CN106995636B - 一种工业防护面漆用丙烯酸聚合物乳液及其生产工艺 - Google Patents
一种工业防护面漆用丙烯酸聚合物乳液及其生产工艺 Download PDFInfo
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- CN106995636B CN106995636B CN201710359139.9A CN201710359139A CN106995636B CN 106995636 B CN106995636 B CN 106995636B CN 201710359139 A CN201710359139 A CN 201710359139A CN 106995636 B CN106995636 B CN 106995636B
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- 239000000839 emulsion Substances 0.000 title claims abstract description 227
- 229920000058 polyacrylate Polymers 0.000 title claims abstract description 53
- 238000005516 engineering process Methods 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 133
- 239000004908 Emulsion polymer Substances 0.000 claims abstract description 106
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 106
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 69
- 150000001450 anions Chemical class 0.000 claims abstract description 65
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 58
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims abstract description 45
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 45
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 44
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims abstract description 40
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims abstract description 38
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 37
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 37
- 239000000417 fungicide Substances 0.000 claims abstract description 37
- 238000004132 cross linking Methods 0.000 claims abstract description 10
- 239000000178 monomer Substances 0.000 claims abstract description 9
- 239000011258 core-shell material Substances 0.000 claims abstract description 4
- 239000003999 initiator Substances 0.000 claims description 105
- 238000002360 preparation method Methods 0.000 claims description 73
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 54
- 238000006243 chemical reaction Methods 0.000 claims description 49
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 27
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 18
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 18
- 239000000908 ammonium hydroxide Substances 0.000 claims description 18
- 238000001914 filtration Methods 0.000 claims description 17
- 238000010792 warming Methods 0.000 claims description 17
- 150000002148 esters Chemical class 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 14
- 239000006071 cream Substances 0.000 claims description 10
- 238000012703 microemulsion polymerization Methods 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000006210 lotion Substances 0.000 abstract description 34
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 description 21
- 239000003973 paint Substances 0.000 description 19
- 238000000034 method Methods 0.000 description 9
- 125000000129 anionic group Chemical group 0.000 description 7
- 230000001804 emulsifying effect Effects 0.000 description 7
- 150000004702 methyl esters Chemical class 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 241000276489 Merlangius merlangus Species 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical group CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- -1 process conditions Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
项目 | 泡水24h | 泡水7天 | 泡水14天 | 泡水21天 |
本发明 | 无变化 | 无变化 | 无变化 | 无变化 |
竞品乳液1 | 无变化 | 无变化 | 轻微泛白 | 严重泛白 |
竞品乳液2 | 无变化 | 轻微泛白 | 严重泛白 | 严重泛白、起泡 |
项目 | 本发明 | 竞品乳液1 | 竞品乳液2 |
耐冲击性/cm | >95 | 75 | 58 |
项目 | 本发明 | 竞品乳液1 | 竞品乳液2 |
光泽度(60°) | >98 | 85 | 89 |
项目 | 本发明 | 竞品乳液1 | 竞品乳液2 |
硬度 | H | HB | B |
项目 | 本发明 | 竞品乳液1 | 竞品乳液2 |
附着力/级 | 0 | 0 | 1 |
25℃浸泡48h附着力/级 | 0 | 2 | 3 |
项目 | 本发明工 | 竞品乳液1 | 竞品2乳液 |
耐盐雾/h | >330 | 223 | 172 |
Claims (7)
Priority Applications (1)
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CN201710359139.9A CN106995636B (zh) | 2017-05-19 | 2017-05-19 | 一种工业防护面漆用丙烯酸聚合物乳液及其生产工艺 |
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CN201710359139.9A CN106995636B (zh) | 2017-05-19 | 2017-05-19 | 一种工业防护面漆用丙烯酸聚合物乳液及其生产工艺 |
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Publication Number | Publication Date |
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CN106995636A CN106995636A (zh) | 2017-08-01 |
CN106995636B true CN106995636B (zh) | 2019-04-23 |
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CN201710359139.9A Active CN106995636B (zh) | 2017-05-19 | 2017-05-19 | 一种工业防护面漆用丙烯酸聚合物乳液及其生产工艺 |
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CN (1) | CN106995636B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108580239B (zh) * | 2018-04-26 | 2021-07-23 | 安康创立宝节能环保科技有限公司 | 耐水花岗岩涂料及其施工工艺 |
CN111607028B (zh) * | 2020-06-04 | 2022-04-29 | 山东凯威尔新材料有限公司 | 耐盐雾面漆用苯丙乳液及其制备方法和应用 |
CN111548698A (zh) * | 2020-06-19 | 2020-08-18 | 佛山市南海双维水性材料有限公司 | 用于高pvc内墙涂料的水性乳液 |
CN114437277A (zh) * | 2022-01-10 | 2022-05-06 | 浙江圣美环保材料有限公司 | 一种水性丙烯酸树脂生产配方及其合成工艺 |
CN115838554B (zh) * | 2022-10-11 | 2023-10-03 | 远大洪雨(唐山)防水材料有限公司 | 一种底面合一金属屋面防水涂料及制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04320475A (ja) * | 1991-04-19 | 1992-11-11 | Mitsui Toatsu Chem Inc | 水性分散型粘着剤組成物 |
CN103172786A (zh) * | 2012-03-26 | 2013-06-26 | 唐述华 | 一种抗粘、耐水、平滑、附着力好同时具有低温成膜性的丙烯酸乳液 |
CN105859954A (zh) * | 2016-05-05 | 2016-08-17 | 常熟林润氟硅材料有限公司 | 一种水性亚光丙烯酸乳液的制备方法 |
CN106084139A (zh) * | 2016-08-16 | 2016-11-09 | 衡水新光化工有限责任公司 | 一种水性多彩涂料用的丙烯酸乳液及其制备工艺 |
CN106279515A (zh) * | 2016-08-16 | 2017-01-04 | 衡水新光化工有限责任公司 | 一种防腐水性丙烯酸乳液的制备工艺 |
-
2017
- 2017-05-19 CN CN201710359139.9A patent/CN106995636B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04320475A (ja) * | 1991-04-19 | 1992-11-11 | Mitsui Toatsu Chem Inc | 水性分散型粘着剤組成物 |
CN103172786A (zh) * | 2012-03-26 | 2013-06-26 | 唐述华 | 一种抗粘、耐水、平滑、附着力好同时具有低温成膜性的丙烯酸乳液 |
CN105859954A (zh) * | 2016-05-05 | 2016-08-17 | 常熟林润氟硅材料有限公司 | 一种水性亚光丙烯酸乳液的制备方法 |
CN106084139A (zh) * | 2016-08-16 | 2016-11-09 | 衡水新光化工有限责任公司 | 一种水性多彩涂料用的丙烯酸乳液及其制备工艺 |
CN106279515A (zh) * | 2016-08-16 | 2017-01-04 | 衡水新光化工有限责任公司 | 一种防腐水性丙烯酸乳液的制备工艺 |
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Denomination of invention: Acrylic polymer emulsion for industrial protective top coat and its production process Effective date of registration: 20210713 Granted publication date: 20190423 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: Y2021130000015 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
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Date of cancellation: 20220708 Granted publication date: 20190423 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2021130000015 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An acrylic polymer lotion for industrial protective topcoat and its production process Effective date of registration: 20220713 Granted publication date: 20190423 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2022130000047 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230706 Granted publication date: 20190423 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2022130000047 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Acrylic polymer lotion for industrial protective finish and its production process Effective date of registration: 20230713 Granted publication date: 20190423 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2023980048488 |