CN103738035B - Antifouling antibacterial high-molecular furniture decorative film and preparation method thereof - Google Patents
Antifouling antibacterial high-molecular furniture decorative film and preparation method thereof Download PDFInfo
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Abstract
The invention relates to an antifouling antibacterial high-molecular furniture decorative film and a preparation method thereof. The antifouling antibacterial high-molecular furniture decorative film is characterized by comprising a base material, an antibacterial film and a printed surface film. The antifouling antibacterial high-molecular furniture decorative film is formed by hot-pressing lamination of the base material, the antibacterial film and the printed surface film. The preparation method of the antifouling antibacterial high-molecular furniture decorative film comprises the following steps: step one, preparing the base material; step two, preparing the antibacterial film; step three, preparing the printed surface film; step four, printing the surface film; and step five, carrying out hot-pressing lamination. The antifouling antibacterial high-molecular furniture decorative film has the advantages of fire resistance and high strength, and the preparation method has the advantages of low production cost and high product production quality.
Description
Technical field
The present invention relates to a kind of antifouling and antibiosis high-molecular furniture decorative film and preparation method thereof, belong to ornament materials preparation field.
Background technology
Modern furniture product pays much attention to decoration, and to the ornament materials of top-grade furniture, the main dependence on import of China, existing domestic ornament materials can not reach due technique effect, and such as, intensity is lower, antifouling and antibiosis ability, fire resistance are poor.Therefore a kind of antifouling and antibiosis high-molecular furniture decorative film with fire resistance and high strength and preparation method thereof is sought particularly important.
Summary of the invention
The object of the invention is to overcome above-mentioned deficiency, antifouling and antibiosis high-molecular furniture decorative film that a kind of fire resistance and high strength are provided and preparation method thereof.
The object of the present invention is achieved like this:
A kind of antifouling and antibiosis high-molecular furniture decorative film and preparation method thereof, this antifouling and antibiosis high-molecular furniture decorative film comprises base material, antibacterial film and printing facial mask, described base material, antibacterial film and printing facial mask hot pressing laminating form antifouling and antibiosis high-molecular furniture decorative film, and the preparation method of this antifouling and antibiosis high-molecular furniture decorative film comprises the following steps:
Step one, prepare base material
1.1, prepare burden
Employing polyvinyl chloride resin is major ingredient, and add PE reinforcing agent, 1000 object titanium dioxides, dioctyl ester, background color slurry and other plasticizing adjuvants by proportioning, the weight proportion of its each component is as follows:
Polyvinyl chloride resin 100 parts
PE reinforcing agent 12 parts
1000 object titanium dioxide 25-30 parts
Dioctyl ester 20-25 part
1 ~ 2 part, background color slurry
Other plasticizing adjuvants 1 ~ 2 part
1.2, stir
1.3, blended copolymerization plasticizing
1.4, Polish filtration
1.5, roll
1.6, sided corona treatment
1.7, cool
Step 2, prepare antibacterial film
2.1, prepare burden
Employing polyvinyl chloride resin is major ingredient, and add dioctyl ester, 1000 order titanium dioxides, antimicrobial silver ionic agent and other plasticizing aid by proportioning, the weight proportion of its each component is:
Polyvinyl chloride resin 100 parts
Dioctyl ester 20-23 part
1000 order titanium dioxide 25-28 parts
Other plasticizing adjuvants 1 ~ 2 part
Antimicrobial silver ionic agent 1 ~ 2 part
2.2, stir
2.3, plastify
2.4, Polish filtration
2.5, roll
2.6, antimicrobial silver sheath coating
2.7, sided corona treatment
2.8, cool
Step 3, preparation printing facial mask
3.1, prepare burden
Adopt PP plastics to be major ingredient, add PE reinforcing agent, dioctyl ester, fire-retardant N H1197, background color slurry and other plasticizing aid by proportioning, the weight proportion of its each component is:
100 parts, PP plastics
PE reinforcing agent 10 parts
Dioctyl ester 18-20 part
Fire-retardant N H1197 1.5 parts
1 ~ 2 part, background color slurry
Other plasticizing aid 1 ~ 2 part
3.2, stir
3.3, blended copolymerization plasticizing
3.4, Polish filtration
3.5, roll
3.6, cool
Step 4, facial mask are printed
4.1, ink is allocated
4.2, printing machine heating
4.3, to get the raw materials ready inking up
4.4, start printing
4.5, dry
4.6, acupuncture
To print completing and the printing facial mask of drying carries out acupuncture by spiked roller;
Step 5, hot pressing laminating
5.1, smoothly to dry
5.2, opposite side
5.3, degasification
5.4, hot pressing laminating
5.5, cooling and shaping.
Preferred as one, 2.6, antimicrobial silver sheath application step is as follows:
The antibacterial film of calendering formation is delivered to antimicrobial silver sheath apparatus for coating by deflector roll and carries out silver ion antimicrobial agent coating, antimicrobial silver sheath apparatus for coating comprises twice applicator roll, per pass applicator roll rear is provided with scraper and warm-up mill, the antibacterial film of calendering formation is delivered to applicator roll by deflector roll and carries out silver ion antimicrobial agent slurry sizing, after the starching of per pass applicator roll, unnecessary slurry scrapes by scraper, make slurry be coated with evenly by scraper pressurization, antibacterial film is successively by twice applicator roll and warm-up mill.
Preferred as one, described silver ion antimicrobial agent slurry is that the silver ion agent of 5:95 and ethyl acetate are formulated by weight ratio.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention by adding fire-retardant N H1197 in printing surface film preparation, improve fire resistance, at base material, reinforcing agent is added in the preparation of antibacterial film and printing facial mask, improve intensity, silver ion is added in antibacterial film preparation, the antibacterial film surface of product is made to have micropore by needle-punching run, good permeability, silver ion can come out has good antifouling and antibiosis performance, by twice applicator roll during the coating of antimicrobial silver sheath, the combination of scraper and warm-up mill, silver ion antimicrobial agent is made again to be coated with all even effect moulding while making valuable silver ion reach optimum utilization best.Therefore this invention antifouling and antibiosis high-molecular furniture decorative film has the advantage of fire resistance and high strength, and it is low that its preparation method has production cost, the advantage that production product quality is high.
Detailed description of the invention
A kind of antifouling and antibiosis high-molecular furniture decorative film that the present invention relates to, it comprises base material, antibacterial film and printing facial mask, and described base material, antibacterial film and printing facial mask hot pressing laminating form antifouling and antibiosis high-molecular furniture decorative film.Described base material is formed by polyvinyl chloride resin and the blended copolymerization calendering of PE reinforcing agent, time prepared by described antibacterial film, inside is added with silver ion, add fire retardant calendering during described printing surface film preparation to form, then be printed as the printing facial mask of various pattern color on request, and described printing facial mask, antibacterial film and base material directly develop.
The preparation method of this antifouling and antibiosis high-molecular furniture decorative film comprises the following steps:
Step one, prepare base material
1.1, prepare burden
Employing polyvinyl chloride resin is major ingredient, adds PE reinforcing agent, 1000 object titanium dioxides, dioctyl ester, background color slurry and other plasticizing adjuvants by proportioning.The weight proportion of its each component is as follows:
Polyvinyl chloride resin 100 parts
PE reinforcing agent 12 parts
1000 object titanium dioxide 25-30 parts
Dioctyl ester 20-25 part
Background color starches 1 part
Other plasticizing adjuvants 1 part
Wherein background color slurry can be: natural wood color slurry, red wingceltis, red sandalwood mill base material, Manchurian ash and pear wood mill base material.
Other plasticizing adjuvants can be: plastics reinforcing agent, and plastics are high temperature resistant dose, plastic extrusion forming lubricant.
1.2, stir
Weigh up formulation material by proportioning, first polyvinyl chloride resin is added mixer, then add PE reinforcing agent and 1000 object titanium dioxides, stir 3 minutes, then add dioctyl ester, stir after 7 minutes and add background color slurry and other plasticizing adjuvants again, then stir 5 minutes.
Omnidistance whipping temp is 105 ~ 115 DEG C, and mixing speed is 145 ~ 160 turns/min.
1.3, blended copolymerization plasticizing
The compound be fully stirred is added banbury and is heated to 170 ~ 175 DEG C, be polymerized plasticizing in sealed states with the rotating speed of 120 ~ 130 turns/min, this process is 20 minutes, and compound copolymerization is plastified.
1.4, Polish filtration
The compound plastified is transported to extruder, extruder control temperature is at 175 ~ 180 DEG C, and extruder screw rotating speed is that 85-95 turns/min, and extruder carries out extruding and advances stirring refining, then push to die orifice footpath 180 order screen pack, " flake " that do not plastify and contaminant filter are fallen.
1.5, roll
The clinker conveyor plastified completely is after filtering entered five roll calendars, is rolled into the opaque base material of all size according to thickness, width, specification requirement.The calendering heating roller temperature of five roll calendars controls at 180 ~ 185 DEG C, rotating speed 40 ~ 42 turns/min.
1.6, sided corona treatment
The base material of calendering formation is delivered to corona treatment plant by deflector roll, and the front of base material is through high-pressure electrostatic impact process.
1.7, cool
It is for subsequent use that base material after sided corona treatment is delivered to five roller spacer cooling cylinder roller rolling after cooling through deflector roll again, and chill-roll temperature controls at 10 ~ 30 DEG C.
Step 2, prepare antibacterial film
2.1, prepare burden
Adopt polyvinyl chloride resin, add antimicrobial silver ionic agent, dioctyl ester, 1000 order titanium dioxides and other plasticizing aid, the weight proportion of its each component is:
Polyvinyl chloride resin 100 parts
Dioctyl ester 20-23 part
1000 order titanium dioxide 25-28 parts
Other plasticizing adjuvants 1 part
Antimicrobial silver ionic agent 1 part
2.2, stir
Weigh up formulation material by proportioning, first polyvinyl chloride resin is added, then add 1000 order titanium dioxides and stir 3 minutes, then add dioctyl ester and antimicrobial silver ionic agent stirs 7 minutes, then add other plasticizing adjuvants, then stir 5 minutes.
Omnidistance whipping temp is 115 DEG C, and mixing speed is 145 ~ 160 turns/min.
2.3, plastify
The compound be fully stirred is added banbury and is heated to 155 ~ 160 DEG C, be polymerized plasticizing in sealed states with the rotating speed of 120 ~ 130 turns/min.This process is 22 minutes, and compound copolymerization is plastified.
2.4, Polish filtration
The compound plastified is transported to extruder, extruder control temperature is at 160 ~ 165 DEG C, and extruder screw rotating speed is 70 ~ 80 turns/min, and extruder carries out extruding and advances stirring refining, then push to die orifice footpath 200 order screen pack, " flake " that do not plastify and contaminant filter are fallen.
2.5, roll
The clinker conveyor plastified completely is after filtering entered five roll calendars, is rolled into antibacterial film according to thickness, width, specification requirement.The calendering heating roller temperature of five roll calendars controls at 165 ~ 170 DEG C, rotating speed 38 ~ 40 turns/min.
2.6, antimicrobial silver sheath coating
The antibacterial film of calendering formation is delivered to antimicrobial silver sheath apparatus for coating by deflector roll and carries out silver ion antimicrobial agent coating.Silver ion agent is become the silver ion antimicrobial agent slurry of 5:95 with ethyl acetate proportioning.Fill two road applicator rolls at calendering procedure after-frame and form antimicrobial silver sheath apparatus for coating, by the antibacterial film of calendering formation by silver ion antimicrobial agent slurry on two roads, install additional after period per pass applicator roll warm-up mill make starching after the volatilization of antibacterial film surface size solvent.And by scraper unnecessary slurry scraped after each starching and fall into stock tank.Meanwhile, by scraper pressurization, slurry is coated with evenly, and scraper adjustable pressure, control starching amount by regulating pressure.In order to make valuable silver ion reach optimum utilization, except scraper regulates, also by two road coating processes, by slurry concentration proportioning to very rare, thus reach and both save silver ion antimicrobial agent use amount, make again silver ion antimicrobial agent be coated with all even effect moulding best.Silver ion antimicrobial agent slurry applicator roll linear velocity is synchronous with front road calender.Scraper pressure is at 0.6kg ~ 0.8kg, and heating roller temperature controls at 135 ~ 140 DEG C.
2.7, sided corona treatment
Antibacterial film after the coating of antimicrobial silver sheath is delivered to corona treatment plant through deflector roll, and positive and negative is through high-pressure electrostatic impact process.
2.8, cool
It is for subsequent use that antibacterial film after sided corona treatment is delivered to five roller spacer cooling cylinder roller rolling after cooling through deflector roll.Cooling cylinder roll temperature controls at 10 ~ 20 DEG C.
Step 3, preparation printing facial mask
3.1, prepare burden
Adopt PP plastics to be major ingredient, add PE reinforcing agent, dioctyl ester, fire-retardant N H1197, background color slurry and other plasticizing aid, the weight proportion of its each component is:
100 parts, PP plastics
PE reinforcing agent 10 parts
Dioctyl ester 18-20 part
Fire-retardant N H1197 1.5 parts
Background color starches 1 part
Other plasticizing aid 1 part
3.2, stir
Weigh up formulation material by proportioning, first PP plastics are added mixer, then add PE reinforcing agent, stir 2 minutes, then add dioctyl ester and stir 5 minutes, then add fire-retardant N H1197 and other plasticizing aid stir 3 minutes, finally add background color slurry stirring 2 minutes.
Omnidistance whipping temp is 105 ~ 115 DEG C, and mixing speed is 145 ~ 160 turns/min.
3.3, blended copolymerization plasticizing
The compound be fully stirred is added banbury and is heated to 170 ~ 175 DEG C, be polymerized plasticizing in sealed states with the rotating speed of 125 ~ 130 turns/min.This process is 22 minutes, and compound copolymerization is plastified.
3.4, Polish filtration
The compound plastified is transported to extruder, extruder control temperature is at 175 ~ 180 DEG C, and extruder screw rotating speed is 85 ~ 95 turns/min, and extruder carries out extruding and advances stirring refining, then push to die orifice footpath 220 order screen pack, " flake " that do not plastify and contaminant filter are fallen.
3.5, roll
The clinker conveyor plastified completely is after filtering entered five roll calendars, and being rolled into according to thickness, width, specification requirement very thinly has background color, has the antibacterial film of anti-flaming function.The calendering heating roller temperature of five roll calendars controls at 180 ~ 185 DEG C, rotating speed 95 ~ 105 turns/min.
3.6, cool
Shaping printing facial mask is delivered to five roller spacer cooling cylinder roller rolling after cooling through deflector roll for subsequent use.Cooling cylinder roll temperature controls at 10 ~ 20 DEG C, rotating speed 95 ~ 105 turns/min of five roller spacer cooling cylinder rollers.
Step 4, facial mask are printed
4.1, ink is allocated
By the deployed corresponding color and luster ink of specification requirement, the good printing ink concentration of special GPRS, configure rear container should cover tightly prevent volatilization, put ink for subsequent use.
4.2, printing machine heating
Start heating power supply, make printing machine need heat position and start to be heated to set point of temperature.
4.3, to get the raw materials ready inking up
Printing machine unreeling shaft on printing facial mask frame to be printed, regulate tension, to good limit, deployed ink is injected ink in printing press groove, and periodic agitation and test ink concentration.
4.4, start printing
To start shooting when Deng Ge road warm-up mill liter reaches 130 ~ 135 DEG C printing, and regulate opposite side rapidly, to flower, contraposition, and ink knife angle and pressure, regulate outer net and roller pressure.Regulate speed, normal line speed is 95 ~ 100m/min.
4.5, dry
The printing facial mask printed is dried through multiple tracks warm-up mill, through rolling after cooling after the solvent volatilization allowing in ink.
4.6, acupuncture
To print completing and the printing facial mask of drying carries out acupuncture by spiked roller, not seeing pin hole for principle with naked eyes, grasp the pin hole degree of depth and size, then rolling is for subsequent use.
Step 5, hot pressing laminating
5.1, smoothly to dry
By make-up machine material axle on the base material prepared, antibacterial film and the printing facial mask frame that prints, base material is at bottom, and antibacterial film is in centre, and printing facial mask is at surface layer, and the printing surface of printing facial mask is at internal layer.Warm-up mill is heated to 100 ~ 105 DEG C, adopts tension roller and twill roller respectively by base material, the longitudinal direction of antibacterial film and printing facial mask, laterally draw floating whole, and by heating by base material, the aqueous vapor evaporation on antibacterial film and printing facial mask surface, prevents from producing bubble and bright spot during laminating.
5.2, opposite side
Utilize " light eye " opposite side device and tension guide roller levelling base material, antibacterial film and printing facial mask vertical, horizontal trend, prevent the dislocation laminating that wanders off.
5.3, degasification
Fold through degasification two-wheel, base material, antibacterial film and printing facial mask binding face to air first squeeze out and remerge, generation bubble when preventing hot pressing from fit.
5.4, hot pressing laminating
After degasification and the base material be combined, antibacterial film and printing facial mask are heated to 160 ~ 170 DEG C through two-wheel roller, and pressurization 0.4kg, is in the hotting mask pressurizing attaching jail of just plasticizing phase together by three layers.
5.5, cooling and shaping
The hotting mask in hot pressing laminating jail becomes antifouling and antibiosis high-molecular furniture decorative film finished product through the then rolling of getting off of the upper chill roll cooling and shaping of deflector roll traction.
5.1 ~ 5.5 operation speed are 60-65m/min.
Claims (3)
1. the preparation method of an antifouling and antibiosis high-molecular furniture decorative film, it is characterized in that this antifouling and antibiosis high-molecular furniture decorative film comprises base material, antibacterial film and printing facial mask, described base material, antibacterial film and printing facial mask hot pressing laminating form antifouling and antibiosis high-molecular furniture decorative film, and the preparation method of this antifouling and antibiosis high-molecular furniture decorative film comprises the following steps:
Step one, prepare base material
1.1, prepare burden
Employing polyvinyl chloride resin is major ingredient, and add PE reinforcing agent, 1000 object titanium dioxides, dioctyl ester, background color slurry and other plasticizing adjuvants by proportioning, the weight proportion of its each component is as follows:
Polyvinyl chloride resin 100 parts
PE reinforcing agent 12 parts
1000 object titanium dioxide 25-30 parts
Dioctyl ester 20-25 part
1 ~ 2 part, background color slurry
Other plasticizing adjuvants 1 ~ 2 part
1.2, stir
1.3, blended copolymerization plasticizing
1.4, Polish filtration
1.5, roll
1.6, sided corona treatment
1.7, cool
Step 2, prepare antibacterial film
2.1, prepare burden
Employing polyvinyl chloride resin is major ingredient, and add dioctyl ester, 1000 order titanium dioxides, antimicrobial silver ionic agent and other plasticizing aid by proportioning, the weight proportion of its each component is:
Polyvinyl chloride resin 100 parts
Dioctyl ester 20-23 part
1000 order titanium dioxide 25-28 parts
Other plasticizing adjuvants 1 ~ 2 part
Antimicrobial silver ionic agent 1 ~ 2 part
2.2, stir
2.3, plastify
2.4, Polish filtration
2.5, roll
2.6, antimicrobial silver sheath coating
2.7, sided corona treatment
2.8, cool
Step 3, preparation printing facial mask
3.1, prepare burden
Adopt PP plastics to be major ingredient, add PE reinforcing agent, dioctyl ester, fire-retardant N H1197, background color slurry and other plasticizing aid by proportioning, the weight proportion of its each component is:
100 parts, PP plastics
PE reinforcing agent 10 parts
Dioctyl ester 18-20 part
Fire-retardant N H1197 1.5 parts
1 ~ 2 part, background color slurry
Other plasticizing aid 1 ~ 2 part
3.2, stir
3.3, blended copolymerization plasticizing
3.4, Polish filtration
3.5, roll
3.6, cool
Step 4, facial mask are printed
4.1, ink is allocated
4.2, printing machine heating
4.3, to get the raw materials ready inking up
4.4, start printing
4.5, dry
4.6, acupuncture
To print completing and the printing facial mask of drying carries out acupuncture by spiked roller;
Step 5, hot pressing laminating
5.1, smoothly to dry
5.2, opposite side
5.3, degasification
5.4, hot pressing laminating
5.5, cooling and shaping.
2. the preparation method of a kind of antifouling and antibiosis high-molecular furniture decorative film according to claim 1, is characterized in that 2.6, antimicrobial silver sheath application step is as follows:
The antibacterial film of calendering formation is delivered to antimicrobial silver sheath apparatus for coating by deflector roll and carries out silver ion antimicrobial agent coating, antimicrobial silver sheath apparatus for coating comprises twice applicator roll, per pass applicator roll rear is provided with scraper and warm-up mill, the antibacterial film of calendering formation is delivered to applicator roll by deflector roll and carries out silver ion antimicrobial agent slurry sizing, after the starching of per pass applicator roll, unnecessary slurry scrapes by scraper, make slurry be coated with evenly by scraper pressurization, antibacterial film is successively by twice applicator roll and warm-up mill.
3. the preparation method of a kind of antifouling and antibiosis high-molecular furniture decorative film according to claim 2, is characterized in that described silver ion antimicrobial agent slurry is that the silver ion agent of 5:95 and ethyl acetate are formulated by weight ratio.
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| CN201310500581.0A CN103738035B (en) | 2013-10-21 | 2013-10-21 | Antifouling antibacterial high-molecular furniture decorative film and preparation method thereof |
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| CN103738035B true CN103738035B (en) | 2015-07-15 |
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| BR112016029633A2 (en) | 2014-06-30 | 2017-08-22 | Dow Global Technologies Llc | antimicrobial coating composition with improved yellowing resistance |
| CN105925103A (en) * | 2016-06-23 | 2016-09-07 | 江苏科德宝建筑节能科技有限公司 | Production method of antibacterial coating, antibacterial coating and ventilated antibacterial film containing antibacterial coating |
| CN106118155B (en) * | 2016-06-23 | 2019-01-22 | 江苏科德宝建筑节能科技有限公司 | A kind of antibiotic paint and air-permeable anti-bacterial film and its waterproof and breathable Antibiotic Membrane |
| CN107901552B (en) * | 2016-06-30 | 2019-06-04 | 浙江汇锋薄膜科技有限公司 | A kind of processing method of furniture film |
| CN108752793A (en) * | 2018-06-14 | 2018-11-06 | 江苏海美新材料有限公司 | A kind of preparation method of antifouling anti-scribble high-molecular decorative film |
| CN108773147A (en) * | 2018-06-14 | 2018-11-09 | 江苏海美新材料有限公司 | A kind of preparation method of Antistatic type high-molecular decorative film |
| CN109094124A (en) * | 2018-08-28 | 2018-12-28 | 江苏海美新材料有限公司 | Antifouling and antibiosis skin sense furniture decoration film and preparation method thereof |
| CN111571838A (en) * | 2020-05-09 | 2020-08-25 | 杭州丹诗丽装饰有限公司 | Antibacterial decorative film and preparation method thereof |
| CN111923545B (en) * | 2020-07-23 | 2023-09-15 | 安徽嘉阳新材料科技有限公司 | PVC furniture film and processing technology thereof |
| CN114103339A (en) * | 2021-10-27 | 2022-03-01 | 南通百晟新材料科技有限责任公司 | Bending-resistant and impact-resistant steel plate water-based decorative film and preparation method thereof |
| CN115042491A (en) * | 2022-06-22 | 2022-09-13 | 全椒光太胶粘制品有限公司 | Antibacterial furniture film and production process thereof |
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Inventor after: Zhao Xia Inventor after: Fei Chunyan Inventor after: Zhu Guanghe Inventor after: Xu Wei Inventor after: Xu Yu Inventor after: Zhao Lifang Inventor after: Li Xianghua Inventor after: Wang Yan Inventor before: Zhao Xia Inventor before: Fei Chunyan Inventor before: Zhu Jianxiong Inventor before: Xu Wei Inventor before: Xu Yu Inventor before: Zhao Lifang Inventor before: Li Xianghua Inventor before: Wang Yan Inventor before: Zhu Guanghe |
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Effective date of registration: 20181219 Address after: 214421 No. 58 Haida Road, Huashizhen, Jiangyin City, Wuxi City, Jiangsu Province Patentee after: Jiangsu Econess Energy Co.,Ltd. Address before: 214421 Huashi Town Industrial Park, Jiangyin City, Wuxi City, Jiangsu Province Patentee before: Jiangyin Huadong Decorative Material Co., Ltd. |