CN101177244A - Preparation of solid chlorine dioxide - Google Patents
Preparation of solid chlorine dioxide Download PDFInfo
- Publication number
- CN101177244A CN101177244A CNA2006101460830A CN200610146083A CN101177244A CN 101177244 A CN101177244 A CN 101177244A CN A2006101460830 A CNA2006101460830 A CN A2006101460830A CN 200610146083 A CN200610146083 A CN 200610146083A CN 101177244 A CN101177244 A CN 101177244A
- Authority
- CN
- China
- Prior art keywords
- chlorine dioxide
- solid
- acid
- monobasic
- stablizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention relates to a preparation method for unified packing of the solid chlorine dioxide, which comprises the adsorbent, the sodium chlorite (or 5 to 6% stable chlorine dioxide water- solution), the solid acid and the stabilizing agent.
Description
The present invention relates to the preparation that a kind of monobasic of being made up of Textone and solid acid (activator), stablizer is packed solid chlorine dioxide.
Dioxide peroxide is efficient, wide spectrum, multifunctional disinfectant.Be gas at normal temperatures, but because unstable properties makes production, transportation, the storage of dioxide peroxide all comparatively difficult, applying of dioxide peroxide is restricted.Though since last century the seventies, the emerging company of U.S. lily at first succeeds in developing a kind of stability chlorine dioxide aqueous solution, to add acid (citric acid etc.) in addition when using and activate, dioxide peroxide is discharged, be two-component packaging, very inconvenient, nowadays on the verge of being replaced.Therefore, the development of monobasic packing Pickering dioxide peroxide is subjected to the attention of domestic and international scientific and technological circle.
So far, aspect the research of solid chlorine dioxide, mainly be divided into adsorptive type and response type two classes, made product has tablet, pulvis, and its packing has unary form and binary form.From adsorptive type, also can be made into sustained release dosage (long-acting) solid chlorine dioxide, mainly as purifying air, deodorizing, fresh-keeping.
The adsorptive type solid chlorine dioxide adopts the adsorbents adsorb stability chlorine dioxide aqueous solution.Add other additive again and mix earlier, or compressing tablet (CN1195641A).Need to obtain in advance the stability chlorine dioxide aqueous solution.
The response type solid chlorine dioxide is mainly formed with solid Textone and solid acid (being citric acid, tartrate etc.), and this series products is a two-component packaging, drops into together during use to activate in the water, uses inconvenience, transformation efficiency lower (ZL93121244.8).
Slow-release solid chlorine dioxide generally is to mix with solid acid and other additive with the sorbent material stability chlorine dioxide aqueous solution (or Textone), and it the most important thing is and should control the release rate of dioxide peroxide well by service requirements.
Typical case comparatively, and a kind of tablet manufacturing method that can obtain high conversion in recent years comes into one's own, (U.S.P6432322).Mainly be to adopt chlorite, dichlorocyanuric acid sodium salt, hydrosulfate, molecular sieve etc., form, every 1 gram through mixing, compressing tablet.The development aspect of monobasic packing solid chlorine dioxide tablet at home generally still exists in the tablet effective constituent relatively low, and compressing tablet is big with other material relative proportion, makes the cost pulvis more suitable than effective ingredient higher.When simultaneously, tablet uses in water the consoluet time longer.
In solid chlorine dioxide preparation involved in the present invention, the sorbent material that can adopt has: Calucium Silicate powder, silicon-dioxide, super absorbent resin, gac, diatomite, molecular sieve etc.; Solid acid has: citric acid, tartrate, hydrosulphite, hydrosulfate, pyrosulfite, phthalic acid, aluminum chloride, iron trichloride; Stablizer has magnesium chloride, vitriolate of tartar, sal epsom, sodium sulfate etc.
Available two kinds of methods prepare monobasic packing solid chlorine dioxide, and its raw material weight is such as following:
(a) sorbent material: Textone: solid acid: stablizer
＝(40～85)∶(2～20)∶(3～25)∶(10～15)
(b) sorbent material: 5～6% stability chlorine dioxide aqueous solution: solid acid: stablizer
＝(15～85)∶(10～60)∶(2～10)∶(3～15)
Only need Textone (or 5-6% stability chlorine dioxide aqueous solution) is adsorbed in the solid adsorbent, mix with solid acid and stablizer again.But the raw materials used dried powder that all should be.
In use acid is discharged, just produced dioxide peroxide owing to absorb water in air part.And the character of solid acid can influence the release rate of dioxide peroxide.The burst size of acid and pH value descend direct relation, and the available adjustment pH value is controlled the release rate of dioxide peroxide.And the validity period of solid chlorine dioxide is also relevant with the adsorptive capacity of Textone (or 5-6% stability chlorine dioxide aqueous solution).Release rate and validity period should be considered user's needs.
Pulvis among the present invention generally is applicable under the environment that requires the snap-out release dioxide peroxide (as sterilization, sterilization) and is used for fresh-keeping or purifying air etc. the sustained release dosage.The prescription difference of pulvis and sustained release dosage mainly is that the character and the consumption of used acid is inequality, and the consumption of Textone (or 5-6% stability chlorine dioxide) is also inequality simultaneously.But the pH value of product should be alkalescence, and pH value is generally 6～9.
Example of the present invention is as follows:
Example one:
Get 2 parts of Textones, 80 parts of Calucium Silicate powder, 3 parts of citric acids, 15 parts of thorough mixing of vitriolate of tartar, packing.Obtain pulvis.
Example two:
Get 30 parts of the 5-6% stability chlorine dioxide aqueous solution,, soak 30 minutes (or in stirring, spraying) 50 parts of silicon-dioxide, airing, with 10 parts of the citric acids after pulverizing, sal epsom is mixed together for 10 parts, and packing obtains sustained release dosage.
Example three:
Get 2 parts of calcium chlorites, 80 parts in diatomite, 3 parts of adjacent benzene tricarboxylic acids, 15 parts in sodium sulfate mixes, is packaged to be sustained release dosage.
Example four:
Get 33 parts of Calucium Silicate powder, soaked 30 minutes for 60 parts with the 5-6% stability chlorine dioxide aqueous solution, airing, with 5 parts in sal epsom, 2 parts of mixing of Sodium Pyrosulfite, packing obtain sustained release dosage.
Claims (5)
1. a monobasic of being made up of sorbent material, Textone (or 5-6% stability chlorine dioxide aqueous solution) and solid acid, stablizer is packed the solid chlorine dioxide preparation method.
2. according to the prepared monobasic packing solid chlorine dioxide of claim 1, the weight ratio of its constituent is as follows:
(a) sorbent material: Textone: solid acid: stablizer
＝(40～85)∶(2～20)∶(3～25)∶(10～15)
(b) sorbent material: the 5-6% stability chlorine dioxide aqueous solution: solid acid: stablizer
＝(15～85)∶(10～60)∶(2～10)∶(3～15)
3. according to the prepared monobasic packing solid chlorine dioxide of claim 1, the sorbent material during it is formed is Calucium Silicate powder, super absorbent resin, activated carbon, diatomite, silicon-dioxide, molecular sieve.Solid acid is: citric acid, oxysuccinic acid, tartrate, hydrosulphite, hydrosulfate, Sodium Pyrosulfite (or potassium), aluminum chloride, phthalic acid, iron trichloride.Stablizer is: magnesium chloride, sal epsom, sodium sulfate, vitriolate of tartar etc.
4. in the monobasic wrapped product of being produced according to claim 1,2,3, comprise the pulvis that is used for sterilization, deodorizing, fresh-keeping usefulness and be mainly used in fresh-keeping slow-release solid chlorine dioxide.
5. according to the prepared monobasic packing solid chlorine dioxide of claim 1～4, the monobasic of its finished product is packaged as the slow-release solid chlorine dioxide of every bag 1～5 gram (also can adjust on demand) or packs with the compound bag of moulding, every bag 1～20 gram (also can adjust on demand) powdery solid dioxide peroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006101460830A CN101177244A (en) | 2006-11-06 | 2006-11-06 | Preparation of solid chlorine dioxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006101460830A CN101177244A (en) | 2006-11-06 | 2006-11-06 | Preparation of solid chlorine dioxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101177244A true CN101177244A (en) | 2008-05-14 |
Family
ID=39403695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006101460830A Pending CN101177244A (en) | 2006-11-06 | 2006-11-06 | Preparation of solid chlorine dioxide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101177244A (en) |
Cited By (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101803610A (en) * | 2010-03-22 | 2010-08-18 | 北京欧凯纳斯科技有限公司 | Self regulation and control type chlorine dioxide combination and application thereof in tobacco warehouse storage |
| CN101822287A (en) * | 2010-04-15 | 2010-09-08 | 浙江温州轻工研究院 | Fruit and vegetable fresh-keeping agent and preparation method thereof |
| CN102106375A (en) * | 2009-12-29 | 2011-06-29 | 新疆大学 | Solid chloride dioxide generating agent |
| CN102835421A (en) * | 2012-09-26 | 2012-12-26 | 深圳万和制药有限公司 | Stable product containing chlorine dioxide and preparation method of stable product |
| CN102847181A (en) * | 2012-09-26 | 2013-01-02 | 深圳万和制药有限公司 | Product capable of delaying generation and releasing of chlorine dioxide and preparation method thereof |
| CN103621554A (en) * | 2013-11-14 | 2014-03-12 | 浙江大学 | Chlorine dioxide generator and preparation method thereof |
| CN104174269A (en) * | 2014-08-29 | 2014-12-03 | 成都顺发消洗科技有限公司 | Preparation method of slow-release chlorine dioxide powder |
| CN104208733A (en) * | 2014-08-29 | 2014-12-17 | 成都顺发消洗科技有限公司 | Sustained-release chlorine dioxide powder applicable to purifying indoor air |
| CN104255785A (en) * | 2014-08-26 | 2015-01-07 | 艾波 | Long-acting controllable chlorine dioxide sustained release agent |
| CN104255788A (en) * | 2014-08-29 | 2015-01-07 | 成都顺发消洗科技有限公司 | Slow-release chlorine dioxide sterilizing and purifying powder and preparation method thereof |
| CN104286147A (en) * | 2014-10-20 | 2015-01-21 | 柳州市天姿园艺有限公司 | Preservative |
| CN104304429A (en) * | 2014-10-20 | 2015-01-28 | 柳州市天姿园艺有限公司 | Fruit-vegetable fresh-keeping method |
| CN104304428A (en) * | 2014-10-20 | 2015-01-28 | 柳州市天姿园艺有限公司 | Method for preparing preservative |
| CN104351325A (en) * | 2014-10-20 | 2015-02-18 | 柳州市天姿园艺有限公司 | Preparation method of preservative |
| CN104381428A (en) * | 2014-10-20 | 2015-03-04 | 柳州市天姿园艺有限公司 | Fruit and vegetable fresh-keeping method |
| CN104381431A (en) * | 2014-10-20 | 2015-03-04 | 柳州市天姿园艺有限公司 | Preservative |
| CN104557690A (en) * | 2013-10-23 | 2015-04-29 | 丹阳恒安化学科技研究所有限公司 | Method for preparing amrinone midbody |
| CN104891442A (en) * | 2015-05-06 | 2015-09-09 | 湖北南五洲生化科技有限公司 | Method for preparing high-purity chlorine dioxide |
| CN105010389A (en) * | 2014-04-30 | 2015-11-04 | 四川新天地环保科技有限公司 | Slow-release chlorine dioxide powder and preparation method thereof |
| CN106614558A (en) * | 2016-12-18 | 2017-05-10 | 钦州阜康农副食品有限公司 | Solid chlorine dioxide controlled release formulation and preparation method thereof |
| CN106835799A (en) * | 2017-03-13 | 2017-06-13 | 广西大学 | A kind of method for improving ClO 2 solution stability |
| CN106865501A (en) * | 2015-12-11 | 2017-06-20 | 深圳市罗奇环保科技有限公司 | The absorption process of chlorine dioxide |
| CN108402075A (en) * | 2018-04-28 | 2018-08-17 | 汉广中药科技（天津）有限公司 | A kind of compound Chinese medicinal material curing agent and preparation method and application of long-acting controllable sustained-release chlorine dioxide |
| CN108751385A (en) * | 2018-04-24 | 2018-11-06 | 苏州国科芯感医疗科技有限公司 | Solid chlorine dioxide slow-release material and preparation method thereof |
| CN108904850A (en) * | 2018-06-14 | 2018-11-30 | 长沙标朗住工科技有限公司 | A kind of persistence eliminates the unusual smell ointment and preparation method thereof |
| CN108991007A (en) * | 2018-08-20 | 2018-12-14 | 青岛大学 | A kind of safe slow released ClO 2 disinfectant and preparation method thereof |
| CN109996761A (en) * | 2017-09-29 | 2019-07-09 | 株式会社阿玛特拉 | Method for generation, the chlorine dioxide of chlorine dioxide occur to use set group and gel-form composition |
| JP2019202918A (en) * | 2018-05-25 | 2019-11-28 | 株式会社環境衛生 | Chlorine dioxide generating powder and chlorine dioxide generator |
| CN111387205A (en) * | 2020-04-20 | 2020-07-10 | 健康源(广州)投资合伙企业(有限合伙) | Long-acting chlorine dioxide slow-release composite material and preparation method thereof |
| CN111436456A (en) * | 2020-05-09 | 2020-07-24 | 南京协心健康科技有限公司 | Chlorine dioxide solution spray and preparation method thereof |
-
2006
- 2006-11-06 CN CNA2006101460830A patent/CN101177244A/en active Pending
Cited By (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102106375A (en) * | 2009-12-29 | 2011-06-29 | 新疆大学 | Solid chloride dioxide generating agent |
| CN101803610B (en) * | 2010-03-22 | 2012-07-18 | 北京欧凯纳斯科技有限公司 | Self regulation and control type chlorine dioxide combination and application thereof in tobacco warehouse storage |
| CN101803610A (en) * | 2010-03-22 | 2010-08-18 | 北京欧凯纳斯科技有限公司 | Self regulation and control type chlorine dioxide combination and application thereof in tobacco warehouse storage |
| CN101822287A (en) * | 2010-04-15 | 2010-09-08 | 浙江温州轻工研究院 | Fruit and vegetable fresh-keeping agent and preparation method thereof |
| CN101822287B (en) * | 2010-04-15 | 2013-02-20 | 浙江温州轻工研究院 | Fruit and vegetable fresh-keeping agent and preparation method thereof |
| CN102835421A (en) * | 2012-09-26 | 2012-12-26 | 深圳万和制药有限公司 | Stable product containing chlorine dioxide and preparation method of stable product |
| CN102847181A (en) * | 2012-09-26 | 2013-01-02 | 深圳万和制药有限公司 | Product capable of delaying generation and releasing of chlorine dioxide and preparation method thereof |
| CN104557690A (en) * | 2013-10-23 | 2015-04-29 | 丹阳恒安化学科技研究所有限公司 | Method for preparing amrinone midbody |
| CN103621554A (en) * | 2013-11-14 | 2014-03-12 | 浙江大学 | Chlorine dioxide generator and preparation method thereof |
| CN103621554B (en) * | 2013-11-14 | 2016-04-20 | 浙江大学 | A kind of chlorine dioxide generating agent and preparation method thereof |
| CN105010389A (en) * | 2014-04-30 | 2015-11-04 | 四川新天地环保科技有限公司 | Slow-release chlorine dioxide powder and preparation method thereof |
| CN104255785A (en) * | 2014-08-26 | 2015-01-07 | 艾波 | Long-acting controllable chlorine dioxide sustained release agent |
| CN104208733A (en) * | 2014-08-29 | 2014-12-17 | 成都顺发消洗科技有限公司 | Sustained-release chlorine dioxide powder applicable to purifying indoor air |
| CN104255788A (en) * | 2014-08-29 | 2015-01-07 | 成都顺发消洗科技有限公司 | Slow-release chlorine dioxide sterilizing and purifying powder and preparation method thereof |
| CN104174269A (en) * | 2014-08-29 | 2014-12-03 | 成都顺发消洗科技有限公司 | Preparation method of slow-release chlorine dioxide powder |
| CN104174269B (en) * | 2014-08-29 | 2016-08-24 | 成都顺发消洗科技有限公司 | A kind of preparation method of slow released ClO 2 powder |
| CN104304429A (en) * | 2014-10-20 | 2015-01-28 | 柳州市天姿园艺有限公司 | Fruit-vegetable fresh-keeping method |
| CN104304428A (en) * | 2014-10-20 | 2015-01-28 | 柳州市天姿园艺有限公司 | Method for preparing preservative |
| CN104351325A (en) * | 2014-10-20 | 2015-02-18 | 柳州市天姿园艺有限公司 | Preparation method of preservative |
| CN104381428A (en) * | 2014-10-20 | 2015-03-04 | 柳州市天姿园艺有限公司 | Fruit and vegetable fresh-keeping method |
| CN104381431A (en) * | 2014-10-20 | 2015-03-04 | 柳州市天姿园艺有限公司 | Preservative |
| CN104286147A (en) * | 2014-10-20 | 2015-01-21 | 柳州市天姿园艺有限公司 | Preservative |
| CN104891442A (en) * | 2015-05-06 | 2015-09-09 | 湖北南五洲生化科技有限公司 | Method for preparing high-purity chlorine dioxide |
| CN106865501A (en) * | 2015-12-11 | 2017-06-20 | 深圳市罗奇环保科技有限公司 | The absorption process of chlorine dioxide |
| CN106865501B (en) * | 2015-12-11 | 2019-03-22 | 深圳市罗奇环保科技有限公司 | The absorption process of chlorine dioxide |
| CN106614558A (en) * | 2016-12-18 | 2017-05-10 | 钦州阜康农副食品有限公司 | Solid chlorine dioxide controlled release formulation and preparation method thereof |
| CN106835799A (en) * | 2017-03-13 | 2017-06-13 | 广西大学 | A kind of method for improving ClO 2 solution stability |
| CN106835799B (en) * | 2017-03-13 | 2018-04-10 | 广西大学 | A kind of method for improving ClO 2 solution stability |
| US11274040B2 (en) | 2017-09-29 | 2022-03-15 | Amatera, Inc. | Method for generating chlorine dioxide gas, kit for generating chlorine dioxide gas, and gel composition |
| CN109996761B (en) * | 2017-09-29 | 2020-06-09 | 株式会社阿玛特拉 | Method for generating chlorine dioxide gas, kit for generating chlorine dioxide gas, and gel-like composition |
| CN109996761A (en) * | 2017-09-29 | 2019-07-09 | 株式会社阿玛特拉 | Method for generation, the chlorine dioxide of chlorine dioxide occur to use set group and gel-form composition |
| CN108751385A (en) * | 2018-04-24 | 2018-11-06 | 苏州国科芯感医疗科技有限公司 | Solid chlorine dioxide slow-release material and preparation method thereof |
| CN108402075A (en) * | 2018-04-28 | 2018-08-17 | 汉广中药科技（天津）有限公司 | A kind of compound Chinese medicinal material curing agent and preparation method and application of long-acting controllable sustained-release chlorine dioxide |
| JP2019202918A (en) * | 2018-05-25 | 2019-11-28 | 株式会社環境衛生 | Chlorine dioxide generating powder and chlorine dioxide generator |
| CN108904850A (en) * | 2018-06-14 | 2018-11-30 | 长沙标朗住工科技有限公司 | A kind of persistence eliminates the unusual smell ointment and preparation method thereof |
| CN108991007A (en) * | 2018-08-20 | 2018-12-14 | 青岛大学 | A kind of safe slow released ClO 2 disinfectant and preparation method thereof |
| CN111387205A (en) * | 2020-04-20 | 2020-07-10 | 健康源(广州)投资合伙企业(有限合伙) | Long-acting chlorine dioxide slow-release composite material and preparation method thereof |
| CN111436456A (en) * | 2020-05-09 | 2020-07-24 | 南京协心健康科技有限公司 | Chlorine dioxide solution spray and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101177244A (en) | Preparation of solid chlorine dioxide | |
| CN102379310A (en) | Unitary-package-reaction-type chlorine dioxide tablet and preparation method thereof | |
| EP2716599B1 (en) | Chlorine dioxide-containing product and method for generating chlorine dioxide | |
| CN101632916B (en) | Bamboo carbon composite adsorbent and preparation method thereof | |
| CN102379309B (en) | Binary-packaged reactive chlorine dioxide tablet and preparation method thereof | |
| CN103621554B (en) | A kind of chlorine dioxide generating agent and preparation method thereof | |
| CN102422841A (en) | Reactive chlorine dioxide powder and its preparation method | |
| CN101073319A (en) | Aromatic chlorinedioxide air-antiseptic table and its production | |
| CN101861890A (en) | Slow-release solid chlorine dioxide preservative | |
| CN1449991A (en) | Chlorine dioxide gas generation agent | |
| CN104255785A (en) | Long-acting controllable chlorine dioxide sustained release agent | |
| CN103734864A (en) | Deoxidizing and drying agent for food and feed and preparation method thereof | |
| CN110898246A (en) | Gel powder capable of purifying air and preparation method thereof | |
| CN111226979A (en) | Reactive chlorine dioxide solid preparation and preparation method thereof | |
| CN104174267A (en) | Aromatic air purification powder and preparation method thereof | |
| CN1201660C (en) | Granulated CLO2 disinfectant and its production process | |
| JPS58161904A (en) | Composition for slowly generating gaseous chlorine dioxide | |
| JPH0416180B2 (en) | ||
| JP2014034511A (en) | Time of use moisture absorption reactivity chlorine dioxide generating agent | |
| CN102870809B (en) | Trichloroisocyanuric acid sustained release tablets and preparation method thereof | |
| CN104189938A (en) | Sustained-release chlorine dioxide air purifying agent | |
| CN102145188A (en) | Deodorizing adsorbent | |
| CN102246819B (en) | Instant chlorine dioxide effervescent tablet and preparation method thereof | |
| CN100360188C (en) | Refrigerator deodorant of natural organics | |
| CN1086548C (en) | Powdered ClO2 disinfectant and preparing process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Ye Qing Document name: Notification of Publication of the Application for Invention |
|
| DD01 | Delivery of document by public notice |
Addressee: Ye Qing Document name: Notification that Application Deemed to be Withdrawn |
|
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20080514 |