CN102199411B - Preparation method of multi-functional liquid glue - Google Patents
Preparation method of multi-functional liquid glue Download PDFInfo
- Publication number
- CN102199411B CN102199411B CN 201110073619 CN201110073619A CN102199411B CN 102199411 B CN102199411 B CN 102199411B CN 201110073619 CN201110073619 CN 201110073619 CN 201110073619 A CN201110073619 A CN 201110073619A CN 102199411 B CN102199411 B CN 102199411B
- Authority
- CN
- China
- Prior art keywords
- parts
- weight
- preparation
- glue
- liquid glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003292 glue Substances 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000007788 liquid Substances 0.000 title abstract description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 8
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012530 fluid Substances 0.000 claims description 11
- 239000013530 defoamer Substances 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 6
- 238000003825 pressing Methods 0.000 claims description 6
- 230000003068 static effect Effects 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 239000003643 water by type Substances 0.000 claims description 6
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 16
- 239000000123 paper Substances 0.000 abstract description 8
- 239000010985 leather Substances 0.000 abstract description 7
- 229920003023 plastic Polymers 0.000 abstract description 7
- 239000004033 plastic Substances 0.000 abstract description 7
- 239000007799 cork Substances 0.000 abstract description 6
- 239000004744 fabric Substances 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 230000035484 reaction time Effects 0.000 abstract description 2
- 238000004026 adhesive bonding Methods 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000004599 antimicrobial Substances 0.000 abstract 1
- 239000011111 cardboard Substances 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000008367 deionised water Substances 0.000 abstract 1
- 229910021641 deionized water Inorganic materials 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000011094 fiberboard Substances 0.000 description 5
- -1 pottery Substances 0.000 description 5
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004830 Super Glue Substances 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000000914 phenoxymethylpenicillanyl group Chemical group CC1(S[C@H]2N([C@H]1C(=O)*)C([C@H]2NC(COC2=CC=CC=C2)=O)=O)C 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Abstract
The invention discloses a preparation method of multi-functional liquid glue. The preparation method comprises: adding 5 parts by weight of deionized water and 10 to 15 parts by weight of polyvinyl alcohol into a reaction vessel under room temperature; heating the materials to a temperature of 90 DEG C; after the materials are completely dissolved, adding 20 to 25 parts by weight of butyl acetate and 15 to 20 parts by weight of glycerin; leaving the materials to react for 1 hour with preserved temperature; cooling the materials to room temperature; adding 8 to 15 parts by weight of ethanol,15 to 20 parts by weight of polyvinyl acetate, a proper amount of an antiseptic agent and a proper amount of an antifoaming agent; leaving the material to de-foam by standing. The technology of the invention is simple. Once the component proportions, the temperatures, and the reaction times are controlled accurately, the preparation can be successful. During the whole process, no wasting is caused, and no pollution is generated. The production process remains in a clean condition. The produced liquid glue is a single-component liquid glue which is easy to use and is multi-purposed. The liquid glue has strong viscosity and can be widely applied for gluing papers, card boards, fabrics, cork, leather, wood materials, ceramics, colored glaze, cards, plastics, and the like.
Description
Technical field
The present invention relates to a kind of preparation method of full-service fluid glue.
Background technology
Liquid glue has good viscosity, can be used for the adhesive paper goods, is office and the study article of a high-quality.
But liquid glue commonly used just is used for pasting paper, and the material require of other side is when pasting, more use be 502 glue, hundred glue such as glue.
502 glue are based on ethyl, add tackifier, stablizer, toughner, stopper etc., by the synthetic single-component instantaneous solidification tackiness agent of vanguard technology.
502 glue are a kind of super glue, water white transparency, and good fluidity, volatile, meeting water is polymerizing curable.And 502 glue are single-component, curing speed is fast, easy to use, bonding force is strong, adhesives is extensive, can be used for iron and steel, non-ferrous metal, rubber, leather, plastics, pottery, glass, timber etc., but be used for polyethylene, polypropylene, polytetrafluoroethylproducts products, material surface needs through special processing.Be widely used in electrical equipment, instrument, machinery, electronics, light instrument, medical treatment, the civilian industry by the time of light industry.
But, 502 glue, hundred the organic solvent that contains of glue such as glue is toluene, benzene, acetone, influential to person health, the limitation of use is also more intense.
Summary of the invention
The technical issues that need to address of the present invention just are to overcome the defective of prior art, a kind of preparation method of full-service fluid glue is provided, technology of the present invention is simple, the liquid glue of preparation is a kind of single-component liquid glue, easy to use, have multiduty function, its viscosity is strong, of many uses, main bonding paper, fiber board, fabric, cork, leather, timber, pottery, coloured glaze, card and plastic or other material.The human consumer be as long as buying one bottle just can use in many-side, do not need to paste to glue the glue that a kind of material will adapt with purchase.Its heavy metal detects and meets relevant criterion fully.
For addressing the above problem, the present invention adopts following technical scheme:
The invention provides a kind of preparation method of full-service fluid glue, pressing row weight part proportioning adds raw materials used: under normal temperature condition, in anti-still, add 5 parts of deionized waters, polyvinyl alcohol 10-15 part, be warming up to 90 ℃, add N-BUTYL ACETATE 20-25 part, glycerol 15-20 part, insulation reaction 1 hour after the dissolving fully, being down to normal temperature adds ethanol 8-15 part, polyvinyl acetate 15-20 part again, adds an amount of sanitas and defoamer, static froth breaking again.
Described sanitas is Ka Song and Bu Luo bohr, and described defoamer is silicone oil.Technology of the present invention is simple, only need the proportioning weighing is accurate, temperature to be controlled well, and the reaction times has been controlled well just.In whole process, there is not any waste, pollution-free generation, production keeps clean.
Full-service fluid glue environment-protecting asepsis, burning-point height, the viscosity height of the present invention's preparation; Of many uses, be suitable for daily, the home decoration of the daily life of a family etc., main bonding paper, fiber board, fabric, cork, leather, timber, metal, pottery, coloured glaze, card and plastic or other material.
The liquid glue of the present invention's preparation is a kind of single-component liquid glue, and is easy to use, has multiduty function, and its viscosity is strong, and is of many uses, main bonding paper, fiber board, fabric, cork, leather, timber, pottery, coloured glaze, card and plastic or other material.The human consumer be as long as buying one bottle just can use in many-side, do not need to paste to glue the glue that a kind of material will adapt with purchase.Its heavy metal detects and meets relevant criterion fully.
It is main raw material that the present invention adopts polyvinyl acetate, is added with reactions such as PVA, ethanol, glycerol, N-BUTYL ACETATE and generates.Compare with the general-purpose glue on the market:
1, full-service fluid glue of the present invention is environment protection type multifunctional glue, and nontoxic, burning-point is low.
The general-purpose glue that market is used has dense smell, and to the people of life-time service, health has certain influence.And the general-purpose glue burning-point height on the market, when producing, very big danger being arranged, the friction of doughnut during answering cell phone, causes possibly and catches fire.
2, to add glycerol mainly be to improve boiling point in the present invention, makes the formation ternary azeotropic, improves the burning grade, thereby improve burning-point, and when producing, any Mars can not cause and catches fire.
Embodiment
In the following example, sanitas is Ka Song and Bu Luo bohr, and defoamer is silicone oil.
Embodiment 1
Pressing row weight part proportioning adds raw materials used: under 23 ℃ of conditions, in anti-still, add 5 parts of deionized waters, 10 parts of polyvinyl alcohol, be warming up to 90 ℃, add 25 parts of N-BUTYL ACETATEs, 15 parts of glycerol after the dissolving fully, insulation reaction 1 hour is down to 23 ℃ and is added 8 parts of ethanol, 20 parts of polyvinyl acetate again, adds an amount of sanitas and defoamer, static froth breaking again.
Embodiment 2
Pressing row weight part proportioning adds raw materials used: under 20 ℃ of conditions, in anti-still, add 5 parts of deionized waters, 15 parts of polyvinyl alcohol, be warming up to 90 ℃, add 20 parts of N-BUTYL ACETATEs, 20 parts of glycerol after the dissolving fully, insulation reaction 1 hour is down to 20 ℃ and is added 15 parts of ethanol, 15 parts of polyvinyl acetate again, adds an amount of sanitas and defoamer, static froth breaking again.
Embodiment 3
Pressing row weight part proportioning adds raw materials used: under 25 ℃ of conditions, in anti-still, add 5 parts of deionized waters, 12 parts of polyvinyl alcohol, be warming up to 90 ℃, add 22 parts of N-BUTYL ACETATEs, 18 parts of glycerol after the dissolving fully, insulation reaction 1 hour is down to 23 ℃ and is added 10 parts of ethanol, 17 parts of polyvinyl acetate again, adds an amount of sanitas and defoamer, static froth breaking again.
Embodiment 4
Pressing row weight part proportioning adds raw materials used: under 18 ℃ of conditions, in anti-still, add 5 parts of deionized waters, 9 parts of polyvinyl alcohol, be warming up to 90 ℃, add 23 parts of N-BUTYL ACETATEs, 17 parts of glycerol after the dissolving fully, insulation reaction 1 hour is down to 18 ℃ and is added 11 parts of ethanol, 17 parts of polyvinyl acetate again, adds an amount of sanitas and defoamer, static froth breaking again.
The liquid glue of embodiment 1-embodiment 4 preparations is a kind of single-component liquid glue, and is easy to use, has multiduty function, its viscosity is strong, and is of many uses, main bonding paper, fiber board, fabric, cork, leather, timber, pottery, coloured glaze, card and plastic or other material.The human consumer be as long as buying one bottle just can use in many-side, do not need to paste to glue the glue that a kind of material will adapt with purchase.Its heavy metal detects and meets relevant criterion fully.
The full-service fluid glue of embodiment 1-embodiment 4 preparations is nontoxic, burning-point is low, viscosity is high, benzene content≤1ppm.
The full-service fluid glue of embodiment 1-embodiment 4 preparation is of many uses, is suitable for that the daily life of a family is daily, home decoration etc., main bonding paper, fiber board, fabric, cork, leather, timber, metal, pottery, coloured glaze, card and many plastics water-absorbing materials.
Be applicable to thin cap, more be applicable to thick metal, can well force together into a part to two portions of identical material.If press immediately, two parts do not bond together, and two portions are forced together after can vaporing away a bit earlier again.
The full-service fluid glue of embodiment 1-embodiment 4 preparation belongs to the solvent-borne type product, and forming can be not water-soluble behind the piece, nontoxic, nonflammable, after eating by mistake to child, can not be dissolved in the body, also can not influence healthyly, discharges easily.
It should be noted that at last: obviously, above-described embodiment only is for example of the present invention clearly is described, and is not the restriction to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here need not also can't give all embodiments exhaustive.And the apparent variation of being amplified out thus or change still are among protection scope of the present invention.
Claims (2)
1. the preparation method of a full-service fluid glue, it is characterized in that, pressing row weight part proportioning adds raw materials used: under normal temperature condition, add 5 parts of deionized waters in anti-still, polyvinyl alcohol 10-15 part is warming up to 90 ℃, add N-BUTYL ACETATE 20-25 part, glycerol 15-20 part after the dissolving fully, insulation reaction 1 hour is down to normal temperature and is added ethanol 8-15 part, polyvinyl acetate 15-20 part again, adds an amount of sanitas and defoamer, static froth breaking again.
2. the preparation method of full-service fluid glue as claimed in claim 1, it is characterized in that: described sanitas is Ka Song and Bu Luo bohr, and described defoamer is silicone oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110073619 CN102199411B (en) | 2011-03-25 | 2011-03-25 | Preparation method of multi-functional liquid glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110073619 CN102199411B (en) | 2011-03-25 | 2011-03-25 | Preparation method of multi-functional liquid glue |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102199411A CN102199411A (en) | 2011-09-28 |
| CN102199411B true CN102199411B (en) | 2013-07-10 |
Family
ID=44660405
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110073619 Expired - Fee Related CN102199411B (en) | 2011-03-25 | 2011-03-25 | Preparation method of multi-functional liquid glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102199411B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106147699A (en) * | 2016-07-21 | 2016-11-23 | 柳州市五源科技有限公司 | Liquid glue |
| CN106366948A (en) * | 2016-08-30 | 2017-02-01 | 佛山市三水区奇力王化工有限公司 | Water-based all-purpose adhesive |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048226A (en) * | 1989-06-21 | 1991-01-02 | 福建省医学科学研究所 | Medical cotton stick glue |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1214086C (en) * | 2001-12-28 | 2005-08-10 | 北京制浆造纸研究院 | Composite rewetting rebonding adhesive |
-
2011
- 2011-03-25 CN CN 201110073619 patent/CN102199411B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048226A (en) * | 1989-06-21 | 1991-01-02 | 福建省医学科学研究所 | Medical cotton stick glue |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102199411A (en) | 2011-09-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103361012B (en) | A kind of applicable wide HDPE self-adhesive coiled material hot-fusible pressure-sensitive adhesive and preparation method thereof | |
| CN104774587B (en) | High-viscosity high-heat resistance modified organic silicone resin binder and preparation method thereof | |
| CN101503604A (en) | SBS universal glue and preparation thereof | |
| CN103881618B (en) | A kind of fast package hot melt adhesive and preparation method thereof | |
| CN102153968A (en) | Hot melt adhesive for medical dialyzing paper | |
| CN103709976A (en) | Hot-melt glue and preparation method thereof | |
| CN102199411B (en) | Preparation method of multi-functional liquid glue | |
| CN102786898A (en) | Hot melt adhesive composition for carpet skid resistance and preparation method of hot melt adhesive composition | |
| CN106634716A (en) | Water-based adhesive, and preparation method and application thereof | |
| CN104610892A (en) | Formula of environment-friendly particle hot-melt type pressure-sensitive adhesive and preparation method for adhesive | |
| CN105315933B (en) | A kind of antistripping instant drying adhesive and preparation method thereof | |
| CN103665270A (en) | Preparation method of soy protein adhesive | |
| CN105623563A (en) | Environment-friendly film mulching glue and preparation method thereof | |
| CN107987757A (en) | The plastic bottle environmentally friendly adhesive for labels of series and its preparation method | |
| CN106833454A (en) | Modified Environment-friendlyglue glue of a kind of bamboo fiber and preparation method thereof | |
| CN103360992A (en) | Packaging paper adhesive and preparation method thereof | |
| CN103360985A (en) | Natural rubber packing adhesive and preparation method thereof | |
| CN103305166A (en) | Hot-melt type environment-friendly pressure-sensitive adhesive for double sticky tape and preparation method of pressure-sensitive adhesive | |
| CN103333630A (en) | Environment-friendly high-viscosity double-sided adhesive tape | |
| CN104877063A (en) | Polyvinyl acetate emulsion and preparation method thereof | |
| CN103952101A (en) | Heat-sealing glue and preparation method thereof | |
| US20130008342A1 (en) | Glue stick formulated with naturally occurring polymers | |
| CN1073192A (en) | A kind of method of synthetic polystyrene adhesive | |
| CN107722887A (en) | A kind of low temperature resistant label PUR and preparation method thereof | |
| CN106221608A (en) | A kind of glue |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: JIANGSU XINGDA STATIONERY GROUP CO., LTD. Free format text: FORMER OWNER: SONG SHILIANG Effective date: 20120620 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20120620 Address after: 214000 Jiangsu province Yixing Zhoutie Town Creek Industrial Zone Applicant after: JIANGSU XINGDA STATIONERY GROUP Co.,Ltd. Address before: 214000 Jiangsu city of Yixing Province Wang Zhen Zhou Yang Xi Lu Lily Applicant before: Song Shiliang |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130710 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |