CN107006596A - 一种沙糖桔保鲜剂 - Google Patents
一种沙糖桔保鲜剂 Download PDFInfo
- Publication number
- CN107006596A CN107006596A CN201710251456.9A CN201710251456A CN107006596A CN 107006596 A CN107006596 A CN 107006596A CN 201710251456 A CN201710251456 A CN 201710251456A CN 107006596 A CN107006596 A CN 107006596A
- Authority
- CN
- China
- Prior art keywords
- imazalil
- sugar orange
- antistaling agent
- platycodon root
- root polysaccharide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 235000000346 sugar Nutrition 0.000 title claims abstract description 38
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 39
- 239000005017 polysaccharide Substances 0.000 claims abstract description 39
- 150000004676 glycans Chemical class 0.000 claims abstract description 38
- 235000006751 Platycodon Nutrition 0.000 claims abstract description 37
- 229930189914 platycodon Natural products 0.000 claims abstract description 37
- PZBPKYOVPCNPJY-UHFFFAOYSA-N 1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]imidazole Chemical compound ClC1=CC(Cl)=CC=C1C(OCC=C)CN1C=NC=C1 PZBPKYOVPCNPJY-UHFFFAOYSA-N 0.000 claims abstract description 35
- 244000274050 Platycodon grandiflorum Species 0.000 claims abstract description 35
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- 239000005795 Imazalil Substances 0.000 claims abstract description 34
- 229960002125 enilconazole Drugs 0.000 claims abstract description 34
- 239000004480 active ingredient Substances 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 5
- 235000012055 fruits and vegetables Nutrition 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 13
- 239000000203 mixture Substances 0.000 description 12
- 235000013399 edible fruits Nutrition 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 235000006753 Platycodon grandiflorum Nutrition 0.000 description 5
- 240000003582 Platycodon grandiflorus Species 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 5
- 201000010099 disease Diseases 0.000 description 5
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 206010064458 Penicilliosis Diseases 0.000 description 4
- 230000000295 complement effect Effects 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- -1 Alcohol glycosides Chemical class 0.000 description 3
- 241000675108 Citrus tangerina Species 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 235000021552 granulated sugar Nutrition 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 238000004321 preservation Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 241000357613 Platycodon Species 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 230000003064 anti-oxidating effect Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229930182470 glycoside Natural products 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 241000208671 Campanulaceae Species 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 240000004528 Catalpa ovata Species 0.000 description 1
- 235000010005 Catalpa ovata Nutrition 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 206010061998 Hepatic lesion Diseases 0.000 description 1
- 241001272567 Hominoidea Species 0.000 description 1
- 206010062717 Increased upper airway secretion Diseases 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 241000228143 Penicillium Species 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 230000003260 anti-sepsis Effects 0.000 description 1
- 230000000259 anti-tumor effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- RJWJHRPNHPHBRN-FKVJWERZSA-N aucubin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@H]1[C@@H]2C(CO)=C[C@@H](O)[C@@H]2C=CO1 RJWJHRPNHPHBRN-FKVJWERZSA-N 0.000 description 1
- UTDFQMAXCUGNJR-UHFFFAOYSA-N aucubin Natural products OCC1OC(Oc2ccoc2C3C(O)CCC3O)C(O)C(O)C1O UTDFQMAXCUGNJR-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- 230000023597 hemostasis Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000001575 pathological effect Effects 0.000 description 1
- 230000000144 pharmacologic effect Effects 0.000 description 1
- 208000026435 phlegm Diseases 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000192 social effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000004614 tumor growth Effects 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/14—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
- A23B7/153—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
- A23B7/154—Organic compounds; Microorganisms; Enzymes
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicines Containing Plant Substances (AREA)
Abstract
本发明涉及一种沙糖桔保鲜剂，有效成分由桔梗多糖和抑霉唑组成，其中桔梗多糖和抑霉唑的重量比为(15‑1):(1‑10)。本发明有效成分协同增效，相互混用能减少单一成分的用量，协同抑菌作用能有效降低沙糖桔采后病菌的侵染，有效延长沙糖桔保鲜期。本发明原材料丰富易得、成本低、安全，符合果蔬保鲜的绿色环保要求。
Description
技术领域
本发明涉及果蔬保鲜技术领域，具体涉及一种沙糖桔保鲜剂。
背景技术
沙糖桔，又名：十月桔。最初产自肇庆的四会市黄田镇沙糖村，因而得名沙糖橘。现在主要产地有广西和广东。沙糖桔味甘酸、性温，具有理气化痰、润肺清肠、补血健脾等功效。广西桂林市荔浦县现为国家种沙糖桔面积最大的县。沙糖桔产区一般均地处亚热带地区，温湿度均较适合果实病原菌的生长，每年由于病理性腐烂导致的采后损失巨大。目前，化学杀菌剂是控制果实采后腐烂的主要方法。但是由于长期使用单一杀菌剂，病原菌能进化产生了大量抗药性菌种。为降低抗性风险和延缓抗性产生，将不同作用机理的有效成分进行复配使用是行之有效的方法之一。因此开发新型、高效且低毒、安全、使用方便以及廉价的水果保鲜剂，具有重大的社会意义和广阔的应用前景。
桔梗(Platycodon grandiflorus)，为桔梗科多年生草本植物。作为重要的经济植物在南北各地广为种植，以东北、华北地区种植的产量最大。桔梗富含多糖、桔梗苷、二氢梓醇苷、桃叶珊瑚苷及多种维生素及氨基酸。多糖类化合物是桔梗中的一类重要活性成分，具有抑菌、降低血糖、止血、抑制肿瘤生长，抗炎、抗肝损害、调节机体免疫等功能。桔梗多糖是其主要成分之一，研究表明桔梗多糖有抗肿瘤、抗氧化及增强人体免疫力等多种药理作用，而对桔梗多糖的抑菌及抗氧化性研究鲜见报道。齐齐哈尔大学的杨晓杰、董亚楠、李娜、孙百良等人发表的《桔梗多糖的抑菌性和抗氧化性研究》证实桔梗多糖对黑根霉、青霉、黄曲霉具有抑制作用。
抑霉唑(Imazalil)，又叫烯菌灵，为内吸性杀菌剂。对人畜毒性低，是优良的果蔬防腐保鲜剂，对柑橘、忙果、香蕉、苹果、瓜类尤为有效，对抗多菌灵、噻菌灵的青绿霉菌有特效，也可用于防治谷类作物病害。
鉴于沙糖桔在保鲜、储运过程中易受病害的侵染，有必要提出一种能抑制病害且能延长货架期的安全保鲜产品。目前以桔梗多糖、抑霉唑混配作有效成分的保鲜剂还未见有相关报道。
发明内容
本发明的目的是提供一种成本低、安全有效的沙糖桔保鲜剂。
本发明采取的技术方案是：一种沙糖桔保鲜剂，有效成分由桔梗多糖和抑霉唑组成，其中桔梗多糖和抑霉唑的重量比为(15-1):(1-10)。优选地，桔梗多糖和抑霉唑的重量比为(5-1):(1-3)。
所述的保鲜剂有效成分占保鲜剂总重量的5-30％。
所述的保鲜剂按照本领域技术人员所公知的方法，加入相应辅助剂制成的剂型是水乳剂。
本发明保鲜剂使用的辅助剂包括分散剂、乳化剂、抗冻剂、溶剂等或其它有益于有效成分在制剂中稳定和药效发挥的已知物质，都是本领域中常用或允许使用的各种成分。
所述沙糖桔保鲜剂的使用方法：本发明保鲜剂按有效成分用药量为200-500mg/kg，将新鲜采收的沙糖桔放入配好的保鲜液中浸泡1-3min，取出，自然晾干，后储藏保存即可。
本发明的有益效果是：
(1)桔梗多糖和抑霉唑协同增效，相互混用能减少单一成分的用量，协同抑菌作用能有效降低沙糖桔采后病菌的侵染，有效延长沙糖桔保鲜期。
(2)本发明原材料丰富易得、成本低、安全，符合果蔬保鲜的绿色环保要求。
具体实施方式
以下结合实施例对本发明的技术方案和有益效果作进一步说明，本发明所述的百分比均为重量百分比。
一、应用实施例试验
试验1：桔梗多糖和抑霉唑用于沙糖桔青霉病的室内毒力测定试验
经预试确定桔梗多糖和抑霉唑有效抑制浓度范围后，将桔梗多糖、抑霉唑及其混合物按有效成分含量分别设5个剂量梯度处理，设一清水对照。参照《农药室内生物测定试验准则杀菌剂》进行，采用菌丝生长速率法测定药剂对沙糖桔青霉病的室内毒力测定试验。72h后用十字交叉法测量菌落直径，计算各处理净生长量菌丝生长抑制率。
用DPS数据处理软件进行统计分析，将菌丝生长抑制率换算成机率值(y)，药液浓度(μg/mL)转换成对数值(x)，以最小二乘法求得毒力回归方程(y＝a+bx)，并由此计算出每种药剂的EC50值，然后按孙云沛等1960年提出的共毒系数法(CTC)来评价物质混用的增效作用，当共毒系数(CTC)≥120时，组合物表现为增效作用；当CTC≤80时，组合物表现为拮抗作用；当80＜CTC＜120时，组合物表现为相加作用，试验结果见表1。
表1：桔梗多糖、抑霉唑及其混合物对沙糖桔青霉病的室内毒力测定表
| 供试药剂 | 配比 | 回归方程(y＝a+bx) | 相关系数 | EC50(μg/mL) | 共毒系数 |
| 桔梗多糖(A) | / | y＝1.2878+1.5326x | 0.9956 | 264.36 | |
| 抑霉唑(B) | / | y＝4.2142+1.8560x | 0.9897 | 2.65 | |
| A：B | 15:1 | y＝1.8146+2.1512x | 0.9990 | 30.25 | 121.9 |
| A：B | 10:1 | y＝2.5496+1.8917x | 0.9856 | 19.74 | 134.3 |
| A：B | 5:1 | y＝3.4470+1.5978x | 0.9947 | 9.37 | 161.6 |
| A：B | 1:1 | y＝4.3235+1.5018x | 0.9909 | 2.82 | 186.1 |
| A：B | 1:3 | y＝4.4537+1.6030x | 0.9869 | 2.19 | 160.9 |
| A：B | 1:7 | y＝4.4453+1.5169x | 0.9916 | 2.32 | 130.4 |
| A：B | 1:10 | y＝4.4545+1.4313x | 0.9939 | 2.40 | 121.4 |
| A：B | 20:1 | y＝1.6627+1.8245x | 0.9887 | 67.47 | 68.7 |
| A：B | 1:15 | y＝3.9322+1.9037x | 0.9865 | 3.64 | 77.6 |
由上表1可知，桔梗多糖和抑霉唑在(15-1):(1-10)的比例范围内混配，其共毒系数(CTC)均大于120，对沙糖桔青霉病的抑制均表现出协同增效作用，相互间混配能减少用量，提高防治效果。而桔梗多糖和抑霉唑在重量比在(5-1):(1-3)范围内增效作用尤为突出。二、制备实施例
实施例1：22.0％(桔梗多糖·抑霉唑)沙糖桔保鲜剂
称取桔梗多糖11.0％、抑霉唑11.0％、烷基酚聚氧乙烯醚3％、十二烷基苯磺酸钙2.5％、黄原胶0.4％、乙二醇3％、甲苯18％、水补足至100％。
实施例2：24.0％(桔梗多糖·抑霉唑)沙糖桔保鲜剂
称取桔梗多糖3.0％、抑霉唑21.0％、苯乙烯基苯酚聚氧乙烯醚3％、十二烷基硫酸钠3.0％、阿拉伯胶0.5％、丙二醇3％、二甲苯20％、水补足至100％。
实施例3：24.0％(桔梗多糖·抑霉唑)沙糖桔保鲜剂
称取桔梗多糖20.0％、抑霉唑4.0％、脂肪醇聚氧乙烯醚3％、十二烷基硫酸钠3.0％、阿拉伯胶0.5％、乙二醇3％、甲苯20％、水补足至100％。
实施例4：22.0％(桔梗多糖·抑霉唑)沙糖桔保鲜剂
称取桔梗多糖20.0％、抑霉唑2.0％、木质素磺酸盐3％、十二烷基苯磺酸钙2.5％、黄原胶0.4％、尿素3％、甲苯18％、水补足至100％。
三、应用实施例用于沙糖桔保鲜的试验
试验处理及设计：
试验组1：上述实施例1制备的保鲜剂，即22.0％(桔梗多糖·抑霉唑)沙糖桔保鲜剂(1:1)；
试验组2：上述实施例2制备的保鲜剂，即24.0％(桔梗多糖·抑霉唑)沙糖桔保鲜剂(1:7)；
试验组3：上述实施例3制备的保鲜剂，即24.0％(桔梗多糖·抑霉唑)沙糖桔保鲜剂(5:1)；
试验组4：上述实施例4制备的保鲜剂，即22.0％(桔梗多糖·抑霉唑)沙糖桔保鲜剂(10:1)；
对比组1：市购的20％桔梗多糖粉剂；
对比组2：市购的22％抑霉唑水乳剂；
对比组3：空白对照CK。
试验地点在广西荔浦，时间为2016年12月16日。采摘处于成熟期的沙糖桔，要求选择无机械损伤、无病虫害感染、大小和成熟度等外观品质基本一致的果实，设7个处理组，即试验组1-4和对比组1-3。试验组1-4分别对应上述实施例1-4所制备的保鲜剂，对比组1-2则分别是桔梗多糖和抑霉唑单剂，对比组3为空白对照CK。浸泡前测得每处理组沙糖桔可溶性固形物平均含量为14.43％、可滴定酸平均含量为0.57％，每个处理三个重复。分别将沙糖桔放进较大的塑料网里置于试验组1-4和对比组1-2制备好的保鲜液中浸泡1min，轻轻的提起塑料网，沥干水分，晾干，放入货架；其中对比组3的沙糖桔不浸泡任何保鲜剂，作为空白对照CK，直接放入货架。然后将各处理组的沙糖桔转入贮藏库中进行贮存，贮存温度为10℃，相对湿度90％。入贮后60天测定所需的各项数据。
测定内容：采用手持数显折光仪测定沙糖桔可溶性固形物含量；可滴定酸含量采用指示剂滴定法测定；烂果率为腐烂果数/调查总果数×100；好果率为好果数/调查总果数×100。
表2
从表2可知，与对比组1-2比较，试验组1-4对沙糖桔有较好的保鲜作用，说明本发明产品明显优于单纯使用桔梗多糖或抑霉唑的保鲜效果。本发明复配制剂的防效与单剂相比具有极显著差异，可见两种有效成分复配后具有很好的保鲜作用，有效延长沙糖桔的贮存时间。
Claims (4)
1.一种沙糖桔保鲜剂，其特征在于，有效成分由桔梗多糖和抑霉唑组成，其中桔梗多糖和抑霉唑的重量比为(15-1):(1-10)。
2.根据权利要求1所述的保鲜剂，其特征在于，桔梗多糖和抑霉唑的重量比为(5-1):(1-3)。
3.根据权利要求1或2所述的保鲜剂，其特征在于，所述的有效成分占保鲜剂总重量的5-30％。
4.根据权利要求1-3任一项所述的保鲜剂，其特征在于，所述的保鲜剂制备成水乳剂。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710251456.9A CN107006596A (zh) | 2017-04-18 | 2017-04-18 | 一种沙糖桔保鲜剂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710251456.9A CN107006596A (zh) | 2017-04-18 | 2017-04-18 | 一种沙糖桔保鲜剂 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107006596A true CN107006596A (zh) | 2017-08-04 |
Family
ID=59448439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710251456.9A Withdrawn CN107006596A (zh) | 2017-04-18 | 2017-04-18 | 一种沙糖桔保鲜剂 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107006596A (zh) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102461652A (zh) * | 2010-11-14 | 2012-05-23 | 中国科学院华南植物园 | 盐酸聚六亚甲基胍在防治柑桔酸腐病上的应用及其保鲜剂 |
| CN106376895A (zh) * | 2016-08-31 | 2017-02-08 | 安徽天美食品有限公司 | 一种香草止咳杀菌松子仁 |
-
2017
- 2017-04-18 CN CN201710251456.9A patent/CN107006596A/zh not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102461652A (zh) * | 2010-11-14 | 2012-05-23 | 中国科学院华南植物园 | 盐酸聚六亚甲基胍在防治柑桔酸腐病上的应用及其保鲜剂 |
| CN106376895A (zh) * | 2016-08-31 | 2017-02-08 | 安徽天美食品有限公司 | 一种香草止咳杀菌松子仁 |
Non-Patent Citations (1)
| Title |
|---|
| 杨晓杰、董亚楠 等: "桔梗多糖的抑菌性和抗氧化性研究", 《食品研究与研发》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ali et al. | Antimicrobial activity of chitosan enriched with lemongrass oil against anthracnose of bell pepper | |
| CN104322558A (zh) | 杀菌组合物及其应用 | |
| CN103300024A (zh) | 含梧宁霉素的杀菌组合物 | |
| CN103918681A (zh) | 一种含噻菌铜的杀菌组合物 | |
| CN103444729A (zh) | 一种杀菌药物组合物及其应用 | |
| CN1327770C (zh) | 一种含有多抗霉素·多菌灵的杀菌组合物 | |
| CN103271050A (zh) | 一种复配杀菌剂 | |
| CN105454273B (zh) | 一种杀菌剂组合物 | |
| CN102028001A (zh) | 含苦豆子生物碱的植物源增效复配杀蚜剂及其制备方法 | |
| CN104642369B (zh) | 咪鲜胺和稻瘟灵复配乳油及其制备方法 | |
| CN101180963A (zh) | 含有中生菌素和甲基硫菌灵的具有增效作用的组合物 | |
| CN106172425A (zh) | 一种含辛菌胺和丙环唑的杀菌组合物及其应用 | |
| CN109757477A (zh) | 一种防治番茄灰霉病的杀菌增效组合物 | |
| CN107006596A (zh) | 一种沙糖桔保鲜剂 | |
| CN106387033A (zh) | 一种含蔗糖酯和香菇多糖的香蕉保鲜剂 | |
| CN106615064A (zh) | 一种含蔗糖酯和肉桂醛的芒果保鲜剂 | |
| CN103858885B (zh) | 防治苹果病害的杀菌组合物及其应用 | |
| CN106819090A (zh) | 一种含氨基寡糖素和茶多酚的果蔬保鲜剂 | |
| CN106912596A (zh) | 一种安全环保的苹果保鲜剂 | |
| CN107183160A (zh) | 一种水果保鲜剂 | |
| CN103651772B (zh) | 杀菌组合物 | |
| CN106135238B (zh) | 一种含藻酸丙二醇酯和环氧虫啶的农药组合物 | |
| CN109662098A (zh) | 一种含噻菌灵与多抗霉素的杀菌组合物及其应用 | |
| CN107518068A (zh) | 一种蔬菜保鲜组合物 | |
| CN108651458A (zh) | 一种含香芹酚和己唑醇的杀菌组合物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170804 |
|
| WW01 | Invention patent application withdrawn after publication |