CN106995571A - A kind of water-based ink printing PVC film and preparation method thereof - Google Patents

A kind of water-based ink printing PVC film and preparation method thereof Download PDF

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Publication number
CN106995571A
CN106995571A CN201710277853.3A CN201710277853A CN106995571A CN 106995571 A CN106995571 A CN 106995571A CN 201710277853 A CN201710277853 A CN 201710277853A CN 106995571 A CN106995571 A CN 106995571A
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China
Prior art keywords
water
film
based ink
pvc film
pvc
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Pending
Application number
CN201710277853.3A
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Chinese (zh)
Inventor
刘湛祥
贺小云
曾勇华
赵建民
曾宪进
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FOSHAN TIANJIN PLASTICS Co Ltd
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FOSHAN TIANJIN PLASTICS Co Ltd
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Priority to CN201710277853.3A priority Critical patent/CN106995571A/en
Publication of CN106995571A publication Critical patent/CN106995571A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00Producing flat articles, e.g. films or sheets
    • B29D7/01Films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Optics & Photonics (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Printing Methods (AREA)

Abstract

The present invention provides a kind of water-based ink printing PVC film, it is characterised in that:Including PVC film, water-based ink and polishes, the PVC film by following weight than component composition:PVC resin powder:90 110, plasticizer:22 26, calcium powder:25 35, stabilization agent:24, processing aid:0.2 0.6, the water-based ink includes red, yellow, blueness, black and white water-borne ink, by the control of the manufacturing parameter to above-mentioned formula, can produce a water-based ink printing PVC film best in quality, non-toxic, free from extraneous odour.

Description

A kind of water-based ink printing PVC film and preparation method thereof
Technical field
The present invention relates to thin film technique field, more particularly to a kind of negative ion powder and the anion comprising the negative ion powder PVC decorative Film and preparation method thereof.
Background technology
Ink is the maximum pollution sources of current printing industry, the global organic volatile disposal of pollutants as caused by ink every year Amount is up to hundreds of thousands ton.These organic volatiles, can form the greenhouse effects more serious than carbon dioxide, and in sunlight Oxide and photochemical fog can be formed under irradiation, severe contamination atmospheric environment influences health of people.In addition, food, toy etc. Containing harmful compositions such as heavy metals in the common ink that package printed matter is used, the body that can directly endanger eater is good for Health.With the enhancing of people's environmental consciousness, many countries are limited ink containing benzene solvent, the water-based ink of environmental protection Start to be widely popularized to come.A water-based ink best in quality how is produced, is major factories to meet the demand in market Family's thinking.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a water best in quality, non-toxic, free from extraneous odour Property ink printing PVC film.
To achieve the above object, technical scheme provided by the present invention is:A kind of water-based ink prints PVC film, and it is special Levy and be:Including PVC film, water-based ink and polishes, the PVC film by following weight than component composition:Polyvinyl chloride resin Powder:90-110, plasticizer:22-26, calcium powder:25-35, stabilization agent:2-4, processing aid:0.2-0.6, the water-based ink bag Include red, yellow, blueness, black and white water-borne ink.
Preferably, the PVC film by following weight than component composition:PVC resin powder:100, plasticizer:24, calcium Powder:30, stabilization agent:3, processing aid:0.4.
The present invention also provides the preparation method that a kind of above-mentioned water-based ink prints PVC film, it is characterised in that:First carry out Prepared by PVC film, then the PVC film prepared is carried out into water-based ink printing;
Prepared by wherein described PVC film comprises the following steps:
A1. the raw material in above-mentioned formula are passed through into metering system automatic gauge;
A2. the raw material measured are transported to ten thousand horsepowers of high speed mixing, plasticizing;
A3. preliminary mixed raw material carry out mixing plasticizing by banbury again;
A4. plastified again by rolling turbine A, B again;
A5. the raw material after plastifying pass through filter impurity screening;
A6. it is calendered plasticized that the raw material after filtering are delivered to calendering adhesive tape machine progress;
A7. the film after calendered plasticized is embossed by embossed wheel;
A8. the film after being embossed is cooled down by cooling wheel;
A9. finally by coiling machine by film take-up;It is standby;
More than, the effect of various components:
PVC resin powder:It is the main raw material(s) for producing PVC film;
Plasticizer:Improve polyvinyl chloride plasticity and pliability, reduction polyvinyl chloride processing temperature;
Stabilization agent:Ensure that PVC does not allow degradable, it is more stable;
Calcium powder:Hardness, the stability of product can be improved, and improves the lustrous surface and profile pattern of product, and because Calcium carbonate whiteness can also replace the Chinese white of costliness, reduce cost up to more than 90;
Auxiliary agent:Be conducive to improving the plasticizing capacity of resin;
Assorted water-based ink and polishes are used for mixing colours;
The water-based ink printing comprises the following steps:
Thin-film unreeling-tension force-film pressing-the color of the chromatography first-color of first time drying-chromatography second-second is dry Dry-color of chromatography the 3rd-four drying-traction wheel-windings of the 4th Se-the of third time drying-chromatography, the speed of production control of film In 35m/min, tension force is in 191N, and the pressing wheel hot blast control of the pressing is in 58 DEG C, the control of first time drying temperature In 60 DEG C, second of 60 DEG C of drying temperature, 55 DEG C of third time drying temperature, the 4th 55 DEG C of drying temperature.
Compared with prior art, water-based ink of the invention is as primary solvent or decentralized medium, so significantly with water Reduce the consumption of organic solvent or even the presence of organic solvent can be substantially eliminated, meet environmental protection requirement;In addition it is produced Process safety, nontoxicity, free from extraneous odour, are a kind of new " green " printing materials.
Embodiment
With reference to specific embodiment, the invention will be further described:
Embodiment 1:The present embodiment provides a kind of water-based ink printing PVC film, including PVC film, water-based ink and gold Oil, the PVC film by following weight than component composition:The PVC film by following weight than component composition:PVC trees Cosmetics:90, plasticizer:22, calcium powder:25, stabilization agent:2, processing aid:0.2;The water-based ink includes red, yellow, indigo plant Depending on color, black and white water-borne ink, the model color that the amount of the water-based ink and polishes is provided according to client.
Embodiment 2:Relative to embodiment 1, difference is:The PVC film by following weight than component composition:PVC Resin-oatmeal:110, plasticizer:26, calcium powder:35, stabilization agent:4, processing aid:0.6;
Embodiment 3:Relative to embodiment 1, difference is:The PVC film by following weight than component composition:PVC Resin-oatmeal:100, plasticizer:24, calcium powder:30, stabilization agent:3, processing aid:0.4.
The present invention also provides the preparation method that a kind of above-mentioned water-based ink prints PVC film, above three is respectively adopted real The formula in example is applied, PVC film preparation is first carried out, then the PVC film prepared is subjected to water-based ink printing;
Prepared by wherein described PVC film comprises the following steps:
A1. the raw material in above-mentioned formula are passed through into metering system automatic gauge;
A2. the raw material measured are transported to ten thousand horsepowers of high speed mixing, plasticizing;
A3. preliminary mixed raw material carry out mixing plasticizing by banbury again;
A4. plastified again by rolling turbine A, B again;
A5. the raw material after plastifying pass through filter impurity screening;
A6. it is calendered plasticized that the raw material after filtering are delivered to calendering adhesive tape machine progress;
A7. the film after calendered plasticized is embossed by embossed wheel;
A8. the film after being embossed is cooled down by cooling wheel;
A9. finally by coiling machine by film take-up;It is standby;
The water-based ink printing comprises the following steps:
Thin-film unreeling-tension force-film pressing-the color of the chromatography first-color of first time drying-chromatography second-second is dry Dry-color of chromatography the 3rd-four drying-traction wheel-windings of the 4th Se-the of third time drying-chromatography, the speed of production control of film In 35m/min, tension force is in 191N, and the pressing wheel hot blast control of the pressing is in 58 DEG C, the control of first time drying temperature In 60 DEG C, second of 60 DEG C of drying temperature, 55 DEG C of third time drying temperature, the 4th 55 DEG C of drying temperature.
During printing, intaglio press is used, intaglio press controls print speed printing speed using stepless speed variator system, in order to Make assorted printing element synchronous, using a main motor and buncher, whole Department of Printing is driven with rotary shaft one long System.Pump is started, checks whether pump reverses.Start main motor under the situation that assorted printing plate clutch departs from, check speed change Device speed change situation, then changes drier and air blower, and clutch is closed under the low speed, carries out chromatography.On the basis of the first color, Start crawl beginning carry out second, third, the alignment of longitudinal chromatography of the 4th color;Then still on the basis of the first color, progress second, The transverse direction chromatography alignment of three, the 4th colors, horizontal chromatography is finely tuned with handwheel to be aligned.Vertically and horizontally after chromatography alignment, accelerate printing speed Degree.Operator should keep a close eye on chromatography situation, at any time manual adjustment.Apply after curing ink, ink enters drier, drier temperature The arrangement of degree is set in low-high-low form, is easy to rapid draing.High dry is immediately entered after can not printing, it is to avoid occurred It is anti-viscous.
Examples of implementation described above are only the preferred embodiments of the invention, and the implementation model of the present invention is not limited with this Enclose, therefore the change that all shape, principles according to the present invention are made, it all should cover within the scope of the present invention.

Claims (3)

1. a kind of water-based ink prints PVC film, it is characterised in that:Including PVC film, water-based ink and polishes, the PVC is thin Film by following weight than component composition:PVC resin powder:90-110, plasticizer:22-26, calcium powder:25-35, stabilization agent:2-4, Processing aid:0.2-0.6, the water-based ink includes red, yellow, blueness, black and white water-borne ink.
2. water-based ink according to claim 1 prints PVC film, it is characterised in that:The PVC film presses following weight The component composition of ratio:PVC resin powder:100, plasticizer:24, calcium powder:30, stabilization agent:3, processing aid:0.4.
3. a kind of water-based ink as claimed in claim 1 prints the preparation method of PVC film, it is characterised in that:First carry out PVC Film preparation, then the PVC film prepared is subjected to water-based ink printing;
Prepared by wherein described PVC film comprises the following steps:
A1. the raw material in above-mentioned formula are passed through into metering system automatic gauge;
A2. the raw material measured are transported to ten thousand horsepowers of high speed mixing, plasticizing;
A3. preliminary mixed raw material carry out mixing plasticizing by banbury again;
A4. plastified again by rolling turbine A, B again;
A5. the raw material after plastifying pass through filter impurity screening;
A6. it is calendered plasticized that the raw material after filtering are delivered to calendering adhesive tape machine progress;
A7. the film after calendered plasticized is embossed by embossed wheel;
A8. the film after being embossed is cooled down by cooling wheel;
A9. finally by coiling machine by film take-up;It is standby;
The water-based ink printing comprises the following steps:
Drying-the set of the thin-film unreeling-tension force-film pressing-color of the chromatography first-color of first time drying-chromatography second-second The 3rd color-four drying-traction wheel-windings of the 4th Se-the of third time drying-chromatography are printed, the speed of production control of film exists 35m/min, tension force is in 191N, and the pressing wheel hot blast control of the pressing is at 58 DEG C, and the control of first time drying temperature exists 60 DEG C, second of 60 DEG C of drying temperature, 55 DEG C of third time drying temperature, the 4th 55 DEG C of drying temperature.
CN201710277853.3A 2017-04-25 2017-04-25 A kind of water-based ink printing PVC film and preparation method thereof Pending CN106995571A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107953563A (en) * 2017-12-01 2018-04-24 南亚共和塑胶(南通)有限公司 A kind of preparation method of low smell PVC building materials and ornaments films
CN108219577A (en) * 2017-12-29 2018-06-29 杭州卡丽佛装饰材料科技有限公司 A kind of printing water-based ink of pvc coloured silk films and water-based ink printing technology
CN109181153A (en) * 2018-08-08 2019-01-11 广东冠盛新材料有限公司 A kind of high durable outdoor decoration film and preparation method thereof
CN110039894A (en) * 2019-04-02 2019-07-23 浙江康豪诺特装饰材料有限公司 It is a kind of using water-based ink be printing color pure PVC wallpaper production technology
CN112280218A (en) * 2020-11-09 2021-01-29 江苏兴业联合装备技术有限公司 Environment-friendly PVC color film and preparation method thereof
CN114393899A (en) * 2022-02-16 2022-04-26 吴白浪 PVC printing decorative film and preparation process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850689A (en) * 2012-08-02 2013-01-02 佛山市天安塑料有限公司 Lead-free low-toxicity environment-friendly polyvinyl chloride (PVC) decorative material and manufacture method thereof
CN105133814A (en) * 2015-07-24 2015-12-09 浙江帝龙新材料股份有限公司 Manufacturing technology of environment-friendly high-temperature resistant compression-resistant floor color film
CN105482548A (en) * 2015-12-28 2016-04-13 佛山市天元汇邦装饰材料有限公司 Environment-friendly PVC (polyvinyl chloride) decorative film and preparation method thereof
CN105885290A (en) * 2016-05-13 2016-08-24 佛山市天进塑胶有限公司 Production formula of high-grade inkjet advertisement film for outdoor advertisements

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850689A (en) * 2012-08-02 2013-01-02 佛山市天安塑料有限公司 Lead-free low-toxicity environment-friendly polyvinyl chloride (PVC) decorative material and manufacture method thereof
CN105133814A (en) * 2015-07-24 2015-12-09 浙江帝龙新材料股份有限公司 Manufacturing technology of environment-friendly high-temperature resistant compression-resistant floor color film
CN105482548A (en) * 2015-12-28 2016-04-13 佛山市天元汇邦装饰材料有限公司 Environment-friendly PVC (polyvinyl chloride) decorative film and preparation method thereof
CN105885290A (en) * 2016-05-13 2016-08-24 佛山市天进塑胶有限公司 Production formula of high-grade inkjet advertisement film for outdoor advertisements

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107953563A (en) * 2017-12-01 2018-04-24 南亚共和塑胶(南通)有限公司 A kind of preparation method of low smell PVC building materials and ornaments films
CN108219577A (en) * 2017-12-29 2018-06-29 杭州卡丽佛装饰材料科技有限公司 A kind of printing water-based ink of pvc coloured silk films and water-based ink printing technology
CN109181153A (en) * 2018-08-08 2019-01-11 广东冠盛新材料有限公司 A kind of high durable outdoor decoration film and preparation method thereof
CN110039894A (en) * 2019-04-02 2019-07-23 浙江康豪诺特装饰材料有限公司 It is a kind of using water-based ink be printing color pure PVC wallpaper production technology
CN112280218A (en) * 2020-11-09 2021-01-29 江苏兴业联合装备技术有限公司 Environment-friendly PVC color film and preparation method thereof
CN114393899A (en) * 2022-02-16 2022-04-26 吴白浪 PVC printing decorative film and preparation process thereof

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