CN103343460A - Ecological knitting color strip fabric dyeing method with positive ion modifier - Google Patents
Ecological knitting color strip fabric dyeing method with positive ion modifier Download PDFInfo
- Publication number
- CN103343460A CN103343460A CN2013103151831A CN201310315183A CN103343460A CN 103343460 A CN103343460 A CN 103343460A CN 2013103151831 A CN2013103151831 A CN 2013103151831A CN 201310315183 A CN201310315183 A CN 201310315183A CN 103343460 A CN103343460 A CN 103343460A
- Authority
- CN
- China
- Prior art keywords
- knitting
- dyeing
- fabric
- dye
- colour bar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Abstract
The invention discloses an ecological knitting color strip fabric dyeing method with a positive ion modifier. The method comprises the steps of: dyeing a knitting color strip fabric, which is modified by the positive ion modifier Fix-600, in dye liquor, wherein the dye liquor is reactive red 3BS dye, the dye usage is 6%o.w.f, and the bath ratio is 1:10; and after the fabric is dyed at 40-80 DEG C for 0-120min, adding 0-25g/L Na2CO3 for color fixation, warming the fabric at 40-80 DEG C for 10min-50min, and washing, soaping and washing again after the dyeing is ended. The method is easy to operate, and a good dyeing effect is achieved; the color fastness to washing of modified cotton fibers is approximately same with that of common cotton fibers and reaches a 4-5 level; the color fastness to rubbing of the modified cotton fibers is improved by 0.5-1 level than that of the comment cotton fibers.
Description
Technical field
The present invention relates to a kind of knitting colour bar fabric ecological dyeing method of cation modifier.
Background technology
Conventional knitting colour bar dyeing fabric method is polluted greatly, the method complexity, and Color is undesirable, requires further improvement.
Summary of the invention
The object of the present invention is to provide a kind of easy to operate, the knitting colour bar fabric ecological dyeing method of the cation modifier that Color is good.
Technical solution of the present invention is:
A kind of knitting colour bar fabric ecological dyeing method of cation modifier, it is characterized in that: comprise the following steps: that the knitting colour bar fabric of handling through cation modifier Fix-600 modification is put into dye liquor to dye, dyestuff is reactive red 3BS dyestuff, dye dosage 6%o.w.f., bath raio 1:10; Fabric behind dyeing 0～120min, adds 0～25g/LNa under 40～80 ℃
2CO
3Carry out fixation treatment, continue insulation 10～50min down at 40～80 ℃, dyeing finishes after washing, soaps, washes.
Dyeing time is 30min, on to dye temperature be 60 ℃, color fixing temperature is 60 ℃, the fixation time is 20～30min.
The knitting colour bar fabric that described cation modifier Fix-600 modification is handled, its modification processing method is: knitting colour bar fabric is put into modification liquid handled 50 minutes.Treatment temperature is 60 ℃; Described modification liquid is made up of following ingredients:
Modifier Fix-600 6～8%o.w.f.
NaOH 6～8g/L
Water surplus.
The present invention is easy to operate, and Color is good, and water-fastness COLOR FASTNESS and the conventional cotton fiber of modified cotton fiber are roughly the same, all is the 4-5 level.Though anti-dry friction COLOR FASTNESS has improved the 0.5-1 level than conventional cotton fiber.
The invention will be further described below in conjunction with drawings and Examples.
Fig. 1 dyes the relation curve schematic diagram of time and dye-uptake on being.
Fig. 2 dyes the relation curve schematic diagram of temperature and dye-uptake on being.
The specific embodiment
A kind of knitting colour bar fabric ecological dyeing method of cation modifier, it is characterized in that: comprise the following steps: that the knitting colour bar fabric of handling through cation modifier Fix-600 modification is put into dye liquor to dye, dyestuff is reactive red 3BS dyestuff, dye dosage 6%o.w.f., bath raio 1:10; Fabric behind dyeing 0～120min, adds 0～25g/LNa under 40～80 ℃
2CO
3Carry out fixation treatment, continue insulation 10～50min down at 40～80 ℃, dyeing finishes after washing, soaps, washes.
Dyeing time is 30min, on to dye temperature be 60 ℃, color fixing temperature is 60 ℃, the fixation time is 20～30min.
The knitting colour bar fabric that described cation modifier Fix-600 modification is handled, its modification processing method is: knitting colour bar fabric is put into modification liquid handled 50 minutes.Treatment temperature is 60 ℃; Described modification liquid is made up of following ingredients:
Modifier Fix-600 6～8%o.w.f.
NaOH 6～8g/L
Water surplus.
The relation of color fixing temperature and degree of fixation
The relation of table 1 color fixing temperature and degree of fixation
60 ℃ of color fixing temperature location
The relation of fixation time and degree of fixation
The relation of table 2 fixation time and degree of fixation
The fixation time fixes on 20～30min
Modification of and coloration is to the influence of dyefastness
Table 3 dyefastness
Water-fastness COLOR FASTNESS and the conventional cotton fiber of modified cotton fiber are roughly the same, all are the 4-5 level.Though anti-dry friction COLOR FASTNESS has improved the 0.5-1 level than conventional cotton fiber.
The synthesis mechanism of cation modifier Fix-600:
The chloropropylene oxide of molecule chain end forms epoxy radicals under alkali condition, epoxy radicals under alkali condition also can with cellulose fibre in hydroxyl react:
Thermodynamic study to modified cotton fiber shows that dying modified cotton fiber on the REACTIVE DYES belongs to the absorption of Langmiur type location.Wherein, the △ S of reactive red 3BS
0For-54.733JK
-1Mol
-1, △ H
0For-23.873kJmol
-1The △ S of reactive yellow 3BS
0For-75.4JK
-1Mol
-1, △ H
0For-34.999kJmol
-1The △ S of reactive blue KN-B
0For-182.7JK
-1Mol
-1, △ H
0For-74.202kJmol
-1
Cation-modified cotton fiber under salt-free condition, obtains higher dye-uptake and degree of fixation, improves the utilization rate of dyestuff, and the content of inorganic anion and colourity is realized the REACTIVE DYES ecological dyeing in the minimizing sewage.
Cation modifier Fix-600 can obtain (Nantong Si Ente textile technology Co., Ltd product) by the open approach in market.
Claims (3)
1. the knitting colour bar fabric ecological dyeing method of a cation modifier, it is characterized in that: comprise the following steps: that the knitting colour bar fabric of handling through cation modifier Fix-600 modification is put into dye liquor to dye, dyestuff is reactive red 3BS dyestuff, dye dosage 6% o.w.f., bath raio 1:10; Fabric behind dyeing 0～120min, adds 0～25g/L Na under 40～80 ℃
2CO
3Carry out fixation treatment, continue insulation 10～50min down at 40～80 ℃, dyeing finishes after washing, soaps, washes.
2. the knitting colour bar fabric ecological dyeing method of cation modifier according to claim 1, it is characterized in that: dyeing time is 30min, on to dye temperature be 60 ℃, color fixing temperature is 60 ℃, the fixation time is 20～30min.
3. the knitting colour bar fabric ecological dyeing method of cation modifier according to claim 1 and 2, it is characterized in that: the knitting colour bar fabric that described cation modifier Fix-600 modification is handled, its modification processing method is: knitting colour bar fabric is put into modification liquid handled 50 minutes.Treatment temperature is 60 ℃; Described modification liquid is made up of following ingredients:
Modifier Fix-600 6～8% o.w.f.
NaOH 6～8g/L
Water surplus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013103151831A CN103343460A (en) | 2013-07-25 | 2013-07-25 | Ecological knitting color strip fabric dyeing method with positive ion modifier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013103151831A CN103343460A (en) | 2013-07-25 | 2013-07-25 | Ecological knitting color strip fabric dyeing method with positive ion modifier |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103343460A true CN103343460A (en) | 2013-10-09 |
Family
ID=49278285
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013103151831A Pending CN103343460A (en) | 2013-07-25 | 2013-07-25 | Ecological knitting color strip fabric dyeing method with positive ion modifier |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103343460A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104358161A (en) * | 2014-11-26 | 2015-02-18 | 四川省宜宾惠美线业有限责任公司 | Salt-free low-alkali cellulose fiber modified dyeing process |
| CN104452356A (en) * | 2014-11-26 | 2015-03-25 | 华南理工大学 | Modified process for cellulose fiber |
| CN104452357A (en) * | 2014-11-26 | 2015-03-25 | 华南理工大学 | Modification process for cellulosic fibers |
| CN104452354A (en) * | 2014-11-26 | 2015-03-25 | 四川省宜宾惠美线业有限责任公司 | Modified cellulosic fiber obtained through modification of modifier |
| CN106498770A (en) * | 2016-10-19 | 2017-03-15 | 东华大学 | A kind of salt-free dyeing method of the modified fabric of cationic polymer |
| CN112962304A (en) * | 2021-02-03 | 2021-06-15 | 香遇睡眠科技(广州)有限公司 | Wood agilawood fabric and preparation method thereof |
| CN113605114A (en) * | 2021-09-01 | 2021-11-05 | 石家庄吉利纺织衬布有限公司 | Scarf and processing technology thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1342806A (en) * | 2001-10-10 | 2002-04-03 | 广东溢达纺织有限公司 | Cation modifying method for dyeing cotton yarn |
| CN102454118A (en) * | 2010-10-18 | 2012-05-16 | 南通曙光染织有限公司 | Method for ecologically dyeing yarn |
| CN102978952A (en) * | 2012-12-21 | 2013-03-20 | 南通斯恩特纺织科技有限公司 | Ecological low-salt dyeing and finishing agent for reactive dyes and preparation method and applications thereof |
-
2013
- 2013-07-25 CN CN2013103151831A patent/CN103343460A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1342806A (en) * | 2001-10-10 | 2002-04-03 | 广东溢达纺织有限公司 | Cation modifying method for dyeing cotton yarn |
| CN102454118A (en) * | 2010-10-18 | 2012-05-16 | 南通曙光染织有限公司 | Method for ecologically dyeing yarn |
| CN102978952A (en) * | 2012-12-21 | 2013-03-20 | 南通斯恩特纺织科技有限公司 | Ecological low-salt dyeing and finishing agent for reactive dyes and preparation method and applications thereof |
Non-Patent Citations (1)
| Title |
|---|
| 周宏湘: "试论丝绸印染业摆脱困境的途径", 《广西纺织科技》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104358161A (en) * | 2014-11-26 | 2015-02-18 | 四川省宜宾惠美线业有限责任公司 | Salt-free low-alkali cellulose fiber modified dyeing process |
| CN104452356A (en) * | 2014-11-26 | 2015-03-25 | 华南理工大学 | Modified process for cellulose fiber |
| CN104452357A (en) * | 2014-11-26 | 2015-03-25 | 华南理工大学 | Modification process for cellulosic fibers |
| CN104452354A (en) * | 2014-11-26 | 2015-03-25 | 四川省宜宾惠美线业有限责任公司 | Modified cellulosic fiber obtained through modification of modifier |
| CN106498770A (en) * | 2016-10-19 | 2017-03-15 | 东华大学 | A kind of salt-free dyeing method of the modified fabric of cationic polymer |
| CN106498770B (en) * | 2016-10-19 | 2019-03-08 | 东华大学 | A kind of salt-free dyeing method for the fabric that cationic polymer is modified |
| CN112962304A (en) * | 2021-02-03 | 2021-06-15 | 香遇睡眠科技(广州)有限公司 | Wood agilawood fabric and preparation method thereof |
| CN113605114A (en) * | 2021-09-01 | 2021-11-05 | 石家庄吉利纺织衬布有限公司 | Scarf and processing technology thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103343460A (en) | Ecological knitting color strip fabric dyeing method with positive ion modifier | |
| CN102061634B (en) | Method for dyeing yarn containing cellulose fiber by reactive dye | |
| CN104099788B (en) | Eco-friendly cotton fabric dyeing process | |
| CN106012610A (en) | Dyeing method of polyester-cotton blended knitting fabric | |
| CN102162197A (en) | Method for dip-dyeing polyester rayon (cotton) fabrics or yarns with disperse and reactive dyes by one-bath process | |
| CN104452352A (en) | Salt-free low-alkali dyeing process for cellulosic fibers | |
| CN102605652A (en) | Method for dyeing pure silk by regarding rare earth material as mordant | |
| CN102535205B (en) | Post-treatment fixation process for fabric dyeing | |
| CN104099790B (en) | A kind of method utilizing liquefied ammonia eccysis fiber loose colour | |
| CN101240510B (en) | Method for dyeing silk cotton blended spinning knitted fabric | |
| CN102493066A (en) | Processing method of dischargeable colored spun yarns | |
| CN104420365A (en) | Modal/cotton blended fabric dyeing process | |
| CN102392343B (en) | Pretreatment and bath-treatment method for modifying cotton fabrics | |
| CN104746359A (en) | Fluorescent paint dip-dyeing method of cotton fabrics | |
| CN102978979A (en) | Rayon knitted fabric scouring and dyeing one bath process dyeing | |
| CN109322178A (en) | It is a kind of to wash the/dyeing and finishing processing method of cellulose fibre intertexture jacquard fabric | |
| CN103243573A (en) | Printing and dyeing process for imitation memory fabric | |
| CN102747569A (en) | Pad dyeing method for reactive dyes | |
| CN101280526A (en) | Method for dyeing mercerization baffeta with deep color on reactive dyes | |
| CN108118540A (en) | A kind of dyeing of polyester cotton blending fiber | |
| CN101929084B (en) | Method for dyeing slubby yarn cotton fabrics into raindrop or silk rain style | |
| CN104452355A (en) | Cationic modified dyeing process for cellulose fiber | |
| CN104404793A (en) | Salt-free low-alkaline modifying dyeing method of cellulose fiber | |
| CN110184805A (en) | A kind of anti-return of inflaming retarding fabric dye jigger slurry is stained with technique | |
| CN102535192B (en) | Roll dyeing technology by adopting reactive dye |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20131009 |