CN107059041A - A kind of method for the hydroxyl radical negative ion water for preparing degreasing cleaning and sterilizing - Google Patents
A kind of method for the hydroxyl radical negative ion water for preparing degreasing cleaning and sterilizing Download PDFInfo
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- CN107059041A CN107059041A CN201710279830.6A CN201710279830A CN107059041A CN 107059041 A CN107059041 A CN 107059041A CN 201710279830 A CN201710279830 A CN 201710279830A CN 107059041 A CN107059041 A CN 107059041A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
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- C25B13/02—Diaphragms; Spacing elements characterised by shape or form
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
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- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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Abstract
The invention discloses a kind of method for the hydroxyl radical negative ion water for preparing degreasing cleaning and sterilizing:Prepare a casing, the resin cation film that the casing is arranged in casing is separated as cathode electrode case and anode electrode case;Anode electrode is plugged in the anode electrode case and the pure water electrolyte containing potassium carbonate catalyst is passed through in the anode electrode case interior circulation, to make the pH value of liquid in the anode electrode case maintain predetermined value;Cathode electrode is plugged in the cathode electrode case and pure water is passed through into the cathode electrode case;During operation, following steps are performed:It is added in anode and cathode and is electrolysed with 24~45 volts of direct current or pulse electricity, and gradually form larger Faradaic current, it is hydroxyl radical negative ion and hydrogen ion by the hydrone electrolytic separation of the pure water in cathode electrode case, hydrogen ion is obtained on negative electrode forms hydrogen spilling after electronics, and after the hydroxyl concentration formed at cathode electrode reaches specific pH value (12.5 ± 0.5), anion water is extracted out negative electrode by water pump, and is pumped into the production that pure water carries out next round anion water.
Description
Technical field
The present invention relates to a kind of preparation method, more particularly to a kind of prepare degreasing cleaning and the hydroxyl of sterilizing is born
The method of ionized water.
Background technology
Disinfection cleaning agent develops into the third generation and uses table from first generation chlorine class solvent and second generation hydrocarbon solvent
The waterborne cleaning agent of face activating agent, using very frequent in the daily life of the mankind.
Traditional surfactant can produce soap simultaneous with oleophylic and hydrophilic high molecular functional group when being mixed with grease
The foam of change, forms the milkiness shape mixed liquor of Water-In-Oil, and these cleaning agents are all containing substantial amounts of harmful chemistry
Material, either poisonous sexual stimulus and hormone side effect or can cause endocrine disturbance, while antibacterial constituents meeting is used for a long time
Cause the resistance to the action of a drug of bacterium, and the hormone control of human normal may be influenceed, enter again so also needing to substantial amounts of clear water after washing
Row is rinsed, and to remove these chemical residues, and can not have the disinfection cleaning agent composition of residual in beverage and food.
Substantial amounts of pollution is will also result in natural environment using chemical substances such as activating agent or emulsifying agents in large quantities in addition.
The content of the invention
The drawbacks of present invention is directed to prior art there is provided a kind of hydroxyl for preparing degreasing cleaning and sterilizing bear from
The method of sub- water, prepared anion water is free of the chemicals such as surfactant and not chloride sodium phosphorus, and possessing has sterilization to disappear
Effect of poison.
The method of the hydroxyl radical negative ion water of the present invention for preparing degreasing cleaning and sterilizing, that is, prepare a case
Body, the resin cation film that the casing is arranged in casing is separated as cathode electrode case and anode electrode case;The anode electricity
Anode electrode is plugged in the case of pole and the pure water electrolyte containing potassium carbonate catalyst is passed through in the anode electrode case interior circulation, with
The pH value of liquid in the anode electrode case is made to maintain predetermined value;Cathode electrode is plugged in the cathode electrode case and to the moon
Pure water is passed through in the electrode case of pole;
During operation, following steps are performed:
Negative electrode is respectively applied to 24~45 volts of direct current or pulse electricity and anode is electrolysed and forms electrolysis electricity
Stream, is hydroxyl radical negative ion and hydrogen ion by the hydrone electrolytic separation of the pure water in cathode electrode case;
The hydrogen ion is obtained on negative electrode forms hydrogen spilling after electronics;Treat the hydroxyl concentration formed at cathode electrode
When reaching specific pH value, the anion water formed at cathode electrode is extracted out by water pump.
In the method for the hydroxyl radical negative ion water of the present invention for preparing degreasing cleaning and sterilizing, the anode
The pH value of liquid is maintained between 9.5 to 10.5 in electrode case.
In the method for the hydroxyl radical negative ion water of the present invention for preparing degreasing cleaning and sterilizing, the anode
The pH value of liquid is 10 in electrode case.
In the method for the hydroxyl radical negative ion water of the present invention for preparing degreasing cleaning and sterilizing, the negative electrode
At electrode formed hydroxyl concentration pH value be 12 to 13 between.
In the method for the hydroxyl radical negative ion water of the present invention for preparing degreasing cleaning and sterilizing, the negative electrode
The pH value of the hydroxyl concentration formed at electrode is 12.5.
In the method for the hydroxyl radical negative ion water of the present invention for preparing degreasing cleaning and sterilizing, negative electrode electricity is treated
After anion water at pole is extracted, continue to be passed through pure water into cathode electrode case to carry out subsequent production.
Prepared anion water is completely by nanometer H in the present invention2O and a large amount of OH-Anion is constituted.The anion is clear
Clean water is the environment-friendly type cleaning sterilization pure water for having overturned conventional solvent class or active cleaning agent, with the fast of beyond tradition cleaning agent
Speed is deoiled the super effect sterilized with quick sterilization, and is possessed peculiar smell, gone that agriculture is residual, go the spies such as formaldehyde, derusting and relieving itching and eliminating swelling
Distinguished service is imitated.
Brief description of the drawings
Fig. 1 illustrates for the apparatus structure of preparation degreasing cleaning of the present invention and the hydroxyl radical negative ion water of sterilizing
Figure.
Embodiment
The present invention is described in further detail below in conjunction with the accompanying drawings, to make those skilled in the art with reference to specification text
Word can be implemented according to this.
The method of the hydroxyl radical negative ion water of the present invention for preparing degreasing cleaning and sterilizing, is based on as follows
What device was carried out.
I.e. as shown in figure 1, prepare a casing 1, the resin cation film 13 that the casing 1 is arranged in casing 1 separate for
Cathode electrode case 12 and anode electrode case 11, the resin cation film 13 selected here, which has, can stop most of potassium ion
Mobile, only a small amount of potassium ion can form Faradaic current by the resin cation film 13.
Plugged in the anode electrode case 11 anode electrode 111 and the interior circulation of anode electrode case 11 be passed through containing
The pure water electrolyte of potassium carbonate catalyst, with make the pH value in the anode electrode case 11 maintain predetermined value (during concrete operations, can
Ensure sun from external importing potassium carbonate catalyst and in real time monitoring pH value by setting circulation line 113 and circulating pump 112
PH value in pole electrode case 11 is maintained in preset range, the present embodiment, is advisable between pH value is maintained into 9.5 to 10.5,
It is better when especially pH value is 10).Cathode electrode 121 is plugged in the cathode electrode case 12 and to the cathode electrode case 12
Inside it is passed through pure water.
By above-mentioned body structure, perform following steps to prepare the hydroxyl radical negative ion of degreasing cleaning and sterilizing
Water.Specifically, above-mentioned casing is passed through with 24~45 volts of direct current or pulse electricity, made in 24~45 volts of Electrode Fields
Under, a small amount of potassium ion displacement simultaneously gradually forms larger Faradaic current through cationic membrane 13, by cathode electrode
The hydrone electrolytic separation of pure water in case 12 is into hydroxyl radical negative ion (OH-) and hydrogen ion (H+), i.e., following reaction equation:H2O→
OH-+H+, then, the strong basicity (hydroxyl formed i.e. at cathode electrode of -900 millivolts of negative potentials is formed at cathode electrode 121
Concentration reaches specific pH value, and the specific pH value is typically advisable between 12 and 13 with 12.5) anion water is this
The anion water of the preparation is invented, meanwhile, hydrogen ion becomes hydrogen after obtaining electronics on the pole plate of cathode electrode 121.Institute
Stating the anion water of preparation can extract out by instruments such as water pumps, after anion water at by cathode electrode 121 is extracted out, continue to
Pure water is passed through in cathode electrode case 12 to carry out subsequent production.
Prepared anion water is completely by nanometer H in the present invention2O and a large amount of OH-Anion is constituted.The anion is clear
Clean water is the environment-friendly type cleaning sterilization pure water for having overturned conventional solvent class or active cleaning agent, with the fast of beyond tradition cleaning agent
Speed is deoiled the super effect sterilized with quick sterilization, and is possessed peculiar smell, gone that agriculture is residual, go the spies such as formaldehyde, derusting and relieving itching and eliminating swelling
Distinguished service is imitated.Its principle is:Hydroxyl radical negative ion can surround grease, various cations, various odor molecules and bacterium rapidly
Virus, is allowed to soluble in water and forms emulsification and saponification, so as to depart from easily from various matrixes, realizes Rapid Cleaning and sterilization work(
Effect, and substantial amounts of saponification foam will not be produced, without secondary rinsing.And a large amount of OH-Anion formation pH value for 12.5 it is strong
Aqueous slkali so that neutralized the acidic materials such as the living environment and agricultural chemicals beverage of various acid virus and bacterias rapidly, caused bacterium
Virus can not be bred and quick death;Meanwhile, OH-Anion water is by the molecular highly basic water of 99.7% moisture, different from general
Logical M (OH) alkaline metal cpds, wherein without any metal cation or surfactant, harm will not be produced to human body
With side effect.Specifically, its cleaning and sterilizing mechanismses are:
1. it is that identical charges repel each other for HO- radical ions group to clean degreasing alkali negative ion water, can be rapid fat-coated or each
Plant cation so that after grease and spot are segmented, impregnability becomes good, and allows pollution to depart from;And can accomplish to make
With surfactant or emulsifying agent etc.;
Either mineral oil or vegetable and animals oils, it can quickly be cleaned, and cleaning performance is optimal.
2. emulsification
According to HO- bases PH12.5 alkaline speciality, oil component is by rapid emulsification (need not add chemical reagent);
3. anti-rust action
The formation of alkaline epithelium, can prevent the acidifying of metal part surface and get rusty.Sterilizing is acted on
Anion reductive water has obtained substantial amounts of hydroxide ion in electrolysis, and concentration more high alkalinity value is bigger, bacterium
Can not existence and breeding in pH value is 12.5 environment;Therefore using the dissipation water of anion technology in production and use environment
In can accomplish that source sterilizes, and without using other chemical sterilization additives or preservative.
Most of bacterial virus is bred in pickling ambient growth, and anion water is strong alkaline water, and bacterium can be destroyed rapidly
With the sour environment of virus, cause bacterium quick death;Anion hydroxyl can rapid coated bacteria simultaneously so that bacterium can not
Oxygen and nutrient are obtained, therefore bacterium can not growth and breeding with virus.5. repellent antipruritic is acted on
After human body skin rupture, subcutaneous cell can be oxidized rapidly and inflammation;And quantum anion water can then prevent cell
It is oxidized, one layer of alkali film hydroxy is formed outside cell so that wound starts healing, while the bacterium outside killing and disease
Poison, eliminates inflammation;And the acetic acid for being directed to bite by mosquitos injection is not just itched after alkaline water is neutralized.
It is free from extraneous odour, non-combustible, nonirritant 5. nontoxic
Present cleaning agent and cutting fluid, all carry certain volatile flavor and toxicity, continuously use for a long time, meeting substantially
Alopecia, PUD D etc. are caused to employee.And most cleaning agents because it is carbon containing, containing organic matter, easily burn,
When volatilization gas concentration is high, directly explode.But strong basicity electrolysis water is without any toxicity, without any smell, can not
Combustion, it is very safe and reliable.The solution of general strong basicity has strong corrosivity, and human body skin is once contacted, and can be felt
Feel strong impulse, cause burn.But no matter the quantum anion water of how high pH value all without to human body skin cause burn.
6. antirust, anti-corrosion, bacteriostasis property are strong
Metal industry does not use water-base cleaning liquid typically in cleaning, because after cleaning, easily causing corrosion to metal.
But quantum anion water not only only has good oily waste degradation ability, and with good rustless property.Simultaneously quantum bear from
Any bacterium and virus will not be grown in sub- water, places also undergo no deterioration for a long time, be particularly suitable as cutting fluid solvent and use.
Anion water colorless and odorless of the present invention, the security with level identical with drinking water.By adding carbon
Sour potassium catalyst enables the ionic condition that unstable anion maintains a long-term stability, and preserves 1 year to several years in sealed states
Also will not change, and common anion water it is general in 24 hours with regard to being reduced to light water naturally.
Anion water of the present invention has following effect:
One, safety zero is stimulated:
Anion reductive water electrolysis when obtained a large amount of negative hydrogen ions, concentration more high alkalinity value is bigger, when anion also
The oxide of negative hydrogen ion and skin surface is neutralized rapidly after raw water contact skin, then pH value is the weak acid of human body skin when detecting
It is worth (4.5~6.5);It can decompose epicyte protein destruction carefully unlike the alkali ion water using surfactant or NaOH
Born of the same parents are very safe.
The superpower infiltrations of two,:
Anion reductive water is the molecular 1 nano micromolecule water of 3~6 moisture, and osmotic pressure is 100 times of light water,
Cell can be entered by cell ion channel, because having good intermiscibility with cell, any wound will not be constituted to skin
Evil.Find that anion reductive water can be infiltrated into inside skin by Cutaneous permeation experiment, accomplish to give skin moisturizing.
Three, nutrient deliveries:
Found in skin penetration test, anion reductive water itself can not only be infiltrated into inside skin, is also used as
Nutrient delivery carrier, the nutrition needed for is delivered to inside skin.Anion water because have good intermiscibility with cell, because
This will not have any injury to human body.
Four, are anti-oxidant:
Anion reductive water has obtained substantial amounts of negative hydrogen ion in electrolysis, is current minimum, most strong, superior antioxygen
Compound matter, and be the polyphenoils that a kind of only a few does not have any toxic side effect.
Five, anti-inflammations:
Anion reductive water pH value is 12.5, the breeding domain away from microorganism;And its subsidiary a large amount of negative electrical charge can be worn
The cell membrane of saturating negative bacterium, so as to kill negative bacterium.Experiment prove anion reductive water can kill Escherichia coli after 60s, it is green
Purulence bacterium, salmonella, staphylococcus aureus, V. parahaemolyticus, REJIONERA viruses, MRSA, Bai Xian Xian bacterium, the type of bleb 2 virus,
Chlamydiatrachomatis Chlamydias, acne bacterium.
Six, peel off dirt greasy dirt:
After stromal surface sprays anion reductive water, it can be by dirt and the rapid positively ionized of stromal surface;Cation
The dirt or greasy surfaces of change constantly attract anion gradually to be surrounded by it, while stromal surface is also covered by anion;
Anion is overlapping with anion rear mutually exclusive, and dirt or greasy dirt are peeled off with this, and hydroxyl is hydrophilic so that wrapped up hydrogen
The dirt or greasy dirt of oxygen root form oil-in-water structure, last soluble in water.
The characteristics of hydroxyl radical negative ion water of the present invention, is:
One, ability of cleaning greasy dirt is strong:
Any surfactant is not needed, nanometer hydroxyl radical negative ion hydrone is only used, so that it may rapid parcel grease or again
The particles such as metal, in coming off easily from matrix surface or be dissolved into water;Can easily go to degrease, lime scale, lithuria
Liquid and metal iron rust etc..
Two, are free of any chemical industry material:
Wherein hydrone content is nontoxic more than 99.7%, non-stimulated to skin, will not allergy, non-corrosiveness;Even if
The wound of rupture, only because sterilization produces a small amount of pain, and plays a part of that swelling and pain relieving is antipruritic and healing of wound immediately,
And it will not leave behind scar;
Three, anion waters are non-combustible, do not limited by safety rule;Do not limited by the regular and various environment regulations of VOC;
Four, eliminate peculiar smell:
Various fish raw meats and acidic odors can be decomposed, the pungent gas of traditional hypochlorous acid disinfecting liquid and hydrogen peroxide will not be produced
Taste;Formaldehyde molecule can be neutralized within a few minutes after other quantum anion water atomization;
Five, rinsing waters are few,, just can be straight without dilution compared to traditional chemical industry cleaning agent due to composition originally water
Connect cleaning and sterilization;Deoil and clean and once complete, without substantial amounts of pure water rinsing, equivalent to dry-cleaning;
The novel environment friendly anion water that six, can be discharged directly, while the sewer containing a large amount of gutter oils can be dredged;
Seven, quick sterilizations:
Not containing traditional sterilizing compositions such as any hypochlorous acid and hydrogen peroxide in anion water, due to any acid bacteria
Virus can not survive in anion water, thus anion can be killed in 1 minute it is various thin including Escherichia coli
Bacterium and virus;
Eight, go residues of pesticides:
Most of agricultural chemicals is all acidic materials or cation, and the strong basicity of quantum anion water can be neutralized rapidly with dividing
Solve various faintly acid molecules, and hydroxyl OH-Various cations can be enveloped, water insoluble material is distributed to shape in water
Into emulsion, so as to easily be rinsed.
The scope of application of anion water of the present invention is as follows:
One, lampblack absorbers and air-conditioning are inside and outside, dining room dining table tableware, fruits and vegetables are sterilized, the pipeline cleaning of milk foods medicine processing,
Automotive trim, subway carriage, hotel guest room, hospital ward, glass, portable computer, Dali stone ceramic tile, plastics, metal surface, sand
Leatherware is sent out, collar cleaner, western-style clothes dry-cleaning, clothes are except mould taste removal etc.;
Two, breath freshenings, ulcer healing, body odour are decomposed, pet cleaning, pet body odour and urine taste cleaning, tinea pedis sterilization, wound
Sterilized after mouth sterilization, crowded acne sterilization, cup;
The application of three, anion waters of the present invention is extremely wide, except that can substitute traditional cleaning agent for kitchen, heavy oil
The cleaning class of the surfactants such as cleaning, bath of glass, cleaning toilet essence, pet cleaning, automobile subway clean water, collar cleaner and shoe polish
Product, while also there is sterilizing and the residual special efficacy of agriculture is removed;Therefore medicinal alcohol, hydrogen peroxide, NaOH can be substituted strong
Alkali or chloride disinfectant, and traditional dissipation class product has sizable excitant and peculiar smell, so anion water is one
Very environmentally friendly water-based elimination agent is planted, stimulation and side effect will not be produced to skin and in vivo, will not also two be caused to environment
Secondary pollution, simultaneously as other chemical substances are not added with, the great competitive advantage of cost, its economic benefit and social benefit phase are in the ban
Enter, belong to conventional washing and sterilizing product subversive theory completely.
In industrial and agricultural production, there can be following application:
One, hardware stamping parts oil removing cleaning (is cleaned) by formula hydro-peening/ultrasonic wave;
Two, hardware machines add rear oil removing cleaning (can effectively clean cutting fluid, iron filings and greasy dirt);
Three, electronic glasses industries (TP/CG) replace the highly basic technique cleaning programs such as NAOH, and (horizontal is cleaned or groove type ultrasonic
Cleaning);
Four, neodymium iron boron wolfram steel piece lines cut rear removing glue cleaning (90 degree of technological temperature is cleaned by ultrasonic);
The precision cleaning of five, medical treatment implant devices industries;
The civilian cleaning vegetable and fruits of six, go agriculture residual, and heavy oil is removed in kitchen, and house is except formaldehyde etc..
Compared with the cleaning agent such as traditional NAOH, KOH, interfacial agent with following product advantage:
1. dirt-removing power is strong, pH value 12.5, while having saponification, tydrophilization, the effect of molten hydrogen;
No matter 2. how temperature, concentration change, never crystallizing.Traditional NAOH, KOH composition cleaning agent is avoided to draw because of crystallization
Play the problems such as the damage of water pump sealing ring and line clogging;
3. foam is not produced during use, it is to avoid at the foam seal that traditional interface activating agent is produced by saponification
Manage problem;
4. environmental protection, non-corrosiveness.Even if PH12.5 alkali electrolyzed ionic water still can be stirred or touched with human hand, to people
Body skin does not have any injury;
5. rinsing water is few, due to composition originally water, compared to traditional chemical industry cleaning agent, it is only necessary to which a small amount of pure water can
With rinsed clean;
6. the OH in anti-rust action, electrolytic ionic water-Ion can promote the formation of alkaline epithelium, can prevent metal surface
It is acidified and gets rusty;
7. nontoxic due to without chemical industry composition, definitely environmental protection, can directly discharge, reduce cost of sewage disposal.
The hydroxyl radical negative ion water manufactured using the method for the invention is by the Chinese Provincial standard formulation committee
Authorization, and put the company standard of " sterilizing cleaning anion water " on record in the standard division of city-level, while by the matter of Chinese Provincial
Third party's detection of whole has been done by amount supervisory detection research institute, and leading indicator has exceeded the regulation about national standard.Its standard is main
Index is as follows:
1. organoleptic requirements:
The hydroxyl radical negative ion water should be uniform not stratified, no precipitation and suspension, free from extraneous odour.
2. physical and chemical index:
The physical and chemical index of the hydroxyl radical negative ion water is as shown in table 1.
Table 1:Physical and chemical index
3. kill microbiological indicator:
The killing microbiological indicator of the hydroxyl radical negative ion water is as shown in table 2.
Table 2:Microbiological indicator
4. toxicological safety requirement:
The toxicologic index of the hydroxyl radical negative ion water is as shown in table 3.
Table 3:Toxicologic index
Sequence number | Project | Index |
1 | Acute oral toxicity test | It is actual nontoxic |
2 | Multiple intact skin irritant test | It is non-stimulated |
3 | Damaged skin irritant test | Non-stimulated or slight stimulation |
4 | Acute eye irritation test | Non-stimulated or slight stimulation |
5 | Skin metamorphosis experiment | Not it was observed that |
6 | Mutagenicity test | It is negative |
2. the requirement of residues of pesticides
0.2% hydroxyl radical negative ion water should to the ratio of the washout rate of remains of pesticide with water to the washout rate of remains of pesticide
More than or equal to 5.
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed
With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art
Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, the present invention is not limited
In specific details and shown here as the legend with description.
Claims (6)
1. a kind of method for the hydroxyl radical negative ion water for preparing degreasing cleaning and sterilizing, it is characterised in that prepare a case
Body, the resin cation film that the casing is arranged in casing is separated as cathode electrode case and anode electrode case;The anode electricity
Anode electrode is plugged in the case of pole and the pure water electrolyte containing potassium carbonate catalyst is passed through in the anode electrode case interior circulation, with
The pH value of liquid in the anode electrode case is made to maintain predetermined value;Cathode electrode is plugged in the cathode electrode case and to the moon
Pure water is passed through in the electrode case of pole;
During operation, following steps are performed:
Negative electrode is respectively applied to 24~45 volts of direct current or pulse electricity and anode is electrolysed and forms Faradaic current, will
The hydrone electrolytic separation of pure water in cathode electrode case is hydroxyl radical negative ion and hydrogen ion;
The hydrogen ion is obtained on negative electrode forms hydrogen spilling after electronics;Treat that the hydroxyl concentration formed at cathode electrode reaches
During specific pH value, the anion water formed at cathode electrode is extracted out by water pump.
2. the method for the hydroxyl radical negative ion water of degreasing cleaning and sterilizing, its feature are prepared as claimed in claim 1
It is, the pH value of liquid is maintained between 9.5 to 10.5 in the anode electrode case.
3. the method for the hydroxyl radical negative ion water of degreasing cleaning and sterilizing, its feature are prepared as claimed in claim 2
It is, the pH value of liquid is 10 in the anode electrode case.
4. the method for the hydroxyl radical negative ion water of degreasing cleaning and sterilizing, its feature are prepared as claimed in claim 2
Be, at the cathode electrode formed hydroxyl concentration pH value be 12 to 13 between.
5. the method for the hydroxyl radical negative ion water of degreasing cleaning and sterilizing, its feature are prepared as claimed in claim 4
It is, the pH value of the hydroxyl concentration formed at the cathode electrode is 12.5.
6. the method for the hydroxyl radical negative ion water of degreasing cleaning and sterilizing, its feature are prepared as claimed in claim 4
It is, after the anion water at cathode electrode is extracted, continues to be passed through pure water into cathode electrode case to carry out subsequent production.
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CN109266469A (en) * | 2018-10-29 | 2019-01-25 | 澳铂格(上海)环保科技有限公司 | A kind of non-surface-active agent base composition, preparation method and the usage |
CN111534387A (en) * | 2020-05-20 | 2020-08-14 | 李树松 | Cleaning agent and preparation method and application thereof |
CN111570445A (en) * | 2020-05-18 | 2020-08-25 | 上海焕星新能源科技有限公司 | Stainless steel tank cleaning method |
CN115594260A (en) * | 2022-07-08 | 2023-01-13 | 刘小江(Cn) | Anion water generating device and control circuit |
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CN115594260A (en) * | 2022-07-08 | 2023-01-13 | 刘小江(Cn) | Anion water generating device and control circuit |
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