CN103621554B - A kind of chlorine dioxide generating agent and preparation method thereof - Google Patents
A kind of chlorine dioxide generating agent and preparation method thereof Download PDFInfo
- Publication number
- CN103621554B CN103621554B CN201310568132.XA CN201310568132A CN103621554B CN 103621554 B CN103621554 B CN 103621554B CN 201310568132 A CN201310568132 A CN 201310568132A CN 103621554 B CN103621554 B CN 103621554B
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- CN
- China
- Prior art keywords
- water
- chlorine dioxide
- passivator
- benzenesulfonic acid
- methyl benzenesulfonic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 72
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 36
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims abstract description 38
- 229960002218 sodium chlorite Drugs 0.000 claims abstract description 38
- 239000003230 hygroscopic agent Substances 0.000 claims abstract description 30
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000007787 solid Substances 0.000 claims abstract description 17
- 239000002535 acidifier Substances 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 8
- 238000010348 incorporation Methods 0.000 claims description 4
- VISKNDGJUCDNMS-UHFFFAOYSA-M potassium;chlorite Chemical compound [K+].[O-]Cl=O VISKNDGJUCDNMS-UHFFFAOYSA-M 0.000 abstract description 13
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 4
- 238000000227 grinding Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 238000004806 packaging method and process Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000000645 desinfectant Substances 0.000 description 8
- 239000003380 propellant Substances 0.000 description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 239000001110 calcium chloride Substances 0.000 description 4
- 229910001628 calcium chloride Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- -1 contain acidization Chemical compound 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019249 food preservative Nutrition 0.000 description 1
- 239000005452 food preservative Substances 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
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CN201310568132.XA CN103621554B (en) | 2013-11-14 | 2013-11-14 | A kind of chlorine dioxide generating agent and preparation method thereof |
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CN201310568132.XA CN103621554B (en) | 2013-11-14 | 2013-11-14 | A kind of chlorine dioxide generating agent and preparation method thereof |
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CN103621554A CN103621554A (en) | 2014-03-12 |
CN103621554B true CN103621554B (en) | 2016-04-20 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114890485A (en) * | 2022-06-09 | 2022-08-12 | 四川环科检测技术有限公司 | Efficient algae removal medicament bag and preparation method and application thereof |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108402075A (en) * | 2018-04-28 | 2018-08-17 | 汉广中药科技(天津)有限公司 | A kind of compound Chinese medicinal material curing agent and preparation method and application of long-acting controllable sustained-release chlorine dioxide |
CN108946669B (en) * | 2018-07-13 | 2022-04-15 | 艾波 | Gaseous chlorine dioxide initiator and gaseous chlorine dioxide generating agent containing same |
CN109730085A (en) * | 2018-12-30 | 2019-05-10 | 河北润宝环硕科技发展有限公司 | A kind of disinfecting substance generating agent and preparation method thereof |
CN111514355A (en) * | 2020-06-01 | 2020-08-11 | 邱燕军 | Chlorine dioxide effervescent tablet slow-release wet cotton box |
CN112120020A (en) * | 2020-10-19 | 2020-12-25 | 任建军 | Chlorine dioxide slow-release particle sterilizing disinfectant and preparation method thereof |
CN114027319A (en) * | 2021-12-15 | 2022-02-11 | 佛山市南海东方澳龙制药有限公司 | Chlorine dioxide disinfectant and preparation method thereof |
CN115363024B (en) * | 2022-08-31 | 2024-05-03 | 陕西厚亿节能环保新材料科技有限公司 | Preparation method of slow-release type immobilized chlorine dioxide air purifying agent |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1238130A (en) * | 1999-06-14 | 1999-12-15 | 宋红安 | Powdered CLO2 disinfectant and preparing process thereof |
CN101176446A (en) * | 2006-11-10 | 2008-05-14 | 宋小芳 | Novel mildew resistant tablet and preparation method thereof |
CN101177244A (en) * | 2006-11-06 | 2008-05-14 | 叶青 | Preparation of solid chlorine dioxide |
EP1969938A2 (en) * | 2007-03-16 | 2008-09-17 | Bou-Matic Technologies Corporation | Stabilized chlorine dioxide and hypochlorous acid in a liquid biocide |
CN101384507A (en) * | 2006-02-17 | 2009-03-11 | 大幸药品株式会社 | Chlorine dioxide generating composition |
-
2013
- 2013-11-14 CN CN201310568132.XA patent/CN103621554B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1238130A (en) * | 1999-06-14 | 1999-12-15 | 宋红安 | Powdered CLO2 disinfectant and preparing process thereof |
CN101384507A (en) * | 2006-02-17 | 2009-03-11 | 大幸药品株式会社 | Chlorine dioxide generating composition |
CN101177244A (en) * | 2006-11-06 | 2008-05-14 | 叶青 | Preparation of solid chlorine dioxide |
CN101176446A (en) * | 2006-11-10 | 2008-05-14 | 宋小芳 | Novel mildew resistant tablet and preparation method thereof |
EP1969938A2 (en) * | 2007-03-16 | 2008-09-17 | Bou-Matic Technologies Corporation | Stabilized chlorine dioxide and hypochlorous acid in a liquid biocide |
Non-Patent Citations (1)
Title |
---|
二氧化氯固体制剂的开发研究进展;贺启环 等;《化工标准.计量.质量 》;20040930(第9期);1-8 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114890485A (en) * | 2022-06-09 | 2022-08-12 | 四川环科检测技术有限公司 | Efficient algae removal medicament bag and preparation method and application thereof |
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CN103621554A (en) | 2014-03-12 |
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Effective date of registration: 20210115 Address after: 310000 room 402, 35 Kangning street, Xiacheng District, Hangzhou City, Zhejiang Province Patentee after: Hello cloud business technology (Hangzhou) Co.,Ltd. Address before: 310027 No. 38, Zhejiang Road, Hangzhou, Zhejiang, Xihu District Patentee before: ZHEJIANG University |
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Effective date of registration: 20230323 Address after: Room 103, No. 35, Kangning Street, Gongshu District, Hangzhou City, Zhejiang Province, 310000 Patentee after: Hangzhou Restoration Times Technology Innovation Co.,Ltd. Address before: 310000 room 402, 35 Kangning street, Xiacheng District, Hangzhou City, Zhejiang Province Patentee before: Hello cloud business technology (Hangzhou) Co.,Ltd. |
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Effective date of registration: 20240318 Address after: Room 802-4, Unit 1, Building 1, Yile Yinzuo, Xiacheng District, Hangzhou, Zhejiang 310000 Patentee after: Hangzhou Breathing Declaration Health Technology Co.,Ltd. Country or region after: China Address before: Room 103, No. 35, Kangning Street, Gongshu District, Hangzhou City, Zhejiang Province, 310000 Patentee before: Hangzhou Restoration Times Technology Innovation Co.,Ltd. Country or region before: China |