CN106995571A - A kind of water-based ink printing PVC film and preparation method thereof - Google Patents
A kind of water-based ink printing PVC film and preparation method thereof Download PDFInfo
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- CN106995571A CN106995571A CN201710277853.3A CN201710277853A CN106995571A CN 106995571 A CN106995571 A CN 106995571A CN 201710277853 A CN201710277853 A CN 201710277853A CN 106995571 A CN106995571 A CN 106995571A
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- water
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- based ink
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Optics & Photonics (AREA)
- Wood Science & Technology (AREA)
- Physics & Mathematics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Printing Methods (AREA)
Abstract
The present invention provides a kind of water-based ink printing PVC film, it is characterised in that:Including PVC film, water-based ink and polishes, the PVC film by following weight than component composition:PVC resin powder:90 110, plasticizer:22 26, calcium powder:25 35, stabilization agent:24, processing aid:0.2 0.6, the water-based ink includes red, yellow, blueness, black and white water-borne ink, by the control of the manufacturing parameter to above-mentioned formula, can produce a water-based ink printing PVC film best in quality, non-toxic, free from extraneous odour.
Description
Technical field
The present invention relates to thin film technique field, more particularly to a kind of negative ion powder and the anion comprising the negative ion powder
PVC decorative Film and preparation method thereof.
Background technology
Ink is the maximum pollution sources of current printing industry, the global organic volatile disposal of pollutants as caused by ink every year
Amount is up to hundreds of thousands ton.These organic volatiles, can form the greenhouse effects more serious than carbon dioxide, and in sunlight
Oxide and photochemical fog can be formed under irradiation, severe contamination atmospheric environment influences health of people.In addition, food, toy etc.
Containing harmful compositions such as heavy metals in the common ink that package printed matter is used, the body that can directly endanger eater is good for
Health.With the enhancing of people's environmental consciousness, many countries are limited ink containing benzene solvent, the water-based ink of environmental protection
Start to be widely popularized to come.A water-based ink best in quality how is produced, is major factories to meet the demand in market
Family's thinking.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a water best in quality, non-toxic, free from extraneous odour
Property ink printing PVC film.
To achieve the above object, technical scheme provided by the present invention is:A kind of water-based ink prints PVC film, and it is special
Levy and be:Including PVC film, water-based ink and polishes, the PVC film by following weight than component composition:Polyvinyl chloride resin
Powder:90-110, plasticizer:22-26, calcium powder:25-35, stabilization agent:2-4, processing aid:0.2-0.6, the water-based ink bag
Include red, yellow, blueness, black and white water-borne ink.
Preferably, the PVC film by following weight than component composition:PVC resin powder:100, plasticizer:24, calcium
Powder:30, stabilization agent:3, processing aid:0.4.
The present invention also provides the preparation method that a kind of above-mentioned water-based ink prints PVC film, it is characterised in that:First carry out
Prepared by PVC film, then the PVC film prepared is carried out into water-based ink printing;
Prepared by wherein described PVC film comprises the following steps:
A1. the raw material in above-mentioned formula are passed through into metering system automatic gauge;
A2. the raw material measured are transported to ten thousand horsepowers of high speed mixing, plasticizing;
A3. preliminary mixed raw material carry out mixing plasticizing by banbury again;
A4. plastified again by rolling turbine A, B again;
A5. the raw material after plastifying pass through filter impurity screening;
A6. it is calendered plasticized that the raw material after filtering are delivered to calendering adhesive tape machine progress;
A7. the film after calendered plasticized is embossed by embossed wheel;
A8. the film after being embossed is cooled down by cooling wheel;
A9. finally by coiling machine by film take-up;It is standby;
More than, the effect of various components:
PVC resin powder:It is the main raw material(s) for producing PVC film;
Plasticizer:Improve polyvinyl chloride plasticity and pliability, reduction polyvinyl chloride processing temperature;
Stabilization agent:Ensure that PVC does not allow degradable, it is more stable;
Calcium powder:Hardness, the stability of product can be improved, and improves the lustrous surface and profile pattern of product, and because
Calcium carbonate whiteness can also replace the Chinese white of costliness, reduce cost up to more than 90;
Auxiliary agent:Be conducive to improving the plasticizing capacity of resin;
Assorted water-based ink and polishes are used for mixing colours;
The water-based ink printing comprises the following steps:
Thin-film unreeling-tension force-film pressing-the color of the chromatography first-color of first time drying-chromatography second-second is dry
Dry-color of chromatography the 3rd-four drying-traction wheel-windings of the 4th Se-the of third time drying-chromatography, the speed of production control of film
In 35m/min, tension force is in 191N, and the pressing wheel hot blast control of the pressing is in 58 DEG C, the control of first time drying temperature
In 60 DEG C, second of 60 DEG C of drying temperature, 55 DEG C of third time drying temperature, the 4th 55 DEG C of drying temperature.
Compared with prior art, water-based ink of the invention is as primary solvent or decentralized medium, so significantly with water
Reduce the consumption of organic solvent or even the presence of organic solvent can be substantially eliminated, meet environmental protection requirement;In addition it is produced
Process safety, nontoxicity, free from extraneous odour, are a kind of new " green " printing materials.
Embodiment
With reference to specific embodiment, the invention will be further described:
Embodiment 1:The present embodiment provides a kind of water-based ink printing PVC film, including PVC film, water-based ink and gold
Oil, the PVC film by following weight than component composition:The PVC film by following weight than component composition:PVC trees
Cosmetics:90, plasticizer:22, calcium powder:25, stabilization agent:2, processing aid:0.2;The water-based ink includes red, yellow, indigo plant
Depending on color, black and white water-borne ink, the model color that the amount of the water-based ink and polishes is provided according to client.
Embodiment 2:Relative to embodiment 1, difference is:The PVC film by following weight than component composition:PVC
Resin-oatmeal:110, plasticizer:26, calcium powder:35, stabilization agent:4, processing aid:0.6;
Embodiment 3:Relative to embodiment 1, difference is:The PVC film by following weight than component composition:PVC
Resin-oatmeal:100, plasticizer:24, calcium powder:30, stabilization agent:3, processing aid:0.4.
The present invention also provides the preparation method that a kind of above-mentioned water-based ink prints PVC film, above three is respectively adopted real
The formula in example is applied, PVC film preparation is first carried out, then the PVC film prepared is subjected to water-based ink printing;
Prepared by wherein described PVC film comprises the following steps:
A1. the raw material in above-mentioned formula are passed through into metering system automatic gauge;
A2. the raw material measured are transported to ten thousand horsepowers of high speed mixing, plasticizing;
A3. preliminary mixed raw material carry out mixing plasticizing by banbury again;
A4. plastified again by rolling turbine A, B again;
A5. the raw material after plastifying pass through filter impurity screening;
A6. it is calendered plasticized that the raw material after filtering are delivered to calendering adhesive tape machine progress;
A7. the film after calendered plasticized is embossed by embossed wheel;
A8. the film after being embossed is cooled down by cooling wheel;
A9. finally by coiling machine by film take-up;It is standby;
The water-based ink printing comprises the following steps:
Thin-film unreeling-tension force-film pressing-the color of the chromatography first-color of first time drying-chromatography second-second is dry
Dry-color of chromatography the 3rd-four drying-traction wheel-windings of the 4th Se-the of third time drying-chromatography, the speed of production control of film
In 35m/min, tension force is in 191N, and the pressing wheel hot blast control of the pressing is in 58 DEG C, the control of first time drying temperature
In 60 DEG C, second of 60 DEG C of drying temperature, 55 DEG C of third time drying temperature, the 4th 55 DEG C of drying temperature.
During printing, intaglio press is used, intaglio press controls print speed printing speed using stepless speed variator system, in order to
Make assorted printing element synchronous, using a main motor and buncher, whole Department of Printing is driven with rotary shaft one long
System.Pump is started, checks whether pump reverses.Start main motor under the situation that assorted printing plate clutch departs from, check speed change
Device speed change situation, then changes drier and air blower, and clutch is closed under the low speed, carries out chromatography.On the basis of the first color,
Start crawl beginning carry out second, third, the alignment of longitudinal chromatography of the 4th color;Then still on the basis of the first color, progress second,
The transverse direction chromatography alignment of three, the 4th colors, horizontal chromatography is finely tuned with handwheel to be aligned.Vertically and horizontally after chromatography alignment, accelerate printing speed
Degree.Operator should keep a close eye on chromatography situation, at any time manual adjustment.Apply after curing ink, ink enters drier, drier temperature
The arrangement of degree is set in low-high-low form, is easy to rapid draing.High dry is immediately entered after can not printing, it is to avoid occurred
It is anti-viscous.
Examples of implementation described above are only the preferred embodiments of the invention, and the implementation model of the present invention is not limited with this
Enclose, therefore the change that all shape, principles according to the present invention are made, it all should cover within the scope of the present invention.
Claims (3)
1. a kind of water-based ink prints PVC film, it is characterised in that:Including PVC film, water-based ink and polishes, the PVC is thin
Film by following weight than component composition:PVC resin powder:90-110, plasticizer:22-26, calcium powder:25-35, stabilization agent:2-4,
Processing aid:0.2-0.6, the water-based ink includes red, yellow, blueness, black and white water-borne ink.
2. water-based ink according to claim 1 prints PVC film, it is characterised in that:The PVC film presses following weight
The component composition of ratio:PVC resin powder:100, plasticizer:24, calcium powder:30, stabilization agent:3, processing aid:0.4.
3. a kind of water-based ink as claimed in claim 1 prints the preparation method of PVC film, it is characterised in that:First carry out PVC
Film preparation, then the PVC film prepared is subjected to water-based ink printing;
Prepared by wherein described PVC film comprises the following steps:
A1. the raw material in above-mentioned formula are passed through into metering system automatic gauge;
A2. the raw material measured are transported to ten thousand horsepowers of high speed mixing, plasticizing;
A3. preliminary mixed raw material carry out mixing plasticizing by banbury again;
A4. plastified again by rolling turbine A, B again;
A5. the raw material after plastifying pass through filter impurity screening;
A6. it is calendered plasticized that the raw material after filtering are delivered to calendering adhesive tape machine progress;
A7. the film after calendered plasticized is embossed by embossed wheel;
A8. the film after being embossed is cooled down by cooling wheel;
A9. finally by coiling machine by film take-up;It is standby;
The water-based ink printing comprises the following steps:
Drying-the set of the thin-film unreeling-tension force-film pressing-color of the chromatography first-color of first time drying-chromatography second-second
The 3rd color-four drying-traction wheel-windings of the 4th Se-the of third time drying-chromatography are printed, the speed of production control of film exists
35m/min, tension force is in 191N, and the pressing wheel hot blast control of the pressing is at 58 DEG C, and the control of first time drying temperature exists
60 DEG C, second of 60 DEG C of drying temperature, 55 DEG C of third time drying temperature, the 4th 55 DEG C of drying temperature.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107953563A (en) * | 2017-12-01 | 2018-04-24 | 南亚共和塑胶(南通)有限公司 | A kind of preparation method of low smell PVC building materials and ornaments films |
CN108219577A (en) * | 2017-12-29 | 2018-06-29 | 杭州卡丽佛装饰材料科技有限公司 | A kind of printing water-based ink of pvc coloured silk films and water-based ink printing technology |
CN109181153A (en) * | 2018-08-08 | 2019-01-11 | 广东冠盛新材料有限公司 | A kind of high durable outdoor decoration film and preparation method thereof |
CN110039894A (en) * | 2019-04-02 | 2019-07-23 | 浙江康豪诺特装饰材料有限公司 | It is a kind of using water-based ink be printing color pure PVC wallpaper production technology |
CN112280218A (en) * | 2020-11-09 | 2021-01-29 | 江苏兴业联合装备技术有限公司 | Environment-friendly PVC color film and preparation method thereof |
CN114393899A (en) * | 2022-02-16 | 2022-04-26 | 吴白浪 | PVC printing decorative film and preparation process thereof |
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CN105133814A (en) * | 2015-07-24 | 2015-12-09 | 浙江帝龙新材料股份有限公司 | Manufacturing technology of environment-friendly high-temperature resistant compression-resistant floor color film |
CN105482548A (en) * | 2015-12-28 | 2016-04-13 | 佛山市天元汇邦装饰材料有限公司 | Environment-friendly PVC (polyvinyl chloride) decorative film and preparation method thereof |
CN105885290A (en) * | 2016-05-13 | 2016-08-24 | 佛山市天进塑胶有限公司 | Production formula of high-grade inkjet advertisement film for outdoor advertisements |
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CN102850689A (en) * | 2012-08-02 | 2013-01-02 | 佛山市天安塑料有限公司 | Lead-free low-toxicity environment-friendly polyvinyl chloride (PVC) decorative material and manufacture method thereof |
CN105133814A (en) * | 2015-07-24 | 2015-12-09 | 浙江帝龙新材料股份有限公司 | Manufacturing technology of environment-friendly high-temperature resistant compression-resistant floor color film |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107953563A (en) * | 2017-12-01 | 2018-04-24 | 南亚共和塑胶(南通)有限公司 | A kind of preparation method of low smell PVC building materials and ornaments films |
CN108219577A (en) * | 2017-12-29 | 2018-06-29 | 杭州卡丽佛装饰材料科技有限公司 | A kind of printing water-based ink of pvc coloured silk films and water-based ink printing technology |
CN109181153A (en) * | 2018-08-08 | 2019-01-11 | 广东冠盛新材料有限公司 | A kind of high durable outdoor decoration film and preparation method thereof |
CN110039894A (en) * | 2019-04-02 | 2019-07-23 | 浙江康豪诺特装饰材料有限公司 | It is a kind of using water-based ink be printing color pure PVC wallpaper production technology |
CN112280218A (en) * | 2020-11-09 | 2021-01-29 | 江苏兴业联合装备技术有限公司 | Environment-friendly PVC color film and preparation method thereof |
CN114393899A (en) * | 2022-02-16 | 2022-04-26 | 吴白浪 | PVC printing decorative film and preparation process thereof |
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