes every time；
(4) 1 time is washed with aqueous acetic acid, 5 minutes, clear water washed 2 times, 10 minutes every time, water or aqueous acetic acid used
Consumption is yarn weight：Water or aqueous acetic acid weight=1：8, the concentration of acetic acid is 1g/L in the aqueous acetic acid；
(5) deoxyenzyme is added, after adding water running 5 minutes, is drained；
(6) dyed according to standard recipe, dyestuff total concentration is 5%, glauber salt consumption 90g/L；Soda ash consumption is 20g/L；
(7) soaped according to common process in 105 DEG C, 55 DEG C of fixation.
(8) sampling gives colorist to color, gives physical testing portion testing friction fastness after dehydration, drying.
Comparative example 2
Pretreating process and colouring method before a kind of yarn dyeing of this comparative example, its raw material used reality similar with technique
Example 2 is applied, difference is：In step (3), 60 DEG C are warming up to, 90min is incubated.
Comparative example 3
Pretreating process and colouring method before a kind of yarn dyeing of this comparative example, its raw material used reality similar with technique
Example 3 is applied, difference is：
1st, the graft modification agent is replaced with cation modifier CR2000.
2nd, cation-modified step and pre-treatment step are separately carried out, and first carry out the pre-treatment step of yarn, then carry out sun
Ion modification step.
Concretely comprise the following steps：
(1) by the traditional thread binding cage of Quality Pure Cotton Yarn Production, it is placed in dye vat, adds chelated dispersants AVOLAN IS, refining agent KF-110, burns
Alkali, water, turn on pump are run 2 minutes；
Wherein, the mass ratio of yarn and water is 1：20；Chelated dispersants AVOLAN IS concentration is 0.7g/L；Refining agent
KF-110 concentration is 0.7g/L；The concentration of caustic soda is 2g/L；
(2) concentration for adding hydrogen peroxide (27.5%) hydrogen peroxide (27.5%) is 5g/L；
(3) 90 DEG C are warming up to 2 DEG C/min of heating rate, are incubated 30 minutes, liquid in discharge dye vat washes 2 with clear water
It is secondary, continue 3 minutes every time；
(4) cation modifier and water are added, the concentration of cation modifier is 20g/L, and turn on pump is run 2 minutes.
(5) caustic soda is added, the concentration of caustic soda is 8g/L；
(6) 90 DEG C are warming up to 2 DEG C/min of heating rate, are incubated 30 minutes, liquid in discharge dye vat washes 2 with clear water
It is secondary, continue 3 minutes every time；
(7) 1 time is washed with aqueous acetic acid, 5 minutes, clear water washed 2 times, 15 minutes every time, water or aqueous acetic acid used
Consumption is yarn weight：Water or aqueous acetic acid weight=1：8, the concentration of acetic acid is 1g/L in the aqueous acetic acid；
(8) deoxyenzyme is added, after adding water running 5 minutes, is drained；
(9) dyed according to standard recipe, dyestuff total concentration is 5%, glauber salt consumption 90g/L；Soda ash consumption is 20g/L；
(10) soaped according to common process in 105 DEG C, 55 DEG C of fixation.
(11) sampling gives colorist to color, gives physical testing portion testing friction fastness after dehydration, drying.
Yarn made from embodiment 1-3 and comparative example 1-2 technique is tested, as a result as shown in table 1：
Table 1
Note：Detect used in dye level to color instrument model Ai Seli X-Write CE7000A.
For the explanation of color depth：Color depth L* values are not directly proportional to dye-uptake, and its numerical value is smaller, color depth
It is deeper.The L* of navy blue color can be approximately considered L* values difference 1.0, dye-uptake difference 10~30% near 20.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality
Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, the scope of this specification record is all considered to be.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed, but simultaneously
Can not therefore it be construed as limiting the scope of the patent.It should be pointed out that coming for one of ordinary skill in the art
Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (10)
1. the pretreating process before a kind of yarn dyeing, it is characterised in that comprise the following steps：
(1) yarn is taken, chelated dispersants, refining agent, alkali, graft modification agent and water, stirring mixing is added；Wherein, the grafting
Modifying agent is quaternary ammonium salt polymer composite, and consumption is the 2%~5% of the yarn weight；
(2) bleaching agent is added, 70 DEG C~90 DEG C are warming up to, 30min~60min is incubated；
(3) clean, you can.
2. the pretreating process before yarn dyeing according to claim 1, it is characterised in that in step (1), the grafting
Modifying agent is quaternary ammonium salt polymer composite, and molecular weight is 7000~10000.
3. the pretreating process before yarn dyeing according to claim 1, it is characterised in that in step (2), be warming up to 70
DEG C~80 DEG C, it is incubated 30~60min.
4. the pretreating process before yarn dyeing according to claim 3, it is characterised in that in step (2), the heating
Speed be 1~3 DEG C/min.
5. the pretreating process before yarn dyeing according to claim 1, it is characterised in that in step (2), the bleaching
Agent includes hydrogen peroxide and Activation of Hydrogen Peroxide Solution agent；In the water, the concentration of the hydrogen peroxide is 1~3g/L；The hydrogen peroxide is lived
The consumption of agent is 0.8~3g/L.
6. the pretreating process before yarn dyeing according to claim 5, it is characterised in that the Activation of Hydrogen Peroxide Solution agent is
Anionic activator.
7. the pretreating process before yarn dyeing according to claim any one of 1-6, it is characterised in that in step (3),
The step of cleaning is：First add aqueous acetic acid cleaning 5min~15min；Add washing 2~3 times, each 5min~
15min；The concentration of acetic acid is 0.5g/L~1g/L in the aqueous acetic acid.
8. the pretreating process before yarn dyeing according to claim any one of 1-6, it is characterised in that in step (1),
The yarn of the pretreatment and the mass ratio of water are 1：5~1：20；In the water, the concentration of the chelated dispersants is 0.5
~1.5g/L；The concentration of refining agent is 0.5~1.5g/L；The alkali is sodium hydroxide, and concentration is 1~5g/L.
9. a kind of dyeing of yarn, it is characterised in that comprise the following steps：
Yarn is pre-processed according to the pretreating process described in claim any one of 1-8；
Dyestuff and dyeing assistant, water are added in pretreated yarn, is dyed, you can.
10. the yarn that dyeing described in claim 9 is prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710482116.7A CN107119472B (en) | 2017-06-22 | 2017-06-22 | Pretreating process before yarn dyeing |
Applications Claiming Priority (1)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108755188A (en) * | 2018-05-29 | 2018-11-06 | 广东溢达纺织有限公司 | Preprocess method, colouring method and flax dyed yarn before linen thread and yarn dyeing |
| CN109750505A (en) * | 2017-11-06 | 2019-05-14 | 宁波侨泰兴纺织有限公司 | A kind of pretreating process before yarn dyeing |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1936148A (en) * | 2006-10-18 | 2007-03-28 | 江南大学 | Fabric coating dyeing process |
| CN1950062A (en) * | 2004-04-30 | 2007-04-18 | 宝洁公司 | Process and kit-of-parts for improved hair conditioning after coloring, bleaching or perming |
| CN101403185A (en) * | 2008-11-10 | 2009-04-08 | 浙江嘉欣丝绸股份有限公司 | Fabric graft modified full-fixation printing method |
| CN102286880A (en) * | 2010-12-16 | 2011-12-21 | 宁波维科精华浙东针织有限公司 | Knitted fabric dyeing pretreatment method |
-
2017
- 2017-06-22 CN CN201710482116.7A patent/CN107119472B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1950062A (en) * | 2004-04-30 | 2007-04-18 | 宝洁公司 | Process and kit-of-parts for improved hair conditioning after coloring, bleaching or perming |
| CN1936148A (en) * | 2006-10-18 | 2007-03-28 | 江南大学 | Fabric coating dyeing process |
| CN101403185A (en) * | 2008-11-10 | 2009-04-08 | 浙江嘉欣丝绸股份有限公司 | Fabric graft modified full-fixation printing method |
| CN102286880A (en) * | 2010-12-16 | 2011-12-21 | 宁波维科精华浙东针织有限公司 | Knitted fabric dyeing pretreatment method |
Non-Patent Citations (1)
| Title |
|---|
| 房宽峻主编: "《染料应用手册》", 31 July 2013, 中国纺织出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109750505A (en) * | 2017-11-06 | 2019-05-14 | 宁波侨泰兴纺织有限公司 | A kind of pretreating process before yarn dyeing |
| CN108755188A (en) * | 2018-05-29 | 2018-11-06 | 广东溢达纺织有限公司 | Preprocess method, colouring method and flax dyed yarn before linen thread and yarn dyeing |
| CN108755188B (en) * | 2018-05-29 | 2020-11-20 | 广东溢达纺织有限公司 | Pretreatment method before dyeing of linen yarn, dyeing method and linen yarn |
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