CN107082936A - A kind of antiultraviolet plastic - Google Patents
A kind of antiultraviolet plastic Download PDFInfo
- Publication number
- CN107082936A CN107082936A CN201710406900.XA CN201710406900A CN107082936A CN 107082936 A CN107082936 A CN 107082936A CN 201710406900 A CN201710406900 A CN 201710406900A CN 107082936 A CN107082936 A CN 107082936A
- Authority
- CN
- China
- Prior art keywords
- parts
- antiultraviolet
- antioxidant
- plastic
- light stabilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004033 plastic Substances 0.000 title claims abstract description 33
- 229920003023 plastic Polymers 0.000 title claims abstract description 33
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 18
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 16
- 239000004611 light stabiliser Substances 0.000 claims abstract description 11
- -1 polyethylene Polymers 0.000 claims abstract description 8
- 239000004698 Polyethylene Substances 0.000 claims abstract description 4
- 239000004743 Polypropylene Substances 0.000 claims abstract description 4
- 239000004793 Polystyrene Substances 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 4
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 4
- 229920000573 polyethylene Polymers 0.000 claims abstract description 4
- 229920000193 polymethacrylate Polymers 0.000 claims abstract description 4
- 229920001155 polypropylene Polymers 0.000 claims abstract description 4
- 229920002223 polystyrene Polymers 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 6
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000008360 acrylonitriles Chemical class 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 150000008366 benzophenones Chemical class 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002530 phenolic antioxidant Substances 0.000 claims description 3
- 150000008301 phosphite esters Chemical class 0.000 claims description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical group OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 6
- 239000002131 composite material Substances 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 description 2
- 150000003902 salicylic acid esters Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of antiultraviolet plastic, the weight proportion of composition includes：8 20 parts of polyethylene, 8 10 parts of polypropylene, 68 parts of polystyrene, 45 parts of polymethacrylates, 35 parts of polycarbonate resin, 5 parts of kymene, 12 parts of antioxidant, 12 parts of light stabilizer.Through the above way, antiultraviolet plastic of the present invention is by using addition antioxidant and light stabilizer in composite plastic, realize the function of plastics antiultraviolet, the speed of plastics light aging can effectively be reduced, improve service life, structure is novel, performance is stable, preventing ultraviolet effect is good, ageing resistace is good, there is extensive market prospects in the popularization of antiultraviolet plastic.
Description
Technical field
The present invention relates to plastic applications, more particularly to a kind of antiultraviolet plastic.
Background technology
Plastics are one of materials the most frequently used during modern production is lived, and the exposure throughout the year of many exterior products is in the sun, long
Ultraviolet in time contact sunlight can accelerate ageing of plastics, substantially reduce service life, influence quality, be unfavorable for it is long-term, have
Effect is used.
The content of the invention
The present invention solves the technical problem of a kind of antiultraviolet plastic is provided, by using in composite plastic
Interior addition antioxidant and light stabilizer, realize the function of plastics antiultraviolet, can effectively reduce the speed of plastics light aging, carry
High service life, structure is novel, performance is stable, preventing ultraviolet effect is good, ageing resistace is good, in the general of antiultraviolet plastic
And on have extensive market prospects.
In order to solve the above technical problems, the present invention provides a kind of antiultraviolet plastic, the weight proportion of composition includes：
8-20 parts of polyethylene,
8-10 parts of polypropylene,
6-8 parts of polystyrene,
4-5 parts of polymethacrylates,
3-5 parts of polycarbonate resin,
- 5 parts of kymene,
1-2 parts of antioxidant,
1-2 parts of light stabilizer.
In a preferred embodiment of the present invention, the antioxidant includes amine antioxidants, phenolic antioxidant, sulfide
The one or more of kind antioxidant, phosphite ester kind antioxidant.
In a preferred embodiment of the present invention, the light stabilizer includes photomask agent, one kind of ultra-violet absorber
Or it is a variety of.
In a preferred embodiment of the present invention, the photomask agent is carbon black, titanium oxide, phthalocyanine blue or phthalocyanine green.
In a preferred embodiment of the present invention, the ultra-violet absorber is salicylic acid esters, benzophenone class, BTA
Class or group-substituted acrylonitrile.
The beneficial effects of the invention are as follows：Antiultraviolet plastic of the present invention in composite plastic by using adding antioxygen
Agent and light stabilizer, realize the function of plastics antiultraviolet, can effectively reduce the speed of plastics light aging, and raising uses the longevity
Life, structure is novel, performance is stable, preventing ultraviolet effect is good, ageing resistace is good, has in the popularization of antiultraviolet plastic
Extensive market prospects.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common
All other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model that the present invention is protected
Enclose.
The embodiment of the present invention includes：
A kind of antiultraviolet plastic, the weight proportion of composition includes：
8-20 parts of polyethylene,
8-10 parts of polypropylene,
6-8 parts of polystyrene,
4-5 parts of polymethacrylates,
3-5 parts of polycarbonate resin,
- 5 parts of kymene,
1-2 parts of antioxidant,
1-2 parts of light stabilizer.
Preferably, the antioxidant includes amine antioxidants, phenolic antioxidant, sulfide-based antioxidant, phosphite ester
The one or more of kind antioxidant.
Preferably, the light stabilizer includes photomask agent, the one or more of ultra-violet absorber.
Preferably, the photomask agent is carbon black, titanium oxide, phthalocyanine blue or phthalocyanine green.
Preferably, the ultra-violet absorber is salicylic acid esters, benzophenone class, benzotriazole or group-substituted acrylonitrile.
The beneficial effect of antiultraviolet plastic of the present invention is：
By using antioxidant and light stabilizer is added in composite plastic, the function of plastics antiultraviolet is realized, can be had
The speed of effect reduction plastics light aging, improves service life, and structure is novel, performance is stable, preventing ultraviolet effect is good, ageing resistance
Can be good.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (5)
1. a kind of antiultraviolet plastic, it is characterised in that the weight proportion of composition includes：
8-20 parts of polyethylene,
8-10 parts of polypropylene,
6-8 parts of polystyrene,
4-5 parts of polymethacrylates,
3-5 parts of polycarbonate resin,
- 5 parts of kymene,
1-2 parts of antioxidant,
1-2 parts of light stabilizer.
2. antiultraviolet plastic according to claim 1, it is characterised in that the antioxidant includes amine antioxygen
Agent, phenolic antioxidant, sulfide-based antioxidant, the one or more of phosphite ester kind antioxidant.
3. antiultraviolet plastic according to claim 1, it is characterised in that the light stabilizer include photomask agent,
The one or more of ultra-violet absorber.
4. antiultraviolet plastic according to claim 3, it is characterised in that the photomask agent be carbon black, titanium oxide,
Phthalocyanine blue or phthalocyanine green.
5. antiultraviolet plastic according to claim 3, it is characterised in that the ultra-violet absorber is salicylate
Class, benzophenone class, benzotriazole or group-substituted acrylonitrile.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710406900.XA CN107082936A (en) | 2017-06-02 | 2017-06-02 | A kind of antiultraviolet plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710406900.XA CN107082936A (en) | 2017-06-02 | 2017-06-02 | A kind of antiultraviolet plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107082936A true CN107082936A (en) | 2017-08-22 |
Family
ID=59608791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710406900.XA Pending CN107082936A (en) | 2017-06-02 | 2017-06-02 | A kind of antiultraviolet plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107082936A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109306100A (en) * | 2018-07-26 | 2019-02-05 | 北京化工大学 | A kind of resistance to electron beam irradiation polythene material and its preparation and use |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265749A (en) * | 2013-06-13 | 2013-08-28 | 苏州新区华士达工程塑胶有限公司 | High density polyethylene modified plastic |
| WO2015168389A1 (en) * | 2014-05-01 | 2015-11-05 | Cytec Industries Inc. | Stabilizing compositions for stabilizing materials against ultraviolet light and thermal degradation |
| CN106009202A (en) * | 2016-07-29 | 2016-10-12 | 大禹节水（天津）有限公司 | Aging resistant polyethylene flexible water hose |
| CN106220974A (en) * | 2016-08-31 | 2016-12-14 | 芜湖恒耀汽车零部件有限公司 | The effective polytene corrugated tube of automotive exhaust flexible |
| CN106243464A (en) * | 2016-08-31 | 2016-12-21 | 芜湖恒耀汽车零部件有限公司 | The processing method of the effective polytene corrugated tube of automotive exhaust flexible |
-
2017
- 2017-06-02 CN CN201710406900.XA patent/CN107082936A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265749A (en) * | 2013-06-13 | 2013-08-28 | 苏州新区华士达工程塑胶有限公司 | High density polyethylene modified plastic |
| WO2015168389A1 (en) * | 2014-05-01 | 2015-11-05 | Cytec Industries Inc. | Stabilizing compositions for stabilizing materials against ultraviolet light and thermal degradation |
| CN106471049A (en) * | 2014-05-01 | 2017-03-01 | 塞特工业公司 | Resist the stable compositionss of ultraviolet light and thermal degradation for stabilization material |
| CN106009202A (en) * | 2016-07-29 | 2016-10-12 | 大禹节水（天津）有限公司 | Aging resistant polyethylene flexible water hose |
| CN106220974A (en) * | 2016-08-31 | 2016-12-14 | 芜湖恒耀汽车零部件有限公司 | The effective polytene corrugated tube of automotive exhaust flexible |
| CN106243464A (en) * | 2016-08-31 | 2016-12-21 | 芜湖恒耀汽车零部件有限公司 | The processing method of the effective polytene corrugated tube of automotive exhaust flexible |
Non-Patent Citations (2)
| Title |
|---|
| 叶久新等: "《塑料制品成型及模具设计》", 31 July 2004, 湖南科学技术出版社 * |
| 李子东等: "《现代胶粘技术手册》", 31 January 2002, 北京：新时代出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109306100A (en) * | 2018-07-26 | 2019-02-05 | 北京化工大学 | A kind of resistance to electron beam irradiation polythene material and its preparation and use |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170822 |