KR102359725B1 - Natural antibacterial germicide - Google Patents

Natural antibacterial germicide Download PDF

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KR102359725B1
KR102359725B1 KR1020200035826A KR20200035826A KR102359725B1 KR 102359725 B1 KR102359725 B1 KR 102359725B1 KR 1020200035826 A KR1020200035826 A KR 1020200035826A KR 20200035826 A KR20200035826 A KR 20200035826A KR 102359725 B1 KR102359725 B1 KR 102359725B1
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water
lactobacillus
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phytoncide
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이종소
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주식회사 클린이노베이션
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/20Bacteria; Substances produced thereby or obtained therefrom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof

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  • Pest Control & Pesticides (AREA)
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Abstract

본 발명은 강력한 항균력을 가진 천연 피톤치드에 수용성 산호칼슘 미네랄 및 은(Ag)을 접목시켜 각종 부패균, 식중독균 및 바이러스를 99.9 % 이상 제거할 수 있고, 동시에 미생물을 더 포함하여 탈취 효과를 더욱 강화시킨 친환경 항균소독제에 관한 것이다.The present invention grafts water-soluble coral calcium mineral and silver (Ag) to natural phytoncide with strong antibacterial power to remove 99.9% or more of various putrefactive bacteria, food poisoning bacteria and viruses, and at the same time contains more microorganisms to further enhance the deodorizing effect. It is about antibacterial agents.

Description

친환경 항균소독제{Natural antibacterial germicide}Eco-friendly antibacterial disinfectant {Natural antibacterial germicide}

본 발명은 강력한 항균력을 가진 천연 피톤치드에 수용성 산호칼슘 미네랄 및 은(Ag)을 접목시켜 각종 부패균, 식중독균 및 바이러스를 99.9 % 이상 제거할 수 있고, 동시에 미생물을 더 포함하여 탈취 효과를 더욱 강화시킨 친환경 항균소독제에 관한 것이다.The present invention grafts water-soluble coral calcium mineral and silver (Ag) to natural phytoncide with strong antibacterial power to remove 99.9% or more of various putrefactive bacteria, food poisoning bacteria and viruses, and at the same time contains more microorganisms to further enhance the deodorizing effect. It is about antibacterial agents.

코로나 19, 메르스, 사스, 조류인플루엔자, 구제역 방역, 신종플루 등의 방역을 위한 방역기술 중 하나로서 항균소독제가 제시될 수 있다.An antibacterial disinfectant may be suggested as one of the prevention technologies for quarantine of Corona 19, MERS, SARS, avian influenza, foot-and-mouth disease prevention, and swine flu.

이와 관련하여, 등록특허 10-1151753(등록일자 2012년05월24일)의 '실내 유해화학물질 분해 소독제'에는, 물 100 중량부에 물의 온도를 35 내지 40 ℃로 유지시켜 쌀겨 0.5 내지 1중량부를 준비한 후 망태에 넣은 다음 물이 든 용기에 투입하고 수중에서 비벼 쌀뜨물을 제조한 후 녹차 추출액에 당밀 또는 설탕을 혼합한 EM 원액을 배양, 증식시켜 EM 활성액을 제조하는 단계; 천연식물성분인 피톤치드, 허브, 아로마 원액을 증류수 또는 정제수에 혼합하는 단계; 상기 제조된 EM 활성액을 희석한 후 천연식물성분과 혼합하는 단계를 포함하는 실내 유해화학물질 분해 소독제 제조방법에 대한 기술이 개시된 바 있다.In this regard, in the 'indoor hazardous chemical decomposition disinfectant' of registered patent 10-1151753 (registration date: May 24, 2012), 0.5 to 1 weight of rice bran by maintaining the temperature of water at 35 to 40 ℃ in 100 parts by weight of water After preparing the wealth, put it in a mantle, put it in a container with water, rub it in water to prepare rice water, and then culturing and proliferating an EM stock solution in which molasses or sugar is mixed with green tea extract to prepare an EM active solution; Mixing natural plant components phytoncide, herbs, and aroma undiluted solution with distilled or purified water; A technique for a method for producing a disinfectant decomposing harmful chemicals indoors, which includes the step of diluting the prepared EM active solution and mixing it with natural plant components, has been disclosed.

등록특허 10-1863267(등록일자 2018년05월25일)의 '구제역 또는 조류 인플루엔자 방제용 소독제 조성물'에는 맥반석 분말 100중량부에 대하여 운모 분말 10 ~ 20중량부, 장석 분말 10 ~ 20중량부, 도석분말 10 ~ 20중량부, 석화껍질(굴껍질) 분말 20 ~ 30중량부, 머드스톤 분말 5 ~ 10중량부, 참숯 분말 5 ~ 10 중량부, 편백나무 분말 10 ~ 20중량부 및 도토리 분말 3 ~ 5중량부로 조성되는 것을 특징으로 하는 구제역 또는 조류 인플루엔자 방제용 소독제 조성물에 대한 기술이 개시된 바 있다.In the 'disinfectant composition for foot-and-mouth disease or avian influenza control' of registered patent 10-1863267 (registration date May 25, 2018), 10-20 parts by weight of mica powder, 10-20 parts by weight of feldspar powder, Stone powder 10-20 parts by weight, petrified husk (oyster shell) powder 20-30 parts by weight, mudstone powder 5-10 parts by weight, charcoal powder 5-10 parts by weight, cypress powder 10-20 parts by weight, and acorn powder 3 A technique for a disinfectant composition for controlling foot-and-mouth disease or avian influenza, characterized in that it is composed of ~ 5 parts by weight, has been disclosed.

상기 등록특허를 포함하여 종래에는, 강력한 항균력을 가진 천연 피톤치드에 수용성 산호칼슘 미네랄 및 은(Ag)을 접목시켜 각종 부패균, 식중독균 및 바이러스를 99.9 % 이상 제거할 수 있고, 동시에 미생물을 더 포함하여 탈취 효과를 더욱 강화시킨 친환경 항균소독제는 개시된 바 없다.In the past, including the above registered patent, it is possible to remove 99.9% or more of various putrefactive bacteria, food poisoning bacteria and viruses by grafting water-soluble coral calcium mineral and silver (Ag) to natural phytoncide with strong antibacterial power, and at the same time deodorizing by including more microorganisms An eco-friendly antibacterial disinfectant that further enhances the effect has not been disclosed.

등록특허 10-1151753(등록일자 2012년05월24일)Registered Patent 10-1151753 (Registration Date May 24, 2012) 등록특허 10-1863267(등록일자 2018년05월25일)Registered Patent 10-1863267 (Registration date May 25, 2018)

본 발명은 강력한 항균력을 가진 천연 피톤치드에 수용성 산호칼슘 미네랄 및 은(Ag)을 접목시켜 각종 부패균, 식중독균 및 바이러스를 99.9 % 이상 제거할 수 있고, 동시에 미생물을 더 포함하여 탈취 효과를 더욱 강화시킨 친환경 항균소독제를 제공하고자 하는 것을 발명의 목적으로 한다.The present invention grafts water-soluble coral calcium mineral and silver (Ag) to natural phytoncide with strong antibacterial power to remove 99.9% or more of various putrefactive bacteria, food poisoning bacteria and viruses, and at the same time contains more microorganisms to further enhance the deodorizing effect. It is an object of the invention to provide an antibacterial disinfectant.

또한 수용성이라 초음파 가습기에 적용이 용이하여 공간 소독 및 항균에 적합한 친환경 항균소독제를 제공하고자 하는 것을 발명의 목적으로 한다.In addition, it is an object of the invention to provide an eco-friendly antibacterial disinfectant suitable for space disinfection and antibacterial because it is water-soluble and can be easily applied to an ultrasonic humidifier.

상기 목적을 달성하기 위하여,In order to achieve the above object,

본 발명은 the present invention

수용성 산호칼슘 미네랄 1.0 ~ 98.0 wt%와,1.0 ~ 98.0 wt% of water-soluble coral calcium mineral,

피톤치드 원유 0.1 ~ 98.0 wt%와,0.1 ~ 98.0 wt% of phytoncide crude oil,

은(Ag) 0.1 ~ 2.0 wt%를 포함하여 각종 부패균, 식중독균 및 바이러스를 99.9 % 이상 제거할 수 있는 친환경 항균소독제를 제공한다.It provides an eco-friendly antibacterial disinfectant that can remove 99.9% or more of various putrefactive bacteria, food poisoning bacteria and viruses, including 0.1 to 2.0 wt% of silver (Ag).

또한, 상기 친환경 소독제는 미생물 0.1 ~ 20.0 wt%를 더 포함하여 각종 부패균, 식중독균 및 바이러스를 99.9 % 이상 제거기능과 돈분 등에서 발생하는 악취를 제거효과를 동시에 갖는 친환경 항균소독제를 제공한다.In addition, the eco-friendly disinfectant further contains 0.1 to 20.0 wt% of microorganisms to provide an eco-friendly antibacterial disinfectant that simultaneously has a function of removing 99.9% or more of various putrefactive bacteria, food poisoning bacteria and viruses and an effect of removing odors generated from pig manure, etc.

본 발명에 따른 친환경 항균소독제는 다음의 효과를 갖는다.The eco-friendly antibacterial disinfectant according to the present invention has the following effects.

첫째. 강력한 향균력을 가진 천연 피톤치드에 수용성 산호칼슘 미네랄, 미생물 및 은(Ag)을 접목한 친환경 물질로서 인체에 안전하고 각종 부패균, 식중독균 및 최근 발생한 코로나 19를 포함하는 바이러스의 소독에 효과적이다.first. It is an eco-friendly material that grafts water-soluble coral calcium mineral, microorganism and silver (Ag) to natural phytoncide with strong antibacterial power.

둘째. 수용성이라 액상화하여 초음파 가습기에 적용이 용이하여 공간 항균 및 소독에 효과적이며, 이로써 인플루엔자 등 바이러스 항균에 적합하고 탈취 효과도 뛰어나다.second. Because it is water-soluble, it is easy to apply to an ultrasonic humidifier and is effective for space antibacterial and disinfection.

셋째. 미생물을 더 포함하여 이용하여 99.9 % 이상의 탁월한 항균 및 탈취효과를 가져 위생적인 환경을 조성한다.third. By using more microorganisms, it has excellent antibacterial and deodorizing effects of more than 99.9% to create a hygienic environment.

이하, 본 발명에 따른 친환경 항균소독제에 대한 구체적인 기술 내용을 살펴보도록 한다.Hereinafter, the detailed description of the eco-friendly antibacterial disinfectant according to the present invention will be described.

상기한 바와 같이, As mentioned above,

본 발명에 따른 친환경 항균소독제는 The eco-friendly antibacterial disinfectant according to the present invention

수용성 산호칼슘 미네랄 1.0 ~ 98.0 wt%와,1.0 ~ 98.0 wt% of water-soluble coral calcium mineral,

피톤치드 원유 0.1 ~ 98.0 wt%와,0.1 ~ 98.0 wt% of phytoncide crude oil,

은(Ag) 0.1 ~ 2.0 wt%를 포함한다.It contains 0.1 to 2.0 wt% of silver (Ag).

[ 수용성 산호칼슘 미네랄 ][ Water Soluble Coral Calcium Mineral ]

상기 수용성 산호칼슘 미네랄은 산호초(珊瑚礁)와 산호사(珊瑚砂)로 형성된 풍화퇴적(風化堆積) 산호 석회암을 소성하여 제조한 물에 녹는 산호칼슘 미네랄이다.The water-soluble coral calcium mineral is a water-soluble coral calcium mineral prepared by calcining weathered sedimentary coral limestone formed of coral reefs and coral sand.

상기 산호칼슘 미네랄은 원료가 청정해역에서만 자란 산호초가 원재료이기에 안전하다. 화학적 처리를 전혀 하지 않고, 전기 및 물리적 처리만으로 제조하기에 부작용 및 독성이 없다.The coral calcium mineral is safe because the raw material is coral reef grown only in clean waters. There is no side effect and no toxicity because no chemical treatment is performed, and only electrical and physical treatment are used to manufacture it.

반응 속도가 대단히 빠르며, 물의 클러스터(Cluster)를 작게 하여 동식물 생체내에서의 반응력이 크다. 모든 오염물질을 살균, 소독한다. 화학적으로 분해하고, 제거할 수 있는 가장 강력한 물질이다. 산화력(살균, 소독, 탈취, 분해하는 능력)이 강력하지만 인체에는 독성이 있거나 유해한 물질이 아니다. 공기와 물 속의 오염물질에 직접적으로 관여하여 모든 오염물질을 안전한 물(H2O)과 이산화탄소(CO2)로 환원시켜 인체에 무해하다.The reaction rate is very fast, and the reaction force in the living body of animals and plants is large by making the water cluster small. Sterilize and disinfect all contaminants. It is the most powerful substance that can be chemically decomposed and removed. Although it has strong oxidizing power (the ability to sterilize, disinfect, deodorize, and decompose), it is not toxic or harmful to the human body. It is harmless to the human body by directly participating in air and pollutants in water and reducing all pollutants to safe water (H 2 O) and carbon dioxide (CO 2 ).

산호칼슘 미네랄에는 다음의 표 1에 제시하고 있는 바와 같이 다양한 종류의 미네랄이 포함되어 있다.Coral calcium minerals include various types of minerals as shown in Table 1 below.

Figure 112020030945018-pat00001
Figure 112020030945018-pat00001

상기 산호칼슘 미네랄에 포함되어 있는 산호칼슘은 산화칼슘(Calcium Oxide)이다.Coral calcium contained in the coral calcium mineral is calcium oxide (Calcium Oxide).

상기 산화칼슘(Calcium Oxide)은 백색을 띄는 결정으로 공기 중에 놓아두면 수분과 이산화탄소를 흡수하여 수산화칼슘즉 소석회와 탄산칼슘으로 분해된다.The calcium oxide (Calcium Oxide) is a white crystal that absorbs moisture and carbon dioxide when placed in the air and is decomposed into calcium hydroxide, that is, slaked lime and calcium carbonate.

CaO + H2O → Ca(OH)2 CaO + H 2 O → Ca(OH) 2

Ca(OH)2 + CO2 → CaCO3 + H2O Ca(OH) 2 + CO 2 → CaCO 3 + H 2 O

산화칼슘의 가장 큰 특징은 살균작용이다.The greatest characteristic of calcium oxide is its bactericidal action.

천연원료로 식품첨가물이면서 99.9%의 살균력을 보유하고 있으며 산화칼슘을 물에 녹였을 때에 발생하는 강 알칼리성의 세정력에 의해 일반 생균, 곰팡이 균, 식중독의 원인균 등이 제거된다. As a natural raw material, it is a food additive and has 99.9% sterilization power, and the strong alkaline cleaning power generated when calcium oxide is dissolved in water removes common live bacteria, mold bacteria, and bacteria that cause food poisoning.

강력한 살균 및 소독 효과로 99.99 %의 각종 부패균, 식중독균, 바이러스를 5 ~ 10 초 이내에 효과적으로 살균한다.With strong sterilization and disinfection effect, it effectively sterilizes 99.99% of various putrefactive bacteria, food poisoning bacteria and viruses within 5 to 10 seconds.

이와 같은 살균력에 의해, 병원성대장균, 곰팡이(진균류), 박테리아, 살모넬라균, 황색포도구균, 장비브리오, 레지오넬라균, 사스, 조류독감, O-157, 칸피로바쿠타, 녹농균, 노로바이러스, 장염비브리오, 폐렴균, 비브리오균 등 거의 모든 질병균, 조류독감 같은 전염병이 발생했을 때 하얀 옷을 입고 고글과 마스크를 쓰고 하얗게 뿌리는 것도 생석회 가루이다.Due to this sterilizing power, pathogenic Escherichia coli, mold (fungi), bacteria, salmonella, Staphylococcus aureus, Giangbrio, Legionella, SARS, avian influenza, O-157, Canpyrovakuta, Pseudomonas aeruginosa, norovirus, enteritis vibrio , Pneumonia, Vibrio, etc. When an infectious disease such as avian flu occurs, wearing white clothes, goggles and a mask, and spraying white is also quicklime powder.

두 번째 특징은 농약의 분해작용이다. 원리는 다음과 같다.The second characteristic is the decomposition of pesticides. The principle is as follows.

잔류 농약 등 각종불순물을 떼어내는 것에 그치지 않고 분해시켜 기존세정제보다 높은 제거율을 보이며 농약성분들 자체의 분자고리를 끊는“알칼리이온 가수분해 효과”가 있어 효과적으로 농약을 제거한다. 예로는 유기인산계 농약, 유기염소계 농약, 카바메이트계 농약 등이 있다.It not only removes various impurities such as residual pesticides, but also decomposes them, showing a higher removal rate than existing cleaners, and effectively removing pesticides because of the “alkali ion hydrolysis effect” that breaks the molecular chains of pesticides. Examples include organophosphate pesticides, organochlorine pesticides, and carbamate pesticides.

세 번째 특징은 물의 분자 Clust를 작게 만든다. 물의 분자(Clust)를 작게 만들면 물의 결합을 신속하게 하고 효과적으로 결합하게 한다.The third characteristic makes the molecular cluster of water small. Making the molecule (clust) of water small makes the water bond faster and more effectively.

상기 수용성 산호칼슘 미네랄의 사용량은 친환경 항균소독제의 전체 중량에 대해 1.0 ~ 90.0 wt%의 범위 내로 한정한다.The amount of the water-soluble coral calcium mineral used is limited within the range of 1.0 to 90.0 wt% based on the total weight of the eco-friendly antibacterial disinfectant.

상기 수용성 산호칼슘 미네랄의 사용량이 1.0 wt% 미만인 경우에는 물(H2O)의 클러스터를 작게하지 못하여 피톤치드와 미생물의 활성화가 미비하고 다양한 항균 효과와 복합탈취 효과가 떨어지는 문제가 있고, 90.0 wt% 를 초과하게 되는 경우에는 미생물의 활성도가 떨어지는 문제가 있으므로, 상기 수용성 산호칼슘 미네랄의 사용량은 친환경 항균소독제의 전체 중량에 대해 1.0 ~ 90.0 wt%의 범위 내로 한정하는 것이 바람직하다.When the amount of the water-soluble coral calcium mineral used is less than 1.0 wt%, the cluster of water (H 2 O) cannot be reduced, so the activation of phytoncides and microorganisms is insufficient, and there is a problem that various antibacterial effects and complex deodorization effects are deteriorated, and 90.0 wt% If it exceeds, since there is a problem in that the activity of microorganisms decreases, the amount of the water-soluble coral calcium mineral used is preferably limited to 1.0 ~ 90.0 wt% with respect to the total weight of the eco-friendly antibacterial disinfectant.

[ 피톤치드 원유 ][ Phytoncide crude oil ]

피톤치드(phytoncide)는 수목이 생산해 내는 휘발성 물질로 그 성분은 테르펜(terpene)이라는 유기화학물질이다.Phytoncide is a volatile substance produced by trees and its component is an organic chemical called terpene.

피톤치드(Phytoncide)는 수목이 해충이나 미생물로부터 자기를 방어하기 위해 공기중에 발산하는 천연의 항균물질을 말한다. '식물'(Phyton)과 '죽이다'(Cide)를 뜻하는 그리스어의 합성어로서 식물이 내뿜는 살균성 물질을 총칭한다.Phytoncide is a natural antibacterial substance that trees emit in the air to defend themselves from pests and microorganisms. It is a compound word of Greek meaning 'plant' and 'cide', and it is a generic term for bactericidal substances emitted by plants.

피톤치드의 주성분은 휘발성이 강한 테르펜류가 주를 이루며, 향기 이외의 성분도 다수 함유되어 있다. The main component of phytoncide is terpenes with strong volatility, and it contains many components other than fragrance.

피톤치드를 접하기 위해 널리 알려진 방법은 울창한 숲속을 찾아 산림욕을 하는 것입니다. 피톤치드는 곧 산림욕 물질입니다.A widely known way to come into contact with phytoncides is to go for a forest bath in a dense forest. Phytoncides are forest bathing substances.

산림욕효과는 소나무 잣나무 등의 침엽수림에서 우수하며, 특히 편백나무의 피톤치드가 뛰어나다.Forest bathing effect is excellent in coniferous forests such as pine and cypress, and especially in cypress phytoncide.

피톤치드(정유: essential oil)는 대부분 무색 또는 엷은 색으로 빛에 의해 광분해를 일으키기 쉬우며, 공기 중에 산화되어 과산화물이나 결정성 혼탁물질이 생성되고 향기성분의 분자량 범위는 26~300, 끓는점은 120~350 ℃이며, 비중은 0.842~1.172로 알려져 있다. 식물에서 추출된 정유는 단일 화학성분이 아니 휘발성이 강한 모노테르펜계와 페닐프로펜계 화합물의 혼합물로 추출식물 종의 유전적 특성과 재배지역의 환경 및 채취시기에 따라 정유성분의 조성에 차이가 나며 동종 식물에서 유래된 정유라도 식물의 기원에 따라 성분조성에 차이가 있다.Phytoncide (essential oil) is mostly colorless or pale in color and easily photodegradable by light. It is 350 °C, and the specific gravity is known to be 0.842 to 1.172. Essential oil extracted from plants is not a single chemical component, but a mixture of highly volatile monoterpene-based and phenylpropene-based compounds. Even essential oils derived from the same plant have differences in composition depending on the origin of the plant.

정유 내에 탄소(C)와 수소(H)가 5:8의 비율로 구성되어 있는 화합물을 테르펜(terpene) 또는 이소프렌(isoprene)이라고 명명하며, 이 isoprene은 정유를 구성하는 기본적인 단위이다.A compound composed of carbon (C) and hydrogen (H) in a ratio of 5:8 in essential oil is called terpene or isoprene, and this isoprene is a basic unit constituting essential oil.

편백나무(Chamaecyparis obtusa)는 일본과 대만 등에서 자생하고 있는 측백나무과 편백나무속의 상록 침엽 교목으로 줄기에는 독특한 향기가 있는 피톤치드가 다량 생산된다. 편백나무의 피톤치드는 세균, 진균 등 다양한 미생물에 대한 항균작용이 있다.Cypress (Chamaecyparis obtusa) is an evergreen coniferous tree of the genus Cypress, native to Japan and Taiwan. Phytoncide of cypress has antibacterial action against various microorganisms such as bacteria and fungi.

편백 피톤치드는 그람 양성세균인 Staphylococcus epidermidis, 그람음성세균인 Vibrio parahaemolyticus, Pseudomonas aeruginosa, Pseudomonasputida, 효모형 곰팡이인 Candida albicans, 사상형 곰팡이인 Aspergillus nidulas, Alternaria mali, Fusarium oxysporum 등에 항균효과가 있는 것으로 알려져 있다.Cypress phytoncide is known to have antibacterial effects such as Gram-positive bacteria Staphylococcus epidermidis , Gram-negative bacteria Vibrio parahaemolyticus , Pseudomonas aeruginosa , Pseudomonasputida , yeast-type mold Candida albicans , filamentous mold Aspergillus nidulas , Alternaria mali , etc.

상기 편백 피톤치드는 다양한 방법으로 수득할 수 있으나, 일례로서 본 발명에서는 수증기증류추출법(SDE, Steam Distillation Extraction)이 제시된다.The cypress phytoncide can be obtained by various methods, but as an example, in the present invention, steam distillation extraction (SDE) is suggested.

정유성분의 비점보다 낮은 온도에서 유출시킬 수 있으므로 성분의 분해나 변질의 염려가 거의 없다. 증류수를 사용하여 100 ℃에서 4 시간 동안 수증기증류추출하여 정유성분을 수득한다.Since it can be discharged at a temperature lower than the boiling point of the essential oil component, there is little risk of decomposition or deterioration of the component. The essential oil component is obtained by steam distillation extraction using distilled water at 100° C. for 4 hours.

상기 피톤치드 원유의 사용량은 친환경 항균소독제의 전체 중량에 대해 0.1 ~ 80.0 wt%의 범위 내로 한정한다.The amount of phytoncide crude oil used is limited within the range of 0.1 to 80.0 wt% based on the total weight of the eco-friendly antibacterial disinfectant.

상기 피톤치드 원유의 사용량이 0.1 wt% 미만인 경우에는 항균 및 탈취 효과가 약하고, 효과가 있더라도 특정 바이러스에만 항균성을 갖거나 탈취 효과가 매우 제한적이라는 단점이 있고, 80.0 wt%를 초과하게 되는 경우에는 초음파가습기 등에 본 발명에 따른 친환경 항균속독제를 주입하여 사용할 때 진동단자에 무리를 주어 가습기의 작동이 제대로 수행되지 않는 문제가 있을 수 있으므로, 상기 피톤치드 원유의 사용량은 친환경 항균소독제의 전체 중량에 대해 0.1 ~ 80.0 wt%의 범위 내로 한정하는 것이 바람직하다.When the amount of the phytoncide crude oil used is less than 0.1 wt%, the antibacterial and deodorizing effect is weak, and even if there is an effect, there is a disadvantage that it has antibacterial properties only for a specific virus or the deodorization effect is very limited, and when it exceeds 80.0 wt%, ultrasonic humidifier Since there may be a problem that the operation of the humidifier is not performed properly due to excessive stress on the vibrating terminal when using the eco-friendly antibacterial quick poison agent according to the present invention, etc., the amount of phytoncide crude oil used is 0.1 ~ It is preferable to limit it within the range of 80.0 wt%.

[ 은(Ag) ][ Silver (Ag) ]

상기 은(Ag)의 사용량이 0.1 wt% 미만인 경우에는 은(Ag)이 갖는 항균력이 약해지는 문제가 있고, 2.0 wt%를 초과하게 되는 경우에는 미생물을 포함하여 친환경 항균소독제를 구성하는 경우, 상기 미생물의 활성도를 저해하는 문제가 발생할 수 있기 때문에 상기 은(Ag)의 사용량은 친환경 항균소독제의 전체 중량에 대해 0.1 ~ 2.0 wt%의 범위 내로 한정하는 것이 바람직하다.When the amount of silver (Ag) used is less than 0.1 wt%, there is a problem in that the antibacterial power of silver (Ag) is weakened, and when it exceeds 2.0 wt%, when composing an eco-friendly antibacterial disinfectant including microorganisms, the Since a problem of inhibiting the activity of microorganisms may occur, the amount of silver (Ag) used is preferably limited to 0.1 to 2.0 wt% based on the total weight of the eco-friendly antibacterial disinfectant.

[ 미생물 ][ microbe ]

상기 미생물은 수용성 산호칼슘 미네랄, 피톤치드 원유 및 은(Ag)을 포함하는 친환경 항균소독제의 악취 제거 효과를 더욱 강화시키기 위하여 첨가한다.The microorganism is added to further enhance the odor removal effect of an eco-friendly antibacterial disinfectant containing water-soluble coral calcium mineral, phytoncide crude oil, and silver (Ag).

상기 미생물은 친환경 항균소독제를 구성하는 전체 성분 배합비 중 0.1 ~ 20.0 wt%로 한정한다.The microorganisms are limited to 0.1 to 20.0 wt% of the total component mixing ratio constituting the eco-friendly antibacterial disinfectant.

상기 미생물의 사용량이 0.1 wt% 미만인 경우에는 미생물에 의한 탈취 분해성이 떨어지는 문제가 있고, 20.0 wt%를 초과하게 되는 경우에는 피톤치드와 수용성 산호칼슘 미네랄의 항균 및 탈취력을 저하시키는 문제가 있으므로, 상기 미생물의 사용량은 친환경 항균소독제의 전체 중량에 대해 0.1 ~ 20.0 wt%의 범위 내로 한정하는 것이 바람직하다.If the amount of the microorganism is less than 0.1 wt%, there is a problem in that deodorization and decomposition by microorganisms is lowered, and when it exceeds 20.0 wt%, there is a problem of lowering the antibacterial and deodorizing power of phytoncide and water-soluble coral calcium mineral, so the microorganism It is preferable to limit the amount to be used within the range of 0.1 to 20.0 wt% based on the total weight of the eco-friendly antibacterial disinfectant.

상기 미생물은 더욱 상세하게는, 락토바실러스 팬터리스(Lactobacillus pantheris) 6.0 ~ 10.0 wt%, 락토바실러스 파라부치네리(Lactobacillus parabuchneri) 23.0 ~ 31.0 wt%, 락토바실러스 파라카제이(Lactobacillus paracasei) 22.2 ~ 25.7 wt%, 락토바실러스 파라파라지니스(Lactobacillus parafarraginis) 14.7 ~ 22.4 wt%, 락토바실러스 카멜리애(Lactobacillus camelliae) 11.3 ~ 17.2 wt% 및 락토바실러스 비니(Lactobacillus vini) 7.4 ~ 11.7 wt%로 구성되는 복합미생물을 사용한다.The microorganism is more specifically, Lactobacillus pantheris 6.0 to 10.0 wt%, Lactobacillus parabuchneri 23.0 to 31.0 wt%, Lactobacillus paracasei 22.2 to 25.7 wt% %, Lactobacillus parafarraginis 14.7 to 22.4 wt%, Lactobacillus camelliae 11.3 to 17.2 wt%, and Lactobacillus vini 7.4 to 11.7 wt% of complex microorganisms are used do.

더욱 구체적으로는,More specifically,

락토바실러스 팬터리스(Lactobacillus pantheris) 7.0 wt%,Lactobacillus pantheris 7.0 wt%,

락토바실러스 파라부치네리(Lactobacillus parabuchneri) 25.0 wt%,Lactobacillus parabuchneri 25.0 wt%,

락토바실러스 파라카제이(Lactobacillus paracasei) 23.5 wt%,Lactobacillus paracasei 23.5 wt%,

락토바실러스 파라파라지니스(Lactobacillus parafarraginis) 20.3 wt%,Lactobacillus parafarraginis 20.3 wt%,

락토바실러스 카멜리애(Lactobacillus camelliae) 15.1 wt%,Lactobacillus camelliae 15.1 wt%,

락토바실러스 비니(Lactobacillus vini) 9.1 wt%로 구성되는 복합미생물을 사용한다.A complex microorganism composed of 9.1 wt% of Lactobacillus vini is used.

본 발명에 따른 친환경 항균소독제의 제1 실시형태에 따른 구체적인 배합예를 살펴보면 다음의 표 2와 같다.Looking at specific formulation examples according to the first embodiment of the eco-friendly antibacterial disinfectant according to the present invention are shown in Table 2 below.

배합예 1Formulation Example 1 배합예 2Combination Example 2 배합예 3Formulation example 3 배합예 4Formulation example 4 배합예 5Combination Example 5 수용성 산호칼슘 미네랄Soluble Coral Calcium Mineral 48.9 wt%48.9 wt% 62.5 wt%62.5 wt% 74.1 wt%74.1 wt% 80.9 wt%80.9 wt% 89.3 wt%89.3 wt% 피톤치드 원유phytoncide crude oil 48.1 wt%48.1 wt% 34.1 wt%34.1 wt% 21.8 wt%21.8 wt% 16.8 wt%16.8 wt% 10.2 wt%10.2 wt% 은(Ag)Silver (Ag) 1.8 wt%1.8 wt% 1.6 wt%1.6 wt% 1.3 wt%1.3 wt% 1.1 wt%1.1 wt% 0.8 wt%0.8 wt% 합 계Sum 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt%

본 발명에 따른 친환경 항균소독제의 제2 실시형태에 따른 구체적인 배합예를 살펴보면 다음의 표 3과 같다.Looking at specific formulation examples according to the second embodiment of the eco-friendly antibacterial disinfectant according to the present invention are shown in Table 3 below.

배합예 1Formulation Example 1 배합예 2Combination Example 2 배합예 3Formulation example 3 배합예 4Formulation example 4 배합예 5Combination Example 5 수용성 산호칼슘 미네랄Soluble Coral Calcium Mineral 47.4 wt%47.4 wt% 60.9 wt%60.9 wt% 72.8 wt%72.8 wt% 79.8 wt%79.8 wt% 88.5 wt%88.5 wt% 피톤치드 원유phytoncide crude oil 48.1 wt%48.1 wt% 34.1 wt%34.1 wt% 21.8 wt%21.8 wt% 16.8 wt%16.8 wt% 10.2 wt%10.2 wt% 미생물microbe 2.7 wt%2.7 wt% 3.4 wt%3.4 wt% 4.1 wt%4.1 wt% 2.3 wt%2.3 wt% 0.5 wt%0.5 wt% 은(Ag)Silver (Ag) 1.8 wt%1.8 wt% 1.6 wt%1.6 wt% 1.3 wt%1.3 wt% 1.1 wt%1.1 wt% 0.8 wt%0.8 wt% 합 계Sum 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt%

상기 표 3의 배합예 1에 따른 친환경 항균소독제를 사용하여 박테리아 제거 시험을 하였으며, 그 효과는 다음의 표 4와 같다.The bacteria removal test was performed using the eco-friendly antibacterial disinfectant according to Formulation Example 1 of Table 3, and the effect is shown in Table 4 below.

Figure 112020030945018-pat00002
Figure 112020030945018-pat00002

상기 표 4의 CFU는 Colony Forming Unit이다. CFU of Table 4 is Colony Forming Unit.

접종균 세균농도(CFU/mL)는 살모넬라 1.5 × 106, 폐렴균 1.3 × 106, MRSA 1.2 × 106 이다.The inoculum bacterial concentration (CFU/mL) was Salmonella 1.5 × 10 6 , Pneumonia 1.3 × 10 6 , and MRSA 1.2 × 10 6 .

그리고 사용균주는 Salmonella typhimurium IFO 14193, Klebsiella pneumoniae ATCC 4352, MRSA(Staphylococcus aureus subsp. aureus ATCC 33591)이다.And the strains used are Salmonella typhimurium IFO 14193, Klebsiella pneumoniae ATCC 4352, MRSA ( Staphylococcus aureus subsp. aureus ATCC 33591).

상기 표 4를 통해 확인되는 바와 같이, 본 발명에 따른 친환경 항균소독제에 의한 박테리아의 제거율이 99.9 %에 이르는 것을 확인할 수 있었다.As confirmed through Table 4, it was confirmed that the removal rate of bacteria by the eco-friendly antibacterial disinfectant according to the present invention reached 99.9%.

[ 수용성 삼산화규소(SiO[ Water-soluble silicon trioxide (SiO 33 ) ]) ]

상기 제시된 기술 구성 외에, 수용성 삼산화규소(SiO3)를 첨가하여 친환경 항균소독제를 구성하는 수용성 산호칼슘 미네랄, 피톤치드 원유 및 미생물의 기능을 더욱 활성화시킬 수 있다.In addition to the technical configuration presented above, water-soluble silicon trioxide (SiO 3 ) can be added to further activate the functions of water-soluble coral calcium mineral, phytoncide crude oil and microorganisms constituting an eco-friendly antibacterial disinfectant.

보다 상세하게는,More specifically,

수용성 산호칼슘 미네랄 1.0 ~ 98.0 wt%와,Water-soluble coral calcium mineral 1.0 ~ 98.0 wt%,

피톤치드 원유 0.1 ~ 98.0 wt%와,0.1 ~ 98.0 wt% of phytoncide crude oil,

은(Ag) 0.1 ~ 2.0 wt%와,0.1 to 2.0 wt% of silver (Ag), and

수용성 삼산화규소(SiO3) 0.1 ~ 20.0 wt%를 포함한다.Water-soluble silicon trioxide (SiO 3 ) Contains 0.1 to 20.0 wt%.

또는 or

수용성 산호칼슘 미네랄 1.0 ~ 98.0 wt%와,Water-soluble coral calcium mineral 1.0 ~ 98.0 wt%,

피톤치드 원유 0.1 ~ 98.0 wt%와,0.1 ~ 98.0 wt% of phytoncide crude oil,

은(Ag) 0.1 ~ 2.0 wt%와,0.1 to 2.0 wt% of silver (Ag), and

미생물 0.1 ~ 20.0 wt%와,0.1 to 20.0 wt% of microorganisms, and

수용성 삼산화규소(SiO3) 0.1 ~ 20.0 wt%를 포함한다.Water-soluble silicon trioxide (SiO 3 ) Contains 0.1 to 20.0 wt%.

상기 수용성 삼산화규소(SiO3)의 사용량이 0.1 wt% 미만인 경우에는 용성 산호칼슘 미네랄, 피톤치드 원유 및 미생물의 기능 활성화 역할이 미미하고, 20.0 wt%를 초과하게 되는 경우에는 활성화 기능의 증가 정도가 미미하여 무의미하므로, 상기 수용성 삼산화규소(SiO3)는 친환경 항균소독제의 전체 배합비 중 0.1 ~ 20.0 wt%로 한정하는 것이 바람직하다.When the amount of the water-soluble silicon trioxide (SiO 3 ) used is less than 0.1 wt%, the role of functional activation of soluble coral calcium mineral, phytoncide crude oil and microorganisms is insignificant, and when it exceeds 20.0 wt%, the increase in the activation function is insignificant. Since it is meaningless, the water-soluble silicon trioxide (SiO 3 ) is preferably limited to 0.1 to 20.0 wt% of the total mixing ratio of the eco-friendly antibacterial disinfectant.

본 발명에 따른 친환경 항균소독제의 제3 및 제4 실시형태에 따른 구체적인 배합예를 살펴보면 다음의 표 5 및 표 6과 같다.Looking at specific formulation examples according to the third and fourth embodiments of the eco-friendly antibacterial disinfectant according to the present invention, Tables 5 and 6 are shown below.

배합예 1Formulation Example 1 배합예 2Combination Example 2 배합예 3Formulation example 3 배합예 4Formulation example 4 배합예 5Combination Example 5 수용성 산호칼슘 미네랄Soluble Coral Calcium Mineral 46.7 wt%46.7 wt% 60.9 wt%60.9 wt% 72.8 wt%72.8 wt% 79.8 wt%79.8 wt% 88.5 wt%88.5 wt% 피톤치드 원유phytoncide crude oil 48.1 wt%48.1 wt% 34.1 wt%34.1 wt% 21.8 wt%21.8 wt% 16.8 wt%16.8 wt% 10.2 wt%10.2 wt% 은(Ag)Silver (Ag) 1.8 wt%1.8 wt% 1.6 wt%1.6 wt% 1.3 wt%1.3 wt% 1.1 wt%1.1 wt% 0.8 wt%0.8 wt% 수용성 삼산화규소(SiO3)Water-soluble silicon trioxide (SiO 3 ) 3.4 wt%3.4 wt% 3.4 wt%3.4 wt% 4.1 wt%4.1 wt% 2.3 wt%2.3 wt% 0.5 wt%0.5 wt% 합 계Sum 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt%

배합예 1Formulation Example 1 배합예 2Combination Example 2 배합예 3Formulation example 3 배합예 4Formulation example 4 배합예 5Combination Example 5 수용성 산호칼슘 미네랄Soluble Coral Calcium Mineral 44.0 wt%44.0 wt% 58.2 wt%58.2 wt% 70.3 wt%70.3 wt% 77.7 wt%77.7 wt% 87.0 wt%87.0 wt% 피톤치드 원유phytoncide crude oil 48.1 wt%48.1 wt% 34.1 wt%34.1 wt% 21.8 wt%21.8 wt% 16.8 wt%16.8 wt% 10.2 wt%10.2 wt% 은(Ag)Silver (Ag) 1.8 wt%1.8 wt% 1.6 wt%1.6 wt% 1.3 wt%1.3 wt% 1.1 wt%1.1 wt% 0.8 wt%0.8 wt% 미생물microbe 2.7 wt%2.7 wt% 3.4 wt%3.4 wt% 4.1 wt%4.1 wt% 2.3 wt%2.3 wt% 0.5 wt%0.5 wt% 수용성 삼산화규소(SiO3)Water-soluble silicon trioxide (SiO 3 ) 3.4 wt%3.4 wt% 2.7 wt%2.7 wt% 2.5 wt%2.5 wt% 2.1 wt%2.1 wt% 1.5 wt%1.5 wt% 합 계Sum 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt% 100.0 wt%100.0 wt%

본 발명에서 제시되는 친환경 항균소독제는 초음파 가습기에 적용하여 사용이 용이하도록 물(H20)과 혼합하여 액상으로 구성될 수 있다.The eco-friendly antibacterial disinfectant presented in the present invention may be mixed with water (H 2 0) to make it easier to use by being applied to an ultrasonic humidifier to be composed of a liquid.

이때 상기 액상은 친환경 항균소독제 1.0 ~ 40.0 wt%와 물(H20) 60.0 ~ 99.0 wt%로 구성된다. 구체적인 예로는 항균소독제 20.0 wt%와 물(H20) 80.0 wt%로 구성된다.At this time, the liquid is composed of 1.0 ~ 40.0 wt% of an eco-friendly antibacterial disinfectant and 60.0 ~ 99.0 wt% of water (H 2 0). A specific example is composed of 20.0 wt% of antibacterial disinfectant and 80.0 wt% of water (H 2 0).

본 발명에 따른 친환경 항균소독제는 천연 피톤치드에 수용성 산호칼슘 미네랄, 미생물 및 은(Ag)을 접목시켜 각종 부패균, 식중독균 및 바이러스를 99.9 % 이상 제거할 수 있고, 동시에 탈취 효과를 가짐으로써, 최근 발생된 코로나 19와 같은 전염성 바이러스 소독에 효과적이며, 수용성이라 초음파 가습기에 적용하여 공간항균 소독에도 적합하며 인플루엔자 등 바이러스 항균에 적합하고 탈취 효과도 뛰어나, 코로나19, 메르스, 사스, 조류인플루엔자, 구제역 방역, 신종플루 등에 방역, 병원, 약국 소독용으로 적합하여 가정, 사무실, 백화점 등 다중이용시설, 병원, 학교, 관공서 등의 생활공간 항균소독과, 축사, 돈사, 계사, 공장, 장례식장, 군부대 및 차량에 적용이 가능하여 산업상 이용가능성이 크다.The eco-friendly antibacterial disinfectant according to the present invention can remove 99.9% or more of various spoilage bacteria, food poisoning bacteria and viruses by grafting water-soluble coral calcium minerals, microorganisms and silver (Ag) to natural phytoncide, and at the same time has a deodorizing effect. It is effective in disinfecting infectious viruses such as Corona 19, and is suitable for space antibacterial disinfection by applying to an ultrasonic humidifier because it is water-soluble. Suitable for disinfection of swine flu, etc., and disinfection of hospitals and pharmacies It is applicable and has great industrial applicability.

Claims (7)

수용성 산호칼슘 미네랄 1.0~90.0 wt%와,
피톤치드 원유 0.1~80.0 wt%와,
은(Ag) 0.1~2.0 wt%와,
락토바실러스 팬터리스(Lactobacillus pantheris) 6.0 ~ 10.0 wt%, 락토바실러스 파라부치네리(Lactobacillus parabuchneri) 23.0 ~ 31.0 wt%, 락토바실러스 파라카제이(Lactobacillus paracasei) 22.2 ~ 25.7 wt%, 락토바실러스 파라파라지니스(Lactobacillus parafarraginis) 14.7 ~ 22.4 wt%, 락토바실러스 카멜리애(Lactobacillus camelliae) 11.3 ~ 17.2 wt% 및 락토바실러스 비니(Lactobacillus vini) 7.4 ~ 11.7 wt%로 구성된 복합미생물 0.1~20.0wt%를 포함하는 것을 특징으로 하는 친환경 항균소독제.
Water-soluble coral calcium mineral 1.0-90.0 wt%,
0.1 to 80.0 wt% of phytoncide crude oil,
0.1 to 2.0 wt% of silver (Ag),
Lactobacillus pantheris 6.0 ~ 10.0 wt%, Lactobacillus parabuchneri 23.0 ~ 31.0 wt%, Lactobacillus paracasei 22.2 ~ 25.7 wt%, Lactobacillus parabuchneri (Lactobacillus parabuchneri) 22.2 ~ 25.7 wt% Lactobacillus parafarraginis) 14.7 to 22.4 wt%, Lactobacillus camelliae (Lactobacillus camelliae) 11.3 to 17.2 wt%, and Lactobacillus beani (Lactobacillus vini) characterized in that it contains 0.1 to 20.0 wt% of a complex microorganism composed of 7.4 to 11.7 wt% Eco-friendly antibacterial disinfectant.
삭제delete 삭제delete 청구항 1에 있어서,
수용성 삼산화규소(SiO3) 0.1 ~ 20.0 wt%를 더 포함하는 것을 특징으로 하는 친환경 항균소독제.


The method according to claim 1,
Water-soluble silicon trioxide (SiO 3 ) Eco-friendly antibacterial disinfectant, characterized in that it further comprises 0.1 to 20.0 wt%.


삭제delete 삭제delete 삭제delete
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