CN107094762A - A kind of sterilized powder of unitary solid-state Peracetic acid and preparation method thereof - Google Patents
A kind of sterilized powder of unitary solid-state Peracetic acid and preparation method thereof Download PDFInfo
- Publication number
- CN107094762A CN107094762A CN201710298146.2A CN201710298146A CN107094762A CN 107094762 A CN107094762 A CN 107094762A CN 201710298146 A CN201710298146 A CN 201710298146A CN 107094762 A CN107094762 A CN 107094762A
- Authority
- CN
- China
- Prior art keywords
- peracetic acid
- peroxide
- carrier
- acid
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
It is a kind of sterilized powder of unitary solid-state Peracetic acid and preparation method thereof specifically the present invention relates to the manufacturing technology field of disinfectant.In the market Peracetic acid product type is a lot, but the storage of these products is transported and using all inconvenient.Peracetic acid solid state technology of the present invention changes the traditional mode of production of Peracetic acid, transport, storage and occupation mode.The danger of conventional liquid Peracetic acid is greatly reduced, storage and transport need not be managed according to hazardous chemical.Hauled weight and storage area are greatlyd save compared with traditional liquid Peracetic acid.And it is easy to use, product can react in cold water, simple to operate without configuration in addition and now with the current.Therefore Peracetic acid solid state technology has irreplaceable advantage.
Description
Technical field
It is that a kind of unitary solid-state Peracetic acid is efficiently gone out specifically the present invention relates to the manufacturing technology field of disinfectant
Bacterium powder and preparation method thereof.
Background technology
Peracetic acid also known as peracetic acid, are a kind of strong oxidizers, efficiently, sterilization is fast, is a kind of bactericidal agent for broad-spectrum.Pure peroxide
Acetic acid is extremely unstable, and high-explosive will occur at -20 DEG C, so the Peracetic acid that in the market is sold also has greatly the concentration to be
20-40%（20% is in the majority）The peracetic acid soln of left and right, but its property is also very unstable, and oxygen can be decomposed to give off at room temperature
Gas, meets naked light or high temperature occurs spontaneous combustion, burning or exploded.The solution of general high concentration is stable, but the sterilization prepared is used
Solution just it is unstable.
By the strong oxidation of itself, Peracetic acid first destroys the permeability barrier of gemma（Shell）, and then destroy
With dissolving core, make DNA, RNA, the material damage such as protein and DPA is spilt, and gemma is thus dead.
In the market Peracetic acid product forms are mainly：1）Peroxide acetate aqueous solution.2）Coordinate formulation（Liquid）, binary.
3) Its Accompanying Solid Peracetic Acid, binary is individually deposited, and is added water in proportion when using fused.But the storage of these products transport is with using
It is all inconvenient.Fluid product takes a large amount of volumes and weight weight, and binary solid product, which need to configure solution in addition and remix, to be used.
Peracetic acid solid state technology is by compound and the stabilizer one of each effective group containing synthesis Peracetic acid
Rise and proportionally mix, exist in the way of Monophyletic solid powder.When powder is added to the water, each effective group reacts with water
Or occur chemical reaction generation Peracetic acid mutually using water as carrier, so as to form peracetic acid soln.Peracetic acid solid state
Technology changes the traditional mode of production of Peracetic acid, transport, storage and occupation mode.Greatly reduce conventional liquid Peracetic acid
Danger, storage and transport need not be managed according to hazardous chemical.Greatlyd save compared with traditional liquid Peracetic acid
Hauled weight and storage area.And it is easy to use, product can react in cold water, be configured and now with the current without other.
Therefore Peracetic acid solid state technology has irreplaceable advantage.
The content of the invention
The present invention proportionally mixes the compound of each effective group containing synthesis Peracetic acid together with stabilizer
Close, exist in the way of Monophyletic solid powder.When powder is added to the water, each effective group reacts with water or using water as carrier
Chemical reaction occurs mutually and produces Peracetic acid, so as to form peracetic acid soln；It is a further object of the invention to provide institute
The preparation method for the sterilized powder of unitary solid-state Peracetic acid stated.
To realize object above, the present invention is achieved through the following technical solutions：
A kind of sterilized powder of unitary solid-state Peracetic acid, by acetyl carrier, peroxide radical ion carrier, stabilizer, interface is lived
Property agent and auxiliary agent composition, its component constituted by mass percentage is：
Acetyl carrier： 10.3~45.6%
Peroxide radical ion carrier： 9.5~35.5%
Stabilizer： 10~50%
Interfacial agent： 0.1~5%
Auxiliary agent： 1~5%
Described acetyl carrier is：Containing activation acetyl group compound, to diacetyl ethylenediamine, chloroacetic chloride, acetyl ethamine,
The tetra-acetylated imidazolidine of acetic anhydride, 1,3,4,6- simultaneously [4,5-D] imidazoles -2,5 (1H, 3H)-diketone, tetraacetyl ethylene diamine, ice
One or more in acetic acid；
Described peroxide radical ion carrier is：Organic peroxide or inorganic peroxide, hydroperoxides, dialkyl group peroxidating
Thing, diacyl peroxide, peroxy esters, peroxycarbonates, ketone peroxide, perbenzoic acid, cumenyl peroxy esters,
One or more in hydrogen peroxide, sodium peroxide, perborate, percarbonate；
Described stabilizer is：Disodium hydrogen phosphate, dipotassium hydrogen phosphate, sodium dihydrogen phosphate, potassium dihydrogen phosphate, sodium acid carbonate, acetic acid
One or more in sodium, sodium tetraborate；
Described interfacial agent is：One or more in stearic acid, neopelex, quaternary ammonium compound；
Described auxiliary agent is：Drier, the one or more for preventing oxidant；
To realize above goal of the invention, a kind of preparation method of the sterilized powder of unitary solid-state Peracetic acid of the invention is：
By various methods by after each component fine gtinding and sieving, unitary solid-state Peracetic acid is manufactured according still further to ratio mixing
Sterilized powder.
To realize above goal of the invention, a kind of specific preparation process of the sterilized powder of unitary solid-state Peracetic acid of the invention
For：
（1）Acetyl carrier is ground and sieved, the particle below 105 μm of particle diameter is taken；
（2）Cryogrinding sieves after peroxide radical ion carrier, stabilizer and auxiliary agent are premixed in proportion, takes below 149 μm of particle diameter
Particle, operation temperature be 5 ~ 15 DEG C；
（3）Interfacial agent is ground and sieved, the particle below 149 μm of particle diameter is taken；
（4）The above-mentioned particle prepared is sufficiently mixed in medicine powder mixer, operating condition is 10 ~ 30r/min, 10 ~ 30 points
Clock；
（5）Packaging is dispensed after weighing；
To realize object above, a kind of feature of the preparation method of the sterilized powder of unitary solid-state Peracetic acid of the invention is, second
The selection of acyl carrier and peroxide radical ion carrier and its stabilizer and auxiliary agent and ratio are efficiently gone out in unitary solid-state Peracetic acid
Application in bacterium powder preparation.
The positive effect of the present invention is：Peracetic acid solid state technology will contain each the effective group for synthesizing Peracetic acid
Compound proportionally mixed together with stabilizer, exist in the way of Monophyletic solid powder.When powder is added to the water, respectively
Individual effective group reacts with water or occurred mutually using water as carrier chemical reaction and produces Peracetic acid, so that it is molten to form Peracetic acid
Liquid.Peracetic acid solid state technology changes the traditional mode of production of Peracetic acid, transport, storage and occupation mode.Greatly reduce
The danger of conventional liquid Peracetic acid, storage and transport need not be managed according to hazardous chemical.With traditional liquid peroxide
Acetic acid is compared and greatlys save hauled weight and storage area.And it is easy to use, product can react in cold water, without another
It is outer to configure and now with the current.Therefore Peracetic acid solid state technology has irreplaceable advantage.
Embodiment
A kind of specific embodiment party of sterilized powder of unitary solid-state Peracetic acid of the invention presented below and preparation method thereof
Formula, provides 1 embodiment altogether, but the invention is not restricted to the embodiment provided；
Embodiment：
1. raw material：
To diacetyl ethylenediamine 27kg, 1,3,4,6- tetra-acetylated imidazolidine simultaneously [4,5-D] imidazoles -2,5 (1H, 3H)-diketone
21kg, tetraacetyl ethylene diamine 8kg, sodium perborate 55kg, bi-quaternary ammonium salt 10kg, disodium hydrogen phosphate 21kg, potassium dihydrogen phosphate 22kg,
Anhydrous calcium chloride 1kg；
2. preparation method：
（1）By 27kg diacetyl ethylenediamines, the tetra-acetylated imidazolidines of 21kg1,3,4,6- simultaneously [4,5-D] imidazoles -2,5 (1H,
Ground 140 mesh sieve after 3H)-diketone and 8kg tetraacetyl ethylene diamines premix, takes sieving particle；
（2）55kg sodium perborate, 21kg disodium hydrogen phosphates, 22kg potassium dihydrogen phosphates and 1kg anhydrous calcium chlorides are premixed in proportion
Cryogrinding crosses 100 mesh sieves afterwards, takes sieving particle, and operation temperature is 10 DEG C；
（3）By ground 100 mesh sieve of 10kg bi-quaternary ammonium salts, sieving particle is taken；
（4）The above-mentioned particle prepared is sufficiently mixed in medicine powder mixer, operating condition is 10 ~ 30r/min, 10 ~ 30 minutes；
（5）Packaging is dispensed after weighing；
The prepared sterilized powder of unitary solid-state Peracetic acid has efficient up to solid state Peracetic acid and its aqueous solution
The effect of sterilization ability.
Claims (2)
1. a kind of preparation method of the sterilized powder of unitary solid-state Peracetic acid, specific preparation section is：
Acetyl carrier is ground and sieved, the particle below 105 μm of particle diameter is taken；
Cryogrinding sieves after peroxide radical ion carrier, stabilizer and auxiliary agent are premixed in proportion, takes below 149 μm of particle diameter
Grain, operation temperature is 5 ~ 15 DEG C；
Interfacial agent is ground and sieved, the particle below 149 μm of particle diameter is taken；
The above-mentioned particle prepared is sufficiently mixed in medicine powder mixer, operating condition is 10 ~ 30r/min, 10 ~ 30 minutes；
Packaging is dispensed after weighing.
2. a kind of formula of the sterilized powder of unitary solid-state Peracetic acid, its component constituted by mass percentage is：
Acetyl carrier： 10.3~45.6%
Peroxide radical ion carrier： 9.5~35.5%
Stabilizer： 10~50%
Interfacial agent： 0.1~5%
Auxiliary agent： 1~5%
Described acetyl carrier is：Containing activation acetyl group compound, to diacetyl ethylenediamine, chloroacetic chloride, acetyl ethamine,
The tetra-acetylated imidazolidine of acetic anhydride, 1,3,4,6- simultaneously [4,5-D] imidazoles -2,5 (1H, 3H)-diketone, tetraacetyl ethylene diamine, ice
One or more in acetic acid；
Described peroxide radical ion carrier is：Organic peroxide or inorganic peroxide, hydroperoxides, dialkyl group peroxidating
Thing, diacyl peroxide, peroxy esters, peroxycarbonates, ketone peroxide, perbenzoic acid, cumenyl peroxy esters,
One or more in hydrogen peroxide, sodium peroxide, perborate, percarbonate；
Described stabilizer is：Disodium hydrogen phosphate, dipotassium hydrogen phosphate, sodium dihydrogen phosphate, potassium dihydrogen phosphate, sodium acid carbonate, acetic acid
One or more in sodium, sodium tetraborate；
Described interfacial agent is：One or more in stearic acid, neopelex, quaternary ammonium compound；
Described auxiliary agent is：Drier, the one or more for preventing oxidant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710298146.2A CN107094762A (en) | 2017-04-30 | 2017-04-30 | A kind of sterilized powder of unitary solid-state Peracetic acid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710298146.2A CN107094762A (en) | 2017-04-30 | 2017-04-30 | A kind of sterilized powder of unitary solid-state Peracetic acid and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107094762A true CN107094762A (en) | 2017-08-29 |
Family
ID=59657441
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710298146.2A Pending CN107094762A (en) | 2017-04-30 | 2017-04-30 | A kind of sterilized powder of unitary solid-state Peracetic acid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107094762A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108064879A (en) * | 2017-11-27 | 2018-05-25 | 中国人民解放军陆军防化学院 | The application method of Compositional type solid fumigant |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1128257A (en) * | 1994-07-22 | 1996-08-07 | 段庆楠 | Solid chemicals for preparing peroxyacetic acid and its preparation method |
| CN102415380A (en) * | 2011-10-18 | 2012-04-18 | 中国人民解放军疾病预防控制所 | Low-corrosivity peracetic acid solid generating agent and preparation method and application thereof |
| CN104621180A (en) * | 2015-02-02 | 2015-05-20 | 山东威高药业股份有限公司 | Novel sterilization powder |
-
2017
- 2017-04-30 CN CN201710298146.2A patent/CN107094762A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1128257A (en) * | 1994-07-22 | 1996-08-07 | 段庆楠 | Solid chemicals for preparing peroxyacetic acid and its preparation method |
| CN102415380A (en) * | 2011-10-18 | 2012-04-18 | 中国人民解放军疾病预防控制所 | Low-corrosivity peracetic acid solid generating agent and preparation method and application thereof |
| CN104621180A (en) * | 2015-02-02 | 2015-05-20 | 山东威高药业股份有限公司 | Novel sterilization powder |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108064879A (en) * | 2017-11-27 | 2018-05-25 | 中国人民解放军陆军防化学院 | The application method of Compositional type solid fumigant |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105145626B (en) | A kind of immobilized gel chlorine dioxide air cleanser of aroma type | |
| AU720557B2 (en) | Preparation and use of biocidal solutions | |
| US20060088498A1 (en) | Anti-microbial composition using in-situ generation of an oxidizing agent | |
| EP3068222B1 (en) | Disinfectant composition | |
| US7204931B2 (en) | Stable composition with enhanced biocidal and virucidal effect | |
| CN101999405B (en) | Unitary solid chlorine dioxide sustained-release generating agent and preparation method thereof | |
| TW200827437A (en) | A one part, solids containing decontamination blend composition | |
| US20050249658A1 (en) | Solid chlorine dioxide releasing compositions having increased temperature stability and method for delivery of solid chlorine dioxide releasing compositions | |
| CN103621554B (en) | A kind of chlorine dioxide generating agent and preparation method thereof | |
| EP0133354A1 (en) | Denture cleansing compositions | |
| WO2006020248A2 (en) | A solvent-activated reactor | |
| CN102669176A (en) | Slow-release chlorine dioxide solid disinfectant | |
| CA2665523A1 (en) | Method for producing stable, monodispersed, nanometric magnesium hydroxide and resulting product | |
| CN102379310A (en) | Unitary-package-reaction-type chlorine dioxide tablet and preparation method thereof | |
| CN107094762A (en) | A kind of sterilized powder of unitary solid-state Peracetic acid and preparation method thereof | |
| CN102379309A (en) | Binary-packaged reactive chlorine dioxide tablet and preparation method thereof | |
| CN105010389B (en) | A kind of slow released ClO 2 pulvis and preparation method thereof | |
| CN101124914A (en) | Mixing disinfectant containing chlorine dioxide and preparing process thereof | |
| CN101411334A (en) | A kind of production method of disinfection agent of chlorine dioxide | |
| CN109730085A (en) | A kind of disinfecting substance generating agent and preparation method thereof | |
| JPH0437119B2 (en) | ||
| JPH0559960B2 (en) | ||
| CN103314956A (en) | Sustained-release solid ClO2 disinfectant and preparation method and application thereof | |
| CN107094791A (en) | A kind of solid-state hypochlorous acid disinfectant powder and preparation method thereof | |
| JP2009523714A5 (en) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170829 |