CN104746359A - Fluorescent paint dip-dyeing method of cotton fabrics - Google Patents

Fluorescent paint dip-dyeing method of cotton fabrics Download PDF

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Publication number
CN104746359A
CN104746359A CN201510101365.8A CN201510101365A CN104746359A CN 104746359 A CN104746359 A CN 104746359A CN 201510101365 A CN201510101365 A CN 201510101365A CN 104746359 A CN104746359 A CN 104746359A
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China
Prior art keywords
fluorescent paint
dyeing
dye
fabric
cotton
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Pending
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CN201510101365.8A
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Chinese (zh)
Inventor
王春梅
郭珊
胡啸林
李朝晖
缪勤华
张陈成
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Nantong University
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Nantong University
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Priority to CN201510101365.8A priority Critical patent/CN104746359A/en
Publication of CN104746359A publication Critical patent/CN104746359A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a dyeing method of cotton fabrics, which adopts fluorescent paints to obtain fluorescence color. The dyeing method is characterized in that the cotton fabrics subjected to pretreatment are dyed and subjected to color fixation through the cationization modified fluorescent paints. According to the dyeing method, the cationization modification on the fluorescent paints is carried out, so that the fibrous color yield of the paints is improved, the cationization modification on fibers is avoided, the processes are shortened, the aims of energy conservation and emission reduction are fulfilled, and the uniform dyeing property is improved at the same time.

Description

A kind of fluorescent paint exhaust processes of COTTON FABRIC
Technical field
The present invention relates to a kind of fluorescent paint exhaust processes of COTTON FABRIC, belong to technical field of textile printing.
Background technology
The dyeing of COTTON FABRIC is mainly based on REACTIVE DYES, and REACTIVE DYES is bright in colour with it, fastness is good, easy to use, cheap and famous.But REACTIVE DYES always also exists exhaustion rate, problem that degree of fixation is lower.Meanwhile, in dyeing course, need to add a large amount of neutral electrolyte and promote upper dye, need to add a large amount of alkaline agents and carry out fixation, add the difficulty of wastewater treatment.Relative to traditional dyeing technology, pigment dyeing is the clean process technology of a sustainable development, it has, and flow process is short, energy-conservation, water saving, the feature such as low in the pollution of the environment, there is significant advantage in energy saving standard.In addition, pigment dyeing also has unique style, has a extensive future.Especially fluorescent paint compensate for the disappearance of REACTIVE DYES in chromatogram, can obtain and dazzle beautiful, bright-coloured fluorescent staining effect.
Commercial optical coating is generally with negative charge, to cotton fiber without affinity, can not spontaneous upper dye fiber when adopting dip-dye mode to dye, conventional method is after cotton fiber is first carried out cation modifying with cation modifier, carry out dyeing and fixation with fluorescent paint again, as Chinese patent CN 103590261A, CN 104074054A etc.This technology process long flow path, water consumption, energy consumption are large, easily cause uneven dyeing.The present invention, by cation modifying to fluorescent paint, improves the tinctorial yield of coating on fiber, and what avoid fiber is cation-modified, shortens technological process, reaches the object of energy-saving and emission-reduction, improve level-dyeing property simultaneously.
Summary of the invention
The object of the present invention is to provide a kind of fluorescent paint colouring method of COTTON FABRIC, by the cation modifying to fluorescent paint, improve the tinctorial yield of coating on fiber, what avoid fiber is cation-modified, shortens technological process, realizes energy-saving and emission-reduction.
The present invention is by the following technical solutions: by the COTTON FABRIC through pre-treatments such as destarch, kiering, bleaching, biopolishings, directly dye with the fluorescent paint through cation modifying, and carry out fixation treatment with adhesive.
Described pre-treatment routinely technique adopts the auxiliary agents such as hydrogen peroxide, alkali, cellulase to carry out destarch, kiering, bleaching, biopolishing etc.
The cation modifying of described fluorescent paint, modified technique: fluorescent paint 1 ~ 10% (to fabric weight), cation modifier Fix-8005 ~ 30% (to coating weight), paregal O 2 ~ 8% (to coating weight), penetrating agent JFC 3 ~ 5% (to coating weight), stir, be made into certain density dye liquor.
Described dyeing: dyeing temperature 50 ~ 60 DEG C, dyeing time 10 ~ 20min, bath raio 1:10 ~ 15.
Described fixation, after dyeing a period of time, directly adds adhesive and carries out fixation in dye bath.Adhesive therefor PB is esters of acrylic acid, binder dosage 5 ~ 10g/L, color fixing temperature 60 ~ 80 DEG C, fixation time 20 ~ 30min, pH value 4 ~ 5.Then lower the temperature, dewater, dry, bake.
The invention provides a kind of COTTON FABRIC fluorescent paint exhaust processes, by the cation modifying to fluorescent paint, improve the tinctorial yield of coating on fiber, make COTTON FABRIC without the need to carrying out cation modifying, can direct dyeing, shorten technological process, reach the effect of energy-saving and emission-reduction.
Detailed description of the invention
The present invention is further illustrated below by embodiment.
Embodiment 1
Fabric: 32 sall cotton undershirt cloth, grammes per square metre 126g/m 2.
Pre-treatment: 30% hydrogen peroxide 8g/L, stabilizing agent 2g/L, high-efficiency refining agent 2g/L, NaOH 1g/L, bath raio 1:10, at temperature 95 DEG C process 45min, hot water wash.Add acetic acid and be neutralized to pH value 6 ~ 7, add enzyme preparation Eurolan Comli 2% (to fabric weight), at 50 DEG C of process 15min, carry out deoxygenation and biopolishing.Be warming up to 80 DEG C of process 10min and make enzyme deactivation.
Dyeing and fixation: the pink S-27 coating 10% (to fabric weight) of fluorescence, cation modifier Fix-80030% (to coating weight), paregal O 8% (to coating weight), penetrating agent JFC 5% (to coating weight), bath raio 1:10.Fabric, after 60 DEG C of dyeing 20min, directly adds 10g/L adhesive PB, is warming up to 80 DEG C, by acetic acid adjust ph about 4.5, fixation 30min in dye bath.Then lower the temperature, dewater, dry, bake.
The performance of DYED FABRICS is in table 1 after testing.
Embodiment 2
Fabric: 32 sall cotton undershirt cloth, grammes per square metre 126g/m 2.
Pre-treatment: 30% hydrogen peroxide 8g/L, stabilizing agent 2g/L, high-efficiency refining agent 2g/L, NaOH 1g/L, bath raio 1:10, at temperature 95 DEG C process 60min, hot water wash.Add acetic acid and be neutralized to pH value 6 ~ 7, add enzyme preparation Eurolan Comli 2% (to fabric weight), at 50 DEG C of process 15min, carry out deoxygenation and biopolishing.Be warming up to 80 DEG C of process 10min and make enzyme deactivation.
Dyeing and fixation: the pink S-27 coating 1% (to fabric weight) of fluorescence, cation modifier Fix-8005% (to coating weight), paregal O 2% (to coating weight), penetrating agent JFC 3% (to coating weight), bath raio 1:10.Fabric, after 50 DEG C of dyeing 10min, directly adds 5g/L adhesive PB, is warming up to 70 DEG C, by acetic acid adjust ph about 5, fixation 20min in dye bath.Then lower the temperature, dewater, dry, bake.
The performance of DYED FABRICS is in table 1 after testing.
Embodiment 3
Fabric: 32 scotton knop cloth, grammes per square metre 270g/m 2.
Pre-treatment: 30% hydrogen peroxide 10g/L, stabilizing agent 2.5g/L, high-efficiency refining agent 2g/L, NaOH 1g/L, bath raio 1:10, at temperature 95 DEG C process 60min, hot water wash.Add acetic acid and be neutralized to pH value 6 ~ 7, add enzyme preparation Eurolan Comli 3% (to fabric weight), at 50 DEG C of process 15min, carry out deoxygenation and biopolishing.Be warming up to 80 DEG C of process 10min and make enzyme deactivation.
Dyeing and fixation: fluorescence green S-21 coating 8% (to fabric weight), cation modifier Fix-80020% (to coating weight), paregal O 5% (to coating weight), penetrating agent JFC 5% (to coating weight), bath raio 1:10.Fabric, after 50 DEG C of dyeing 15min, directly adds 10g/L adhesive PB, is warming up to 70 DEG C, by acetic acid adjust ph about 4.5, fixation 25min in dye bath.Then lower the temperature, dewater, dry, bake.
The performance of DYED FABRICS is in table 1 after testing.
Table 1 fluorescent paint DYED FABRICS performance
Note: crock fastness is tested according to GB/T3920-2008; Soaping fastness is according to C (3) test in GB/T3921-2008.

Claims (4)

1. a fluorescent paint colouring method for COTTON FABRIC, is characterized in that: by the COTTON FABRIC through pre-treatments such as destarch, kiering, bleaching, biopolishings, directly dye with the fluorescent paint through cation modifying, and carry out fixation treatment with adhesive.
2. the fluorescent paint colouring method of a kind of COTTON FABRIC according to claim 1, it is characterized in that: the cation modifying of fluorescent paint: fluorescent paint 1 ~ 10% (to fabric weight), cation modifier Fix-8005 ~ 30% (to coating weight), paregal O 2 ~ 8% (to coating weight), penetrating agent JFC 3 ~ 5% (to coating weight), be made into certain density dye liquor, dye, dyeing temperature 50 ~ 60 DEG C, dyeing time 10 ~ 20min.
3. the fluorescent paint colouring method of a kind of COTTON FABRIC according to claim 1, it is characterized in that: after dyeing a period of time, directly in dye bath, add adhesive carries out fixation, adhesive therefor PB is esters of acrylic acid, binder dosage 5 ~ 10g/L, color fixing temperature 60 ~ 80 DEG C, fixation time 20 ~ 30min, pH value 4 ~ 5, then lowers the temperature, dewaters, dries, bakes.
4. the fluorescent paint colouring method of a kind of COTTON FABRIC according to claim 1, is characterized in that: be applicable to cotton woven fabric, the dip-dye of knitted fabric.
CN201510101365.8A 2015-03-06 2015-03-06 Fluorescent paint dip-dyeing method of cotton fabrics Pending CN104746359A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105274870A (en) * 2015-11-20 2016-01-27 常熟市梦迪安家饰用品有限公司 Dyeing method for all-cotton fluorescent yarn
CN107059387A (en) * 2017-05-16 2017-08-18 繁昌县清新水洗有限责任公司 A kind of coating dyeing method of bafta
CN108425276A (en) * 2018-03-21 2018-08-21 保定钞票纸业有限公司 A kind of cheque paper and preparation method thereof with irregular punctate fluorescence anti-false fiber
CN109295747A (en) * 2018-08-09 2019-02-01 青岛大学 A kind of fluorescence knitted fabric outside material
CN110886100A (en) * 2019-11-27 2020-03-17 博森织染(嘉兴)有限公司 Fluorescent dyeing process for cotton
CN114507992A (en) * 2020-11-17 2022-05-17 珠海建轩服装有限公司 Fabric with irregular halation effect and preparation method thereof

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CN102787458A (en) * 2012-08-15 2012-11-21 佛山市顺德区鸿昌嘉特威服装有限公司 Production method of pigment-dyed jean fabric with various functions of resisting water, resisting oil and the like

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CN102605653A (en) * 2012-02-28 2012-07-25 青岛大学 One-bath processing method for pure-cotton knitted fabric scouring and bleaching and pigment dyeing
CN102787458A (en) * 2012-08-15 2012-11-21 佛山市顺德区鸿昌嘉特威服装有限公司 Production method of pigment-dyed jean fabric with various functions of resisting water, resisting oil and the like

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105274870A (en) * 2015-11-20 2016-01-27 常熟市梦迪安家饰用品有限公司 Dyeing method for all-cotton fluorescent yarn
CN107059387A (en) * 2017-05-16 2017-08-18 繁昌县清新水洗有限责任公司 A kind of coating dyeing method of bafta
CN108425276A (en) * 2018-03-21 2018-08-21 保定钞票纸业有限公司 A kind of cheque paper and preparation method thereof with irregular punctate fluorescence anti-false fiber
CN109295747A (en) * 2018-08-09 2019-02-01 青岛大学 A kind of fluorescence knitted fabric outside material
CN110886100A (en) * 2019-11-27 2020-03-17 博森织染(嘉兴)有限公司 Fluorescent dyeing process for cotton
CN114507992A (en) * 2020-11-17 2022-05-17 珠海建轩服装有限公司 Fabric with irregular halation effect and preparation method thereof

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