CN107053884A - The decal method that preventing heavy metal is separated out - Google Patents
The decal method that preventing heavy metal is separated out Download PDFInfo
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- CN107053884A CN107053884A CN201611130961.XA CN201611130961A CN107053884A CN 107053884 A CN107053884 A CN 107053884A CN 201611130961 A CN201611130961 A CN 201611130961A CN 107053884 A CN107053884 A CN 107053884A
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- high temperature
- decal
- paper
- heavy metal
- decal paper
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Paper (AREA)
Abstract
The present invention relates to the technical field of printing applique, the decal method that especially a kind of preventing heavy metal is separated out comprises the following steps：S1：Raw material；S2：Feedstock treating；S3：Roll black；S4：Silk-screen printing；S5：Transfer；S6：High-temperature process；S7：Cooling；S8：Spraying；S9：Cleaning；S10：Increase cap layer.The solution of the present invention keeps the bright-colored beautiful of high temperature decal paper, meanwhile, by the way of print high temperature isolation cap layer is added on high temperature decal paper surface so that detection is passed through.
Description
Technical field
The present invention relates to the technical field of printing applique, the decal method that especially a kind of preventing heavy metal is separated out.
Background technology
Bottle is the container for filling wine, and the pattern of bottle is varied, there is glass wine bottle, ceramic wine bottle etc., wherein making pottery
Porcelain bottle outward appearance is magnificent, and ceramic wine bottle also can be therefore, welcomed by the people as showpiece.Existing bottle surface can all print
Make some marble papers, mark producer or the trade mark of bottle, allow consumer it is known that the relevant information of bottle, and using colored
Marble paper is printed, and the aesthetics of bottle can also be increased substantially, after the drinks in bottle have been drunk, and be also used as the art work and entered
Row ornaments.
The existing applique on bottle is more using marble paper in marble paper, glaze on high temperature marble paper, glaze etc..Wherein, spent for high temperature
Paper, is mostly the common high temperature marble paper pigment used in the market.Common hard fire colour have it is bright-colored, it is difficult for drop-off,
Physicochemical properties are stable, and cost is low, marble paper long shelf-life, the advantages of technology maturation, so as to be widely used.But print
High temperature marble paper contain the heavy metals such as substantial amounts of lead cadmium, its stripping quantity is larger.These have printed the bottle of high temperature marble paper in outlet
When, pair in European Union and the U.S. etc., the market product has certain limitation, and these countries can use the detection method of California, USA 65, i.e.,
Bottle surface heavy metal separates out situation and is detected that often content of beary metal is beyond international standard so that bottle outlet has one
Fixed obstruction.
The problem of cadmium leaded for heavy metal in high temperature common marble paper, the market development goes out corresponding low lead high temperature marble paper face
Material, is improved, replaces or reduce the content of the material of leaded cadmium heavy metal as far as possible in itself to pigment, but for now
Low lead high temperature marble paper color is more dim, and outward appearance is not good, it is impossible to adapt to the demand of client.
The content of the invention
It is an object of the invention to provide the anti-huge sum of money that a kind of bright-colored beautiful and cut-off marble paper surface heavy metal is separated out
Belong to the decal method separated out.
To reach above-mentioned purpose, the technical scheme is that：The decal method that a kind of preventing heavy metal is separated out, including it is following
Step：
S1：Raw material：Raw material includes the component of following mass fraction：8~11 parts of feldspar, 15~19 parts of quartz, Datong District's soil 10
~12 parts, 15~20 parts of white glaze；
S2：Feedstock treating：It regard each coloring oxide and mineralizer as dispensing；Datong District's soil is calcined through tunnel cave, is forged
It is 1280~1320 DEG C to burn temperature；Datong District's soil and dispensing after feldspar, quartz, calcining is by material：Ball：Water=1:1.5:1 ball milling, it is right
Pigment after ball milling is sieved and dried；
S3：Roll black：By pigment and tune dirty oil according to mass ratio 10:7~8 ratio blending, after by grinding formed printing
Pigment；
S4：Silk-screen printing：The pigment of printing is screen printed onto on wild goose mulberry paper, high temperature decal paper is made, and in high temperature
One layer of organic bond of decal paper surface smear；
S5：Transfer：High temperature decal paper is posted on biscuiting glazed body, wild goose mulberry paper is torn off, in high temperature decal paper surface spraying
One layer of white glaze；
S6：High-temperature process：By surface have high temperature decal paper biscuiting glazed body carry out high-temperature firing, firing temperature be 600~
730 DEG C, the firing time is 5~8h；
S7：Cooling：The biscuiting glazed body for having high temperature decal paper to surface carries out natural cooling, and cool time is 10~15h；
S8：Spraying：To spraying protein solution at high temperature decal paper, treat that protein solution solidifies, setting time is 8
~10min；
S9：Cleaning：The protein solution on high temperature decal paper surface is cleaned using clear water, it wiped after cleaning
Dry, scavenging period is 10~12min；
S10：Increase cap layer：There is the biscuiting glazed body of high temperature decal paper to carry out high temperature to surface to melt down, melt down temperature for 900~
1000 DEG C, to one layer of white glaze of high temperature decal paper surface spraying and the mixture of plastics, the biscuiting glazed body is subjected to high temperature process, plus
Work temperature is 1200~1300 DEG C, and process time is 2~4h.
Beneficial effects of the present invention：
In the present invention, the biscuiting glazed body for first having high temperature decal paper to surface carries out high-temperature firing, then carries out nature to it
Cooling, during high-temperature firing, the heavy metal such as lead cadmium in high temperature decal paper can be separated out slowly, with the natural cooling time
Extension, heavy metal amount of precipitation can increase, and heavy metal can be attached to the surface of high temperature decal paper, now, then to high temperature decal paper at
Protein solution is sprayed, such protein solution reacts with heavy metal so that protein and heavy metal are combined into insoluble
Salt and cover on biscuiting glazed body surface, reduce the content of part heavy metal, but there are still a large amount of weights in high temperature decal paper
Metal, to keep the color of high temperature decal paper beautiful.For the plurality of heavy metal being still had in high temperature decal paper, the present invention
The mixture of one layer of white glaze and plastics in high temperature decal paper surface spraying, wherein plastics can form one on high temperature decal paper surface
Layer isolation cap layer, the heavy metal of isolation high temperature decal paper is separated out, and white glaze and the composition on high temperature decal paper surface are approached, and are burnt in high temperature
It during system, can well merge, plastics can be made to be combined well with high temperature decal paper, be not in fall with reference to dynamics preferably
Situation.By reducing part content of beary metal, it is to avoid heavy metal amount of precipitation is excessive, simultaneously, it is ensured that a certain amount of heavy metal
Content so that high temperature decal paper it is bright-colored beautiful, meet the demand of client；Meanwhile, coat one layer of white glaze and plastics
Mixture, forms isolation cap layer, is easy to by high temperature decal paper surface heavy metal analysis.
In the preferred scheme 1 that improvement to base case is obtained, S8 steps, surface is had to the biscuiting glazed body of high temperature decal paper
Keep flat on the ground, high temperature decal paper can cause the white glaze of spraying and the mixture of plastics to rest on high temperature patch upward, so
Marble paper surface, the shape and structure for so forming cap layer can be relatively good, and will not waste of materials.
In the preferred scheme 2 that improvement to preferred scheme 1 is obtained, S7 steps, cool time is 12h, now, high temperature applique
The heavy metal of paper can separate out 30% or so, not interfere with the color of high temperature decal paper so that high temperature decal paper keeps color beautiful,
And it can be precipitated by the heavy metal to 30% or so, reduce the content of heavy metal, the cap layer isolation formed so as to the later stage
It is better.
The preferred scheme 3 that improvement to preferred scheme 2 is obtained, biscuiting glazed body is bottle.
The preferred scheme 4 that improvement to preferred scheme 3 is obtained, the compositions of plastics include polyethylene terephthalate,
Makrolon, polyethylene, polypropylene and polyamide, plastics into branch high temperature decal paper surface formed one layer of cap layer, and modeling
Material structure has the suppleness of one end, can be not in the situation of wrinkle around bottle shaping, meanwhile, plastics are formed into branch
Network structure, mesh gap very little, heavy metal is difficult to pass through and dissolution, therefore, can be to the huge sum of money of high temperature decal paper using plastics
Category has good buffer action.
Embodiment
Below by embodiment, the present invention is further detailed explanation：
The decal method that a kind of preventing heavy metal is separated out, other embodiment and contrast is described in detail by taking embodiment 1 as an example below
Example embodies in table 1, and unshowned part is same as Example 1.
Embodiment 1：The decal method that a kind of preventing heavy metal is separated out, comprises the following steps：
S1：Raw material：Raw material includes following component：Feldspar 24g, quartzy 45g, Datong District soil 30g, white glaze 45g；
S2：Feedstock treating：It regard each coloring oxide and mineralizer as dispensing；Datong District's soil is calcined through tunnel cave, is forged
It is 1280 DEG C to burn temperature；Datong District's soil and dispensing after feldspar, quartz, calcining is by material：Ball：Water=1:1.5:1 ball milling, after ball milling
Pigment sieved and dried；
S3：Roll black：By pigment and tune dirty oil according to mass ratio 10:7 ratio blending, after by grinding formed printing face
Material；
S4：Silk-screen printing：The pigment of printing is screen printed onto on wild goose mulberry paper, high temperature decal paper is made, and in high temperature
One layer of organic bond of decal paper surface smear；
S5：Transfer：High temperature decal paper is posted on biscuiting glazed body, wherein biscuiting glazed body is bottle, tears wild goose mulberry paper off,
One layer of white glaze of high temperature decal paper surface spraying；
S6：High-temperature process：The biscuiting glazed body that there is high temperature decal paper on surface is subjected to high-temperature firing, firing temperature is 600 DEG C,
Firing time is 5h；
S7：Cooling：The biscuiting glazed body for having high temperature decal paper to surface carries out natural cooling, and cool time is 10h；
S8：Spraying：The biscuiting glazed body that there is high temperature decal paper on surface is kept flat on the ground, high temperature decal paper upward, to height
Protein solution is sprayed at warm decal paper, treats that protein solution solidifies, setting time is 8min；
S9：Cleaning：The protein solution on high temperature decal paper surface is cleaned using clear water, it wiped after cleaning
Dry, scavenging period is 10min；
S10：Increase cap layer：There is the biscuiting glazed body of high temperature decal paper to carry out high temperature to surface to melt down, it is 900 to melt down temperature
DEG C, to one layer of white glaze of high temperature decal paper surface spraying and the mixture of plastics, the biscuiting glazed body is subjected to high temperature process, processing temperature
Spend for 1200 DEG C, process time is 2h.The composition of plastics includes polyethylene terephthalate, makrolon, polyethylene, poly-
Propylene and polyamide.
The specific number of the decal method separated out according to a kind of preventing heavy metal of above-described embodiment 1, embodiment 2 and embodiment 3
According to as shown in table 1：
Table 1
7 bottles of identical are made according to above-mentioned preparation method, high temperature decal paper are carried out to bottle, to the high temperature being made
Decal paper arrange as shown in table 2：
Table 2
From the data of table 2, the high temperature decal paper that embodiment 1- embodiments 3 are made has passed through Surface testing heavy metal,
And it is bright-colored beautiful.The most brilliant in colors of high temperature decal paper wherein made by embodiment 2 is beautiful, is optimal experimental data.
Embodiment 2 is compared with comparative example 1, and the high temperature decal paper being made in comparative example 1 has passed through surface heavy metal analysis, but
It is to be faint in color.It is primarily due to, during being fired to high temperature decal paper, the firing time is long, high temperature decal paper
Heavy metal separate out and exceed more than 45% so that the leaching ability of heavy metal amount of high temperature decal paper is excessive, the face of such high temperature decal paper
Color can dim out, close with existing low lead high temperature decal paper.
Embodiment 2 detects that surface heavy metal does not pass through compared with comparative example 2, in the high temperature decal paper that comparative example 2 is made, face
Color is bright-coloured beautiful.It is primarily due to not have to be cooled down after firing, the heavy metal precipitation time is short, so that leaching ability of heavy metal amount is very
Few so that the content of beary metal in later stage is up to more than 90%, this improves isolation difficulty to isolation cap layer, has a part huge sum of money
Category is separated out so that heavy metal Surface testing can not pass through.
Embodiment 2 detects that surface heavy metal does not pass through compared with comparative example 3, in the high temperature decal paper that comparative example 3 is made, face
Color is bright-coloured beautiful.It is primarily due to not be combined the heavy metal of precipitation precipitation using protein solution, high temperature decal paper contains
Some content of beary metal are very high, it is impossible to pass through heavy metal Surface testing.
Embodiment 2 detects that surface heavy metal does not pass through compared with comparative example 4, in the high temperature decal paper that comparative example 4 is made, face
Color is bright-coloured beautiful.It is primarily due to not carry out high temperature decal paper surface cap layer isolation, the heavy metal that high temperature decal paper is separated out surpasses
Go out international standard, it is impossible to pass through heavy metal Surface testing.
Above-described is only that the general knowledge such as known characteristic does not make excessive description herein in embodiments of the invention, scheme.
It should be pointed out that for those skilled in the art, without departing from the inventive concept of the premise, some changes can also be made
Shape and improvement, these should also be considered as protection scope of the present invention, these effects and patent for implementing all without the influence present invention
Practicality.The scope of protection required by this application should be based on the content of the claims, the specific embodiment party in specification
Formula etc. records the content that can be used for explaining claim.
Claims (5)
1. the decal method that a kind of preventing heavy metal is separated out, it is characterised in that comprise the following steps：
S1：Raw material：Raw material includes the component of following mass fraction：8~11 parts of feldspar, 15~19 parts of quartz, Datong District's soil 10~12
Part, 15~20 parts of white glaze；
S2：Feedstock treating：It regard each coloring oxide and mineralizer as dispensing；Datong District's soil is calcined through tunnel cave, calcining temperature
Spend for 1280~1320 DEG C；Datong District's soil and dispensing after feldspar, quartz, calcining is by material：Ball：Water=1:1.5:1 ball milling, to ball milling
Pigment afterwards is sieved and dried；
S3：Roll black：By pigment and tune dirty oil according to mass ratio 10:7~8 ratio blending, after by grinding formed printing face
Material；
S4：Silk-screen printing：The pigment of printing is screen printed onto on wild goose mulberry paper, high temperature decal paper is made, and in high temperature applique
One layer of organic bond of paper surface smear；
S5：Transfer：High temperature decal paper is posted on biscuiting glazed body, wild goose mulberry paper is torn off, in one layer of high temperature decal paper surface spraying
White glaze；
S6：High-temperature process：The biscuiting glazed body that there is high temperature decal paper on surface is subjected to high-temperature firing, firing temperature is 600~730
DEG C, the firing time is 5~8h；
S7：Cooling：The biscuiting glazed body for having high temperature decal paper to surface carries out natural cooling, and cool time is 10~15h；
S8：Spraying：To spraying protein solution at high temperature decal paper, treat that protein solution solidify, setting time for 8~
10min；
S9：Cleaning：The protein solution on high temperature decal paper surface is cleaned using clear water, it dried after cleaning, clearly
The time is washed for 10~12min；
S10：Increase cap layer：There is the biscuiting glazed body of high temperature decal paper to carry out high temperature to surface to melt down, it is 900~1000 to melt down temperature
DEG C, to one layer of white glaze of high temperature decal paper surface spraying and the mixture of plastics, the biscuiting glazed body is subjected to high temperature process, processing temperature
Spend for 1200~1300 DEG C, process time is 2~4h.
2. the decal method that a kind of preventing heavy metal according to claim 1 is separated out, it is characterised in that：In the S8 steps,
The biscuiting glazed body that there is high temperature decal paper on surface is kept flat on the ground, high temperature decal paper is upward.
3. the decal method that a kind of preventing heavy metal according to claim 2 is separated out, it is characterised in that：In the S7 steps,
Cool time is 12h.
4. the decal method that a kind of preventing heavy metal according to claim 3 is separated out, it is characterised in that：The biscuiting glazed body is
Bottle.
5. the decal method that a kind of preventing heavy metal according to claim 4 is separated out, it is characterised in that：The composition of the plastics
Including polyethylene terephthalate, makrolon, polyethylene, polypropylene and polyamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611130961.XA CN107053884B (en) | 2016-12-09 | 2016-12-09 | The decal method that preventing heavy metal is precipitated |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611130961.XA CN107053884B (en) | 2016-12-09 | 2016-12-09 | The decal method that preventing heavy metal is precipitated |
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| Publication Number | Publication Date |
|---|---|
| CN107053884A true CN107053884A (en) | 2017-08-18 |
| CN107053884B CN107053884B (en) | 2018-11-30 |
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| CN201611130961.XA Active CN107053884B (en) | 2016-12-09 | 2016-12-09 | The decal method that preventing heavy metal is precipitated |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1348651A (en) * | 1971-01-19 | 1974-03-20 | Ramsden Co Ltd C E | Decoration of ceramic workpieces |
| CN1483597A (en) * | 2003-05-01 | 2004-03-24 | 民 张 | Color glazing decoration craft for ceramic wine bottle |
| CN101671201A (en) * | 2008-09-08 | 2010-03-17 | 吴任可 | Under-glaze and in-glaze picture pattern decorating method of magnesia porcelain |
| CN101811891A (en) * | 2010-04-28 | 2010-08-25 | 伟业陶瓷有限公司 | Method for rapidly removing lead-cadmium residual on surface of |
| CN102166899A (en) * | 2010-12-28 | 2011-08-31 | 宗海燕 | Applique non-removal paper one-time sintered ceramic in-glaze color flower paper |
| CN202989000U (en) * | 2012-12-18 | 2013-06-12 | 广东省潮州市质量计量监督检测所 | Domestic ceramic for reducing heavy metal risks |
| CN105000916A (en) * | 2015-07-10 | 2015-10-28 | 广东宏海陶瓷实业发展有限公司 | Glazed tile manufactured from ceramic wastes and having surface with stone-like luster and preparation method therefor |
-
2016
- 2016-12-09 CN CN201611130961.XA patent/CN107053884B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1348651A (en) * | 1971-01-19 | 1974-03-20 | Ramsden Co Ltd C E | Decoration of ceramic workpieces |
| CN1483597A (en) * | 2003-05-01 | 2004-03-24 | 民 张 | Color glazing decoration craft for ceramic wine bottle |
| CN101671201A (en) * | 2008-09-08 | 2010-03-17 | 吴任可 | Under-glaze and in-glaze picture pattern decorating method of magnesia porcelain |
| CN101811891A (en) * | 2010-04-28 | 2010-08-25 | 伟业陶瓷有限公司 | Method for rapidly removing lead-cadmium residual on surface of |
| CN102166899A (en) * | 2010-12-28 | 2011-08-31 | 宗海燕 | Applique non-removal paper one-time sintered ceramic in-glaze color flower paper |
| CN202989000U (en) * | 2012-12-18 | 2013-06-12 | 广东省潮州市质量计量监督检测所 | Domestic ceramic for reducing heavy metal risks |
| CN105000916A (en) * | 2015-07-10 | 2015-10-28 | 广东宏海陶瓷实业发展有限公司 | Glazed tile manufactured from ceramic wastes and having surface with stone-like luster and preparation method therefor |
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| Publication number | Publication date |
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| CN107053884B (en) | 2018-11-30 |
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