CN107094791A - A kind of solid-state hypochlorous acid disinfectant powder and preparation method thereof - Google Patents

A kind of solid-state hypochlorous acid disinfectant powder and preparation method thereof Download PDF

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Publication number
CN107094791A
CN107094791A CN201710298117.6A CN201710298117A CN107094791A CN 107094791 A CN107094791 A CN 107094791A CN 201710298117 A CN201710298117 A CN 201710298117A CN 107094791 A CN107094791 A CN 107094791A
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China
Prior art keywords
hypochlorous acid
chloride
solid
state
potassium
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CN201710298117.6A
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Chinese (zh)
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辛晨
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Individual
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Individual
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Priority to CN201710298117.6A priority Critical patent/CN107094791A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/02Sulfur; Selenium; Tellurium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06Aluminium; Calcium; Magnesium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/08Alkali metal chlorides; Alkaline earth metal chlorides

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

It is a kind of solid-state hypochlorous acid disinfectant powder and preparation method thereof specifically the present invention relates to the manufacturing technology field of disinfectant.The product containing hypochlorite that in the market is sold is mainly liquor natrii hypochloritis.But liquor natrii hypochloritis has sensitization.Solid-state hypochlorous acid sterilization amidin in the present invention kills microorganism by oxidation.Hypochlorite is not present in solution, does not contain any to the poisonous and harmful ion of human body and chlorine.Hypochlorous acid solid state technology changes Traditional Transportation, storage and the occupation mode of hypochlorous acid class product.The hypochlorous danger of conventional liquid is greatly reduced, storage and transport need not be managed according to hazardous chemical.Hauled weight and storage area are greatlyd save compared with traditional liquid hypochlorous acid class product.And it is easy to use, product can react in cold water to be completely dissolved, and is configured and now with the current without other.Therefore hypochlorous acid solid state technology has irreplaceable advantage.

Description

A kind of solid-state hypochlorous acid disinfectant powder and preparation method thereof
Technical field
It is a kind of solid-state hypochlorous acid disinfectant powder and its system specifically the present invention relates to the manufacturing technology field of disinfectant Preparation Method.
Background technology
Hypochlorous acid is a kind of strong oxidizer, can kill the bacterium in water, so running water often uses chlorine(It is passed through in 1L water About 0.002g chlorine)Carry out sterilizing.Hypochlorous acid can make dyestuff and organic chromaticness fade, and be typically used as bleaching agent, oxidant, remove Smelly dose and disinfectant.In biology, hypochlorous acid is by neutrophil(Neutrophil)For killing bacterium.It is extensive Chlorine-containing disinfectant product for swimming pool.Hypochlorous acid chemical formula HClO, structural formula H-O-Cl, are existed only in solution, dense Solution is in yellow, and weak solution is colourless, there is very pungent smell, extremely unstable, is very weak acid, weaker than carbonic acid, and hydrosulphuric acid Quite.There are very strong oxidisability and blanching effect.Its salt can be used as bleaching agent and disinfectant, thus in the market sell contain The product of hypochlorite is mainly liquor natrii hypochloritis.But conventional hand contact liquor natrii hypochloritis is passed through, palm is largely perspired, referred to First is thinning, trichomadesis.And liquor natrii hypochloritis has sensitization.
The active ingredient in solid-state hypochlorous acid sterilization amidin in the present invention is to destroy microorganism by oxidation Surface and internal protein(Memebrane protein, ion channel, enzyme system etc.)To kill microorganism, in theory to any microorganism all There is killing effect and drug resistance will not be caused.And hypochlorite is not present in solution, act on and completing in the oxidation disinfection of solution Afterwards, it will be free from solution any to the poisonous and harmful ion of human body and chlorine.Only when solution just prepares completion, generation Hypochlorous acid can decompose a small amount of chlorine of generation.
Hypochlorous acid solid state technology will be pressed containing the compound for synthesizing each hypochlorous effective group together with stabilizer According to ratio mixing, exist in the way of solid powder.When powder is added to the water, each effective group and water react or using water as Carrier occurs mutually chemical reaction and produces hypochlorous acid, so as to be formed containing hypochlorous high oxidative solution.Hypochlorous acid solid state Technology changes Traditional Transportation, storage and the occupation mode of hypochlorous acid class product.Greatly reduce the hypochlorous danger of conventional liquid Dangerous, storage and transport need not be managed according to hazardous chemical.Greatlyd save compared with traditional liquid hypochlorous acid class product Hauled weight and storage area.And it is easy to use, product can react in cold water to be completely dissolved, without in addition configuration and It is now with the current.Therefore hypochlorous acid solid state technology has irreplaceable advantage.
The content of the invention
Hypochlorous acid solid state technology will be pressed containing the compound for synthesizing each hypochlorous effective group together with stabilizer According to ratio mixing, exist in the way of solid powder.When powder is added to the water, each effective group and water react or using water as Carrier occurs mutually chemical reaction and produces hypochlorous acid, so as to be formed containing hypochlorous strong oxidizing solution.The present invention's is another Individual purpose is to provide the preparation method of described solid-state hypochlorous acid disinfectant powder.
To realize object above, the present invention is achieved through the following technical solutions:
A kind of solid-state hypochlorous acid disinfectant powder, rolls into a ball carrier, chloride ionophore and auxiliary agent composition, it is constituted by mass percentage by peroxide Component be:
Peroxide group's carrier: 10.3~45.5%
Chloride ionophore: 39.5~84.5%
Auxiliary agent: 10~15%
Described peroxide rolls into a ball carrier:Hydrogen peroxide, sodium peroxide, sodium perborate, potassium perborate, sodium percarbonate, potassium One or more in percarbonate, potassium persulfate, potassium perchlorate, potassium permanganate;
Described chloride ionophore is:One or more in sodium chloride, magnesium chloride, potassium chloride, iron chloride, frerrous chloride;
Described auxiliary agent is:The one or more of drier, buffer;
To realize above goal of the invention, a kind of preparation method of solid-state hypochlorous acid disinfectant powder of the invention is:
Each component is proportionally mixed into manufacture solid-state hypochlorous acid disinfectant powder by various methods;.
To realize above goal of the invention, a kind of specific preparation process of solid-state hypochlorous acid disinfectant powder of the invention is:
(1)By the carrier sieving of peroxide group, the particle below 149 μm of particle diameter is taken;
(2)Chloride ionophore is sieved, the particle below 149 μm of particle diameter is taken;
(3)Auxiliary agent is sieved, the particle below 149 μm of particle diameter is taken;
(4)The above-mentioned particle prepared is sufficiently mixed in medicine powder mixer, operating condition is 10 ~ 30r/min, 10 ~ 30 points Clock;
(5)Packaging is dispensed after weighing.
To realize object above, a kind of feature of the preparation method of solid-state hypochlorous acid disinfectant powder of the invention is that peroxide group carries Body and chlorion carry the application of selection and ratio in the preparation of solid-state hypochlorous acid disinfectant powder.
The positive effect of the present invention is:Hypochlorous acid solid state technology will contain the change for synthesizing each hypochlorous effective group Compound is proportionally mixed together with stabilizer, is existed in the way of solid powder.When powder is added to the water, each effective base Group reacts with water or occurred mutually using water as carrier chemical reaction and produces hypochlorous acid, so as to be formed containing hypochlorous high oxidative Solution.Hypochlorous acid solid state technology changes Traditional Transportation, storage and the occupation mode of hypochlorous acid class product.Greatly reduce biography The system hypochlorous danger of liquid, storage and transport need not be managed according to hazardous chemical.With traditional liquid hypochlorous acid class Product is compared and greatlys save hauled weight and storage area.And it is easy to use, product can react completely molten in cold water Solution, is configured and now with the current without other.Therefore hypochlorous acid solid state technology has irreplaceable advantage.
Embodiment
A kind of embodiment of solid-state hypochlorous acid disinfectant powder of the invention presented below and preparation method thereof, provides 1 altogether Individual embodiment, but the invention is not restricted to the embodiment provided;
Embodiment:
1. raw material:
Sodium peroxide 8kg, sodium percarbonate 8kg, potassium persulfate 14kg, sodium chloride 15kg, potassium chloride 10kg, magnesium chloride 5kg, Potassium dihydrogen phosphate 12kg, anhydrous calcium chloride 1kg;
2. preparation method:
(1)100 mesh sieves are crossed after 8kg sodium peroxides, 8kg sodium percarbonate and 14kg potassium persulfate are premixed, sieving particle is taken;
(2)15kg sodium chloride, 5kg magnesium chlorides, 10kg potassium chloride are sneaked out into 100 mesh sieves in advance in proportion, sieving particle is taken;
(3)By 12kg potassium dihydrogen phosphates, 1kg anhydrous calcium chlorides cross 100 mesh sieves, take sieving particle;
(4)The above-mentioned particle prepared is sufficiently mixed in medicine powder mixer, operating condition is 10 ~ 30r/min, 10 ~ 30 minutes;
(5)Packaging is dispensed after weighing;
Prepared solid-state hypochlorous acid disinfectant powder has the effect of high-effective disinfecting performance up to solid state hypochlorous acid and its aqueous solution.

Claims (2)

1. a kind of specific preparation process of solid-state hypochlorous acid disinfectant powder is:
(1)By the carrier sieving of peroxide group, the particle below 149 μm of particle diameter is taken;
(2)Chloride ionophore is sieved, the particle below 149 μm of particle diameter is taken;
(3)Auxiliary agent is sieved, the particle below 149 μm of particle diameter is taken;
(4)The above-mentioned particle prepared is sufficiently mixed in medicine powder mixer, operating condition is 10 ~ 30r/min, 10 ~ 30 points Clock;
(5)Packaging is dispensed after weighing.
2. a kind of solid-state hypochlorous acid disinfectant powder, carrier, chloride ionophore and auxiliary agent composition are rolled into a ball by peroxide, its structure by mass percentage Into component be:
Peroxide group's carrier: 10.3~45.5%
Chloride ionophore: 39.5~84.5%
Auxiliary agent: 10~15%
Described peroxide rolls into a ball carrier:Hydrogen peroxide, sodium peroxide, sodium perborate, potassium perborate, sodium percarbonate, potassium One or more in percarbonate, potassium persulfate, potassium perchlorate, potassium permanganate.
Described chloride ionophore is:One or more in sodium chloride, magnesium chloride, potassium chloride, iron chloride, frerrous chloride.
Described auxiliary agent is:The one or more of drier, buffer.
CN201710298117.6A 2017-04-30 2017-04-30 A kind of solid-state hypochlorous acid disinfectant powder and preparation method thereof Pending CN107094791A (en)

Priority Applications (1)

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CN201710298117.6A CN107094791A (en) 2017-04-30 2017-04-30 A kind of solid-state hypochlorous acid disinfectant powder and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710298117.6A CN107094791A (en) 2017-04-30 2017-04-30 A kind of solid-state hypochlorous acid disinfectant powder and preparation method thereof

Publications (1)

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CN107094791A true CN107094791A (en) 2017-08-29

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101049107A (en) * 2006-07-11 2007-10-10 成都润兴消毒药业有限公司 Sterilization powder, and preparation method.
CN204400609U (en) * 2015-01-09 2015-06-17 上海日洁环境科技有限公司 The device of a kind of hypochlorite solution of administration measure
CN105613573A (en) * 2014-11-05 2016-06-01 刘聪 Disinfectant

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101049107A (en) * 2006-07-11 2007-10-10 成都润兴消毒药业有限公司 Sterilization powder, and preparation method.
CN105613573A (en) * 2014-11-05 2016-06-01 刘聪 Disinfectant
CN204400609U (en) * 2015-01-09 2015-06-17 上海日洁环境科技有限公司 The device of a kind of hypochlorite solution of administration measure

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