CN107114370A - A kind of composition pesticide containing S-Ethyl ethylthio sulfonate and bromothalonil - Google Patents
A kind of composition pesticide containing S-Ethyl ethylthio sulfonate and bromothalonil Download PDFInfo
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- CN107114370A CN107114370A CN201710479116.1A CN201710479116A CN107114370A CN 107114370 A CN107114370 A CN 107114370A CN 201710479116 A CN201710479116 A CN 201710479116A CN 107114370 A CN107114370 A CN 107114370A
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- bromothalonil
- ethyl ethylthio
- ethylthio sulfonate
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- sulfonate
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/08—Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/34—Nitriles
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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Abstract
The invention discloses a kind of composition pesticide containing S-Ethyl ethylthio sulfonate and bromothalonil, contain active ingredient S-Ethyl ethylthio sulfonate and bromothalonil.The weight ratio of S-Ethyl ethylthio sulfonate and bromothalonil is 20：1~1：20, percentage by weight is 2~95% in the composition for S-Ethyl ethylthio sulfonate and bromothalonil weight summation.S-Ethyl ethylthio sulfonate and bromothalonil composition is needed to can be prepared as aqueous suspension agent, dispersible oil-suspending agent, aqueous emulsion, microemulsion, wettable powder, water dispersible granules or missible oil according to practical application, applied to preventing and treating citrus orchard moss.
Description
Technical field
The present invention relates to a kind of composition pesticide containing S-Ethyl ethylthio sulfonate and bromothalonil, it using S-Ethyl ethylthio sulfonate and bromothalonil is effective to be
Composition, applied to preventing and treating citrus orchard moss.
Background technology
Citrus orchard is huge in the cultivated area of China, due to orchard worker's extensive management, in the citrus orchard on many ground such as Guangxi, Guangdong
Spread all over moss, moss is attached on mandarin tree, cause mandarin tree trunk, blade to lose its physiological function, leverage citrus
Yield.It is mainly the bactericide such as organic copper class, Inorganic Copper class and S-Ethyl ethylthio sulfonate currently used for the Pesticidal products of preventing and treating citrus moss.
Wherein, Inorganic Copper class product is more strict using technology, it can not with other combined use of pesticides, and using easy under hot weather
Citrus young fruit is caused to cause poisoning.The irritant smell of S-Ethyl ethylthio sulfonate, the stimulus to the sense organ to operator is very big.It is of the invention based on this
People is studied the chemical prevention means of moss.
S-Ethyl ethylthio sulfonate English name：Ethylicin, chemical name：Alkane thiosulfonic acid ethyl ester.S-Ethyl ethylthio sulfonate is a kind of plant bionic
Agricultural chemicals, garlic P.E, the ethyl homologue of allicin, it can include the material effect of sulfenyl with thalline, so as to suppress thalline
Eubolism.
Bromothalonil English name：Bromothalonil, chemical name：The bromo- 2,4- dicyanobutanes of 1,2- bis-.Bromothalonil
Be a kind of wide spectrum, efficiently, the bactericide of low toxicity, can suppress and root out fungi, bacterium, the growth of algae, have to corps diseases
Preferable prevention effect, has special efficacy to anthracnose, is widely used in fruit tree, grape, vegetables, cotton, peanut, watermelon, tobacco, tea
The various crops such as tree, flowers, prevent and treat anthracnose, scab, shot hole, powdery mildew, rust, damping-off, samping off, rhizome rotten
A variety of fungoids such as disease, canker, bacterial wilt, angular leaf spot, bacteroidal disease.
S-Ethyl ethylthio sulfonate and bromothalonil combination, applied to the method for preventing and treating citrus orchard moss, there is no report at present.
The content of the invention
It is an object of the invention to：A kind of composition pesticide for being adapted to agriculturally use is provided, and helps to reduce use
Dose, delay disease pest and weed produce resistance and reduction use cost.
To overcome the deficiencies in the prior art, inventor is tested and field control effectiveness test by substantial amounts of indoor bioassay,
After having been surprisingly found that S-Ethyl ethylthio sulfonate and bromothalonil are compounded with certain proportion, moss is had significant synergies.
The technical solution adopted in the present invention is：A kind of synergetic pesticide composition, it is characterised in that contain active ingredient second
The mass ratio of allicin and bromothalonil, S-Ethyl ethylthio sulfonate and bromothalonil is 20：1~1：20, preferred mass ratio is 1：10~10：1, more preferably
Mass ratio is 1：5~5：1.
In the composition pesticide of the present invention, the weight summation of active ingredient S-Ethyl ethylthio sulfonate and bromothalonil is in composition pesticide
Weight percentage is 2~95%, and remaining is auxiliary agent.Described auxiliary agent is solvent, emulsifying agent, wetting agent, stabilizer, scattered
One or more of mixing in agent, thickener, pH adjusting agent, defoamer, antifreezing agent, filler etc., are known substance, are agricultures
The various auxiliary agents commonly used in medicine preparation, can be varied from according to different situations, be not particularly limited.Solvent can be solvent naphtha
S-200, dimethylbenzene, trimethylbenzene, durene, methyl naphthalene, methyl oleate, fatty acid methyl ester, loose base oil, soybean oil, biodiesel,
One or more in sec-Butyl Acetate, dimethyl carbonate, diesel oil, white oil, machine oil, 1-METHYLPYRROLIDONE etc..Emulsifying agent can
Be calcium dodecyl benzene sulfonate, AEO, triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer,
Dibenzyl xenyl APEO, phenethyl phenol polyethenoxy ether, castor oil polyoxyethylene ether, phenethyl phenol formaldehyde resin gather
Oxygen vinethene, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylaryl polyoxyethylene polyoxypropylene ether again, phenethyl phenol first
Urea formaldehyde APEO, Sorbitan fatty acid ester, sorbitan fatty acid ester APEO, natural fatty alcohol and ring
Oxidative ethane addition product, aliphatic acid and ethylene oxide condensate, polyoxyethylene fatty acid ester, phenethyl phenol polyethenoxy ether polyoxy third
One or more in alkene ether etc..Wetting agent can be sodium butylnaphthalenesulfonate, lauryl sodium sulfate, aliphatic alcohol polyethenoxy
(6-7) ether, aerosol-OT salt, Morwet EFW, alkylnaphthalene sulfonate, spaonin powder, bay alcohol radical sodium sulphate
One or more in.Disintegrant can be compound sodium nitrophenolate, sodium acid carbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, sulfuric acid
One or more in ammonium, bentonite etc..Dispersant can be polycarboxylate, the formaldehyde condensation products of methyl naphthalene sulfonic acid sodium, wooden
Plain sodium sulfonate, calcium lignosulfonate, to methoxyl group fatty acyl anilinesulfonic acid, desugar and be classified sodium lignin sulfonate, naphthalene sulphur
One kind in sour condensation product sodium salt, alkyl naphthalene sulfonic acid condensation polymer sodium salt, APES formaldehyde condensation product sulfuric acid etc. or
It is several.Thickener can be the one or more in xanthans, aluminium-magnesium silicate, bentonite, white carbon etc..PH adjusting agent can be
One or more in ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc..Stabilizer can be
Dibutyl phthalate, hexamethylene diisocyanate, epoxidized soybean oil, epoxychloropropane, butylated hydroxy anisole, two fourths
One or more in base hydroxy-methylbenzene, propylgallate, tert-butylhydroquinone etc..Defoamer can be silicone chemical combination
One or more in thing, methanol, silicone oil, azone, dimethyl silicone polymer etc..Antifreezing agent can be glycerine, ethylene glycol, the third two
It is one or more of in alcohol, sorbierite, polyethylene glycol etc..Carrier can be kaolin, diatomite, bentonite, white carbon, lightweight carbon
One kind in sour calcium, attapulgite, clay, talcum powder, quartz sand, starch, APG, urea, potassium chloride, ammonium chloride etc.
Or it is several.Sustained release agent can be one or both of polyvinyl alcohol, Arabic gum.Preservative can be sodium benzoate.Bond
Agent can be one or both of polyethylene glycol, industrial gelatine.
The composition of the present invention can be processed into the formulation agriculturally allowed, and preferable formulation has aqueous suspension agent, dispersible
Oil-suspending agent, aqueous emulsion, microemulsion, wettable powder, water dispersible granules or missible oil.
The composition pesticide of the present invention can be used for preventing and treating moss.Generally used using the method for spraying, can also be according to need
Will using agriculturally apply other use technology.
Compared with prior art, what the present invention was produced has the beneficial effect that：
1st, S-Ethyl ethylthio sulfonate preventing and treating moss is agriculturally being applied, but the irritant smell of S-Ethyl ethylthio sulfonate, and operator is produced
Raw stimulus to the sense organ is very big.The present invention is reduced the consumption of S-Ethyl ethylthio sulfonate, reduced using bromothalonil and S-Ethyl ethylthio sulfonate compounding preventing and treating moss
To the stimulus to the sense organ of human body during dispenser.
2nd, S-Ethyl ethylthio sulfonate and bromothalonil mechanism of action are inconsistent, and the two, which is used with, unexpected synergistic effect to moss, can
To overcome agricultural chemicals long-term single using the shortcoming for easily producing resistance, to the comprehensive regulation important in inhibiting of moss resistance.
Embodiment
In order that the objects, technical solutions and advantages of the present invention are more concise, present invention specific examples below
Illustrate, but the present invention is only limitted to absolutely not these embodiments.As described below is only the present invention preferably embodiment, is used only for
The description present invention, it is impossible to be interpreted as limiting the scope of the present invention.It should be pointed out that all in the spirit and principles in the present invention
Within any modifications, equivalent substitutions and improvements for being done etc., all should include within protection scope of the present invention.Therefore, originally
The protection domain of patent of invention should be determined by the appended claims.
Example of formulations case
Composition pesticide of the present invention can be prepared into the aqueous suspension agent, dispersible for being adapted to agriculturally use with known method
Oil-suspending agent, aqueous emulsion, microemulsion, wettable powder, water dispersible granules or missible oil.As described below is only that the present invention is preferably real
Example is applied, is used only for explaining the present invention, it is impossible to therefore understands that being the limitation to the scope of the claims of the present invention.
Example of formulations 1：
Weigh 20 grams of S-Ethyl ethylthio sulfonate, 1 gram of bromothalonil, 11 grams of alkylnaphthalene sulfonate, 9 grams of sodium lignin sulfonate, 3 grams of propane diols,
3 grams of xanthans, 2 grams of methanol, 1 gram of potassium hydroxide, water is supplemented to 100 grams.Above-mentioned material is mixed, in ball crusher grind 2~
3h, makes a diameter in below 5mm, that is, 21% S-Ethyl ethylthio sulfonate bromothalonil aqueous suspension agent be made.
Example of formulations 2：
Weigh 2 grams of S-Ethyl ethylthio sulfonate, 40 grams of bromothalonil, 15 grams of APES, 8 grams of pull open powder, 2 grams of xanthans, second
2 grams of glycol, 4 grams of dimethyl silicone polymer, 4 grams of sodium benzoate, water are supplemented to 100 grams.Above-mentioned material is mixed, in ball crusher
2~3h is ground, a diameter in below 5mm, that is, 42% S-Ethyl ethylthio sulfonate bromothalonil aqueous suspension agent is made.
Example of formulations 3：
Weigh 30 grams of S-Ethyl ethylthio sulfonate, 2 grams of bromothalonil, 8 grams of lauryl sodium sulfate, 7 grams of Sorbitan fatty acid ester, sulfonation amber
6 grams of amber dioctyl phthalate sodium salt, 6 grams of xanthans, methyl oleate complement to 100 grams.Mentioned component is dissolved into homogeneous oil phase, in height
Under speed stirring, the 32% dispersible oil-suspending agent of S-Ethyl ethylthio sulfonate bromothalonil is mixed to prepare.
Example of formulations 4：
Weigh 1 gram of S-Ethyl ethylthio sulfonate, 15 grams of bromothalonil, 5 grams of alkylnaphthalene sulfonate, 8 grams of polyoxyethylene fatty acid ester, alkyl sulfonic acid
8 grams of salt, 4 grams of white carbon, 3 grams of epoxychloropropane, soybean oil complement to 100 grams.Mentioned component is dissolved into homogeneous oil phase；In height
Under speed stirring, the 16% dispersible oil-suspending agent of S-Ethyl ethylthio sulfonate bromothalonil is mixed to prepare.
Example of formulations 5：
Weigh 20 grams of S-Ethyl ethylthio sulfonate, 2 grams of bromothalonil, 16 grams of trimethylbenzene, 10 grams of Sorbitan fatty acid ester, butylated hydroxy-a
7 grams of benzene, 3 grams of glycerine, 2 grams of silicone oil, 5 grams of aluminium-magnesium silicate, water are supplemented to 100 grams.Agricultural chemicals is successively added in proportion into solvent to live
Property composition, emulsifying agent and defoamer, are sufficiently stirred for dissolving and high concentration mother liquor are made, add deionized water and stir, so
After add antifreezing agent, obtained 22% S-Ethyl ethylthio sulfonate bromothalonil aqueous emulsion after analytical control is qualified.
Example of formulations 6：
Weigh 1 gram of S-Ethyl ethylthio sulfonate, 10 grams of bromothalonil, 8 grams of calcium dodecyl benzene sulfonate, phenethyl phenol polyethenoxy ether polyoxy third
6 grams of alkene ether, 4 grams of alkyl phenol formaldehyde resin polyoxyethylene ether, 8 grams of ethylene glycol, 7 grams of dimethyl silicone polymer, 12 grams of cyclohexanone, water
It is supplemented to 100 grams.Successively add pesticide activity component, emulsifying agent and defoamer in proportion into solvent, be sufficiently stirred for dissolving system
Into high concentration mother liquor, add deionized water and stir, then add antifreezing agent, obtained 11% second after analytical control is qualified
Allicin bromothalonil aqueous emulsion.
Example of formulations 7：
Weigh 5 grams of S-Ethyl ethylthio sulfonate, 15 grams of bromothalonil, 4 grams of fatty acid methyl ester, 10 grams of calcium dodecyl benzene sulfonate, epoxy chloropropionate
8 grams of alkane, 3 grams of acetic acid, water are supplemented to 100 grams.First active component is completely dissolved with solvent, other auxiliary agents are then added, mixed
Close uniform, water is eventually adding, after being sufficiently stirred for, you can 20% S-Ethyl ethylthio sulfonate bromothalonil microemulsion is made.
Example of formulations 8：
Weigh 3 grams of S-Ethyl ethylthio sulfonate, 15 grams of bromothalonil, 12 grams of phenethyl phenol polyoxyethylene poly-oxygen propylene aether, alkylphenol formaldehyde tree
11 grams of fat APEO, 5 grams of calcium dodecyl benzene sulfonate, 15 grams of 1-METHYLPYRROLIDONE, 2 grams of ethanol, water are supplemented to 100
Gram.First active component is completely dissolved with solvent, other auxiliary agents are then added, is well mixed, is eventually adding water, is sufficiently stirred for
Afterwards, you can 18% S-Ethyl ethylthio sulfonate bromothalonil microemulsion is made.
Example of formulations 9：
Weigh 20 grams of S-Ethyl ethylthio sulfonate, 20 grams of bromothalonil, 15 grams of bay alcohol radical sodium sulphate, 5 grams of calcium lignosulfonate, naphthalene sulfonate
10 grams, 6 grams of white carbon, bentonite complement to 100 grams.Mentioned component is mixed, is sufficiently stirred in stirred tank, through air-flow crushing
Machine is well mixed after crushing, you can 40% S-Ethyl ethylthio sulfonate bromothalonil wettable powder is made.
Example of formulations 10：
Weigh 65 grams of S-Ethyl ethylthio sulfonate, 13 grams of bromothalonil, 7 grams of 1-METHYLPYRROLIDONE, phenethyl phenol polyoxypropylene polyoxy second
2 grams of alkene ether, 2 grams of calcium dodecyl benzene sulfonate, dimethylbenzene complement to 100 grams, sequentially add mentioned component in mixing kettle, stirring
Uniformly, you can 78% S-Ethyl ethylthio sulfonate bromothalonil missible oil is made.
Example of formulations 11：
Weigh 60 grams of S-Ethyl ethylthio sulfonate, 20 grams of bromothalonil, 3 grams of alkyl naphthalene sulfonic acid condensation polymer sodium salt, 4 grams of alkylnaphthalene sulfonate, chlorine
Change 2 grams of magnesium, 2 grams of ammonium hydroxide, 1 gram of methanol, 3 grams of epoxychloropropane, white carbon and be supplemented to 100 grams.Mentioned component is mixed equal
It is even, crushed, added after kneading after being granulated in fluidized-bed granulation dryer, drying, sieve, i.e., with micro jet
80% S-Ethyl ethylthio sulfonate bromothalonil water dispersible granule can be made.
Different types of pesticide active ingredient is compounded, is current to solve during agricultural chemicals single dose use cost and anti-
The effective measures of the problems such as property.After different types of pesticide active ingredient mixing, three kinds of type of action are typically exhibited, i.e.,
Summation action, synergistic effect and antagonism.But it is specially which kind of synergy, only by substantial amounts of bioassay test
It can know that.
The present composition has the obvious result coordinated synergistic effect, can tested from following toxicity test to moss
In be clearly seen that.
Indoor bioassay embodiment
The mother liquor that each confession reagent product first are configured into suitable concentration is standby.Add 200mL culture water per test sample, according to setting
Concentration dosing is counted, each test group is reached design concentration.Add per test sample for examination moss 1g (fresh weight), then carry out culture sight
Examine, the test period is 20d, if blank control group.After off-test, moss is filtered with nylon filtering cloth, centrifugation 3min takes off
Weighed after water, EC of each medicine to moss is calculated according to the fresh weight inhibition of moss50.All test datas use DPS
V14.10 statistical softwares are analyzed.Obtain toxicity regression formula, coefficient correlation (r), LC50And LC90And its 95% confidence limit.
Fresh weight inhibition (%)=(blank control group fresh weight-drug-treated group fresh weight)/blank control group fresh weight × 100%
With reference to the method in NY/T 1156.6-2006 standards, the co-toxicity coefficient (CTC) of mixture is calculated according to the abundant methods of Sun Yun.
CTC≤120 show as synergistic effect, and CTC≤80 show as antagonism, 80<CTC<120 show as summation action.Poison is altogether
Number calculation formula is as follows：
Percentage composition+medicament of A medicaments in the mixture of mixture theoretical toxicity index (TTI)=medicament A toxicity index × 100
The percentage composition of the mixture Chinese medicine of B toxicity index × 100
The S-Ethyl ethylthio sulfonate of table 1 and Toxicity Determination result of the test of the bromothalonil to moss
| Active ingredient is matched | EC50(mg/L) | ATI | TTI | CTC |
| S-Ethyl ethylthio sulfonate | 65.20 | 100.00 | -- | -- |
| Bromothalonil | 43.31 | 150.54 | -- | -- |
| S-Ethyl ethylthio sulfonate：Bromothalonil (20:1) | 51.28 | 127.15 | 102.41 | 124.16 |
| S-Ethyl ethylthio sulfonate：Bromothalonil (15:1) | 45.66 | 142.79 | 103.16 | 138.42 |
| S-Ethyl ethylthio sulfonate：Bromothalonil (10:1) | 44.39 | 146.88 | 104.59 | 140.43 |
| S-Ethyl ethylthio sulfonate：Bromothalonil (5:1) | 41.22 | 158.18 | 108.42 | 145.89 |
| S-Ethyl ethylthio sulfonate：Bromothalonil (3:1) | 40.74 | 160.04 | 112.64 | 142.09 |
| S-Ethyl ethylthio sulfonate：Bromothalonil (1:1) | 38.11 | 171.08 | 125.27 | 136.57 |
| S-Ethyl ethylthio sulfonate：Bromothalonil (1:3) | 35.96 | 181.31 | 137.91 | 131.47 |
| S-Ethyl ethylthio sulfonate：Bromothalonil (1:5) | 35.02 | 186.18 | 142.12 | 131.00 |
| S-Ethyl ethylthio sulfonate：Bromothalonil (1:10) | 34.18 | 190.75 | 145.95 | 130.70 |
| S-Ethyl ethylthio sulfonate：Bromothalonil (1:15) | 34.02 | 191.65 | 147.38 | 130.04 |
| S-Ethyl ethylthio sulfonate：Bromothalonil (1:20) | 33.88 | 192.44 | 148.14 | 129.91 |
As can be seen from Table 1, S-Ethyl ethylthio sulfonate and bromothalonil are 20：1~1：Compounded in the range of 20, synergy is shown as to moss
Effect.Wherein, S-Ethyl ethylthio sulfonate and bromothalonil 5:1 ratio compounding is optimal to the co-toxicity coefficient of moss.
Field test embodiment：The present composition is used for the field test for preventing and treating citrus orchard moss
Test site is located at certain citrus orchard by the government of Huizhou Ma Anzhen towns, with 80% S-Ethyl ethylthio sulfonate EC, 20% bromine
Bacterium nitrile WP compares medicine, and experiment sets 13 chemicals treatments altogether, each 4 repetitions of processing, in before dispenser, 10 after dispenser, 30 days it is each
The moss number on 5 plants of mandarin trees is investigated, preventive effect is calculated, result of the test is as shown in table 2.
The S-Ethyl ethylthio sulfonate of table 2 and bromothalonil combination preventing and treating citrus orchard moss field test results
As can be seen from Table 2, example of formulations 1-11, S-Ethyl ethylthio sulfonate and bromothalonil composition, prevent and treat the medicine of citrus orchard moss
Effect and lasting period are all better than single dose treatment group, can effectively control citrus orchard moss.
Claims (6)
1. the weight ratio of a kind of composition pesticide containing S-Ethyl ethylthio sulfonate and bromothalonil, active ingredient S-Ethyl ethylthio sulfonate and bromothalonil is 20：1
~1：20.
2. composition pesticide according to claim 1, it is characterised in that：The mass ratio of active ingredient S-Ethyl ethylthio sulfonate and bromothalonil
It is 1：10~10：1.
3. composition pesticide according to claim 2, it is characterised in that：The mass ratio of active ingredient S-Ethyl ethylthio sulfonate and bromothalonil
It is 1：5~5：1.
4. the composition pesticide according to any one of claims 1 to 3, it is characterised in that：Active ingredient in composition pesticide
The gross mass percentage composition of S-Ethyl ethylthio sulfonate and bromothalonil is 2~95%.
5. composition pesticide according to claim 4, it is characterised in that：The formulation of the composition pesticide is aqueous suspension
Agent, dispersible oil-suspending agent, aqueous emulsion, microemulsion, wettable powder, water dispersible granules or missible oil.
6. application of the composition pesticide according to claim 1 on preventing and treating citrus orchard moss.
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| Application Number | Priority Date | Filing Date | Title |
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| CN114586802A (en) * | 2022-04-01 | 2022-06-07 | 山东汤普乐作物科学有限公司 | Bactericide containing prochloraz and ethylicin and preparation method and application thereof |
| CN115024332A (en) * | 2022-05-20 | 2022-09-09 | 衡阳市蔬菜研究所 | Pesticide composition for preventing and treating pepper anthracnose |
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Application publication date: 20170901 |