CN107027974A - Threonine high yield synergy new technology - Google Patents
Threonine high yield synergy new technology Download PDFInfo
- Publication number
- CN107027974A CN107027974A CN201710377904.XA CN201710377904A CN107027974A CN 107027974 A CN107027974 A CN 107027974A CN 201710377904 A CN201710377904 A CN 201710377904A CN 107027974 A CN107027974 A CN 107027974A
- Authority
- CN
- China
- Prior art keywords
- parts
- threonine
- powder
- liquid
- high yield
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Fodder In General (AREA)
Abstract
The present invention relates to a kind of threonine production method, i.e. a kind of threonine high yield synergy new technology, including zymotic fluid through ceramic membrane filter, cleaner liquid and trapped fluid are generated, threonine enters next procedure with filtering, and cleaner liquid is through being concentrated by evaporation and centrifuging, obtain wet threonine and a mother liquor, mother liquor re-evaporation concentration, obtains wet threonine and secondary mother liquid, is characterized in：The secondary mother liquid obtained after trapped fluid including thalline and a mother liquid evaporation concentration obtained by ceramic membrane filter enters feed grade low content finished product production line.The beneficial effects of the invention are as follows：While the normally threonine of production content 98.5%, and the threonine of output content 65%, total extract yield of Soviet Union's nitronic acid is promoted to more than 85% by 70 75%, it disclosure satisfy that demand of the feed market to low-end product, the waste liquid after the threonine of production 98.5% is particularly directly prepared into feed, economic benefit is greatly improved, and realizes soiling solution zero-emission, is solved the problem of prior art and is opened up a new way for amino acid waste liquid processing.
Description
Technical field
The present invention relates to a kind of threonine production method, i.e., a kind of threonine high yield synergy new technology.
Background technology
Threonine, also known as：L-threonine (L-Threonine) (beta-hydroxy-butyrine) is write a Chinese character in simplified form：Thr, single-letter symbol
Number：T, legal numbering：CAS 72-19-5, structural formula：CH3CH (OH) CH (NH2) COOH, molecular formula：C4H9NO3, molecular weight：
119.12.Threonine is most common, indispensable conditionally essential amino acids in animal and human body, growth to humans and animals,
Development and metabolism play an important roll.In recent years, threonine medicine, Shi Pin He Si material in terms of market demand not
Disconnected increase.But, existing threonine extraction process has many drawbacks, and urgent need is improved.
Existing threonine technological process is：Liquid turn sour through ceramic membrane filter, generation cleaner liquid and trapped fluid, thalline is with retention
Liquid enters composite fertilizer's system, and threonine enters next procedure with cleaner liquid, and cleaner liquid obtains wet through being concentrated by evaporation and centrifuging
Threonine and a mother liquor, one time mother liquor re-evaporation is concentrated to give wet threonine and secondary mother liquid.Wet product drying obtains finished product
Threonine；Secondary mother liquid is discharged into composite fertilizer's system.Said extracted technique has the drawback that：Waste water and waste liquid amount is big, environmental pressure
Greatly, water resource waste is serious；Contain mycoprotein and substantial amounts of threonine in waste liquid, be all lost in, had by composite fertilizer's system
Imitate composition and waste serious, extract yield only has 70-75%.Existing process can only extract the high-purity threonine production of content 98.5%
Product, and market demand amount maximum is feed low content threonine product, existing process can not meet the demand in market.
The content of the invention
It is comprehensively utilized it is an object of the invention to provide a kind of waste water and waste liquid, product yield is significantly improved, is keeping high
Feed grade product is reclaimed while purity product yield, the market demand is met, mitigates environmental pressure, it is to avoid the wasting of resources, energy-conservation
Consumption reduction, increases the benefit, and simple, the with low cost threonine production technology of process.
Above-mentioned purpose is realized by following technical scheme：A kind of threonine high yield synergy new technology, including zymotic fluid warp
Ceramic membrane filter, generation cleaner liquid and trapped fluid, cleaner liquid obtain wet threonine and once female through being concentrated by evaporation and centrifuging
Liquid, a mother liquor re-evaporation concentration, obtains wet threonine and secondary mother liquid；Finished product threonine is obtained after the drying of wet product threonine；
It is characterized in：It is low into feed grade that trapped fluid including thalline obtained by ceramic membrane filter is merged into mixed liquor with secondary mother liquid
Content finished product production line.
The trapped fluid is with secondary mother liquid with 2: 1 weight than synthesis mixed liquor, mixed liquor progress three-effect evaporation and condensation, institute
Obtain concentrate and carry out slurry-spraying pelletizing, obtain the threonine of content 65%.
The mixed liquor carries out vacuum -0.85~-0.09MPa of three-effect evaporation and condensation；One effect temperature：75~85 DEG C,
Two effect temperature：45~50 DEG C.
The spray dryer EAT of the slurry-spraying pelletizing：145~155 DEG C；Spray dryer leaving air temp：85~95
DEG C, cloth bag pressure difference：≤1MPa；Atomizer frequency conversion：20~25HZ；Granulating bed bed pressure difference：8~10KPa；Cooling bed bed pressure
Difference：5~7KPa；Fluid bed leaving air temp：60~65 DEG C；Product moisture：＜ 4.0%；Product cut size：The mesh of 12 mesh~40 is qualified
Rate >=90%；Finished product temperature：40 DEG C of ＜.
The mixed liquor of the trapped fluid and secondary mother liquid adds grass meal, its weight ratio=mixed liquor: grass meal=100: 55-
60, concentration is evaporated at 38-42 DEG C by single effect evaporator, dry matter content 19-21% is concentrated into, concentrate is passed through into spray
Mist drying tower is spray-dried at 68-72 DEG C and obtains powdered finished product.
The manufacture method of the grass meal is：20-30 parts of soybean stalk powder, 10-12 parts of alfalfa meal, 3-5 parts of rhizoma atractylodis powder, Cape jasmine
Sub- powder 4-6 parts, 10-12 parts of dandelion, 3-4 parts of ground nutmeg, 12-16 parts of caragana microphylla powder, 3-5 parts of licorice powder, Radix Isatidis powder 2-3
Part, 5-8 parts of seabuckthorn fruit powder, 3-5 parts of grass-leaved sweetflag powder.
The mixed liquor of the trapped fluid and secondary mother liquid adds grass meal and stone flour, its weight proportion=trapped fluid: grass meal: stone
Powder=100: 55-60: 2-5；The grass meal is made of by weight by following raw material：20-30 parts of soybean stalk powder, alfalfa meal
10-12 parts, 3-5 parts of rhizoma atractylodis powder, 4-6 parts of gardenia powder, 10-12 parts of dandelion, 3-4 parts of ground nutmeg, 12-16 parts of caragana microphylla powder is sweet
3-5 parts of grass meal, 2-3 parts of Radix Isatidis powder, 5-8 parts of seabuckthorn fruit powder, 3-5 parts of grass-leaved sweetflag powder；The stone flour is by weight by following original
Material is made：10-15 parts of crushing 200-250 mesh of zeolite powder, 8-10 parts of crushing 320-330 mesh of dicalcium powder, 5-6 parts of crushing of medical stone powder
330-350 mesh；Concentration is evaporated at 38-42 DEG C by single effect evaporator after mixing, dry matter content 19-21% is concentrated into,
Concentrate is spray-dried by spray drying tower at 68-72 DEG C and obtains powdered finished product.
The beneficial effects of the invention are as follows：While the normally threonine of production content 98.5%, and output content 65%
Threonine, Soviet Union nitronic acid total extract yield be promoted to more than 85% by 70-75%, disclosure satisfy that feed market to low-end product
Demand, the waste liquid after the threonine of production 98.5% is particularly directly prepared into feed, economic benefit is greatly improved, and real
Soiling solution zero-emission is showed, has solved the problem of prior art and opened up a new way for amino acid waste liquid processing.
Brief description of the drawings
Fig. 1 is the process chart of the first embodiment；
Fig. 2 is the process chart of prior art.
Embodiment
The first embodiment：Fig. 1 describes visible following processing step in a kind of threonine high yield synergy new technology, figure：
1st, zymotic fluid is through ceramic membrane filter, generation cleaner liquid and trapped fluid, and thalline expects level low content with trapped fluid Jin Ru Si
Product line, threonine enters next procedure with filtering.60-70 DEG C of membrane filtration temperature, pressure 2.0-3.0MPa.
2nd, cleaner liquid is evaporated concentration, evaporating temperature into triple effect evaporator：One 70~73 DEG C of effect, two effects 66~70
DEG C, 48~52 DEG C of triple effect；Vacuum；- 0.088~-0.089MPa；Striking point：Solid-to-liquid ratio 50%~56%；Steam pressure：
0.35~0.5MPa.
3rd, evaporation concentrated solution, which enters, centrifuges, and obtains wet threonine and a mother liquor, and a mother liquor enters back into single-action steaming
Hair concentration；51~56 DEG C of vacuums -0.085 of evaporating temperature~0.3~0.45MPa of -0.089MPa steam pressures；Obtain wet Soviet Union's ammonia
Acid and secondary mother liquid.
4th, wet product threonine, which enters, obtains finished product threonine after flash evaporation drying, drying；Secondary mother liquid Jin Ru Si expect that level is low and contained
Measure finished product system line.
5th, trapped fluid and secondary mother liquid are carried out into 2: 1 to mix, mixed liquor carries out three-effect evaporation and condensation, concentrate is whitewashed
Granulation.
6th, triple effect evaporator parameter：Vacuum -0.85~-0.09MPa；One effect temperature：75~85 DEG C, two effect temperature：45
~50 DEG C；
7th, spray dryer EAT：145~155 DEG C；Spray dryer leaving air temp：85~95 DEG C；Cloth bag pressure difference：
≤ 1MPa (is formulated) according to leaving air temp；Atomizer frequency conversion：20~25HZ；Granulating bed bed pressure difference：8~10KPa；Cooling bed bed
Lamination is poor：5~7KPa；Fluid bed leaving air temp：60~65 DEG C；
8th, product moisture：＜ 4.0%；Product cut size：The mesh (qualification rate >=90%) of 12 mesh~40；Finished product temperature：40 DEG C of ＜.
With reference to the visible original techniques of Fig. 2：
1st, liquid is turned sour through ceramic membrane filter, generation cleaner liquid and trapped fluid, and thalline enters composite fertilizer's system with trapped fluid；Soviet Union
Propylhomoserin enters next procedure with cleaner liquid.
2nd, cleaner liquid is evaporated concentration into triple effect evaporator,
3rd, it is concentrated by evaporation to enter and centrifuges, obtains wet threonine and a mother liquor, one time mother liquor enters back into single effect evaporation
Concentration：Obtain wet threonine and secondary mother liquid.
4th, wet product threonine, which enters, obtains finished product threonine after flash evaporation drying, drying；Secondary mother liquid is discharged into composite fertilizer's system.
Contrast that original technique is visible, the trapped fluid and secondary mother liquid of former technique send into compound fertilizer workshop, produce composite fertilizer.
And new technology is then intended for low content threonine workshop, threonine is further extracted.In Soviet Union's ammonia of production content 98.5%
Beyond acid, and the threonine of output content 65%.Threonine yield is promoted to more than 85% by 70-75%.Compound fertilizer is per ton
800 yuan/ton are priced at, 65% threonine is fixed a price 6000 yuan/ton, and added value of product is greatly improved.The pure product valency of 65% threonine
9230 yuan/ton of lattice；And 11000 yuan/ton of the 98.5% threonine market price, pure 11168 yuan/ton of product price, low content Soviet Union ammonia
Acid is easily favored by client, and its market prospects will be more wide, it is expected to strengthens the competitiveness of enterprise.In the Soviet Union of production 65% ammonia
In the process of acid, by evaporating and concentrating process, the condensed water that evaporation is produced extracts from using or reuse is to other processes, realizes zero
Discharge, water-saving result and environmental benefit are very prominent, and the development to enterprise is highly beneficial.
Second of embodiment：Trapped fluid is mixed liquor: grass meal with adding grass meal, its weight ratio among secondary mother liquid mixed liquor
=100: 55-60.
The grass meal that can be added has a variety of, such as agricultural crop straw, herbage.In order to increase product nutritive value and
Medicinal function, using following herbaceous material：20-30 parts of soybean stalk powder, 10-12 parts of alfalfa meal, 3-5 parts of rhizoma atractylodis powder, cape jasmine
4-6 parts of powder, 10-12 parts of dandelion, 3-4 parts of ground nutmeg, 12-16 parts of caragana microphylla powder, 3-5 parts of licorice powder, 2-3 parts of Radix Isatidis powder,
5-8 parts of seabuckthorn fruit powder, 3-5 parts of grass-leaved sweetflag powder, is crushed to particle diameter 0.6-1.5mm.
Mixed liquor adds grass meal, then concentration is evaporated at 38-42 DEG C by single-action two-stage evaporation device, is concentrated into dry
Content 19-21%, concentrate is spray-dried at 68-72 DEG C by spray drying tower obtain aqueous less than 10% it is powdered
Finished product.
According to relevant information, soybean stalk protein content is 10%-12%, and hundred jin of stalks can replace 3 kilograms of grains.Clover
Cao Shu leguminous herbaceous plants, amino acid content is 5.7 times of corn, is referred to as King of Pasture.Rhizoma atractylodis are composite family perennial herb
The dry rhizome of plant Atractylis lancea or Atractylis chinensis, belongs to Chinese medicine of removing dampness by means of aromatics, has stomach strengthening and digestion promoting to livestock and poultry through testing, and enhancing is immune
The effect of power.Cape jasmine be dicotyledon Rubiaceae medicinal material, with it is clearing heat and detoxicating the effect of.Dandelion composite family perennial herb
Plant, containing taraxol, taraxacin, choline, organic acid, synanthrin, protein, fat, carbohydrate, trace element and
A variety of health-nutrition compositions such as vitamin, the effects such as having diuresis, laxative, removing jaundice subcutaneous ulcer, cholagogic.Nutmeg is parts of generic medicinal plants, tool
There is the effects such as antidiarrheal, clearing damp, expelling parasite.Caragana microphylla is that pulse family Caragana is fallen leaves big shrub forage plant, and caragana microphylla is good feeding
Plant, nutritive value is very high, and cauline leaf contains thick protein 22.9%, crude fat 4.9%, crude fibre 27.8%；Contain thick egg in seed
White matter 27.4%, crude fat 12.8%, NFE 31.6%.Radix glycyrrhizae is a kind of clearing heat and detoxicating, Chinese herbal medicine of gastral cavity abdomen help.
Radix Isatidis is that one kind is relieved inflammation or internal heat removing toxic substances, prevention disease Chinese medicine.Sea-buckthorn is a kind of fallen leaves property shrub, and nutritive value and medical value are very
Height, Gu, which has, brings back to life saying for battle steed of being at death's door.Grass-leaved sweetflag Acorus tatarinowii Schott are the root of aroid
Stem, is acted on dampness elimination appetizing etc..
Since 2010, repeatedly carry out liquid waste processing experiment and livestock and poultry administering transgenic, test result indicates that, add grass meal it
The time of evaporative drying process and energy consumption substantially shorten afterwards, it might even be possible to save evaporating concentration process, are directly spray-dried.
In addition, the process such as soaking heating of the grass meal of addition, generates obvious curing effect, the feed nutrition index produced is significantly
Increase, mixed feed be made with conventional feed, the weightening of livestock and poultry is accelerated, and fattening period shortens, and epidemic disease is reduced, and cost declines, it is deep by
The welcome of experiment user.
The third embodiment：Among trapped fluid and secondary mother liquid mixed liquor, grass meal and stone flour are added, its weight proportion=
Trapped fluid: grass meal: stone flour=100: 55-60: 2-5.The manufacture method of its grass meal is：20-30 parts of soybean stalk powder, alfalfa meal
10-12 parts, 3-5 parts of rhizoma atractylodis powder, 4-6 parts of gardenia powder, 10-12 parts of dandelion, 3-4 parts of ground nutmeg, 12-16 parts of caragana microphylla powder is sweet
3-5 parts of grass meal, 2-3 parts of Radix Isatidis powder, 5-8 parts of seabuckthorn fruit powder, 3-5 parts of grass-leaved sweetflag powder is crushed to particle diameter 0.6-1.5mm.Its stone flour
Manufacture method be：10-15 parts of zeolite powder, is crushed to 200-250 mesh；8-10 parts of dicalcium powder, 320-330 mesh, whiteness requirement
95%. calcium carbonate contents 99%, pure free from admixture；5-6 parts of medical stone powder, is crushed to 330-350 mesh.Pass through two sections of steamings of single-action again
Hair device is evaporated concentration at 38-42 DEG C, dry matter content 19-21% is concentrated into, by concentrate by spray drying tower in 68-
Spray drying obtains aqueous less than 10% powdered finished product at 72 DEG C.
Data shows：Zeolite is a class calcic, the natural stone based on sodium, and general chemical formula is AmBpO2pnH2O, knot
Structure formula is A (x/q) [(AlO2) x (SiO2) y] n (H2O).Zeolite has adsorptivity, ion exchangeable, catalysis and acidproof heat-proof etc.
Performance, therefore it is widely used as adsorbent, ion-exchanger and catalyst, it can also be used at drying, purification and the sewage of gas
In terms of reason.Zeolite also there is " nutrition " to be worth, and 5% zeolite powder is added in feed, can make poultry growth quickening, and body strengthens meat
Fresh, laying rate is high.This example adds zeolite in amino acids production waste liquid, you can is that the feed produced has additional nutrients, also shows
The effect of the dry such as good thickening and absorption amino acid, concentration and drying process thus shorten.
Dicalcium powder is powdered whiting, can increase Calcium Content in Foodstuff, lifts feed quality.Also have good thickening and
Adsorb the effect of the dry such as amino acid, concentration and drying process thus shorten.
Medical stone is natural medicinal stone, rich in various nutrient elements and trace element, and has stronger suction-operated, before this
Once entered the wheaten food addition experiment of pedestrian, mouthfeel and nutritive value have improvement, adds accordingly in amino acid waste liquid, processing procedure and
Product obtains promising result.
The time of waste liquid evaporative drying process after experiment discovery since 2015, addition grass meal and stone flour and energy consumption
Substantially shorten, it might even be possible to save evaporating concentration process, be directly spray-dried.Material heating can also be concentrated to and do not dripped
The degree of water, feed additive is made by natural drying, is particularly suitable for nearby residents peasant household of plant area dispersion processing.Produced
Feed nutrition index increases substantially, and mixed feed is made with conventional feed, and the weightening of livestock and poultry is accelerated, and fattening period shortens, and epidemic disease subtracts
Few, cost declines, deep to be welcome by experiment user.
Claims (7)
1. a kind of threonine high yield synergy new technology, including zymotic fluid is through ceramic membrane filter, generation cleaner liquid and trapped fluid, filtering
Liquid obtains wet threonine and a mother liquor through being concentrated by evaporation and centrifuging, and a mother liquor re-evaporation concentration obtains wet threonine
And secondary mother liquid；Finished product threonine is obtained after the drying of wet product threonine；It is characterized in that：Include bacterium obtained by ceramic membrane filter
The trapped fluid of body is merged into mixed liquor into feed grade low content finished product production line with secondary mother liquid.
2. threonine high yield synergy new technology according to claim 1, it is characterised in that：The trapped fluid and secondary mother liquid
With 2: 1 weight than synthesis mixed liquor, mixed liquor carries out three-effect evaporation and condensation, and gained concentrate carries out slurry-spraying pelletizing, contained
The threonine of amount 65%.
3. threonine high yield synergy new technology according to claim 2, it is characterised in that：The mixed liquor carries out triple effect steaming
Send out vacuum -0.85~-0.09MPa of concentration；One effect temperature：75~85 DEG C, two effect temperature：45~50 DEG C.
4. threonine high yield synergy new technology according to claim 2, it is characterised in that：The spraying of the slurry-spraying pelletizing is done
Dry device EAT：145~155 DEG C；Spray dryer leaving air temp：85~95 DEG C, cloth bag pressure difference：≤1MPa；Atomizer becomes
Frequently：20~25HZ；Granulating bed bed pressure difference：8~10KPa；Cooling bed bed pressure difference：5~7KPa；Fluid bed leaving air temp：60
~65 DEG C；Product moisture：＜ 4.0%；Product cut size：The mesh of 12 mesh~40, qualification rate >=90%；Finished product temperature：40 DEG C of ＜.
5. threonine high yield synergy new technology according to claim 1, it is characterised in that：The trapped fluid and secondary mother liquid
Mixed liquor add grass meal, its weight ratio=mixed liquor: grass meal=100: 55-60, entered by single effect evaporator at 38-42 DEG C
Row is concentrated by evaporation, and is concentrated into dry matter content 19-21%, concentrate is spray-dried by spray drying tower at 68-72 DEG C
To powdered finished product.
6. threonine high yield synergy new technology according to claim 5, it is characterised in that：The manufacture method of the grass meal
It is：20-30 parts of soybean stalk powder, 10-12 parts of alfalfa meal, 3-5 parts of rhizoma atractylodis powder, 4-6 parts of gardenia powder, 10-12 parts of dandelion, meat
3-4 parts of nutmeg, 12-16 parts of caragana microphylla powder, 3-5 parts of licorice powder, 2-3 parts of Radix Isatidis powder, 5-8 parts of seabuckthorn fruit powder, grass-leaved sweetflag powder 3-5
Part.
7. threonine high yield synergy new technology according to claim 1, it is characterised in that：The trapped fluid and secondary mother liquid
Mixed liquor add grass meal and stone flour, its weight proportion=trapped fluid: grass meal: stone flour=100: 55-60: 2-5；The grass meal is
It is made up by weight of following raw material：20-30 parts of soybean stalk powder, 10-12 parts of alfalfa meal, 3-5 parts of rhizoma atractylodis powder, gardenia powder 4-
6 parts, 10-12 parts of dandelion, 3-4 parts of ground nutmeg, 12-16 parts of caragana microphylla powder, 3-5 parts of licorice powder, 2-3 parts of Radix Isatidis powder, sea-buckthorn
5-8 parts of powder, 3-5 parts of grass-leaved sweetflag powder；The stone flour is made of by weight by following raw material：10-15 parts of crushing 200- of zeolite powder
250 mesh, 8-10 parts of crushing 320-330 mesh of dicalcium powder, 5-6 parts of crushing 330-350 mesh of medical stone powder；Pass through single effect evaporation after mixing
Device is evaporated concentration at 38-42 DEG C, dry matter content 19-21% is concentrated into, by concentrate by spray drying tower in 68-72
Spray drying obtains powdered finished product at DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710377904.XA CN107027974B (en) | 2017-05-10 | 2017-05-10 | Threonine production process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710377904.XA CN107027974B (en) | 2017-05-10 | 2017-05-10 | Threonine production process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107027974A true CN107027974A (en) | 2017-08-11 |
| CN107027974B CN107027974B (en) | 2020-08-18 |
Family
ID=59538954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710377904.XA Active CN107027974B (en) | 2017-05-10 | 2017-05-10 | Threonine production process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107027974B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108586275A (en) * | 2018-04-13 | 2018-09-28 | 沈阳环境科学研究院 | The method of effective component extracting in Threonine Fermentation concentrate |
| CN110604934A (en) * | 2018-06-15 | 2019-12-24 | 内蒙古兆沣生物科技有限公司 | Method for processing threonine mother liquor by roller scraper dryer |
| CN111066960A (en) * | 2018-10-22 | 2020-04-28 | 通辽市海邻生物科技有限公司 | Method for increasing essential amino acids of meal energy feed |
| CN111758840A (en) * | 2020-07-10 | 2020-10-13 | 廊坊梅花生物技术开发有限公司 | Feed using threonine mother liquor as raw material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102351723A (en) * | 2011-08-30 | 2012-02-15 | 无锡荣丰生物工程有限公司 | Triple-effect internal circulation continuous evaporative crystallization process of threonine |
| CN102578385A (en) * | 2011-12-30 | 2012-07-18 | 通辽梅花生物科技有限公司 | Preparation method of feed with low content of L-threonine |
| CN102805227A (en) * | 2011-06-03 | 2012-12-05 | 王道雨 | Feed for feeding cows |
| JP2016506406A (en) * | 2012-12-20 | 2016-03-03 | ヒルズ・ペット・ニュートリシャン・インコーポレーテッド | Methods for improving hair condition in non-human animals |
-
2017
- 2017-05-10 CN CN201710377904.XA patent/CN107027974B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102805227A (en) * | 2011-06-03 | 2012-12-05 | 王道雨 | Feed for feeding cows |
| CN102351723A (en) * | 2011-08-30 | 2012-02-15 | 无锡荣丰生物工程有限公司 | Triple-effect internal circulation continuous evaporative crystallization process of threonine |
| CN102578385A (en) * | 2011-12-30 | 2012-07-18 | 通辽梅花生物科技有限公司 | Preparation method of feed with low content of L-threonine |
| JP2016506406A (en) * | 2012-12-20 | 2016-03-03 | ヒルズ・ペット・ニュートリシャン・インコーポレーテッド | Methods for improving hair condition in non-human animals |
Non-Patent Citations (1)
| Title |
|---|
| 谷子林: "《规模化生态养兔技术》", 31 January 2013 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108586275A (en) * | 2018-04-13 | 2018-09-28 | 沈阳环境科学研究院 | The method of effective component extracting in Threonine Fermentation concentrate |
| CN110604934A (en) * | 2018-06-15 | 2019-12-24 | 内蒙古兆沣生物科技有限公司 | Method for processing threonine mother liquor by roller scraper dryer |
| CN111066960A (en) * | 2018-10-22 | 2020-04-28 | 通辽市海邻生物科技有限公司 | Method for increasing essential amino acids of meal energy feed |
| CN111758840A (en) * | 2020-07-10 | 2020-10-13 | 廊坊梅花生物技术开发有限公司 | Feed using threonine mother liquor as raw material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107027974B (en) | 2020-08-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102992837B (en) | Special organic/inorganic composite fertilizer for rape | |
| CN107027974A (en) | Threonine high yield synergy new technology | |
| CN103829038A (en) | Novel eucommia feed additive and production method thereof | |
| CN103564219A (en) | Stud ram feed containing Chinese herbal medicine additives | |
| CN106116924A (en) | A kind of Fructus Capsici fruiting period dedicated fertilizer | |
| CN105104857A (en) | Fermented feed for feeding wild porkers and production method thereof | |
| CN114376073B (en) | Non-grain type monogastric animal feed and preparation method thereof | |
| CN104522387A (en) | Heat-clearing beef cattle feed containing white poplar barks and preparation method of heat-clearing beef cattle feed | |
| CN110477163B (en) | Coffee fruit tea powder and preparation method thereof | |
| CN107980985A (en) | A kind of worm tea preparation technique | |
| CN101880203B (en) | Vegetable foliar biological fertilizer and preparation method thereof | |
| CN101690546B (en) | Layer chicken feed additive and using method | |
| CN103229906B (en) | Seasoned chicken feed and preparation method thereof | |
| CN104509757A (en) | Processing method of cassava powder | |
| KR101012500B1 (en) | Fertilizer component including natural mineral materials and method of manufacturing the same | |
| CN105981934A (en) | Selenium-enriched meat rabbit feed and feeding method thereof | |
| CN107223772B (en) | High-protein compound feed and production process thereof | |
| CN107500863A (en) | A kind of wine-growing Liquid Fertilizer and preparation method thereof | |
| KR100555086B1 (en) | Organic manure made by natural waste articles and producing method thereof | |
| CN112021570A (en) | Preparation method of beetroot extract | |
| CN105309842A (en) | Fish feed additive and preparation method thereof | |
| KR101067592B1 (en) | Manufacturing method of feed aids which uses the yellow earth and the bamboo powder and the fertilizer | |
| CN104522429A (en) | Bamboo shoot shell fermentation compound duck feed and making method thereof | |
| CN108902551A (en) | A kind of Eriocheir sinensis summer high temperature promotees digestion feed and preparation method thereof | |
| CN104187037A (en) | Edema-alleviating piglet feed and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |