CN107034668A - 一种织物防寒隔热涂料及制备方法 - Google Patents
一种织物防寒隔热涂料及制备方法 Download PDFInfo
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Abstract
一种织物防寒隔热涂料及制备方法，其中，涂料的各原料通过如下重量百分含量制备而成：乙醇25‑32%，2‑羟基‑4‑正辛氧基二苯甲酮0.5‑2%，乙酸乙酯0.1‑0.3%，聚丙烯酸树脂0.5‑1.2%，邻苯二甲酸二辛酯0.05‑0.10%，聚酰胺树脂2‑5%，磷酸酯0.05‑0.09%，含镍锆多孔复合粉体28‑33%，丙烯酸0.1‑0.3%，其余为聚氨酯。本发明通过采用各种辅料和主料配合，各个组分的相互作用和协调，从而使该防寒隔热涂料在保温隔热同时，还具有耐强光照射、耐老化等特性，特别是其隔热性能非常优异。
Description
技术领域
本发明属于涂料领域，具体涉及一种织物防寒隔热涂料及制备方法。
背景技术
织物防寒隔热涂料在生活中存在广泛的应用，因此也得到研究人员的高度重视。如专利CN201410433262.7中公开的一种户外帐篷涂料，由以下重量份的组份制成：环氧树脂40-60份、颜料5-15份、填料5-10份、分散剂1-2份、流平剂1-2份、防腐剂1-2份、消泡剂1-2份、催干剂1-2份、增塑剂1-2份、成膜助剂1-2份、丙酮30份、水70份，但是该涂料原料综合性能不高，不能满足现代工业生活的需求。
发明内容
本发明的针对现有技术中的不足，提供一种织物防寒隔热涂料及制备方法。
为实现上述目的，本发明采用以下技术方案：
一种织物防寒隔热涂料，其特征在于，由如下原料制备而成：乙醇，2-羟基-4-正辛氧基二苯甲酮，乙酸乙酯，聚丙烯酸树脂，邻苯二甲酸二辛酯，聚酰胺树脂，磷酸酯，含镍锆多孔复合粉体，丙烯酸和聚氨酯。
为优化上述技术方案，采取的具体措施还包括：
各原料通过如下重量百分含量制备而成：乙醇25-32％，2-羟基-4-正辛氧基二苯甲酮0.5-2％，乙酸乙酯0.1-0.3％，聚丙烯酸树脂0.5-1.2％，邻苯二甲酸二辛酯0.05-0.10％，聚酰胺树脂2-5％，磷酸酯0.05-0.09％，含镍锆多孔复合粉体28-33％，丙烯酸0.1-0.3％，其余为聚氨酯。
此外，还公开了一种如上所述的织物防寒隔热涂料的制备方法，包括如下步骤：
将四水醋酸镍加入醋酸酐中搅拌配成5-10g/100mL溶液，然后加热到110-120℃保温6-9小时，得到镍前驱体；
将乙醇与水按照3∶1-0.8的体积比混合而得到醇水溶液，将硝酸氧锆溶于醇水溶液中并搅拌，得到硝酸氧锆溶解液，其中，硝酸氧锆的浓度为0.25mol/L；
待硝酸氧锆溶解完全后，加入镍前驱体，镍前驱体与硝酸氧锆溶解液的重量比为1∶2-3；
继续搅拌20-40分钟，使镍前驱体分散均匀，然后加入2，4-戊二酮，搅拌20-30分钟后加入N，N-二甲基甲酰胺，随后搅拌30-40分钟后逐渐加入1，2-氧化丁烯，再搅拌10-20分钟后得含镍溶胶，其中，硝酸氧锆、1，2-氧化丁烯、2，4-戊二酮和N，N-二甲基甲酰胺的摩尔比为1∶8∶4∶1-0.8；
将铁氧体粉加入含镍溶胶并搅拌均匀，置于65-80℃水中保持3-5小时得到凝胶，之后置于马弗炉中得到含镍锆多孔复合粉体，其中，含镍溶胶与铁氧体粉的重量比为1∶3-5；
以重量百分含量为乙醇25-32％、2-羟基-4-正辛氧基二苯甲酮0.5-2％、乙酸乙酯0.1-0.3％、聚丙烯酸树脂0.5-1.2％、邻苯二甲酸二辛酯0.05-0.10％、聚酰胺树脂2-5％、磷酸酯0.05-0.09％、含镍锆多孔复合粉体28-33％、丙烯酸0.1-0.3％、其余为聚氨酯进行配料混合，在容器中搅拌均匀形成涂料；
将涂料在纯棉织物上刮涂一遍，厚度为200-400微米，110-130℃烘干3-9分钟。
所述铁氧体粉的制备如下：将铁芯破碎至粉体粒径为15-25微米的粉末，在910-950℃的温度下预烧60-120分钟，然后再粉碎研磨得到粉体粒径为5-10微米的铁氧体粉。
所述铁氧体粉中各材料的重量百分比为：ZnO 15-20wt％、PbO 0.1-0.3wt％、Na2O0.009-0.015wt％、MnO25-10wt％、Al2O30.2-0.5wt％、SiO20.03-0.05wt％、La2O30.05-0.08wt％、其余为Fe2O3。
本发明的有益效果是：原料来源丰富，成本低廉，可利用电器废料；采用各种辅料和主料配合，通过各个组分的相互作用和协调，使该防寒隔热涂料在保温隔热同时，还具有耐强光照射、耐老化等特性，综合性能良好；多孔氧化物复合体具有均匀分布的微孔，带来了非常优异的隔热性能；制备方法简单，生产成本低，适合于工业化生产。
附图说明
图1是本发明织物防寒隔热涂料的组织图。
具体实施方式
现在结合附图对本发明作进一步详细的说明。
本发明的织物防寒隔热涂料，通过如下重量百分含量的原料制备而成：乙醇25-32％，2-羟基-4-正辛氧基二苯甲酮0.5-2％，乙酸乙酯0.1-0.3％，聚丙烯酸树脂0.5-1.2％，邻苯二甲酸二辛酯0.05-0.10％；聚酰胺树脂2-5％，磷酸酯0.05-0.09％，含镍锆多孔复合粉体28-33％，丙烯酸0.1-0.3％，其余为聚氨酯。
将电器回收的铁芯破碎至粉体粒径为15-25微米的粉末，而后在910-950℃的温度下预烧60-120分钟，然后再粉碎研磨得到粉体粒径为5-10微米的铁氧体粉待用。铁氧体按照重量百分比为ZnO 15-20wt％、PbO 0.1-0.3wt％、Na2O 0.009-0.015wt％、MnO2 5-10wt％、Al2O30.2-0.5wt％、SiO20.03-0.05wt％、La2O30.05-0.08wt％、其余为Fe2O3。
将四水醋酸镍加入醋酸酐中搅拌配成5-10g/100mL溶液，然后加热到110-120℃保温6-9小时，得到镍前驱体。将乙醇与水按照3∶1-0.8的体积比混合而得醇水溶液，然后将硝酸氧锆溶于此溶液并搅拌，浓度为0.25mol/L。待硝酸氧锆溶解完全后，加入镍前驱体。镍前驱体与硝酸氧锆溶解液的重量比为1∶2-3。继续搅拌20-40分钟，使镍前驱体在体系中分散均匀，然后加入2，4-戊二酮，搅拌20-30分钟后加入N，N-二甲基甲酰胺，搅拌30-40分钟后逐渐加入1，2-氧化丁烯，再搅拌10-20分钟后得含镍溶胶。其中，硝酸氧锆∶1，2-氧化丁烯∶2，4-戊二酮∶N，N-二甲基甲酰胺的摩尔比为1∶8∶4∶1-0.8。
这时将铁氧体粉加入含镍溶胶并搅拌均匀，置于65-80℃水中保持3-5小时得凝胶，此后置于马福炉得到含镍锆多孔复合粉体。经研磨后得到粒径为15-30微米的含镍锆多孔复合粉体，含镍溶胶与铁氧体粉的重量比为1∶3-5。
然后以重量百分比为乙醇25-32％、2-羟基-4-正辛氧基二苯甲酮0.5-2％、乙酸乙酯0.1-0.3％、聚丙烯酸树脂0.5-1.2％、邻苯二甲酸二辛酯0.05-0.10％、聚酰胺树脂2-5％、磷酸酯0.05-0.09％、含镍锆多孔复合粉体28-33％、丙烯酸0.1-0.3％、其余为聚氨酯的配料进行混合，在容器中搅拌均匀即形成涂料。
将涂料在纯棉织物上刮涂一遍后，厚度为200-400微米，110-130℃烘干3-9分钟。
图1是该织物防寒隔热涂料的组织，可以看到组织均匀致密。织物防寒隔热涂料的性能见表1，由此可见，该织物防寒隔热涂料不仅原料来源丰富，成本低廉，特别使用了电器废料，并且通过采用各种辅料和主料配合，各个组分的相互作用和协调，从而使该防寒隔热涂料在保温隔热同时，还具有耐强光照射、耐老化等特性，由于多孔氧化物复合体具有均匀分布的微孔，使其隔热性能非常优异。此外，制备方法简单，生产成本低，适合于工业化生产。
表1 各涂料的性能对比
以上仅是本发明的优选实施方式，本发明的保护范围并不仅局限于上述实施例，凡属于本发明思路下的技术方案均属于本发明的保护范围。应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理前提下的若干改进和润饰，应视为本发明的保护范围。
Claims (5)
1.一种织物防寒隔热涂料，其特征在于，由如下原料制备而成：乙醇，2-羟基-4-正辛氧基二苯甲酮，乙酸乙酯，聚丙烯酸树脂，邻苯二甲酸二辛酯，聚酰胺树脂，磷酸酯，含镍锆多孔复合粉体，丙烯酸和聚氨酯。
2.如权利要求1所述的一种织物防寒隔热涂料，其特征在于：各原料通过如下重量百分含量制备而成：乙醇25-32%，2-羟基-4-正辛氧基二苯甲酮0.5-2%，乙酸乙酯0.1-0.3%，聚丙烯酸树脂0.5-1.2%，邻苯二甲酸二辛酯0.05-0.10%，聚酰胺树脂2-5%，磷酸酯0.05-0.09%，含镍锆多孔复合粉体28-33%，丙烯酸0.1-0.3%，其余为聚氨酯。
3.一种如权利要求1所述的织物防寒隔热涂料的制备方法，包括如下步骤：
将四水醋酸镍加入醋酸酐中搅拌配成5-10g/100mL溶液，然后加热到110-120℃保温6-9小时，得到镍前驱体；
将乙醇与水按照3:1-0.8的体积比混合而得到醇水溶液，将硝酸氧锆溶于醇水溶液中并搅拌，得到硝酸氧锆溶解液，其中，硝酸氧锆的浓度为0.25mol/L；
待硝酸氧锆溶解完全后，加入镍前驱体，镍前驱体与硝酸氧锆溶解液的重量比为1:2-3；
继续搅拌20-40分钟，使镍前驱体分散均匀，然后加入2，4-戊二酮，搅拌20-30分钟后加入N，N-二甲基甲酰胺，随后搅拌30-40分钟后逐渐加入1，2-氧化丁烯，再搅拌10-20分钟后得含镍溶胶，其中，硝酸氧锆、1，2-氧化丁烯、2，4-戊二酮和N，N-二甲基甲酰胺的摩尔比为1∶8∶4∶1-0.8；
将铁氧体粉加入含镍溶胶并搅拌均匀，置于65-80℃水中保持3-5小时得到凝胶，之后置于马弗炉中得到含镍锆多孔复合粉体，其中，含镍溶胶与铁氧体粉的重量比为1:3-5；
以重量百分含量为乙醇25-32%、2-羟基-4-正辛氧基二苯甲酮0.5-2%、乙酸乙酯0.1-0.3%、聚丙烯酸树脂0.5-1.2%、邻苯二甲酸二辛酯0.05-0.10%、聚酰胺树脂2-5%、磷酸酯0.05-0.09%、含镍锆多孔复合粉体28-33%、丙烯酸0.1-0.3%、其余为聚氨酯进行配料混合，在容器中搅拌均匀形成涂料；
将涂料在纯棉织物上刮涂一遍，厚度为200-400微米，110-130℃烘干3-9分钟。
4.如权利要求3所述的织物防寒隔热涂料的制备方法，其特征在于：所述铁氧体粉的制备如下：将铁芯破碎至粉体粒径为15-25微米的粉末，在910-950℃的温度下预烧60-120分钟，然后再粉碎研磨得到粉体粒径为5-10微米的铁氧体粉。
5.如权利要求4所述的织物防寒隔热涂料的制备方法，其特征在于：所述铁氧体粉中各材料的重量百分比为：ZnO 15-20wt％、PbO 0.1-0.3wt％、Na2O 0.009-0.015wt％、MnO2 5-10wt％、Al2O3 0.2-0.5wt％、SiO20.03-0.05wt％、La2O30.05-0.08wt％、其余为Fe2O3。
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