CN107028817A - Ozone vegetable oil emulsifier composition and its preparation method and application - Google Patents
Ozone vegetable oil emulsifier composition and its preparation method and application Download PDFInfo
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- CN107028817A CN107028817A CN201710429785.8A CN201710429785A CN107028817A CN 107028817 A CN107028817 A CN 107028817A CN 201710429785 A CN201710429785 A CN 201710429785A CN 107028817 A CN107028817 A CN 107028817A
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- ozone
- vegetable oil
- emulsifier composition
- oil emulsifier
- ozone vegetable
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/70—Biological properties of the composition as a whole
- A61K2800/72—Hypo-allergenic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95
Abstract
The present invention discloses a kind of ozone vegetable oil emulsifier composition and its preparation method and application, it is related to daily chemical products additive technology field, the technical problem that skin provides oxygen, cleaning skin and hair follicle dirt and mite anti-inflammatory effects of dispelling can not be effectively implemented as to improve existing emulsifying agent.According to percent by weight, ozone vegetable oil emulsifier composition of the present invention is mainly prepared by following components：Ozone vegetable oil 30 50%, emulsifying agent 10 20%, water 25 50%, NMF 1 8%, surfactant 9 15%.The present invention also provides the preparation method of the ozone vegetable oil emulsifier composition, and this method has method simple, the advantages of product quality is good.The present invention also provides the application of ozone vegetable oil emulsifier composition, has effects that to provide oxygen, cleaning skin and hair follicle dirt for skin and mite anti-inflammatory of dispelling using the washing product of ozone vegetable oil emulsifier composition of the present invention.
Description
Technical field
The present invention relates to daily chemical products additive technology field, in particular to a kind of ozone vegetable oil emulsifier group
Compound and its preparation method and application.
Background technology
With the offer of living standard, domestic and international cosmetics and washing product consumption market comes into a new development
Climax, Related product constantly upgrading is with updating, and emulsifying agent is then essential composition in these products.
Emulsifying agent is that one kind can make the oily matters such as fat, vegetable oil, wax and hydroaropic substance be mixed to form stabilization
The material of mixture, belongs to a class of surfactant.In washing product, emulsifying agent is usually used in manufacture cream, emulsion and soft
Cream, can effectively ensure that the stability of product property.However, the effect that existing washing product generally has is moisture retention, profit
Skin or compatibility, it is impossible to be effectively implemented as the effect that skin provides oxygen, cleaning skin and hair follicle dirt and mite anti-inflammatory of dispelling.
In view of this, it is special to propose the present invention.
The content of the invention
First purpose of the present invention is to provide a kind of ozone vegetable oil emulsifier composition, to improve existing emulsification
Agent can not be effectively implemented as the technical problem that skin provides oxygen, cleaning skin and hair follicle dirt and mite anti-inflammatory effects of dispelling.
Second object of the present invention is to provide a kind of preparation method of above-mentioned ozone vegetable oil emulsifier composition, is somebody's turn to do
Procedure is simple and easily operated, it is ensured that each component can fully participate in reaction, obtains steady quality, the ozone of uniform properties
Vegetable oil emulsifier composition.
Third object of the present invention is to provide above-mentioned ozone vegetable oil emulsifier composition in moisturizing cream or washes shield
Application in articles for use, ozone vegetable oil emulsifier composition of the present invention contains the compositions such as ozone vegetable oil, emulsifying agent and water, and adds
It is prepared from added with other auxiliary materials, applied to ensureing that the moisturizing cream or washing product can be after moisturizing cream or washing product
Skin provides suitable oxygen, also with cleaning skin and hair follicle dirt and the effect of anti-inflammatory.
In order to realize the above-mentioned purpose of the present invention, spy uses following technical scheme：
The present invention provides a kind of ozone vegetable oil emulsifier composition, according to percent by weight, mainly by following components
Prepare：Ozone vegetable oil 30-50%, emulsifying agent 10-20%, water 25-50%, NMF 1-8%, surfactant 9-
15%.
Alternatively, according to percent by weight, the ozone vegetable oil emulsifier composition that the present invention is provided is main by following
Component is prepared：Ozone vegetable oil 35-45%, emulsifying agent 12-18%, water 30-45%, NMF 2-7%, surfactant
10-14%.
Alternatively, according to percent by weight, the component of the ozone vegetable oil emulsifier composition also includes skin and adjusted
Manage agent 1-2%, essence 0.3-2%, fatting agent 1-3%.
Alternatively, in the present invention, the ozone vegetable oil include ozone soybean oil, ozone olive oil, ozone rapeseed oil,
One or more in ozone corn oil, ozone tea-seed oil or ozone sunflower oil.
Alternatively, in the present invention, the emulsifying agent includes tween, oleic acid, sorbitan trioleate, Sorbitan
Alcohol monoleate, methyl glycol fatty acid ester, glycerin monostearate, glycerin mono-fatty acid ester, two monooleins or different tristearin
One or more in sour monoglyceride.
Alternatively, in the present invention, the NMF includes glycerine, sorbierite, 1,3-BDO, 1,2-PD, sweet tea
One or more in dish alkali or hyaluronic acid.
Alternatively, in the ozone vegetable oil emulsifier composition that the present invention is provided, the surfactant includes cocounut oil
Base both sexes sodium acetate, sodium sulfate of polyethenoxy ether of fatty alcohol, cocoanut fatty acid diethanolamide, Cocoamidopropyl betaine
Or the one or more in sodium lauroyl glutamate.
The present invention also provides a kind of preparation method of the ozone vegetable oil emulsifier composition, comprises the following steps：Will
After ozone vegetable oil, emulsifying agent and water are heated respectively, water and emulsifying agent are added in ozone vegetable oil and is incubated while stirring；It is cold
But NMF, surfactant, skin conditioning agent, essence and fatting agent are added afterwards, and ozone plant is obtained after the cooling that stirs
Thing emulsifier composition.
Alternatively, in the preparation method of ozone vegetable oil emulsifier composition of the present invention, heating-up temperature is 65-80 DEG C, is protected
The warm time is 1-2h, and the temperature after cooling is less than 40 DEG C.
Alternatively, the present invention also provides a kind of ozone vegetable oil emulsifier composition of the present invention and is preparing moisturizing cream
Or the application in washing product；Preferably, ozone vegetable oil emulsifier composition is preparing skin care milk, face cream, face cream, moisturizing
Application in frost, mildy wash, shampoo, shower cream, conditioning liquid or hand cleanser.
Compared with prior art, beneficial effects of the present invention are：
(1) in ozone vegetable oil emulsifier composition of the present invention, it regard ozone vegetable oil as main composition and emulsification
Agent and water are used cooperatively, then are aided with NMF, surfactant, skin conditioning agent, essence and fatting agent, and each component is according to science
Proportioning is combined, and generates positive synergy, overcome ozone vegetable oil be used for skin it is especially facial too greasy,
Easy cleaning, the problem of easily blocking pore, can not leniently provide suitable oxygen for skin, while also having cleaning skin
With hair follicle dirt, the effect of dispel mite and anti-inflammatory, restraining and sterilizing bacteria effect is notable.
(2) method that the preparation method of ozone vegetable oil emulsifier composition of the present invention uses batch charging, ozone is planted
After thing oil, emulsifying agent and water are heated respectively, water and emulsifying agent are added in ozone vegetable oil and is incubated while stirring, after cooling again
Add NMF, surfactant, skin conditioning agent, essence and fatting agent and stir, ozone trials of emulsion of plant oil is arrived after cooling
Agent composition, this method process is simple and easily operated, it is considered to the dissolubility and thermal sensitivity of each component it is different there is provided
Preferably dissolution system and reaction temperature, ensure that each component fully participates in reaction, obtain steady quality, uniform properties it is smelly
Oxygen vegetable oil emulsifier composition.
(3) ozone vegetable oil emulsifier composition of the present invention is applied to after moisturizing cream or washing product, ensure that this
Moisturizing cream or washing product provide suitable oxygen, the effect also with cleaning skin and hair follicle and anti-inflammatory for skin；In addition,
Soft and smooth property when the moisturizing cream or washing product prepared using the ozone vegetable oil emulsifier composition is used on skin, it is complete
Entirely without sticky sensation, and moistening effect is good, gentle non-stimulated.
Embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment or embodiment, but this area skill
Art personnel will be understood that following embodiments or embodiment are merely to illustrate the present invention, and are not construed as the model of the limitation present invention
Enclose.Unreceipted actual conditions person in embodiment or embodiment, the condition advised according to normal condition or manufacturer is carried out.It is used
Reagent or the unreceipted production firm person of instrument, are the conventional products that can be obtained by commercially available purchase.
" mainly by ... " described in embodiment of the present invention, it is intended that it can also include other in addition to the component
Component, these other components assign the ozone vegetable oil emulsifier composition different characteristics.In addition, the present invention is implemented
" mainly by ... " described in mode, may be replaced by enclosed " being " or " by ... ".
According to an aspect of the present invention, embodiment of the present invention provides a kind of ozone vegetable oil emulsifier composition, presses
According to percent by weight, mainly prepared by following components：Ozone vegetable oil 30-50%, emulsifying agent 10-20%, water 25-
50%, NMF 1-8%, surfactant 9-15%.
Relative to prior art, the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided has following beneficial
Effect：
Embodiment of the present invention provide ozone vegetable oil emulsifier composition, using ozone vegetable oil as primary efficacy into
Divide and used cooperatively with emulsifying agent and water, then be aided with NMF, surfactant, skin conditioning agent, essence and fatting agent, each component
Combined according to scientific matching, generate positive synergy, overcoming ozone vegetable oil is used for skin especially face
Portion is too greasy, not easy cleaning, the problem of easily blocking pore, suitable oxygen can be leniently provided for skin, while also having
There are cleaning skin and hair follicle dirt, the effect of dispel mite and anti-inflammatory, restraining and sterilizing bacteria effect is notable.
Specifically, ozone vegetable oil is also referred to as ozonisation vegetable oil or ozone solidified plant oil, is to solidify skill using ozone
A kind of pure natural mixture that pure ozone is cured to first squeezing plant oil and generated by art.
Preferably, in ozone vegetable oil the content of ozonide in 60-80g/L.
Alternatively, ozone vegetable oil is the commercially available prod of purchase.
Alternatively, in embodiments of the present invention, it is purified water that water used is typical but non-limiting.
Alternatively, it is 30% that the percetage by weight of ozone vegetable oil is typical but non-limiting, 32%, 35%, 37%,
39%th, 40%, 41%, 42%, 43%, 44%, 45%, 46%, 47%, 48%, 49% or 50%.
Alternatively, it is 10% that the percetage by weight of emulsifying agent is typical but non-limiting, 11%, 12%, 13%, 14%,
15%th, 16%, 17%, 18%, 19% or 20%.
Alternatively, it is 25% that the percetage by weight of water is typical but non-limiting, 27%, 30%, 32%, 35%, 37%,
40%th, 42%, 45%, 47%, 49% or 50%.
Alternatively, it is 1%, 2%, 3%, 4%, 5%, 6%, 7% that the percetage by weight of NMF is typical but non-limiting
Or 8%.
Alternatively, it is 9% that the percetage by weight of surfactant is typical but non-limiting, 10%, 11%, 12%, 13%,
14% or 15%.
Alternatively, the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, it is main according to percent by weight
To be prepared by following components：Ozone vegetable oil 35-45%, emulsifying agent 12-18%, water 30-45%, NMF 2-7%, table
Face activating agent 10-14%.
, being capable of reasonable adjusting ozone vegetable oil emulsifier composition by further adjustment and the optimization of the content to each component
Thick dilute degree, and further enhance the effect of ozone vegetable oil emulsifier composition inhibiting bacteria and diminishing inflammation and oxygen supply, it is more effective clear
Clean skin and hair follicle dirt, while carrying out moisturizing and nourishing to skin.
Alternatively, the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, it is main according to percent by weight
To be prepared by following components：Ozone vegetable oil 38-42%, emulsifying agent 14-17%, water 32-42%, NMF 3-6%, table
Face activating agent 13-14%.
Alternatively, according to percent by weight, the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided
Component also includes skin conditioning agent 1-2%, essence 0.3-2%, fatting agent 1-3%.
Due to also including skin conditioning agent, essence and fatting agent in ozone vegetable oil emulsifier composition, therefore, it is possible to have
Effect improves the nourishing of ozone vegetable oil emulsifier composition and the effect of lubrication, while can also have more pleasant fragrance, more
Easily liked by user.
Alternatively, it is vitamin E that skin conditioning agent is typical but non-limiting.
By adding skin conditioning agent, skin quality can be effectively improved, the tender slickness of skin is improved, wrinkle is reduced, resisted
Aging, so as to effectively improve the both effectiveness of ozone vegetable oil emulsifier composition, and then can be improved using ozone of the present invention plant
The moisturizing cream of thing emulsifier composition or washing product it is both effectiveness.
Alternatively, it is daily chemical essence, such as material with the fragrance of a flower or fruity that essence is typical but non-limiting；Preferably,
Can be caryophyllus oil, orange oil or Rosa Damascana.
Alternatively, it is cosmetics-stage lanolin or natural phospholipid that fatting agent is typical but non-limiting.
By adding fatting agent in the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, it can make because lacking
Few natural moisture and dry or rough skin soften and is restored, the water content of skin is maintained, with excellent nourishing effect
Really.
Alternatively, the percetage by weight of skin conditioning agent it is typical but non-limiting be 1%, 1.2%, 1.5%, 1.7% or
2%.
Alternatively, it is 0.3% that the percetage by weight of essence is typical but non-limiting, 0.5%, 1%, 1.2%, 1.5%,
1.7% or 2%.
Alternatively, it is 1% that the percetage by weight of fatting agent is typical but non-limiting, 1.2%, 1.5%, 1.7%, 2%,
2.2%th, 2.5%, 2.7% or 3%.
Alternatively, in the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, ozone vegetable oil includes
One kind in ozone soybean oil, ozone olive oil, ozone rapeseed oil, ozone corn oil, ozone tea-seed oil or ozone sunflower oil
Or it is several.
In the present invention, ozone soybean oil is referred to as ozonisation soybean oil or ozone solidification soybean oil, ozone olive
Oil is referred to as ozonisation olive oil or ozone solidification olive oil, and ozone rapeseed oil is referred to as ozonizing rapeseed oil or smelly
Oxygen solidifies rapeseed oil, and ozone corn oil is referred to as ozonisation corn oil or ozone solidification corn oil, and ozone tea-seed oil also may be used
To be referred to as ozonizing tea-seed oil or ozone solidification tea-seed oil, ozone sunflower oil is referred to as ozonisation sunflower oil or ozone
Solidify sunflower oil.
Preferably, in the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, ozone vegetable oil typical case
But non-limiting is ozone soybean oil, ozone olive oil, ozone rapeseed oil, ozone corn oil, ozone tea-seed oil, ozone soybean oil
Combination, the combination of ozone rapeseed oil and ozone corn oil, the combination of ozone tea-seed oil and ozone soybean oil with ozone olive oil,
Or the combination of ozone sunflower oil and ozone olive oil.
Alternatively, embodiment of the present invention provide ozone vegetable oil emulsifier composition in, emulsifying agent include tween,
Oleic acid, sorbitan trioleate, sorbitan monooleate, methyl glycol fatty acid ester, glycerin monostearate, glycerine
One or more in monoleate, two monooleins or isostearic acid monoglyceride.
Preferably, in the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, emulsifying agent is typical but non-
Restricted combination, oleic acid and mistake for tween, oleic acid, sorbitan monooleate, methyl glycol fatty acid ester, tween and oleic acid
The combination of water sorbitol olein, the combination of sorbitan monooleate and methyl glycol fatty acid ester, glycerol monostearate
Ester and glycerin mono-fatty acid ester and combination or the isostearic acid monoglyceride of two monooleins.
Alternatively, embodiment of the present invention provide ozone vegetable oil emulsifier composition in, NMF include glycerine,
One or more in sorbierite, 1,3-BDO, 1,2-PD, glycine betaine or hyaluronic acid.
Preferably, in the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, NMF is typical but non-
It is restricted for glycerine, 1,2-PD, the combination of glycerine and 1,2-PD, the combination of sorbierite and 1,3-BDO, 1,2-
The combination of propane diols and glycine betaine, glycine betaine, the group of glycerine and the combination of hyaluronic acid or hyaluronic acid and 1,2-PD
Close.
Alternatively, in the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, surfactant includes
Cocoyl both sexes sodium acetate, sodium sulfate of polyethenoxy ether of fatty alcohol, cocoanut fatty acid diethanolamide, cocamidopropyl propyl amide sweet tea
One or more in dish alkali or sodium lauroyl glutamate.
Preferably, in the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, surfactant is coconut palm
Oil base both sexes sodium acetate, sodium sulfate of polyethenoxy ether of fatty alcohol, cocoanut fatty acid diethanolamide, cocoyl both sexes sodium acetate
With the combination of Cocoamidopropyl betaine, Cocoamidopropyl betaine, sodium sulfate of polyethenoxy ether of fatty alcohol and coconut oil
The combination of fatty diglycollic amide or the combination of Cocoamidopropyl betaine and sodium lauroyl glutamate.
Embodiment of the present invention provides a kind of preparation method of above-mentioned ozone vegetable oil emulsifier composition, including following step
Suddenly：After ozone vegetable oil, emulsifying agent and water are heated respectively, water and emulsifying agent are added in ozone vegetable oil and protected while stirring
Temperature；NMF, surfactant, skin conditioning agent, essence and fatting agent are added after cooling, obtains smelly after the cooling that stirs
Oxygen vegetable oil emulsifier composition.
The preparation method for the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided uses the side of batch charging
Method, water and emulsifying agent after ozone vegetable oil, emulsifying agent and water are heated respectively, added in ozone vegetable oil and protected while stirring
NMF, surfactant, skin conditioning agent, essence and fatting agent are added after temperature, cooling and is stirred, is obtained after cooling
Ozone vegetable oil emulsifier composition, this method process is simple and easily operated, it is considered to which the dissolubility and thermal sensitivity of each component are each
Differ there is provided preferably dissolution system and reaction temperature, ensure that each component fully participates in reaction, obtain quality steady
Fixed, the ozone vegetable oil emulsifier composition of uniform properties.
Alternatively, in the preparation method for the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, heating temperature
Spend for 65-80 DEG C, soaking time is 1-2h, the temperature after cooling is less than 40 DEG C.
Due to considering that the dissolubility and thermal sensitivity of each component are different, therefore the ozone plant added at 65-80 DEG C
Oil, emulsifying agent and water fully can be dissolved and disperse, and form homogeneous system, and other components are added below 40 DEG C and are more beneficial for instead
The progress answered, embodiment of the present invention provides preferably dissolution system and reaction temperature, ensure that each component is fully participated in
Reaction, obtains steady quality, the ozone vegetable oil emulsifier composition of uniform properties.
Alternatively, it is 65 DEG C that heating-up temperature is typical but non-limiting, 66 DEG C, 67 DEG C, 68 DEG C, 69 DEG C, 70 DEG C, 71 DEG C, 72
DEG C, 73 DEG C, 74 DEG C, 75 DEG C, 76 DEG C, 77 DEG C, 78 DEG C, 79 DEG C or 80 DEG C；Soaking time it is typical but it is non-limiting for 1h, 1.5h or
2h；Typical but non-limiting temperature after cooling is 38 DEG C, 37 DEG C, 36 DEG C, 35 DEG C, 32 DEG C or 30 DEG C.
Preferably, in the preparation method for the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, by ozone
After vegetable oil, emulsifying agent and water are heated respectively, the step of water and emulsifying agent are added in ozone vegetable oil while stirring and are incubated
Specifically include：Ozone vegetable oil, emulsifying agent and water are heated separately to after 65-80 DEG C, while stirring water and emulsifying agent is added
Mixed in ozone vegetable oil, ozone vegetable oil, emulsifying agent and water is fully dissolved, be incubated 1-2h.
In order to avoid NMF, surfactant, skin conditioning agent, essence and fatting agent are oxidized during the course of the reaction,
In the preparation method for the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, NMF, table are added after cooling
Face activating agent, skin conditioning agent, essence and fatting agent, stir and are specifically included the step of cooling：It is cooled to less than 40 DEG C
Afterwards, NMF, surfactant, skin conditioning agent, essence and fatting agent are added while stirring, and continue to be evenly stirred until normal temperature
(20-25℃)。
Preferably, the preparation method for the ozone vegetable oil emulsifier composition that embodiment of the present invention is provided, including as follows
Step：Ozone vegetable oil, emulsifying agent and water are heated separately to after 75 DEG C, water and emulsifying agent are added into ozone plant while stirring
Mixed in oil, ozone vegetable oil, emulsifying agent and water is fully dissolved, be incubated 1h；It is cooled to after less than 40 DEG C, while stirring
NMF, surfactant, skin conditioning agent, essence and fatting agent are added, and continues to be evenly stirred until normal temperature (20-25 DEG C),
Just ozone vegetable oil emulsifier composition is obtained.
Meanwhile, embodiment of the present invention also provides a kind of above-mentioned ozone vegetable oil emulsifier composition and is preparing moisturizing cream
Or the application in washing product；Preferably, ozone vegetable oil emulsifier composition is preparing skin care milk, face cream, face cream, moisturizing
Application in frost, mildy wash, shampoo, shower cream, conditioning liquid or hand cleanser.
The ozone vegetable oil emulsifier composition that embodiment of the present invention is provided is applied to after moisturizing cream or washing product,
It ensure that the moisturizing cream or washing product provide suitable oxygen for skin, also with cleaning skin and hair follicle dirt and disappear
Scorching effect；In addition, the moisturizing cream or washing product that are prepared using the ozone vegetable oil emulsifier composition make on skin
Used time soft and smooth property, completely without sticky sensation, and moistening effect is good, gentle non-stimulated.
Alternatively, moisturizing cream is typical but non-limiting for skin care milk, face cream, face cream or skin cream in the present invention；Wash shield
Typical but non-limiting articles for use are mildy wash, shampoo, hair conditioner, shower cream, conditioning liquid or hand cleanser.
With reference to specific embodiment and comparative example, the invention will be further described.
Embodiment 1
According to percetage by weight, following components is weighed：Ozone tea-seed oil 32%, sorbitan monooleate 20% is pure
Change water 25%, glycerine 8%, cocoyl both sexes sodium acetate 15%.
Then ozone vegetable oil emulsifier composition is prepared in accordance with the following steps：By ozone tea-seed oil, anhydrous sorbitol list
Oleate and purified water are separately heated to after 65 DEG C, and purified water and sorbitan monooleate are added into ozone tea while stirring
Mixed in seed oil, ozone tea-seed oil, sorbitan monooleate and purified water is fully dissolved, be incubated 1h；It is cooled to
After 32 DEG C, glycerine, cocoyl both sexes sodium acetate are added while stirring, and continues to be evenly stirred until normal temperature, just obtain ozone plant
Emulsifier composition.
Embodiment 2
According to percetage by weight, following components is weighed：Ozone soybean oil 50%, oleic acid 10%, purified water 30%, 1,2- third
Glycol 1%, Cocoamidopropyl betaine 9%.
Then ozone vegetable oil emulsifier composition is prepared in accordance with the following steps：By ozone soybean oil, oleic acid and purified water
Be separately heated to after 80 DEG C, oleic acid and purified water added and mixed in ozone soybean oil while stirring, make ozone soybean oil,
Oleic acid fully dissolves with purified water, is incubated 1.5h；It is cooled to after 30 DEG C, 1,2-PD, coconut oleoyl amine third is added while stirring
Base glycine betaine, and continue to be evenly stirred until normal temperature, just obtain ozone vegetable oil emulsifier composition.
Embodiment 3
According to percetage by weight, following components is weighed：Ozone olive oil 40%, sorbitan monooleate 12% is pure
Change water 28%, glycerine 4%, cocoyl both sexes sodium acetate 12%, vitamin E 1%, caryophyllus oil 1%, cosmetics-stage lanolin
2%.
Then ozone vegetable oil emulsifier composition is prepared in accordance with the following steps：By ozone olive oil, anhydrous sorbitol list
Oleate and purified water are separately heated to after 75 DEG C, and sorbitan monooleate and purified water are added into ozone olive while stirring
Mixed in olive oil, ozone olive oil, sorbitan monooleate and purified water is fully dissolved, be incubated 1h；It is cooled to
After 35 DEG C, glycerine, cocoyl both sexes sodium acetate, vitamin E, caryophyllus oil and cosmetics-stage lanolin are added while stirring, and after
It is continuous to be evenly stirred until normal temperature, just obtain ozone vegetable oil emulsifier composition.
Embodiment 4
According to percetage by weight, following components is weighed：Ozone corn oil 35%, sorbitan monooleate 13% is pure
Change water 35%, glycerine 2%, cocoyl both sexes sodium acetate 11%, vitamin E 2%, Rosa Damascana 0.3%, cosmetics-stage wool
Fat 1.7%.
Preparation method be the same as Example 3, and respective sets are allocated as adaptability addition.
Embodiment 5
According to percetage by weight, following components is weighed：Ozone soybean oil 30%, isostearic acid monoglyceride 11%, purifying
Water 45%, glycine betaine 1%, cocoyl both sexes sodium acetate 10%, vitamin E 1%, orange oil 0.5%, natural phospholipid 1.5%.
Preparation method be the same as Example 3, and respective sets are allocated as adaptability addition.
Embodiment 6
According to percetage by weight, following components is weighed：Ozone rapeseed oil 45%, methyl glycol fatty acid ester 12%, purified water
26%, glycerine 1%, Cocoamidopropyl betaine 13%, vitamin E 1.2%, caryophyllus oil 0.8%, cosmetics-stage lanolin
1%.
Preparation method be the same as Example 3, and respective sets are allocated as adaptability addition.
Comparative example 1
According to percetage by weight, following components is weighed：Ozone olive oil 20%, purified water 48%, other components and content
Be the same as Example 3.
Preparation method be the same as Example 3.
Comparative example 2
According to percetage by weight, following components is weighed：Ozone olive oil 55%, purified water 13%, other components and content
Be the same as Example 3.
Preparation method be the same as Example 3.
Comparative example 3
According to percetage by weight, following components is weighed：Sorbitan monooleate 5%, purified water 35%, other components
And content be the same as Example 3.
Preparation method be the same as Example 3.
Comparative example 4
According to percetage by weight, following components is weighed：Sorbitan monooleate 25%, purified water 15%, other groups
Divide and content be the same as Example 3.
Preparation method be the same as Example 3.
Experimental example
In order to further examine the both effectiveness and toxicologic properties of the ozone vegetable oil emulsifier composition of the invention provided,
Following experimental study is carried out：
1st, both effectiveness experiment
Ozone vegetable oil emulsifier composition obtained by embodiment 1-6 and comparative example 1-4 is handled by identical and is made
Mildy wash.
110 volunteers are randomly selected, the age is 18-40 Sui, and average age 25 years old, M-F is 1：1, it is divided into
11 groups.Each group volunteer, which washes one's face to correspond to respectively every morning, uses the above-mentioned ozone plant containing embodiment 1-6 and comparative example 1-4
The mildy wash of emulsifier composition, while also setting up blank example, this group of volunteer washes one's face without using any face cleaning every morning
Breast, is only washed one's face with clear water.Test period is 14 days.
After use by the way of volunteer's marking evaluation effect, scoring criterion as shown in table 1, counts the average mark of each group
Afterwards, specific scores are as shown in table 2.
The scoring criterion of table 1
| For skin follicle oxygen supply | Cleaning skin and hair follicle dirt | Dispel mite and anti-inflammatory | |
| Effect is notable | 7-10 | 7-10 | 7-10 |
| Effect is general | 2-6.9 | 2-6.9 | 2-6.9 |
| It is invalid | 0-1.9 | 0-1.9 | 0-1.9 |
The using effect score of table 2
| For skin follicle oxygen supply | Cleaning skin and hair follicle dirt | Dispel mite and anti-inflammatory | ||
| 1 | Embodiment 1 | 8.8 | 8.5 | 7.9 |
| 2 | Embodiment 2 | 9.0 | 8.7 | 8.8 |
| 3 | Embodiment 3 | 9.1 | 8.9 | 8.6 |
| 4 | Embodiment 4 | 8.3 | 8.1 | 8.0 |
| 5 | Embodiment 5 | 8.4 | 8.4 | 8.3 |
| 6 | Embodiment 6 | 8.9 | 8.9 | 8.7 |
| 7 | Comparative example 1 | 5.2 | 4.7 | 5.1 |
| 8 | Comparative example 2 | 7.0 | 6.8 | 8.3 |
| 9 | Comparative example 3 | 6.2 | 6.5 | 6.8 |
| 10 | Comparative example 4 | 7.1 | 6.4 | 7.5 |
| 11 | Blank example | 0 | 0 | 0 |
The mildy wash that 1-6 groups are used it can be seen from the result of table 2 is skin follicle oxygen supply, the dirt of cleaning skin hair follicle
Dirt, the effect of dispel mite and anti-inflammatory are substantially better than 7-11 groups, show ozone vegetable oil, emulsifying agent and water in inventive formulation with
Rationally, each component coordinates can produce preferably effect to the scientific formulation of other components.By 1-6 groups and the 7th group and the 8th group
Comparative result understands that within the specific limits, the ratio of ozone vegetable oil and water is higher in ozone vegetable oil emulsifier composition, then
Effect for skin follicle oxygen supply, cleaning skin and hair follicle dirt, dispel mite and anti-inflammatory is better；For the 7th group, i.e. ozone vegetable oil
When the ratio of ozone vegetable oil and water is too low in emulsifier combination, it is skin follicle oxygen supply, cleaning skin and hair follicle dirt, dispels
The effect of mite and anti-inflammatory is poor；For the ratio mistake of ozone vegetable oil and water in the 8th group, i.e. ozone vegetable oil emulsifier composition
Gao Hou is skin follicle oxygen supply, cleaning skin and hair follicle dirt, effect of the effect of dispel mite and anti-inflammatory also not than the 3rd group is excellent
Change, but add the cost of material of ozone vegetable oil, and injury easily is produced to skin, do not meet wanting for actual production
Ask.In addition, from 1-6 groups and the 9th group and the 10th group of Comparative result, the amount of emulsifying agent is for prepared ozone plant
The property of emulsifier composition also has a certain impact, so that the mildy wash containing corresponding ozone vegetable oil emulsifier composition
Property be also affected.Compared with the 3rd group, emulsifier content is too low in the 9th group, then is easily caused ozone vegetable oil emulsifier
The uniformity and less stable of composition, so that the both effectiveness reduction of corresponding mildy wash；Compared with the 3rd group, in the 10th group
The too high levels of emulsifying agent, the both effectiveness of corresponding mildy wash does not also optimize more, but add the raw material of emulsifying agent into
This, does not meet the requirement of actual production.
By further detecting, in ozone vegetable oil emulsifier composition of the present invention, the average value of ozonide content is
20g/L or so, is conducive to leniently providing suitable oxygen for skin, promotes cutaneous respiration.
In summary, ozone vegetable oil emulsifier composition of the present invention scientific formulation rationally, for skin have compared with
Good mite of dispelling, inhibiting bacteria and diminishing inflammation and oxygen supply effect, can aid in cleaning skin and hair follicle dirt, is effectively improved skin quality.
2nd, toxicological experiment
Using ozone vegetable oil emulsifier composition made from embodiment 1-6 as sample, toxicological study is carried out, specifically such as
Under：
(1) multiple Skin Irritation Test
Family's rabbit back backbone both sides dorsal body setae is cut before experiment, unhairing scope is 3cm × 3cm, and surface covered is 2.5cm
×2.5cm.Take 0.5mL sample applications on the side skin of rabbit backbone, opposite side is used as control.Cleaned after smearing 4h with water
Totally.Carry out once daily, continuously coating 14d, other experimental condition all sames.24h observes result and commented after each coating
Point, judge skin irritatin intensity.Detection foundation is the Ministry of Public Health《Disinfection technology standard》(version in 2002).
Ozone vegetable oil emulsifier composition of the present invention is without obvious stimulation to the multiple skin irritation assay of rabbit
Effect, has no other toxicity.
(2) Tests For Irritating Effects
Experimental rabbits are faced upward fixation, perineum and introitus is exposed, (children that length is 8cm or so are with leading by conduit
Urinary catheter and 5mL syringe connection) moistened with sample after gently insert vagina (4cm), and be slowly injected into syringe 2mL samples
Product, extract conduit out；Control group rabbit physiological saline makees same processing.
24 put to death rabbit using aeroembolism methods after processing, the complete vagina of taking-up of cutting open the belly, and longitudinally split, seen whether it is congested or
Oedema etc. is showed, and is then placed in 10% formalin solution and is fixed 48h, chooses the two ends of vagina and the group at middle 3 positions
Film-making is knitted, HE dyeing carries out histopathological examination.Stimulate the reaction is scored, and calculate stimulus index (stimulus index=
Test group average mark-control group average mark).Detection foundation is the Ministry of Public Health《Disinfection technology standard》(version in 2002).
Ozone vegetable oil emulsifier composition of the present invention is pierced to rabbit vagina mucosa irritation response intensity for absence of vagina mucous membrane
Swash property.
3 bactericidal properties are tested
Sample is placed in 37 DEG C of insulating boxs 3 months, relative humidity 76% is kept, bactericidal property test, control group is carried out
Do not deal with, the bactericidal action time is 5min.Detection method refers to GB15979-2002.Experimental result is as shown in table 3.
The result of the test of table 3
Result of the test shows that ozone vegetable oil emulsifier composition of the present invention has the effect of bactericidal antiphlogistic, and meets《One
Secondary property uses amenities sanitary standard GB15979-2002》Requirement.Ozone vegetable oil emulsifier combination of the present invention after testing
It is still constant that thing can preserve bactericidal effect after 2 years at normal temperatures, with higher stability.
The ozone vegetable oil emulsifier composition that the present invention is provided may apply to different moisturizing cream or washing product
In, such as skin care milk, face cream, face cream, skin cream, mildy wash, shampoo, hair conditioner, shower cream, conditioning liquid or hand cleanser, phase
The moisturizing cream or washing product answered also provide oxygen with what ozone vegetable oil emulsifier composition of the present invention had for skin
The effect of gas, cleaning skin and hair follicle dirt, dispel mite and inhibiting bacteria and diminishing inflammation.
Specific embodiment described in this specification is only to spirit explanation for example of the invention.Skill belonging to of the invention
The technical staff in art field can make various modifications or supplement to described specific embodiment or use similar side
Formula is substituted, but without departing from the spiritual of the present invention or surmounts scope defined in appended claims.
Although illustrate and describing the present invention with specific embodiment, but it will be appreciated that without departing substantially from the present invention's
Many other changes and modification can be made in the case of spirit and scope.It is, therefore, intended that in the following claims
Including belonging to all such changes and modifications in the scope of the invention.
Claims (10)
1. a kind of ozone vegetable oil emulsifier composition, it is characterised in that according to percent by weight, mainly by following components system
It is standby to obtain：Ozone vegetable oil 30-50%, emulsifying agent 10-20%, water 25-50%, NMF 1-8%, surfactant 9-
15%.
2. ozone vegetable oil emulsifier composition according to claim 1, it is characterised in that according to percent by weight,
Mainly prepared by following components：Ozone vegetable oil 35-45%, emulsifying agent 12-18%, water 30-45%, NMF 2-7%,
Surfactant 10-14%.
3. ozone vegetable oil emulsifier composition according to claim 1 or 2, it is characterised in that according to percetage by weight
Meter, in addition to skin conditioning agent 1-2%, essence 0.3-2%, fatting agent 1-3%.
4. ozone vegetable oil emulsifier composition according to claim 1 or 2, it is characterised in that the ozone vegetable oil
Including in ozone soybean oil, ozone olive oil, ozone rapeseed oil, ozone corn oil, ozone tea-seed oil or ozone sunflower oil
It is one or more of.
5. ozone vegetable oil emulsifier composition according to claim 1 or 2, it is characterised in that the emulsifying agent includes
Tween, oleic acid, sorbitan trioleate, sorbitan monooleate, methyl glycol fatty acid ester, glycerol monostearate
One or more in ester, glycerin mono-fatty acid ester, two monooleins or isostearic acid monoglyceride.
6. ozone vegetable oil emulsifier composition according to claim 1 or 2, it is characterised in that the NMF includes
One or more in glycerine, sorbierite, 1,3-BDO, 1,2-PD, glycine betaine or hyaluronic acid.
7. ozone vegetable oil emulsifier composition according to claim 1 or 2, it is characterised in that the surfactant
Including cocoyl both sexes sodium acetate, sodium sulfate of polyethenoxy ether of fatty alcohol, cocoanut fatty acid diethanolamide, coconut oleoyl amine third
One or more in base glycine betaine or sodium lauroyl glutamate.
8. the preparation method of ozone vegetable oil emulsifier composition described in a kind of claim 3, it is characterised in that including following step
Suddenly：After ozone vegetable oil, emulsifying agent and water are heated respectively, water and emulsifying agent are added in ozone vegetable oil and protected while stirring
Temperature；NMF, surfactant, skin conditioning agent, essence and fatting agent are added after cooling, obtains smelly after the cooling that stirs
Oxygen vegetable oil emulsifier composition.
9. preparation method according to claim 8, it is characterised in that heating-up temperature is 65-80 DEG C, and soaking time is 1-
2h, the temperature after cooling is less than 40 DEG C.
10. the ozone vegetable oil emulsifier composition described in claim any one of 1-7 is preparing moisturizing cream or washing product
In application；
Preferably, ozone vegetable oil emulsifier composition prepare skin care milk, face cream, face cream, skin cream, mildy wash, shampoo,
Application in shower cream, conditioning liquid or hand cleanser.
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| CN109592646A (en) * | 2018-12-20 | 2019-04-09 | 常州大学 | A kind of preparation method of ozonated water emulsion |
| CN109607485A (en) * | 2018-12-20 | 2019-04-12 | 常州大学 | A method of improving ozonated water stability of solution |
| CN109607484A (en) * | 2018-12-20 | 2019-04-12 | 常州大学 | A kind of rapidly and efficiently preparation method of ozonated water emulsion |
| CN110663700A (en) * | 2019-09-12 | 2020-01-10 | 河北众成七星生物科技有限公司 | Ozone disinfectant and preparation method thereof |
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