CN107033801A - A kind of fire-retardant heat-sensitive variable colour adhesive tape - Google Patents
A kind of fire-retardant heat-sensitive variable colour adhesive tape Download PDFInfo
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- CN107033801A CN107033801A CN201710254037.0A CN201710254037A CN107033801A CN 107033801 A CN107033801 A CN 107033801A CN 201710254037 A CN201710254037 A CN 201710254037A CN 107033801 A CN107033801 A CN 107033801A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J145/00—Adhesives based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/245—Vinyl resins, e.g. polyvinyl chloride [PVC]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of fire-retardant heat-sensitive variable colour adhesive tape, include each component of following mass fraction：3 10 parts of nitrile rubber, 58 parts of polyethylene glycol, 10 20 parts of modified terpene resin, 10 15 parts of ACM, 6 10 parts of carbonic acid silicon, 10 15 parts of platelet talcum, 57 parts of titanium dioxide, 10 20 parts of epoxy resin, 69 parts of hydroxyethyl cellulose, 56 parts of polyacrylamide, 5 10 parts of stearic acid pentaerythritol ester, 30 50 parts of EHMA, 15 20 parts of polyvinyl chloride, 15 25 parts of heat-sensitive variable colour microcapsules, the heat-sensitive variable colour microcapsules are that thermo-varing liquid crystal is filled with transparent capsule, the heat-sensitive variable colour microcapsules.The present invention can make adhesive tape have stronger fire retardant performance, and water proofing property is strong, acid and alkali-resistance, while by heat-sensitive variable colour the temperature province in belt packing face can also be shown in real time, be easy to quick Inspection and maintenance, beneficial to popularization.
Description
【Technical field】
The present invention relates to the technical field of adhesive tape manufacture, particularly a kind of technical field of fire-retardant heat-sensitive variable colour adhesive tape.
【Background technology】
Use of the adhesive in packaging industry has had the history of last 100 yearses.It is gluing with the development of packaging industry
The consumption figure of agent remains higher level, and global packaging industry year glue consumption accounts for the 35% of the total consumption of adhesive, pushed away accordingly
It is probably the maximum consumption market of adhesive to survey packaging industry.Adhesive tape, adhesive tape is made up of base material and binding agent two parts, is led to
Crossing bonding makes two or more disjunct objects link together.One layer of sticker is scribbled on its surface.Sticker can glue
Firmly thing, is due to that the intermolecular formation of the molecule of itself and article to be connected is bonded, this bond can be molecule firmly
Stick together.With expanding economy and the progress of science and technology, China has turned into gluing industry processing factory of the world and consumption
Big country.With reference to supporting experience for many years.Speed with annual 16% increases.Particularly adhesive tape, diaphragm and adhesive sticker are extensive
It is applied to electronics, communication, packaging, building, papermaking, carpenter, Aero-Space, automobile, weaving, metallurgy, machine-building, medical industry
Turn into important industry most active in China's chemical industry Deng, gluing industry.
【The content of the invention】
The purpose of the present invention is exactly to solve the problems of the prior art, proposes a kind of fire-retardant heat-sensitive variable colour adhesive tape, can make
Adhesive tape has stronger fire retardant performance, and water proofing property is strong, acid and alkali-resistance, while adhesive tape can also be shown in real time by heat-sensitive variable colour
The temperature province of packed surface, is easy to quick Inspection and maintenance, beneficial to popularization.
To achieve the above object, the present invention proposes a kind of fire-retardant heat-sensitive variable colour adhesive tape, including following mass fraction is each
Component：3-10 parts of nitrile rubber, 5-8 parts of polyethylene glycol, 10-20 parts of modified terpene resin, 10-15 parts of ACM, carbon
Sour silicon 6-10 parts, it is 10-15 parts of platelet talcum, 5-7 parts of titanium dioxide, 10-20 parts of epoxy resin, 6-9 parts of hydroxyethyl cellulose, poly-
5-6 parts of acrylamide, 5-10 parts of stearic acid pentaerythritol ester, 30-50 parts of EHMA, 15-20 parts of polyvinyl chloride,
15-25 parts of heat-sensitive variable colour microcapsules, the heat-sensitive variable colour microcapsules are to be filled with transparent capsule, the heat-sensitive variable colour microcapsules
Thermo-varing liquid crystal.
Preferably, the mass fraction of each component is：3 parts of nitrile rubber, 5 parts of polyethylene glycol, modified terpene resin
10 parts, 10 parts of ACM, 6 parts of carbonic acid silicon, 10 parts of platelet talcum, 5 parts of titanium dioxide, 10 parts of epoxy resin, ethoxy
6 parts of cellulose, 5 parts of polyacrylamide, 5 parts of stearic acid pentaerythritol ester, 30 parts of EHMA, polyvinyl chloride 15
Part, 15 parts of heat-sensitive variable colour microcapsules.
Preferably, the mass fraction of each component is：10 parts of nitrile rubber, 8 parts of polyethylene glycol, modified terpene resin
20 parts, 15 parts of ACM, 10 parts of carbonic acid silicon, 15 parts of platelet talcum, 7 parts of titanium dioxide, 20 parts of epoxy resin, ethoxy
9 parts of cellulose, 6 parts of polyacrylamide, 10 parts of stearic acid pentaerythritol ester, 50 parts of EHMA, polyvinyl chloride 20
Part, 25 parts of heat-sensitive variable colour microcapsules.
Preferably, the mass fraction of each component is：8 parts of nitrile rubber, 8 parts of polyethylene glycol, modified terpene resin
15 parts, 12 parts of ACM, 8 parts of carbonic acid silicon, 12 parts of platelet talcum, 5 parts of titanium dioxide, 20 parts of epoxy resin, ethoxy
9 parts of cellulose, 6 parts of polyacrylamide, 9 parts of stearic acid pentaerythritol ester, 40 parts of EHMA, polyvinyl chloride 20
Part, 25 parts of heat-sensitive variable colour microcapsules.
The present invention proposes a kind of production technology of fire-retardant heat-sensitive variable colour adhesive tape, comprises the following steps successively：
Step one：It is different pungent according to 3-10 parts of mass fraction accurate weighing nitrile rubber, the methacrylic acid given by component
30-50 parts of ester, the raw material of 15-20 parts of polyvinyl chloride are simultaneously uniformly mixed, and are prepared into qualified basement membrane batch；
Step 2：Batch prepared by step one carries out three-stage in melt extruder and founded, and glass melting temperature is successively
For 90~140 DEG C, 150~180 DEG C, 190~200 DEG C, 20min is incubated after founding, extrudes, is made at a temperature of 190-200 DEG C
Basement membrane；
Step 3：According to 5-8 parts of mass fraction accurate weighing polyethylene glycol, the modified terpene resin 10- given by component
20 parts, 10-15 parts of ACM, 6-10 parts of carbonic acid silicon, 10-15 parts of platelet talcum, 5-7 parts of titanium dioxide, epoxy resin
10-20 parts, 6-9 parts of hydroxyethyl cellulose, 5-6 parts of polyacrylamide, 5-10 parts of stearic acid pentaerythritol ester, the micro- glue of heat-sensitive variable colour
The raw material that 15-25 part of capsule is simultaneously uniformly mixed, and is prepared into qualified adhesive batch；
Step 4：Batch prepared by step 3 carries out founding reaction, glass melting temperature 180-220 in melt extruder
DEG C, melting time 1 hour is stirred acceleration in melting process, insulation stands 30min after founding, and adhesive is made in extrusion；
Step 5：Say that adhesive prepared by step 4 heats melt coating on basement membrane prepared by step 2, obtain fire-retardant
Heat-sensitive variable colour adhesive tape finished product.
Beneficial effects of the present invention：The present invention can make adhesive tape have stronger fire retardant performance, and water proofing property is strong, acidproof
Alkali, while the temperature province in belt packing face can also be shown in real time by heat-sensitive variable colour, be easy to quick Inspection and maintenance, beneficial to pushing away
Extensively.
The feature and advantage of the present invention will be described in detail by embodiment.
【Embodiment】
A kind of fire-retardant heat-sensitive variable colour adhesive tape of the present invention, includes each component of following mass fraction：It is 3-10 parts of nitrile rubber, poly-
5-8 parts of ethylene glycol, 10-20 parts of modified terpene resin, 10-15 parts of ACM, 6-10 parts of carbonic acid silicon, platelet talcum 10-
15 parts, 5-7 parts of titanium dioxide, 10-20 parts of epoxy resin, 6-9 parts of hydroxyethyl cellulose, 5-6 parts of polyacrylamide, stearic acid season
5-10 parts of Doutrate, 30-50 parts of EHMA, 15-20 parts of polyvinyl chloride, 15-25 parts of heat-sensitive variable colour microcapsules,
The heat-sensitive variable colour microcapsules are that thermo-varing liquid crystal is filled with transparent capsule, the heat-sensitive variable colour microcapsules.
Embodiment one, the mass fraction of each component is：3 parts of nitrile rubber, 5 parts of polyethylene glycol, modified terpene resin
10 parts, 10 parts of ACM, 6 parts of carbonic acid silicon, 10 parts of platelet talcum, 5 parts of titanium dioxide, 10 parts of epoxy resin, ethoxy
6 parts of cellulose, 5 parts of polyacrylamide, 5 parts of stearic acid pentaerythritol ester, 30 parts of EHMA, polyvinyl chloride 15
Part, 15 parts of heat-sensitive variable colour microcapsules.
Embodiment two, the mass fraction of each component is：10 parts of nitrile rubber, 8 parts of polyethylene glycol, modified terpene resin
20 parts, 15 parts of ACM, 10 parts of carbonic acid silicon, 15 parts of platelet talcum, 7 parts of titanium dioxide, 20 parts of epoxy resin, ethoxy
9 parts of cellulose, 6 parts of polyacrylamide, 10 parts of stearic acid pentaerythritol ester, 50 parts of EHMA, polyvinyl chloride 20
Part, 25 parts of heat-sensitive variable colour microcapsules.
Embodiment three, the mass fraction of each component is：8 parts of nitrile rubber, 8 parts of polyethylene glycol, modified terpene resin
15 parts, 12 parts of ACM, 8 parts of carbonic acid silicon, 12 parts of platelet talcum, 5 parts of titanium dioxide, 20 parts of epoxy resin, ethoxy
9 parts of cellulose, 6 parts of polyacrylamide, 9 parts of stearic acid pentaerythritol ester, 40 parts of EHMA, polyvinyl chloride 20
Part, 25 parts of heat-sensitive variable colour microcapsules.
The present invention proposes a kind of production technology of fire-retardant heat-sensitive variable colour adhesive tape, comprises the following steps successively：
Step one：It is different pungent according to 3-10 parts of mass fraction accurate weighing nitrile rubber, the methacrylic acid given by component
30-50 parts of ester, the raw material of 15-20 parts of polyvinyl chloride are simultaneously uniformly mixed, and are prepared into qualified basement membrane batch；
Step 2：Batch prepared by step one carries out three-stage in melt extruder and founded, and glass melting temperature is successively
For 90~140 DEG C, 150~180 DEG C, 190~200 DEG C, 20min is incubated after founding, extrudes, is made at a temperature of 190-200 DEG C
Basement membrane；
Step 3：According to 5-8 parts of mass fraction accurate weighing polyethylene glycol, the modified terpene resin 10- given by component
20 parts, 10-15 parts of ACM, 6-10 parts of carbonic acid silicon, 10-15 parts of platelet talcum, 5-7 parts of titanium dioxide, epoxy resin
10-20 parts, 6-9 parts of hydroxyethyl cellulose, 5-6 parts of polyacrylamide, 5-10 parts of stearic acid pentaerythritol ester, the micro- glue of heat-sensitive variable colour
The raw material that 15-25 part of capsule is simultaneously uniformly mixed, and is prepared into qualified adhesive batch；
Step 4：Batch prepared by step 3 carries out founding reaction, glass melting temperature 180-220 in melt extruder
DEG C, melting time 1 hour is stirred acceleration in melting process, insulation stands 30min after founding, and adhesive is made in extrusion；
Step 5：Say that adhesive prepared by step 4 heats melt coating on basement membrane prepared by step 2, obtain fire-retardant
Heat-sensitive variable colour adhesive tape finished product.
The present invention can make adhesive tape have stronger fire retardant performance, and water proofing property is strong, acid and alkali-resistance, while can also pass through heat
Quick discoloration to show the temperature province in belt packing face in real time, is easy to quick Inspection and maintenance, beneficial to popularization.
Above-described embodiment is the description of the invention, is not limitation of the invention, it is any to simple transformation of the present invention after
Scheme belong to protection scope of the present invention.
Claims (5)
1. a kind of fire-retardant heat-sensitive variable colour adhesive tape, it is characterised in that：Include each component of following mass fraction：Nitrile rubber 3-10
Part, 5-8 parts of polyethylene glycol, 10-20 parts of modified terpene resin, 10-15 parts of ACM, 6-10 parts of carbonic acid silicon, platelet are slided
It is 10-15 parts of stone, 5-7 parts of titanium dioxide, 10-20 parts of epoxy resin, 6-9 parts of hydroxyethyl cellulose, 5-6 parts of polyacrylamide, hard
5-10 parts of resin acid pentaerythritol ester, 30-50 parts of EHMA, 15-20 parts of polyvinyl chloride, heat-sensitive variable colour microcapsules
15-25 parts, the heat-sensitive variable colour microcapsules are that thermo-varing liquid crystal is filled with transparent capsule, the heat-sensitive variable colour microcapsules.
2. a kind of fire-retardant heat-sensitive variable colour adhesive tape as claimed in claim 1, it is characterised in that：The mass fraction of each component
For：3 parts of nitrile rubber, 5 parts of polyethylene glycol, 10 parts of modified terpene resin, 10 parts of ACM, 6 parts of carbonic acid silicon, platelet are slided
10 parts of stone, 5 parts of titanium dioxide, 10 parts of epoxy resin, 6 parts of hydroxyethyl cellulose, 5 parts of polyacrylamide, stearic acid pentaerythrite
5 parts of ester, 30 parts of EHMA, 15 parts of polyvinyl chloride, 15 parts of heat-sensitive variable colour microcapsules.
3. a kind of fire-retardant heat-sensitive variable colour adhesive tape as claimed in claim 1, it is characterised in that：The mass fraction of each component
For：10 parts of nitrile rubber, 8 parts of polyethylene glycol, 20 parts of modified terpene resin, 15 parts of ACM, 10 parts of carbonic acid silicon, platelet
15 parts of talcum, 7 parts of titanium dioxide, 20 parts of epoxy resin, 9 parts of hydroxyethyl cellulose, 6 parts of polyacrylamide, stearic acid Ji Wusi
10 parts of alcohol ester, 50 parts of EHMA, 20 parts of polyvinyl chloride, 25 parts of heat-sensitive variable colour microcapsules.
4. a kind of fire-retardant heat-sensitive variable colour adhesive tape as claimed in claim 1, it is characterised in that：The mass fraction of each component
For：8 parts of nitrile rubber, 8 parts of polyethylene glycol, 15 parts of modified terpene resin, 12 parts of ACM, 8 parts of carbonic acid silicon, platelet are slided
12 parts of stone, 5 parts of titanium dioxide, 20 parts of epoxy resin, 9 parts of hydroxyethyl cellulose, 6 parts of polyacrylamide, stearic acid pentaerythrite
9 parts of ester, 40 parts of EHMA, 20 parts of polyvinyl chloride, 25 parts of heat-sensitive variable colour microcapsules.
5. a kind of production technology of fire-retardant heat-sensitive variable colour adhesive tape, it is characterised in that：Comprise the following steps successively：
Step one：According to 3-10 parts of mass fraction accurate weighing nitrile rubber, the EHMA 30- given by component
50 parts, the raw material of 15-20 parts of polyvinyl chloride and uniformly mix, be prepared into qualified basement membrane batch；
Step 2：Batch prepared by step one carries out three-stage in melt extruder and founded, and glass melting temperature is followed successively by 90
~140 DEG C, 150~180 DEG C, 190~200 DEG C, 20min is incubated after founding, is extruded at a temperature of 190-200 DEG C, basement membrane is made；
Step 3：According to 10-20 parts of 5-8 parts of mass fraction accurate weighing polyethylene glycol, modified terpene resin given by component,
10-15 parts of ACM, 6-10 parts of carbonic acid silicon, 10-15 parts of platelet talcum, 5-7 parts of titanium dioxide, epoxy resin 10-20
Part, 6-9 parts of hydroxyethyl cellulose, 5-6 parts of polyacrylamide, 5-10 parts of stearic acid pentaerythritol ester, heat-sensitive variable colour microcapsules 15-
25 parts of raw material is simultaneously uniformly mixed, and is prepared into qualified adhesive batch；
Step 4：Batch prepared by step 3 carries out founding reaction in melt extruder, and 180-220 DEG C of glass melting temperature melts
The 1 hour time processed, acceleration is stirred in melting process, insulation stands 30min after founding, and adhesive is made in extrusion；
Step 5：Say that adhesive prepared by step 4 heats melt coating on basement membrane prepared by step 2, obtain fire-retardant temperature-sensitive
Change colour adhesive tape finished product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710254037.0A CN107033801A (en) | 2017-04-18 | 2017-04-18 | A kind of fire-retardant heat-sensitive variable colour adhesive tape |
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| CN201710254037.0A CN107033801A (en) | 2017-04-18 | 2017-04-18 | A kind of fire-retardant heat-sensitive variable colour adhesive tape |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107573861A (en) * | 2017-08-17 | 2018-01-12 | 苏州市新广益电子有限公司 | Novel flame-retardant adhesive tape |
| CN110343479A (en) * | 2019-07-23 | 2019-10-18 | 新纶科技（常州）有限公司 | A kind of non-flammable adhesive tape and preparation method thereof with high-temperature discoloration warning function |
| CN111116056A (en) * | 2019-12-31 | 2020-05-08 | 华南理工大学 | Super-hydrophobic thin film with electrochromic effect by electric heating and preparation method thereof |
| CN112029438A (en) * | 2020-08-14 | 2020-12-04 | 凌健 | Color-changing adhesive tape |
| CN114196347A (en) * | 2022-01-07 | 2022-03-18 | 湖南万祺科技有限公司 | Intelligent temperature control adhesive tape and production process thereof |
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| CN106281092A (en) * | 2016-08-31 | 2017-01-04 | 济宁迅大管道防腐材料有限公司 | A kind of underground piping polythene anticorrosive adhesive tape |
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| CN107573861A (en) * | 2017-08-17 | 2018-01-12 | 苏州市新广益电子有限公司 | Novel flame-retardant adhesive tape |
| CN110343479A (en) * | 2019-07-23 | 2019-10-18 | 新纶科技（常州）有限公司 | A kind of non-flammable adhesive tape and preparation method thereof with high-temperature discoloration warning function |
| CN110343479B (en) * | 2019-07-23 | 2021-07-27 | 新纶科技（常州）有限公司 | Flame-retardant adhesive tape with high-temperature discoloration early warning function and preparation method thereof |
| CN111116056A (en) * | 2019-12-31 | 2020-05-08 | 华南理工大学 | Super-hydrophobic thin film with electrochromic effect by electric heating and preparation method thereof |
| CN112029438A (en) * | 2020-08-14 | 2020-12-04 | 凌健 | Color-changing adhesive tape |
| CN112029438B (en) * | 2020-08-14 | 2022-07-19 | 凌健 | Color-changing adhesive tape |
| CN114196347A (en) * | 2022-01-07 | 2022-03-18 | 湖南万祺科技有限公司 | Intelligent temperature control adhesive tape and production process thereof |
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Application publication date: 20170811 |