WO2013129847A1 - Chemical-free synthetic wood using reed and method for manufacturing same - Google Patents

Chemical-free synthetic wood using reed and method for manufacturing same Download PDF

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Publication number
WO2013129847A1
WO2013129847A1 PCT/KR2013/001598 KR2013001598W WO2013129847A1 WO 2013129847 A1 WO2013129847 A1 WO 2013129847A1 KR 2013001598 W KR2013001598 W KR 2013001598W WO 2013129847 A1 WO2013129847 A1 WO 2013129847A1
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Prior art keywords
wood
synthetic wood
synthetic
reed
composition
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PCT/KR2013/001598
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French (fr)
Korean (ko)
Inventor
백철기
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주식회사 우드원
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Priority to CN201380011140.2A priority Critical patent/CN104136180B/en
Publication of WO2013129847A1 publication Critical patent/WO2013129847A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • B27N3/28Moulding or pressing characterised by using extrusion presses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D5/00Other working of veneer or plywood specially adapted to veneer or plywood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00Pretreatment of moulding material

Definitions

  • the present invention relates to a pollution-free reed synthetic wood and a method of manufacturing the same, and more particularly, by mixing and extruding a mixture of dyes, processing aids, UV absorbers, mineral fillers and colorants in wood powder and pulverized reeds removed formaldehyde, And it relates to a method for producing a pollution-free reed synthetic wood that can exhibit the texture of natural wood.
  • Natural wood is a wood material necessary to produce architecture, furniture, boards, pulp and paper. It is environmentally friendly, easy to process, and has the effect of improving the aesthetics through the texture of natural wood. Mainly used. However, the natural wood is not only easy to deform the water resistance or antibacterial, but also used as a building material, because the maintenance work is required continuously, the economic loss is also large, the problem that the forest is damaged by the felling of trees.
  • the synthetic wood is a material having a similar appearance or properties to natural wood by mixing finely ground wood powder and synthetic resin, and manufactured by injection or extrusion molding, and compared with natural wood, mechanical strength, water resistance, heat resistance and The antimicrobial activity is improved and the price is low, thereby reducing the manufacturing cost.
  • Korean Patent Publication No. 10-1000337 as a technique for producing a synthetic wood, after mixing and drying palm tree bark powder and aluminum hydroxide, and the natural mixture, a thermoplastic resin, a sunscreen and a pigment in the dried mixture Mixing and putting the mixture into a mold to provide a method for producing artificial composite wood comprising the step of forming a work by applying heat of 110 ⁇ 230 °C.
  • the method does not include the step of removing formaldehyde, and when used as a building material, formaldehyde may be released from the building material, which may have a harmful effect on the human body. The texture of the wood does not appear properly.
  • An object of the present invention is to solve the problems as described above, to provide a method for producing a pollution-free reed synthetic wood that can minimize the environmentally friendly and harmful substances by removing formaldehyde.
  • the present invention provides a method for producing a pollution-free reed synthetic wood that can exhibit the texture of natural wood by dyeing the wood powder and crushed reed particles themselves.
  • the pollution-free reed synthetic wood according to the present invention and a method for preparing the same are (a) removing formaldehyde from wood powder and pulverized reed, and (b) dyes of wood powder and pulverized reed from which the formaldehyde is removed.
  • Dyeing by adding (c) drying the dyed wood powder and pulverized reed, (d) mixing a synthetic resin with the dried wood flour and pulverized reed to form a pre-synthetic wood composition, (e) Adding to the pre-synthetic wood composition any one or more selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to form a synthetic wood composition; and (f) extruding the synthetic wood composition.
  • a method for producing a pollution-free reed synthetic wood is provided.
  • the step (a) is characterized in that it is carried out at 50 °C to 80 °C.
  • the step (b) is characterized in that it is carried out at 30 °C to 60 °C.
  • the pollution-free reed synthetic wood and its manufacturing method the wood powder is 30% to 40% by weight relative to the total weight of the synthetic wood composition, the crushed reed is 20% by weight relative to the total weight of the synthetic wood composition to 30% by weight, the synthetic resin is 5% to 10% by weight relative to the total weight of the synthetic wood composition, the processing aids, UV absorbers and mineral fillers are 5% to 15% by weight relative to the total weight of the synthetic wood composition and the coloring agent It is characterized in that 20 to 30% by weight relative to the total weight of the synthetic wood composition.
  • the step (c) is characterized in that the moisture content of wood flour and crushed reeds are dried to 5% to 15%.
  • the pollution-free reed synthetic wood and its manufacturing method is characterized in that any one or more selected from the group consisting of binders, lubricants, antioxidants, flame retardants and heat stabilizers. .
  • a pollution-free reed synthetic wood and a method for manufacturing the same, (a) removing formaldehyde from wood flour and pulverized reed, (b) adding dye to the wood powder and pulverized reed from which the formaldehyde is removed Dyeing, (c) drying the dyed wood flour and pulverized reed, (d) mixing synthetic resin with the dried wood flour and pulverized reed to form a pre-synthetic wood composition, (e) the preliminary Adding to the synthetic wood composition any one or more selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to form a synthetic wood composition, (f) adding coffee powder to the synthetic wood composition, and (g ) Provides a method for producing a pollution-free reed synthetic wood comprising the step of extruding the synthetic wood composition to which the coffee powder is added.
  • the pollution-free reed synthetic wood and its manufacturing method the wood powder is 30% to 40% by weight relative to the total weight of the synthetic wood composition
  • the crushed reed is 20% by weight relative to the total weight of the synthetic wood composition
  • the synthetic resin is 5 to 10% by weight relative to the total weight of the synthetic wood composition
  • the processing aid, UV absorber and mineral filler is 5 to 15% by weight relative to the total weight of the synthetic wood composition
  • the colorant 15 to 25% by weight relative to the total weight of the synthetic wood composition and the coffee powder is characterized in that 5 to 10% by weight relative to the total weight of the synthetic wood composition.
  • non-pollution reed synthetic wood by adding a dye to the wood powder and pulverized reed particles themselves can be dyed by showing the color and texture of natural wood without a separate surface treatment and durability The effect of producing this strong synthetic wood is also obtained.
  • the pollution-free reed synthetic wood according to the present invention by using the reed is excellent in elasticity and durability, the effect that can be used not only for building exterior materials but also for interior interior materials.
  • the pollution-free reed synthetic wood according to the present invention by using the reed can satisfy the wood fibers that can be lacking in the wood powder, the synthetic wood light weight about 25 to 30% compared to the weight of the general synthetic wood The effect which can be manufactured is also acquired.
  • the color of the coffee powder is colored on the surface of the synthetic wood to exhibit a natural natural coffee color and texture rather than an artificial coffee color by the pigment and coffee The effect of expressing a subtle fragrance is also obtained.
  • FIG. 1 is a flow chart illustrating a method for manufacturing a pollution-free reed synthetic wood according to an embodiment of the present invention.
  • Figure 2 is a flow chart for explaining a method for producing a pollution-free reed synthetic wood according to another embodiment of the present invention.
  • FIG. 1 is a flow chart illustrating a method for manufacturing a pollution-free reed synthetic wood according to an embodiment of the present invention.
  • the method for producing a pollution-free reed synthetic wood includes the step of removing formaldehyde from wood flour and crushed reed (S1).
  • the formaldehyde (Formaldehyde) is a colorless gas having a very strong irritant occurs in formalin, plywood and chemical production.
  • it is considered to be a harmful substance that has a harmful effect on indoor air pollution and human body, because it is included in the insulation materials and adhesives of indoor furniture, which are frequently used in buildings. Prolonged exposure to formaldehyde causes eye, nose, neck and skin irritation, respiratory distress, respiratory failure, atopic dermatitis and other skin and cancer diseases.
  • the step (S1) is preferably performed at a temperature of 50 ° C to 80 ° C, but is not limited thereto.
  • the filter and the humidity controller may be used to keep the humidity of the air flowing into the container at 3% to 10%.
  • the heating temperature is 50 °C or less, the molecular motion of the formaldehyde is not active is not sufficiently volatilized, if the heating temperature is more than 80 °C may cause a problem that the formaldehyde is not properly removed.
  • the step (S1) may be performed before producing the synthetic wood to minimize the harmful substances to reduce indoor air pollution and to produce a synthetic wood composition harmless to the human body.
  • the dye is added to the wood powder and pulverized reed remove the formaldehyde (S2).
  • the dye is used to dye the material, can be dissolved in water and organic solvents, dispersed as a single molecule and combined with the molecules of the material to color the inside of the material.
  • the dye may represent the color of the synthetic wood by mixing the red, yellow and black dyes in an appropriate ratio as necessary.
  • the red-based dyes may be used, such as marshmallow, safflower, ginger, firewood, joiner, lump, birch, brown oak, camellia, grape, brown stone and ocher, and as the yellow dye, gardenia, old tree, painting tree, Onion, yellow wall, barberry, cloves, plum, turmeric, alder, paulownia. chestnut.
  • Oak and pine trees may be used, and as the black dye, old wood, plum, pomegranate, cassia, yew, red wood, lotus shell, gall bladder, dermis, oak, pomegranate, prunus oak, maple and basalt can be used. But it is not limited thereto.
  • the step (S2) is preferably performed at 30 ° C to 60 ° C using an infrared ray lamp. If the temperature is 30 °C or less, the dye is not completely colored in the wood powder and crushed reeds to obtain a vivid color, if the temperature is 60 °C or more the viscosity of the dye is lowered may cause the color of the synthetic wood quickly discolored have.
  • the step (S2) is carried out before the preparation of the pre-synthetic wood composition to directly dye the wood powder and crushed reeds, so that the color of the synthetic wood can be vividly expressed and does not discolor even after long use.
  • the synthetic wood surface is beautifully expressed can exhibit the color and texture of natural wood without a separate coating treatment.
  • the infrared ray penetrates into the wood powder and the crushed reed particles by using an infrared light lamp to promote the reaction with the dye, so that the dye may be dispersed properly and the color of the synthetic wood may appear clearly.
  • the dyed wood flour and crushed reeds are dried (S3).
  • the step (S3) is preferably dried so that the moisture content of wood flour and crushed reeds is 5% to 15%.
  • the moisture content is less than 5%, the moisture contained in the wood flour and crushed reeds is excessively drained, so that the volume may be reduced and constricted. If the moisture content is 15% or more, the moisture content of the wood flour and crushed reeds is increased. Synthetic wood may decay or deteriorate durability.
  • the step (S3) not only controls the moisture content of the wood flour and crushed reeds, but also the dye penetrates deeply into the particles of the wood flour and crushed reeds to prevent the color of the synthetic wood from appearing vividly and discoloring and discoloring. .
  • step (S3) After performing the step (S3), to form a pre-synthetic wood composition by mixing a synthetic resin in the dry wood powder and crushed reed (S4).
  • the wood powder may be any one or more selected from the group consisting of coniferous trees such as pine, fir, pine, and hardwoods such as zelkova, maple, persimmon, chestnut, and cherry, as crushed wood finely, but not limited thereto.
  • the wood powder may be used by grinding the particle size of the wood to the size of 50 Mesh to 120 Mesh.
  • the reeds contain chitin components that form the cell walls of plants and are excellent in elasticity, elasticity and water resistance, and are suitable as a material for interior materials.
  • the reed can be used by adjusting the size of the particle according to the use, preferably 40 mesh to 180 mesh (the size of particles that can pass through a sieve having 180 scales in 1 square inch) It is not limited. If the particle size is 40 Mesh or less, the particle size is large, and thus the fiber contained in the reed and synthetic resin do not bond properly, so that the uniformity of density is lowered. If the particle size is 180 Mesh or less, the synthetic resin is contained in the reed. It may not be filled into the pores of the poor mixing can cause a problem that the strength of the synthetic wood is reduced.
  • the synthetic resin may be any one or more selected from the group consisting of polypropylene, polyethylene, and polystyrene having good processability, but is not limited thereto.
  • step (S4) it is preferable to put the wood powder, the crushed reeds and the synthetic resin into a blender at a temperature of 70 °C to 80 °C.
  • a blender it is preferable to put the wood powder, the crushed reeds and the synthetic resin into a blender at a temperature of 70 °C to 80 °C.
  • the wood powder is preferably 30% to 40% by weight relative to the total weight of the synthetic wood composition
  • the crushed reed is 20% to 30% by weight relative to the total weight of the synthetic wood composition.
  • the synthetic resin is preferably 5 to 10% by weight relative to the total weight of the synthetic wood composition.
  • the texture of the wood is lowered, if more than 40% by weight, the screw (extruder) of the extruder during the extrusion molding during the synthetic wood manufacturing process may cause a problem of wear Can be.
  • the pulverized reed is less than 20% by weight relative to the total weight of the synthetic wood composition, the elasticity and durability of the synthetic wood may decrease.
  • the synthetic resin When the synthetic resin is less than 5% by weight relative to the total weight of the synthetic wood composition, the bonding strength between the wood powder and the crushed reed particles is lowered, and the strength of the synthetic wood is lowered. When the synthetic resin is more than 10% by weight, the texture of the wood may be deteriorated. Can be.
  • step (S4) After performing the step (S4), at least one selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to the pre-synthetic wood composition to form a synthetic wood composition (S5).
  • the processing aid is not limited to any one or more selected from the group consisting of a binder, a lubricant, an antioxidant, a flame retardant, and a heat stabilizer as an additive capable of improving the processability and physical properties by adding a small amount in the production of synthetic wood.
  • the binder is a material used to improve the bonding strength between wood flour and crushed reeds and synthetic resin, and serves to increase the strength of the synthetic wood by giving elasticity and adhesion.
  • the binder may be a material in which polypropylene and polyethylene and maleic anhydride are chemically bonded, but is not limited thereto.
  • the lubricant is used to improve the fluidity of the polymer when heat-molding to facilitate processing, and serves to improve the surface properties of the synthetic wood by increasing the dispersibility of wood flour, crushed reeds and synthetic resin.
  • the lubricant may include, but is not limited to, stearic acid, polyethylene wax, and paraffin wax.
  • the antioxidant is a material used to prevent the deterioration or discoloration of mechanical properties by preventing the access of oxygen supplied from the air to the synthetic wood, phosphate-based antioxidants and calcium stearate (Calcium Stearate) But it is not limited thereto.
  • the flame retardant is a material used to suppress the combustion of synthetic resins that are easy to burn and to improve the flame resistance in the production of synthetic wood, including tricresyl phosphate, chlorinated paraffin and antimony oxide, Inorganic substances such as ammonium phosphate and boric acid may be used, but are not limited thereto.
  • the heat stabilizer is a material used to minimize decomposition by heat in the manufacturing process of synthetic wood, and serves to maintain the original color of the pigment during processing and improve the lubricity of the synthetic resin.
  • the heat stabilizer may be an epoxidized vegetable oil such as epoxidized Soy Bean Oil and epoxidized Linseed Oil, but is not limited thereto.
  • the UV absorber is a material used to block and absorb ultraviolet rays from the sun to prevent the mechanical properties or color of the synthetic wood from changing, benzophenone, benzotriazole, salicylic acid ) And acrylonitrile may be used, but is not limited thereto.
  • the mineral fillers is a material used to prevent deformation due to impact, heat and load, and serves to improve the lubricity and processability of the synthetic wood and to absorb the moisture contained in the wood and reed flour.
  • the mineral filler may be calcium carbonate, talc and mica, but is not limited thereto.
  • the processing aid, UV absorber and mineral filler is preferably 5% to 15% by weight relative to the total weight of the synthetic wood composition. If the processing aid, UV absorber and mineral filler is less than 5% by weight relative to the total weight of the synthetic wood composition may cause a problem that the mechanical strength of the synthetic wood and the stability to heat or light is lowered.
  • the colorant (Stain) is a material used to impart color stability of the synthetic wood and to prevent discoloration, and may exhibit a texture of natural wood and may improve resistance to ultraviolet rays.
  • the colorant may be an oil colorant (Oil-Stain), an alcoholic colorant, an aqueous colorant, NGR (Non Grain Raisine) stain, a pigment colorant, and Unistein, but are not limited thereto.
  • the pigment colorant serves to protect the synthetic wood from the outside by adding to the pre-synthetic wood composition and to give a color or three-dimensional impression to improve the texture of the wood.
  • the staining and coloring of the dyed wood flour and crushed reeds serves to control the incomplete portion, thereby smoothly reconditioning the dyeing state of the wood flour and crushed reeds.
  • inorganic dyes having strong light resistance, heat resistance and solvent resistance are used, and more preferably, extender pigments can be used.
  • the extender pigment (Extender Filler) is a transparent pigment with a low hiding power used in various formulations in the production of pigments, paints, optical properties of the material by mixing with paints, printing inks, plastics, rubber, paper, adhesives, etc. It plays a role to improve the property and fluidity.
  • the extender pigment is preferably a natural extender pigment such as white germ, gypsum, kaolin, but is not limited thereto.
  • Unistein is a colorant prepared by dissolving an organometallic composite dye in an organic solvent, chemical resistance, light resistance, weather resistance, colorability, dryness and workability is good and does not swell wood.
  • S2 stained wood powder and crushed reeds
  • S3 drying step
  • the colorant is preferably 20 to 30% by weight relative to the total weight of the synthetic wood composition. If the colorant is 20% by weight or less relative to the total weight of the synthetic wood composition, the color of the synthetic wood is not properly expressed, and if the colorant is 30% by weight or more, the dispersibility of the colorant is lowered, the vividness of color is lowered, and the resistance and durability of the synthetic wood are lowered. Problems may arise.
  • the step (S5) can be sufficiently mixed by adding any one or more selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to the pre-synthetic wood composition using a stirred mixer, a temperature of 60 °C to 70 °C It may be carried out in but not limited to.
  • the synthetic wood composition is extrusion molded (S6).
  • the step (S6) is to extrude the synthetic wood composition using a extruder at a pressure of 20 kgf / cm 2 to 35 kgf / cm 2 at a temperature of 160 °C to 200 °C, to obtain a synthetic wood composition in the form of a gel.
  • the synthetic wood composition may be cooled and cut to be used as a building material for a desired use.
  • the method for producing the synthetic wood composition is not limited to the extrusion molding method, any method for obtaining a synthetic wood composition such as injection molding can be used.
  • the present invention after adding any one or more selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to the pre-synthetic wood composition to form a synthetic wood composition (S5), coffee to the synthetic wood composition
  • a synthetic wood composition S5
  • coffee to the synthetic wood composition
  • it may be a method for producing a pollution-free reed synthetic wood to perform the step (S17) of extruding the synthetic wood composition to which the coffee powder is added.
  • Figure 2 is a flow chart for explaining a method for producing a pollution-free reed synthetic wood according to another embodiment of the present invention.
  • the method of manufacturing a pollution-free reed synthetic wood to which coffee powder is added is another embodiment of the present invention compared with the manufacturing method according to the embodiment of Figure 1 S1 to S5 is the same, and thus the present production method In the detailed description thereof will be omitted, it will be described directly from the step (S16) of adding the coffee powder to the synthetic wood composition.
  • the coffee powder is to use the residue left after making coffee by extracting the coffee beans, it serves as a colorant that can be colored on the surface of the synthetic wood to give a natural brown light.
  • by using the coffee powder can reduce the amount of colorant used can reduce the cost.
  • the coffee powder is preferably 5% to 10% by weight relative to the total weight of the synthetic wood composition. If the coffee powder is less than 5% by weight relative to the total weight of the synthetic wood composition, the color and aroma of the coffee powder does not appear properly. If the coffee powder is more than 10% by weight, the amount of pigment colorant and unsteine is reduced, so that staining may not be compensated for incomplete dyeing. Problems may arise.
  • the color of the coffee powder is colored on the surface of the synthetic wood by using the coffee powder, so that the natural color and texture of the coffee may be represented, rather than an artificial coffee color caused by the pigment. Aroma can be expressed.
  • the synthetic wood composition to which the coffee powder is added is extruded (S17).
  • the step (S17) is to extrude the synthetic wood composition using a extruder at a pressure of 20 kgf / cm 2 to 35 kgf / cm 2 at a temperature of 160 °C to 200 °C, to obtain a synthetic wood composition in the form of a gel.
  • the synthetic wood composition may be cooled and cut to be used as a building material for a desired use.
  • the method for producing the synthetic wood composition is not limited to the extrusion molding method, any method for obtaining a synthetic wood composition such as injection molding can be used.
  • step (S17) is different only in that it proceeds after the step of S16 compared to the step S6 of the embodiment, the overall process of extrusion molding such as temperature and pressure is the same as the step S6.
  • a dye is added to the wood powder and the pulverized reed from which the formaldehyde has been removed, and the wood powder and the pulverized reed particles themselves are dyed at a temperature of 40 ° C. to 50 ° C. using an infrared light lamp.
  • the dyed wood flour and pulverized reeds are dried using a far-infrared air blower at a temperature of 70 ° C. to 80 ° C. so that the water content of the wood flour and pulverized reeds becomes 8% to 12%.
  • the synthetic wood composition is extruded using a extruder at a temperature of 180 ° C. at a pressure of 30 kgf / cm 2 to prepare a material of synthetic wood.
  • a dye is added to the wood powder and the pulverized reed from which the formaldehyde has been removed, and the wood powder and the pulverized reed particles themselves are dyed at a temperature of 40 ° C. to 50 ° C. using an infrared light lamp.
  • the dyed wood flour and pulverized reeds are dried using a far-infrared air blower at a temperature of 70 ° C. to 80 ° C. so that the water content of the wood flour and pulverized reeds becomes 8% to 12%.
  • the synthetic wood composition is extruded using a extruder at a temperature of 180 ° C. at a pressure of 30 kgf / cm 2 to prepare a material of synthetic wood.
  • the concentration of formaldehyde released from the synthetic wood can be reduced to 0.08 ppm to 0.1 ppm. have.
  • the concentration indicates the WHO and Japanese indoor environmental standards, and the effect on the human body by the concentration of formaldehyde is shown in Table 1 below.
  • the pollution-free reed synthetic wood of the present invention is an environmentally friendly and can be seen that the synthetic wood that can minimize the harmful substances to the human body Can be.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The present invention relates to chemical-free synthetic wood using reed and to a method for manufacturing same. The method for manufacturing chemical-free synthetic wood using reed comprises: (a) a step of removing formaldehyde from wood flour and pulverized reed; (b) a step of adding dye to the wood flour and pulverized reed from which formaldehyde is removed; (c) a step of drying the dyed wood flour and pulverized reed; (d) a step of mixing synthetic resin and the dried wood flour and pulverized reed to prepare a preliminary synthetic wood composition; (e) a step of adding one or more selected from the group consisting of a processing aid, a UV absorber, a mineral filler and a colorant to the preliminary synthetic wood composition to prepare a synthetic wood composition; and (f) a step of extrusion molding the wood composition. According to the present invention, chemical-free synthetic wood using reed which is eco-friendly and exhibits the texture of natural wood can be manufactured.

Description

[규칙 제26조에 의한 보정 16.05.2013] 무공해 갈대 합성 목재 및 그의 제조방법[Revision 16.05.2013 under Rule 26] (해) Pollution-free reed synthetic wood and its manufacturing method
본 발명은 무공해 갈대 합성 목재 및 그의 제조방법에 관한 것으로서, 더욱 상세하게는, 포름알데히드를 제거한 목분 및 분쇄한 갈대에 염료, 가공조제, UV 흡수제, 미네랄 충전제 및 착색제를 혼합하여 압출 성형함으로써, 친환경적이며 천연목재의 질감을 나타낼 수 있는 무공해 갈대 합성 목재를 제조하는 방법에 관한 것이다.The present invention relates to a pollution-free reed synthetic wood and a method of manufacturing the same, and more particularly, by mixing and extruding a mixture of dyes, processing aids, UV absorbers, mineral fillers and colorants in wood powder and pulverized reeds removed formaldehyde, And it relates to a method for producing a pollution-free reed synthetic wood that can exhibit the texture of natural wood.
천연목재는 건축, 가구, 보드류, 펄프 및 종이 등을 생산하는데 필요한 나무재료로서, 환경친화적이고 가공이 용이하며 자연적인 나무의 질감을 통해 미관을 향상시키는 효과를 가지므로 건축물의 내장재 또는 외장재의 재료로 주로 사용되고 있다. 하지만, 상기 천연목재는 내수성이나 항균성이 떨어져 변형되기 쉬울 뿐만 아니라, 건축재로 사용할 경우 지속적으로 유지 관리작업이 필요하므로 경제적 손실도 크며, 나무의 벌목에 의해 산림이 훼손되는 문제점도 심각하다.Natural wood is a wood material necessary to produce architecture, furniture, boards, pulp and paper. It is environmentally friendly, easy to process, and has the effect of improving the aesthetics through the texture of natural wood. Mainly used. However, the natural wood is not only easy to deform the water resistance or antibacterial, but also used as a building material, because the maintenance work is required continuously, the economic loss is also large, the problem that the forest is damaged by the felling of trees.
상기와 같은 문제점을 해결하기 위하여, 천연목재와 유사한 질감과 외관을 가진 합성 목재에 관한 연구가 활발히 이루어지고 있다.In order to solve the above problems, research on synthetic wood having a texture and appearance similar to natural wood is being actively conducted.
상기 합성 목재는 재활용 목재를 잘게 분쇄한 목분과 합성수지를 혼합하여 천연목재와 비슷한 외관이나 성질을 갖게 한 재료로서, 사출 또는 압출성형의 방법으로 제조하며, 천연목재에 비하여 기계적 강도, 내수성, 내열성 및 항균성이 향상되고 가격이 저렴하여 제조원가가 절감되는 효과가 있다. The synthetic wood is a material having a similar appearance or properties to natural wood by mixing finely ground wood powder and synthetic resin, and manufactured by injection or extrusion molding, and compared with natural wood, mechanical strength, water resistance, heat resistance and The antimicrobial activity is improved and the price is low, thereby reducing the manufacturing cost.
한편, 합성 목재를 제조하는 기술로서 대한민국 등록특허공보 제10-1000337호는 야자수열매 껍질분말 및 수산화알루미늄을 혼합하고 건조시킨 후, 상기 건조된 혼합물에 천연미네랄제, 열가소성 수지, 자외선방지제 및 안료를 혼합하고 상기 혼합물을 성형틀에 넣고 110~230℃의 열을 가하여 가공 성형하는 단계를 포함하여 제조하는 인조복합목재의 제조 방법을 제공한다. 하지만, 상기 방법은 포름알데히드를 제거하는 단계를 포함하고 있지 않아 건축재로 사용할 경우 건축재로부터 포름알데히드가 방출되어 인체에 유해한 영향을 끼칠 수 있고, 표면가공 단계를 수행함으로써 합성수지의 사용량이 증가하고 자연적인 나무의 질감이 제대로 나타나지 않는 문제점을 갖는다. On the other hand, Korean Patent Publication No. 10-1000337 as a technique for producing a synthetic wood, after mixing and drying palm tree bark powder and aluminum hydroxide, and the natural mixture, a thermoplastic resin, a sunscreen and a pigment in the dried mixture Mixing and putting the mixture into a mold to provide a method for producing artificial composite wood comprising the step of forming a work by applying heat of 110 ~ 230 ℃. However, the method does not include the step of removing formaldehyde, and when used as a building material, formaldehyde may be released from the building material, which may have a harmful effect on the human body. The texture of the wood does not appear properly.
본 발명의 목적은 상술한 바와 같은 문제점을 해결하기 위해 이루어진 것으로서, 포름알데히드를 제거함으로써 친환경적이고 인체에 유해한 물질을 최소화할 수 있는 무공해 갈대 합성 목재의 제조방법을 제공하는 것이다.An object of the present invention is to solve the problems as described above, to provide a method for producing a pollution-free reed synthetic wood that can minimize the environmentally friendly and harmful substances by removing formaldehyde.
또한, 본 발명은 목분 및 분쇄한 갈대 입자 자체에 염료를 첨가하여 염색함으로써 천연목재의 질감을 나타낼 수 있는 무공해 갈대 합성 목재의 제조방법을 제공하는 것이다.In addition, the present invention provides a method for producing a pollution-free reed synthetic wood that can exhibit the texture of natural wood by dyeing the wood powder and crushed reed particles themselves.
상기 목적을 달성하기 위해 본 발명에 따른 무공해 갈대 합성 목재 및 그의 제조방법은 (a) 목분 및 분쇄한 갈대에서 포름알데히드를 제거하는 단계, (b) 상기 포름알데히드를 제거한 목분 및 분쇄한 갈대에 염료를 첨가하여 염색하는 단계, (c) 상기 염색된 목분 및 분쇄한 갈대를 건조하는 단계, (d) 상기 건조한 목분 및 분쇄한 갈대에 합성수지를 혼합하여 예비 합성 목재 조성물을 형성하는 단계, (e) 상기 예비 합성 목재 조성물에 가공조제, UV 흡수제, 미네랄 충전제 및 착색제로 이루어진 군으로부터 선택된 어느 하나 이상을 첨가하여 합성 목재 조성물을 형성하는 단계 및 (f) 상기 합성 목재 조성물을 압출 성형하는 단계를 포함하는 무공해 갈대 합성 목재의 제조방법을 제공한다.In order to achieve the above object, the pollution-free reed synthetic wood according to the present invention and a method for preparing the same are (a) removing formaldehyde from wood powder and pulverized reed, and (b) dyes of wood powder and pulverized reed from which the formaldehyde is removed. Dyeing by adding (c) drying the dyed wood powder and pulverized reed, (d) mixing a synthetic resin with the dried wood flour and pulverized reed to form a pre-synthetic wood composition, (e) Adding to the pre-synthetic wood composition any one or more selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to form a synthetic wood composition; and (f) extruding the synthetic wood composition. Provided is a method for producing a pollution-free reed synthetic wood.
또한, 본 발명에 따른 무공해 갈대 합성 목재 및 그의 제조방법에 의하면, 상기 단계 (a)는 50 ℃ 내지 80 ℃에서 수행되는 것을 특징으로 한다.In addition, according to the pollution-free reed synthetic wood according to the present invention and a method for producing the same, the step (a) is characterized in that it is carried out at 50 ℃ to 80 ℃.
또한, 본 발명에 따른 무공해 갈대 합성 목재 및 그의 제조방법에 의하면, 상기 단계 (b)는 30 ℃ 내지 60 ℃에서 수행되는 것을 특징으로 한다.In addition, according to the pollution-free reed synthetic wood according to the present invention and a method for producing the same, the step (b) is characterized in that it is carried out at 30 ℃ to 60 ℃.
또한, 본 발명에 따른 무공해 갈대 합성 목재 및 그의 제조방법에 의하면, 상기 목분은 합성 목재 조성물의 총 중량대비 30 중량% 내지 40 중량%, 상기 분쇄한 갈대는 합성 목재 조성물의 총 중량대비 20 중량% 내지 30 중량%, 상기 합성수지는 합성 목재 조성물의 총 중량대비 5 중량% 내지 10 중량%, 상기 가공조제, UV 흡수제 및 미네랄 충전제는 합성 목재 조성물의 총 중량대비 5 중량% 내지 15 중량% 및 상기 착색제는 합성 목재 조성물의 총 중량대비 20 중량% 내지 30 중량%인 것을 특징으로 한다.In addition, according to the present invention, the pollution-free reed synthetic wood and its manufacturing method, the wood powder is 30% to 40% by weight relative to the total weight of the synthetic wood composition, the crushed reed is 20% by weight relative to the total weight of the synthetic wood composition To 30% by weight, the synthetic resin is 5% to 10% by weight relative to the total weight of the synthetic wood composition, the processing aids, UV absorbers and mineral fillers are 5% to 15% by weight relative to the total weight of the synthetic wood composition and the coloring agent It is characterized in that 20 to 30% by weight relative to the total weight of the synthetic wood composition.
또한, 본 발명에 따른 친환경 갈대 합성 목재 및 그의 제조방법에 의하면, 상기 단계 (c)는 목분 및 분쇄한 갈대의 수분 함량이 5 % 내지 15 %가 되도록 건조하는 것을 특징으로 한다.In addition, according to the eco-friendly reed synthetic wood and its manufacturing method according to the present invention, the step (c) is characterized in that the moisture content of wood flour and crushed reeds are dried to 5% to 15%.
또한, 본 발명에 따른 무공해 갈대 합성 목재 및 그의 제조방법에 의하면, 상기 단계 (e)에서 가공조제는 결합제, 윤활제, 항산화제, 내염제 및 열안정제로 이루어진 군으로부터 선택된 어느 하나 이상인 것을 특징으로 한다.In addition, according to the present invention, the pollution-free reed synthetic wood and its manufacturing method, the processing aid in the step (e) is characterized in that any one or more selected from the group consisting of binders, lubricants, antioxidants, flame retardants and heat stabilizers. .
또한, 본 발명에 따른 무공해 갈대 합성 목재 및 그의 제조방법에 의하면, (a) 목분 및 분쇄한 갈대에서 포름알데히드를 제거하는 단계, (b) 상기 포름알데히드를 제거한 목분 및 분쇄한 갈대에 염료를 첨가하여 염색하는 단계, (c) 상기 염색된 목분 및 분쇄한 갈대를 건조하는 단계, (d) 상기 건조한 목분 및 분쇄한 갈대에 합성수지를 혼합하여 예비 합성 목재 조성물을 형성하는 단계, (e) 상기 예비 합성 목재 조성물에 가공조제, UV 흡수제, 미네랄 충전제 및 착색제로 이루어진 군으로부터 선택된 어느 하나 이상을 첨가하여 합성 목재 조성물을 형성하는 단계, (f) 상기 합성 목재 조성물에 커피 분말을 첨가하는 단계 및 (g) 상기 커피 분말이 첨가된 합성 목재 조성물을 압출 성형하는 단계를 포함하는 무공해 갈대 합성 목재의 제조방법을 제공한다.In addition, according to the present invention, a pollution-free reed synthetic wood and a method for manufacturing the same, (a) removing formaldehyde from wood flour and pulverized reed, (b) adding dye to the wood powder and pulverized reed from which the formaldehyde is removed Dyeing, (c) drying the dyed wood flour and pulverized reed, (d) mixing synthetic resin with the dried wood flour and pulverized reed to form a pre-synthetic wood composition, (e) the preliminary Adding to the synthetic wood composition any one or more selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to form a synthetic wood composition, (f) adding coffee powder to the synthetic wood composition, and (g ) Provides a method for producing a pollution-free reed synthetic wood comprising the step of extruding the synthetic wood composition to which the coffee powder is added.
또한, 본 발명에 따른 무공해 갈대 합성 목재 및 그의 제조방법에 의하면, 상기 목분은 합성 목재 조성물의 총 중량대비 30 중량% 내지 40 중량%, 상기 분쇄한 갈대는 합성 목재 조성물의 총 중량대비 20 중량% 내지 30 중량%, 상기 합성수지는 합성 목재 조성물의 총 중량대비 5 중량% 내지 10 중량%, 상기 가공조제, UV 흡수제 및 미네랄 충전제는 합성 목재 조성물의 총 중량대비 5 중량% 내지 15 중량%, 상기 착색제는 합성 목재 조성물의 총 중량대비 15 중량% 내지 25 중량% 및 상기 커피 분말은 합성 목재 조성물의 총 중량대비 5 중량% 내지 10 중량%인 것을 특징으로 한다.In addition, according to the present invention, the pollution-free reed synthetic wood and its manufacturing method, the wood powder is 30% to 40% by weight relative to the total weight of the synthetic wood composition, the crushed reed is 20% by weight relative to the total weight of the synthetic wood composition To 30% by weight, the synthetic resin is 5 to 10% by weight relative to the total weight of the synthetic wood composition, the processing aid, UV absorber and mineral filler is 5 to 15% by weight relative to the total weight of the synthetic wood composition, the colorant 15 to 25% by weight relative to the total weight of the synthetic wood composition and the coffee powder is characterized in that 5 to 10% by weight relative to the total weight of the synthetic wood composition.
상술한 바와 같이, 본 발명에 따른 무공해 갈대 합성 목재에 의하면, 포름알데히드를 제거한 목분 및 분쇄한 갈대에 염료, 가공조제, UV 흡수제, 미네랄 충전제 및 착색제를 혼합하여 압출 성형함으로써, 친환경적이며 천연목재의 질감을 나타낼 수 있는 효과가 얻어진다.As described above, according to the pollution-free reed synthetic wood according to the present invention, by mixing and extruding a mixture of dyes, processing aids, UV absorbers, mineral fillers and colorants in the wood powder and crushed reeds to remove formaldehyde, The effect of expressing texture is obtained.
또한, 본 발명에 따른 무공해 갈대 합성 목재에 의하면, 예비 합성 목재 조성물을 혼합하기 전에 포름알데히드를 제거함으로써 친환경적이고 인체에 유해한 물질을 최소화할 수 있는 효과도 얻어진다.In addition, according to the pollution-free reed synthetic wood according to the present invention, by removing the formaldehyde before mixing the pre-synthetic wood composition is also obtained the effect of minimizing environmentally friendly and harmful to the human body.
또한, 본 발명에 따른 무공해 갈대 합성 목재에 의하면, 목분 및 분쇄한 갈대 입자 자체에 염료를 첨가하여 염색하는 단계를 포함함으로써 별도의 표면 가공처리를 하지 않고 천연목재의 색감 및 질감을 나타낼 수 있으며 내구성이 강한 합성 목재를 제조할 수 있는 효과도 얻어진다.In addition, according to the non-pollution reed synthetic wood according to the present invention, by adding a dye to the wood powder and pulverized reed particles themselves can be dyed by showing the color and texture of natural wood without a separate surface treatment and durability The effect of producing this strong synthetic wood is also obtained.
또한, 본 발명에 따른 무공해 갈대 합성 목재에 의하면, 갈대를 이용함으로써 탄력성 및 내구성이 우수하여 건축 외장재뿐만 아니라 실내 인테리어재의 용도로 이용할 수 있는 효과도 얻어진다.In addition, according to the pollution-free reed synthetic wood according to the present invention, by using the reed is excellent in elasticity and durability, the effect that can be used not only for building exterior materials but also for interior interior materials.
또한, 본 발명에 따른 무공해 갈대 합성 목재에 의하면, 갈대를 이용함으로써 목분에서 부족할 수 있는 목질 섬유를 충족시켜 줄 수 있고, 일반 합성 목재의 중량에 비해 25 % 내지 30 % 정도 중량이 가벼운 합성 목재를 제조할 수 있는 효과도 얻어진다. In addition, according to the pollution-free reed synthetic wood according to the present invention, by using the reed can satisfy the wood fibers that can be lacking in the wood powder, the synthetic wood light weight about 25 to 30% compared to the weight of the general synthetic wood The effect which can be manufactured is also acquired.
또한, 본 발명에 따른 무공해 갈대 합성 목재에 의하면, 커피 분말을 이용함으로써 합성 목재의 표면에 커피 분말의 색이 착색되어 안료에 의한 인위적인 커피 색감이 아닌 천연의 자연스러운 커피 색감 및 질감을 나타낼 수 있으며 커피의 은은한 향을 발현시킬 수 있는 효과도 얻어진다.In addition, according to the pollution-free reed synthetic wood according to the present invention, by using the coffee powder, the color of the coffee powder is colored on the surface of the synthetic wood to exhibit a natural natural coffee color and texture rather than an artificial coffee color by the pigment and coffee The effect of expressing a subtle fragrance is also obtained.
도 1은 본 발명의 일 실시예에 따른 무공해 갈대 합성 목재의 제조방법을 설명하기 위한 플로우 차트이다.1 is a flow chart illustrating a method for manufacturing a pollution-free reed synthetic wood according to an embodiment of the present invention.
도 2는 본 발명의 다른 실시예에 따른 무공해 갈대 합성 목재의 제조방법을 설명하기 위한 플로우 차트이다.Figure 2 is a flow chart for explaining a method for producing a pollution-free reed synthetic wood according to another embodiment of the present invention.
본 발명의 상기 및 그 밖의 목적과 새로운 특징은 본 명세서의 기술 및 첨부 도면에 의해 더욱 명확하게 될 것이다.The above and other objects and novel features of the present invention will become more apparent from the description of the specification and the accompanying drawings.
이하, 도 1을 참조하여 본 발명의 일 실시예에 따른 무공해 갈대 합성 목재의 제조방법을 상세하게 설명하기로 한다.Hereinafter, with reference to Figure 1 will be described in detail a method for producing a pollution-free reed synthetic wood according to an embodiment of the present invention.
도 1은 본 발명의 일 실시예에 따른 무공해 갈대 합성 목재의 제조방법을 설명하기 위한 플로우 차트이다.1 is a flow chart illustrating a method for manufacturing a pollution-free reed synthetic wood according to an embodiment of the present invention.
도 1을 참조하면, 본 발명의 일 실시예에 따른 무공해 갈대 합성 목재의 제조방법은 목분 및 분쇄한 갈대에서 포름알데히드를 제거하는 단계를 포함한다(S1).Referring to Figure 1, the method for producing a pollution-free reed synthetic wood according to an embodiment of the present invention includes the step of removing formaldehyde from wood flour and crushed reed (S1).
상기 포름알데히드(Formaldehyde)는 자극성이 매우 강한 무색의 기체로 포르말린제조, 합판제조 및 화학제품제조 등에서 발생한다. 특히, 건물에 많이 사용되는 단열재와 실내가구의 접착제 등에 포함되어 실내공기오염 및 인체에 해로운 영향을 끼치는 유해물질로 여겨지고 있다. 상기 포름알데히드에 장기간 동안 노출될 경우에는 눈, 코, 목 및 피부에 자극을 일으키고, 호흡곤란, 호흡기의 이상, 아토피 피부염 및 기타피부질환 및 암 질환을 유발하게 된다.The formaldehyde (Formaldehyde) is a colorless gas having a very strong irritant occurs in formalin, plywood and chemical production. In particular, it is considered to be a harmful substance that has a harmful effect on indoor air pollution and human body, because it is included in the insulation materials and adhesives of indoor furniture, which are frequently used in buildings. Prolonged exposure to formaldehyde causes eye, nose, neck and skin irritation, respiratory distress, respiratory failure, atopic dermatitis and other skin and cancer diseases.
상기 포름알데히드는 휘발성이 강하므로, 목분 및 분쇄한 갈대를 용기에 넣고 이를 가열함으로써 제거된다. 상기 단계(S1)는 50 ℃ 내지 80 ℃의 온도에서 수행하는 것이 바람직하지만 이에 한정되지 않는다. 상기 단계(S1)에서 필터 및 습도 제어기를 사용하여 용기에 유입되는 공기의 습도를 3 % 내지 10 %로 일정하게 유지시킬 수 있다. Since the formaldehyde is highly volatile, wood powder and pulverized reed are put in a container and removed by heating it. The step (S1) is preferably performed at a temperature of 50 ° C to 80 ° C, but is not limited thereto. In the step S1, the filter and the humidity controller may be used to keep the humidity of the air flowing into the container at 3% to 10%.
상기 가열온도가 50 ℃ 이하이면 포름알데히드의 분자운동이 활발하지 않아 충분히 휘발되지 못하고, 가열온도가 80 ℃ 이상이면 습도가 높아져 포름알데히드를 제대로 제거하지 못하는 문제점이 발생할 수 있다.If the heating temperature is 50 ℃ or less, the molecular motion of the formaldehyde is not active is not sufficiently volatilized, if the heating temperature is more than 80 ℃ may cause a problem that the formaldehyde is not properly removed.
상기 단계(S1)는 합성 목재를 생산하기 전에 수행됨으로써 유해 물질을 최소화하여 실내공기오염을 감소시키고 인체에 무해한 합성 목재 조성물을 제조할 수 있다.The step (S1) may be performed before producing the synthetic wood to minimize the harmful substances to reduce indoor air pollution and to produce a synthetic wood composition harmless to the human body.
상기 단계(S1)를 수행한 다음, 상기 포름알데히드를 제거한 목분 및 분쇄한 갈대에 염료를 첨가하여 염색한다(S2). After performing the step (S1), the dye is added to the wood powder and pulverized reed remove the formaldehyde (S2).
상기 염료는 물질을 염색하기 위해 사용하는 것으로서, 물 및 유기용제에 녹아 단분자로 분산되어 물질의 분자와 결합함으로써 물질의 내부까지 착색할 수 있다. 상기 염료는 필요에 따라 적색계, 황색계 및 흑색계 염료를 적정비율로 혼합함으로써 합성 목재의 색상을 나타낼 수 있다. 상기 적색계 염료로는 꼭두서니, 홍화, 생강나무, 소방목, 소목, 괴화, 자작나무, 갈참나무, 동백, 포도, 브라운석 및 황토를 사용할 수 있고, 상기 황색계 염료로는 치자, 노목, 회화나무, 양파, 황벽, 황련, 정향나무, 자소, 울금, 오리나무, 개오동나무. 밤나무. 상수리나무 및 소나무를 사용할 수 있으며, 상기 흑색계 염료로는 노목, 양매, 석류, 계수나무, 주목, 붉나무, 연자각, 오배자, 진피, 상수리나무, 석류나무, 졸참나무, 단풍나무 및 현무암을 사용할 수 있으나 이에 한정되지 않는다.The dye is used to dye the material, can be dissolved in water and organic solvents, dispersed as a single molecule and combined with the molecules of the material to color the inside of the material. The dye may represent the color of the synthetic wood by mixing the red, yellow and black dyes in an appropriate ratio as necessary. The red-based dyes may be used, such as marshmallow, safflower, ginger, firewood, joiner, lump, birch, brown oak, camellia, grape, brown stone and ocher, and as the yellow dye, gardenia, old tree, painting tree, Onion, yellow wall, barberry, cloves, plum, turmeric, alder, paulownia. chestnut. Oak and pine trees may be used, and as the black dye, old wood, plum, pomegranate, cassia, yew, red wood, lotus shell, gall bladder, dermis, oak, pomegranate, prunus oak, maple and basalt can be used. But it is not limited thereto.
상기 단계(S2)는 적외선 광열등을 사용하여 30 ℃ 내지 60 ℃에서 수행하는 것이 바람직하다. 상기 온도가 30 ℃ 이하이면 염료가 목분 및 분쇄한 갈대에 완전하게 착색되지 않아 선명한 색을 얻을 수 없고, 온도가 60 ℃ 이상이면 염료의 점도가 낮아져 합성 목재의 색이 빨리 변색되는 문제점이 발생할 수 있다. The step (S2) is preferably performed at 30 ° C to 60 ° C using an infrared ray lamp. If the temperature is 30 ℃ or less, the dye is not completely colored in the wood powder and crushed reeds to obtain a vivid color, if the temperature is 60 ℃ or more the viscosity of the dye is lowered may cause the color of the synthetic wood quickly discolored have.
상기 단계(S2)는 예비 합성 목재 조성물을 제조하기 전에 수행되어 목분 및 분쇄한 갈대의 입자를 직접 염색함으로써, 합성 목재의 색이 선명하게 발현될 수 있고 오랜 시간 동안 사용하여도 변색되지 않는다. 또한, 합성 목재를 제조할 경우 표면이 미려하게 표현되어 별도의 코팅 처리를 하지 않고 천연목재의 색감 및 질감을 나타낼 수 있다. 또한, 적외선 광열등을 사용하여 적외선이 목분 및 분쇄한 갈대 입자 내에 침투하여 염료와의 반응을 촉진함으로써 염료가 제대로 분산되어 합성 목재의 색이 선명하게 나타날 수 있다.The step (S2) is carried out before the preparation of the pre-synthetic wood composition to directly dye the wood powder and crushed reeds, so that the color of the synthetic wood can be vividly expressed and does not discolor even after long use. In addition, when manufacturing the synthetic wood surface is beautifully expressed can exhibit the color and texture of natural wood without a separate coating treatment. In addition, the infrared ray penetrates into the wood powder and the crushed reed particles by using an infrared light lamp to promote the reaction with the dye, so that the dye may be dispersed properly and the color of the synthetic wood may appear clearly.
상기 단계(S2)를 수행한 후에, 상기 염색된 목분 및 분쇄한 갈대를 건조한다(S3).After performing the step (S2), the dyed wood flour and crushed reeds are dried (S3).
상기 단계(S3)는 목분 및 분쇄한 갈대의 수분 함량이 5 % 내지 15 %가 되도록 건조하는 것이 바람직하다. 상기 수분 함량이 5 % 이하이면 목분 및 분쇄한 갈대에 포함되어 있는 수분이 지나치게 빠져나가므로 부피가 줄어들게 되어 수축될 수 있고, 수분 함량이 15 % 이상이면 목분 및 분쇄한 갈대의 수분함량이 증가하므로 합성 목재가 부패하거나 내구성이 저하되는 문제점이 발생할 수 있다. The step (S3) is preferably dried so that the moisture content of wood flour and crushed reeds is 5% to 15%. When the moisture content is less than 5%, the moisture contained in the wood flour and crushed reeds is excessively drained, so that the volume may be reduced and constricted. If the moisture content is 15% or more, the moisture content of the wood flour and crushed reeds is increased. Synthetic wood may decay or deteriorate durability.
상기 단계(S3)는 목분 및 분쇄한 갈대의 수분함량을 조절할 뿐만 아니라, 상기 염료가 목분 및 분쇄한 갈대의 입자 내에 깊숙이 침투하여 합성 목재의 색이 선명하게 나타나고 탈색 및 변색되는 것을 방지할 수 있다.The step (S3) not only controls the moisture content of the wood flour and crushed reeds, but also the dye penetrates deeply into the particles of the wood flour and crushed reeds to prevent the color of the synthetic wood from appearing vividly and discoloring and discoloring. .
상기 단계(S3)를 수행한 후에, 상기 건조한 목분 및 분쇄한 갈대에 합성수지를 혼합하여 예비 합성 목재 조성물을 형성한다(S4).After performing the step (S3), to form a pre-synthetic wood composition by mixing a synthetic resin in the dry wood powder and crushed reed (S4).
상기 목분은 목재를 잘게 분쇄한 것으로 소나무, 전나무, 잣나무 등의 침엽수 및 느티나무, 단풍나무, 감나무, 밤나무, 벚나무 등의 활엽수로 이루어진 군으로부터 선택된 어느 하나 이상인 것을 사용할 수 있으나 이에 한정되지 않는다. 상기 목분은 목재의 입자 크기를 50 Mesh 내지 120 Mesh의 크기로 분쇄하여 사용할 수 있다.The wood powder may be any one or more selected from the group consisting of coniferous trees such as pine, fir, pine, and hardwoods such as zelkova, maple, persimmon, chestnut, and cherry, as crushed wood finely, but not limited thereto. The wood powder may be used by grinding the particle size of the wood to the size of 50 Mesh to 120 Mesh.
상기 갈대는 식물의 세포벽을 형성하는 키틴질 성분을 함유하여 탄력성 및 신축성이 뛰어나고 내수성이 강한 것으로서 내장재의 재료로 적합하다. 상기 갈대는 사용하는 용도에 따라 입자의 크기를 조절하여 사용할 수 있으며, 바람직하게는 40 Mesh 내지 180 Mesh(1 평방인치 안에 180 개의 눈금을 가진 체를 통과할 수 있는 입자의 크기)일 수 있으나 이에 한정되지 않는다. 상기 입자의 크기가 40 Mesh 이하이면 입자 크기가 크므로 갈대에 함유된 섬유질과 합성수지가 제대로 결합하지 못하므로 밀도의 균일성이 저하되고, 입자의 크기가 180 Mesh 이하이면 합성수지가 갈대에 함유된 섬유질의 기공 내로 채워지지 못하여 제대로 혼합되지 못하여 합성 목재의 강도가 저하되는 문제점이 발생할 수 있다.The reeds contain chitin components that form the cell walls of plants and are excellent in elasticity, elasticity and water resistance, and are suitable as a material for interior materials. The reed can be used by adjusting the size of the particle according to the use, preferably 40 mesh to 180 mesh (the size of particles that can pass through a sieve having 180 scales in 1 square inch) It is not limited. If the particle size is 40 Mesh or less, the particle size is large, and thus the fiber contained in the reed and synthetic resin do not bond properly, so that the uniformity of density is lowered. If the particle size is 180 Mesh or less, the synthetic resin is contained in the reed. It may not be filled into the pores of the poor mixing can cause a problem that the strength of the synthetic wood is reduced.
상기 합성수지는 가공성이 좋은 폴리프로필렌, 폴리에틸렌 및 폴리스티렌으로 이루어진 군으로부터 선택된 어느 하나 이상일 수 있으나 이에 한정되지 않는다.The synthetic resin may be any one or more selected from the group consisting of polypropylene, polyethylene, and polystyrene having good processability, but is not limited thereto.
상기 단계(S4)는 목분, 분쇄한 갈대 및 합성수지를 믹서기에 넣고 70 ℃ 내지 80 ℃의 온도에서 혼합하는 것이 바람직하다. 상기 목분, 분쇄한 갈대 및 합성수지를 혼합함으로써 결합력이 강해져 합성 목재를 제조할 경우 합성 목재의 충격강도, 인장 강도, 탄력성 및 내수성이 향상되므로 변형되지 않고 오랜 기간 동안 사용할 수 있는 효과를 가진다.In the step (S4), it is preferable to put the wood powder, the crushed reeds and the synthetic resin into a blender at a temperature of 70 ℃ to 80 ℃. By combining the wood powder, pulverized reeds and synthetic resin is stronger bond strength when producing synthetic wood has the effect that can be used for a long time without deformation because the impact strength, tensile strength, elasticity and water resistance of the synthetic wood is improved.
상기 단계(S4)에서, 상기 목분은 합성 목재 조성물의 총 중량대비 30 중량% 내지 40 중량%인 것이 바람직하고, 상기 분쇄한 갈대는 합성 목재 조성물의 총 중량대비 20 중량% 내지 30 중량%인 것이 바람직하며, 상기 합성수지는 합성 목재 조성물의 총 중량대비 5 중량% 내지 10 중량%인 것이 바람직하다. In the step (S4), the wood powder is preferably 30% to 40% by weight relative to the total weight of the synthetic wood composition, the crushed reed is 20% to 30% by weight relative to the total weight of the synthetic wood composition. Preferably, the synthetic resin is preferably 5 to 10% by weight relative to the total weight of the synthetic wood composition.
상기 목분이 합성 목재 조성물의 총 중량대비 30 중량% 이하이면 목재의 재질감이 저하되고, 40 중량% 이상이면 합성 목재 제조과정에서 압출 성형시 압출기의 스크루(screw)가 부하를 받아 마모되는 문제점이 발생할 수 있다.If the wood powder is less than 30% by weight relative to the total weight of the synthetic wood composition, the texture of the wood is lowered, if more than 40% by weight, the screw (extruder) of the extruder during the extrusion molding during the synthetic wood manufacturing process may cause a problem of wear Can be.
상기 분쇄한 갈대가 합성 목재 조성물의 총 중량대비 20 중량% 이하이면 합성 목재의 탄력성 및 내구성이 저하되는 문제점이 발생할 수 있다.If the pulverized reed is less than 20% by weight relative to the total weight of the synthetic wood composition, the elasticity and durability of the synthetic wood may decrease.
상기 합성수지가 합성 목재 조성물의 총 중량대비 5 중량% 이하이면 목분 및 분쇄한 갈대 입자와의 결합력이 저하되어 합성 목재 제조시 강도가 낮아지고, 10 중량% 이상이면 목재의 재질감이 저하되는 문제점이 발생할 수 있다.When the synthetic resin is less than 5% by weight relative to the total weight of the synthetic wood composition, the bonding strength between the wood powder and the crushed reed particles is lowered, and the strength of the synthetic wood is lowered. When the synthetic resin is more than 10% by weight, the texture of the wood may be deteriorated. Can be.
상기 단계(S4)를 수행한 후에, 상기 예비 합성 목재 조성물에 가공조제, UV 흡수제, 미네랄 충전제 및 착색제로 이루어진 군으로부터 선택된 어느 하나 이상을 첨가하여 합성 목재 조성물을 형성한다(S5).After performing the step (S4), at least one selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to the pre-synthetic wood composition to form a synthetic wood composition (S5).
상기 가공조제는 합성 목재 제조시 소량을 첨가하여 가공성 및 물성을 향상시킬 수 있는 첨가제로서 결합제, 윤활제, 항산화제, 난연제 및 열안정제로 이루어진 군으로부터 선택된 어느 하나 이상인 것이나 이에 한정되지 않는다. The processing aid is not limited to any one or more selected from the group consisting of a binder, a lubricant, an antioxidant, a flame retardant, and a heat stabilizer as an additive capable of improving the processability and physical properties by adding a small amount in the production of synthetic wood.
상기 결합제는 목분 및 분쇄한 갈대와 합성수지와의 결합력을 개선하기 위해 사용하는 물질로서, 탄력성과 점착성을 부여하여 합성 목재의 강도를 증가하는 역할을 한다. 상기 결합제는 폴리프로필렌 및 폴리에틸렌과 말레산무수물(Maleic Anhydride)이 화학적으로 결합한 물질을 사용할 수 있으나 이에 한정되지 않는다.The binder is a material used to improve the bonding strength between wood flour and crushed reeds and synthetic resin, and serves to increase the strength of the synthetic wood by giving elasticity and adhesion. The binder may be a material in which polypropylene and polyethylene and maleic anhydride are chemically bonded, but is not limited thereto.
상기 윤활제는 중합체를 가열 성형할 때에 그 유동성을 개선하여 가공을 쉽게 하기 위하여 사용하는 물질로서, 목분, 분쇄한 갈대 및 합성수지의 분산성을 높여 합성 목재의 표면 성질을 개선하는 역할을 한다. 상기 윤활제는 스테아린산(Stearic Acid), 폴리에틸렌 왁스 및 파라핀 왁스를 사용할 수 있으나 이에 한정되지 않는다.The lubricant is used to improve the fluidity of the polymer when heat-molding to facilitate processing, and serves to improve the surface properties of the synthetic wood by increasing the dispersibility of wood flour, crushed reeds and synthetic resin. The lubricant may include, but is not limited to, stearic acid, polyethylene wax, and paraffin wax.
상기 항산화제는 합성 목재에 공기로부터 공급되는 산소의 접근을 막아 기계적 성질이 저하되거나 변색되는 것을 방지하기 위해 사용하는 물질로서, 인산염(Phosphate) 계통의 산화방지제 및 칼슘 스테아린산염(Calcium Stearate)을 사용할 수 있으나 이에 한정되지 않는다.The antioxidant is a material used to prevent the deterioration or discoloration of mechanical properties by preventing the access of oxygen supplied from the air to the synthetic wood, phosphate-based antioxidants and calcium stearate (Calcium Stearate) But it is not limited thereto.
상기 난연제는 연소하기 쉬운 합성수지의 연소를 억제하고 합성 목재 제조시 내연성을 개선하기 위해 사용하는 물질로서, 인산트리크레질(Tricresyl Phosphate), 염소화 파라핀(Chlorinated Paraffin) 및 산화안티모니(antimony oxide), 암모늄포스페이트(Ammonium Phosphate) 및 붕산 등의 무기물을 사용할 수 있으나 이에 한정되지 않는다.The flame retardant is a material used to suppress the combustion of synthetic resins that are easy to burn and to improve the flame resistance in the production of synthetic wood, including tricresyl phosphate, chlorinated paraffin and antimony oxide, Inorganic substances such as ammonium phosphate and boric acid may be used, but are not limited thereto.
상기 열안정제는 합성 목재의 제조과정에서 열에 의한 분해를 최소화하기 위해 사용하는 물질로서, 가공시 안료의 본래의 색을 유지하고 합성수지의 윤활성을 개선하는 역할을 한다. 상기 열안정제는 에폭시화유(Expoxidized Soy Bean Oil) 및 에폭시화 아마인유(Epoxidized Linseed Oil) 등의 에폭시화 식물유를 사용할 수 있으나 이에 한정되지 않는다.The heat stabilizer is a material used to minimize decomposition by heat in the manufacturing process of synthetic wood, and serves to maintain the original color of the pigment during processing and improve the lubricity of the synthetic resin. The heat stabilizer may be an epoxidized vegetable oil such as epoxidized Soy Bean Oil and epoxidized Linseed Oil, but is not limited thereto.
상기 UV 흡수제는 태양광선으로부터 자외선을 차단 및 흡수하여 합성 목재의 기계적 성질이나 색이 변하는 것을 방지하기 위해 사용하는 물질로서, 벤조페논계(Benzophenone), 벤조트리아졸계(Benzotriazole), 살리실산계(Salicylic Acid) 및 아크릴로나이트릴계(Acrylonitrile)를 사용할 수 있으나 이에 한정되지 않는다.The UV absorber is a material used to block and absorb ultraviolet rays from the sun to prevent the mechanical properties or color of the synthetic wood from changing, benzophenone, benzotriazole, salicylic acid ) And acrylonitrile may be used, but is not limited thereto.
상기 미네랄 충전제(Mineral Fillers)는 충격, 열 및 하중에 의한 변형을 방지하기 위해 사용하는 물질로서, 합성 목재의 윤활성 및 가공성을 개선하고 목분 및 갈대분에 함유된 수분을 흡수하는 역할을 한다. 상기 미네랄 충전제는 탄산칼슘, 활석 및 운모를 사용할 수 있으나 이에 한정되지 않는다.The mineral fillers (Mineral Fillers) is a material used to prevent deformation due to impact, heat and load, and serves to improve the lubricity and processability of the synthetic wood and to absorb the moisture contained in the wood and reed flour. The mineral filler may be calcium carbonate, talc and mica, but is not limited thereto.
상기 단계(S5)에서, 상기 가공조제, UV 흡수제 및 미네랄 충전제는 합성 목재 조성물의 총 중량대비 5 중량% 내지 15 중량%인 것이 바람직하다. 상기 가공조제, UV 흡수제 및 미네랄 충전제가 합성 목재 조성물의 총 중량대비 5 중량% 이하이면 합성 목재의 기계적인 강도 및 열 또는 빛에 대한 안정성이 저하되는 문제점이 발생할 수 있다.In the step (S5), the processing aid, UV absorber and mineral filler is preferably 5% to 15% by weight relative to the total weight of the synthetic wood composition. If the processing aid, UV absorber and mineral filler is less than 5% by weight relative to the total weight of the synthetic wood composition may cause a problem that the mechanical strength of the synthetic wood and the stability to heat or light is lowered.
상기 착색제(Stain)는 합성 목재의 색의 안정성을 부여하고 변색을 방지하기 위해 사용하는 물질로서, 천연목재의 질감을 나타낼 수 있고 자외선에 대한 저항성을 향상시킬 수 있는 역할을 한다. 상기 착색제는 유성 착색제(Oil-Stain), 알코올성 착색제, 수성 착색제, NGR(Non Grain Raisine) 스테인, 안료 착색제 및 유니스테인(Unistain)을 사용할 수 있으나 이에 한정되지 않는다. The colorant (Stain) is a material used to impart color stability of the synthetic wood and to prevent discoloration, and may exhibit a texture of natural wood and may improve resistance to ultraviolet rays. The colorant may be an oil colorant (Oil-Stain), an alcoholic colorant, an aqueous colorant, NGR (Non Grain Raisine) stain, a pigment colorant, and Unistein, but are not limited thereto.
상기 안료 착색제는 예비 합성 목재 조성물에 첨가함으로써 외부로부터 합성 목재를 보호하고 색채나 입체감을 주어 목재 고유의 질감을 향상시킬 수 있는 역할을 한다. 또한, 염색된 목분 및 분쇄한 갈대의 얼룩 및 착색이 불완전한 부분을 조절하는 기능을 함으로써 목분 및 분쇄한 갈대에 염색된 상태를 더 부드럽게 재조정하는 역할을 한다. 본 발명에서는 내광성, 내열성 및 내용제성이 강한 무기염료를 사용하고, 보다 바람직하게는 체질안료를 사용할 수 있다.The pigment colorant serves to protect the synthetic wood from the outside by adding to the pre-synthetic wood composition and to give a color or three-dimensional impression to improve the texture of the wood. In addition, the staining and coloring of the dyed wood flour and crushed reeds serves to control the incomplete portion, thereby smoothly reconditioning the dyeing state of the wood flour and crushed reeds. In the present invention, inorganic dyes having strong light resistance, heat resistance and solvent resistance are used, and more preferably, extender pigments can be used.
상기 체질안료(Extender Filler)는 안료, 도료의 제조에 있어서 여러 목적으로 배합되어 사용되는 은폐력이 낮은 투명한 안료로서, 도료, 인쇄 잉크, 플라스틱, 고무, 종이, 접착제 등에 배합하여 물질의 광학적 성질, 기계적 성질, 유동성을 개선하는 역할을 한다. 상기 체질안료는 백아, 석고, 카올린(Kaolin) 등 천연 체질안료를 사용하는 것이 바람직하나 이에 한정되지 않는다. The extender pigment (Extender Filler) is a transparent pigment with a low hiding power used in various formulations in the production of pigments, paints, optical properties of the material by mixing with paints, printing inks, plastics, rubber, paper, adhesives, etc. It plays a role to improve the property and fluidity. The extender pigment is preferably a natural extender pigment such as white germ, gypsum, kaolin, but is not limited thereto.
상기 유니스테인(Unistain)은 유기용제에 유기 금속 복합염료를 용해시켜 제조한 착색제로서, 내화학성, 내광성, 내후성, 착색성, 건조성 및 작업성이 양호하고 목질을 부풀지 않게 하는 역할을 한다. 또한, 염색 단계(S2)에서 염색된 목분 및 분쇄한 갈대에 얼룩이 생길 경우, 이를 보완하여 목분 및 분쇄한 갈대의 색을 균일하게 나타낼 수 있으며, 상기 유니스테인은 건조 단계(S3)에서도 첨가하여 사용할 수 있다.Unistein (Unistain) is a colorant prepared by dissolving an organometallic composite dye in an organic solvent, chemical resistance, light resistance, weather resistance, colorability, dryness and workability is good and does not swell wood. In addition, when staining occurs in the stained wood powder and crushed reeds (S2), the color of the wood powder and crushed reeds can be uniformly represented by complementing, and the unit stain is used in addition to the drying step (S3) Can be.
상기 단계(S5)에서, 상기 착색제는 합성 목재 조성물의 총 중량대비 20 중량% 내지 30 중량%인 것이 바람직하다. 상기 착색제가 합성 목재 조성물의 총 중량대비 20 중량% 이하이면 합성 목재의 색이 제대로 발현되지 못하고, 30 중량% 이상이면 착색제의 분산성이 저하되어 색의 선명도가 떨어지고 합성 목재의 저항성 및 내구성이 저하되는 문제점이 발생할 수 있다.In the step (S5), the colorant is preferably 20 to 30% by weight relative to the total weight of the synthetic wood composition. If the colorant is 20% by weight or less relative to the total weight of the synthetic wood composition, the color of the synthetic wood is not properly expressed, and if the colorant is 30% by weight or more, the dispersibility of the colorant is lowered, the vividness of color is lowered, and the resistance and durability of the synthetic wood are lowered. Problems may arise.
상기 단계(S5)는 교반혼합기를 이용하여 예비 합성 목재 조성물에 가공조제, UV 흡수제, 미네랄 충전제 및 착색제로 이루어진 군으로부터 선택된 어느 하나 이상을 첨가하여 충분히 혼합시킬 수 있으며, 60 ℃ 내지 70 ℃의 온도에서 수행할 수 있으나 이에 한정되지 않는다.The step (S5) can be sufficiently mixed by adding any one or more selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to the pre-synthetic wood composition using a stirred mixer, a temperature of 60 ℃ to 70 ℃ It may be carried out in but not limited to.
상기 단계(S5)를 수행한 다음에는 상기 합성 목재 조성물을 압출 성형한다(S6).After performing the step (S5), the synthetic wood composition is extrusion molded (S6).
상기 단계(S6)는 압출기를 사용하여 합성 목재 조성물을 160 ℃ 내지 200 ℃의 온도에서 20 kgf/㎠ 내지 35 kgf/㎠의 압력으로 압출하는 것으로, 젤 형태의 합성 목재 조성물을 얻을 수 있다. 상기 합성 목재 조성물을 냉각 및 절단하여 원하는 용도의 건축재로 이용할 수 있다. 상기 합성 목재 조성물을 생산하는 방법은 압출성형방법에만 한정되지 않고 사출성형 등 합성 목재 조성물을 얻을 수 있는 방법은 모두 사용될 수 있다.The step (S6) is to extrude the synthetic wood composition using a extruder at a pressure of 20 kgf / cm 2 to 35 kgf / cm 2 at a temperature of 160 ℃ to 200 ℃, to obtain a synthetic wood composition in the form of a gel. The synthetic wood composition may be cooled and cut to be used as a building material for a desired use. The method for producing the synthetic wood composition is not limited to the extrusion molding method, any method for obtaining a synthetic wood composition such as injection molding can be used.
또한, 본 발명은 상기 예비 합성 목재 조성물에 가공조제, UV 흡수제, 미네랄 충전제 및 착색제로 이루어진 군으로부터 선택된 어느 하나 이상을 첨가하여 합성 목재 조성물을 형성하는 단계(S5) 후에, 상기 합성 목재 조성물에 커피 분말을 첨가하는 단계(S16)를 수행한 다음, 상기 커피 분말이 첨가된 합성 목재 조성물을 압출 성형하는 단계(S17)를 수행하는 무공해 갈대 합성 목재의 제조방법일 수 있다. In addition, the present invention after adding any one or more selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to the pre-synthetic wood composition to form a synthetic wood composition (S5), coffee to the synthetic wood composition After the step of adding the powder (S16), it may be a method for producing a pollution-free reed synthetic wood to perform the step (S17) of extruding the synthetic wood composition to which the coffee powder is added.
이하, 도 2를 참조하여 본 발명의 다른 실시예에 따른 무공해 갈대 합성 목재의 제조방법을 상세하게 설명하기로 한다.Hereinafter, with reference to Figure 2 will be described in detail a method for producing a pollution-free reed synthetic wood according to another embodiment of the present invention.
도 2는 본 발명의 다른 실시예에 따른 무공해 갈대 합성 목재의 제조방법을 설명하기 위한 플로우 차트이다.Figure 2 is a flow chart for explaining a method for producing a pollution-free reed synthetic wood according to another embodiment of the present invention.
설명에 앞서, 본 발명의 다른 실시예인 커피 분말이 첨가된 무공해 갈대 합성 목재의 제조방법은 도 1의 일 실시예에 따른 제조방법과 비교하여 S1 내지 S5까지의 단계는 동일하며, 따라서 본 제조방법에서 그 구체적인 설명은 생략하며, 바로 상기 합성 목재 조성물에 커피 분말을 첨가하는 단계(S16)부터 설명하기로 한다.Prior to the description, the method of manufacturing a pollution-free reed synthetic wood to which coffee powder is added is another embodiment of the present invention compared with the manufacturing method according to the embodiment of Figure 1 S1 to S5 is the same, and thus the present production method In the detailed description thereof will be omitted, it will be described directly from the step (S16) of adding the coffee powder to the synthetic wood composition.
상기 커피 분말은 커피 원두를 추출하여 커피를 만든 후 남은 찌꺼기를 이용하는 것으로, 합성 목재의 표면에 착색되어 자연스러운 갈색 빛을 나타낼 수 있는 착색제의 역할을 한다. 또한, 상기 커피 분말을 사용함으로써 착색제의 사용량을 줄일 수 있어 비용을 절감할 수 있다. The coffee powder is to use the residue left after making coffee by extracting the coffee beans, it serves as a colorant that can be colored on the surface of the synthetic wood to give a natural brown light. In addition, by using the coffee powder can reduce the amount of colorant used can reduce the cost.
상기 단계(S16)에서, 상기 커피 분말은 합성 목재 조성물의 총 중량대비 5 중량% 내지 10 중량%인 것이 바람직하다. 상기 커피 분말이 합성 목재 조성물의 총 중량대비 5 중량% 이하이면 커피 분말의 색감 및 향이 제대로 나타나지 못하고, 10 중량% 이상이면 안료 착색제 및 유니스테인의 사용량이 줄어들어 염색이 불완전한 부분을 보완하지 못하여 얼룩이 나타나는 문제점이 발생할 수 있다.In the step (S16), the coffee powder is preferably 5% to 10% by weight relative to the total weight of the synthetic wood composition. If the coffee powder is less than 5% by weight relative to the total weight of the synthetic wood composition, the color and aroma of the coffee powder does not appear properly. If the coffee powder is more than 10% by weight, the amount of pigment colorant and unsteine is reduced, so that staining may not be compensated for incomplete dyeing. Problems may arise.
상기 단계(S16)는 커피 분말을 이용함으로써 커피 분말의 색이 합성 목재의 표면에 커피 분말의 색이 착색되어 안료에 의한 인위적인 커피 색감이 아닌 천연의 자연스러운 커피 색감 및 질감을 나타낼 수 있으며 커피의 은은한 향을 발현시킬 수 있다. In the step S16, the color of the coffee powder is colored on the surface of the synthetic wood by using the coffee powder, so that the natural color and texture of the coffee may be represented, rather than an artificial coffee color caused by the pigment. Aroma can be expressed.
상기 단계(S16)를 수행한 다음에는 상기 커피 분말이 첨가된 합성 목재 조성물을 압출 성형한다(S17).After performing the step (S16), the synthetic wood composition to which the coffee powder is added is extruded (S17).
상기 단계(S17)는 압출기를 사용하여 합성 목재 조성물을 160 ℃ 내지 200 ℃의 온도에서 20 kgf/㎠ 내지 35 kgf/㎠의 압력으로 압출하는 것으로, 젤 형태의 합성 목재 조성물을 얻을 수 있다. 상기 합성 목재 조성물을 냉각 및 절단하여 원하는 용도의 건축재로 이용할 수 있다. 상기 합성 목재 조성물을 생산하는 방법은 압출성형방법에만 한정되지 않고 사출성형 등 합성 목재 조성물을 얻을 수 있는 방법은 모두 사용될 수 있다.The step (S17) is to extrude the synthetic wood composition using a extruder at a pressure of 20 kgf / cm 2 to 35 kgf / cm 2 at a temperature of 160 ℃ to 200 ℃, to obtain a synthetic wood composition in the form of a gel. The synthetic wood composition may be cooled and cut to be used as a building material for a desired use. The method for producing the synthetic wood composition is not limited to the extrusion molding method, any method for obtaining a synthetic wood composition such as injection molding can be used.
부연 설명하면, 상기 단계(S17)는 일 실시예의 S6 단계와 비교하여 S16의 단계 이후에 진행되는 점에서만 차이가 있을 뿐, 온도 및 압력 등 압출 성형하는 전체적인 공정은 S6 단계와 동일하다.In other words, the step (S17) is different only in that it proceeds after the step of S16 compared to the step S6 of the embodiment, the overall process of extrusion molding such as temperature and pressure is the same as the step S6.
이하, 이하, 실시예를 통하여 본 발명을 더욱 상세히 설명하고자 한다. 이들 실시예는 오로지 본 발명을 보다 구체적으로 설명하기 위한 것으로, 본 발명의 요지에 따라 본 발명의 범위가 이들 실시예에 의해 제한되지 않는다는 것은 당업계에서 통상의 지식을 가진 자에 있어서 자명할 것이다.Hereinafter, the present invention will be described in more detail with reference to Examples. These examples are only for illustrating the present invention in more detail, it will be apparent to those skilled in the art that the scope of the present invention is not limited by these examples in accordance with the gist of the present invention. .
<실시예 1> 무공해 갈대 합성 목재 제조단계<Example 1> pollution-free reed synthetic wood manufacturing step
(1) 습도 제어기를 사용하여 습도를 3 % 내지 5 %로 유지시킨 후, 100 Mesh의 입자크기로 분쇄한 목분 35 중량% 및 갈대분 25 중량%를 용기에 넣고 60 ℃ 내지 70 ℃의 온도로 가열하여 포름알데히드를 제거한다.(1) After maintaining the humidity at 3% to 5% by using the humidity controller, put 35% by weight of the wood powder and 25% by weight of the crushed wood powder into a particle size of 100 Mesh into a container at a temperature of 60 ℃ to 70 ℃ Heat removes formaldehyde.
(2) 상기 포름알데히드를 제거한 목분 및 분쇄한 갈대에 염료를 첨가하고 적외선 광열등을 이용하여 40 ℃ 내지 50 ℃의 온도에서 목분 및 분쇄한 갈대 입자 자체를 염색한다.(2) A dye is added to the wood powder and the pulverized reed from which the formaldehyde has been removed, and the wood powder and the pulverized reed particles themselves are dyed at a temperature of 40 ° C. to 50 ° C. using an infrared light lamp.
(3) 상기 염색된 목분 및 분쇄한 갈대를 원적외선 온풍기를 이용하여 70 ℃ 내지 80 ℃의 온도에서 목분 및 분쇄한 갈대의 수분함량이 8 % 내지 12 %가 되도록 건조한다.(3) The dyed wood flour and pulverized reeds are dried using a far-infrared air blower at a temperature of 70 ° C. to 80 ° C. so that the water content of the wood flour and pulverized reeds becomes 8% to 12%.
(4) 상기 건조한 목분 및 분쇄한 갈대에 합성수지 8 중량%를 70 ℃ 내지 80 ℃의 온도 하에서 혼합하여 예비 합성 목재 조성물을 만든다.(4) 8% by weight of a synthetic resin is mixed with the dried wood powder and pulverized reed under a temperature of 70 ° C to 80 ° C to form a pre-synthetic wood composition.
(5) 상기 예비 합성 목재 조성물에 가공조제, UV 흡수제 및 미네랄 충전제 10 중량%를 첨가하고, 착색제 30 중량% 첨가하여 60 ℃의 온도에서 교반 혼합기를 이용하여 혼합하여 합성 목재 조성물을 만든다.(5) 10 wt% of the processing aid, the UV absorber and the mineral filler are added to the presynthetic wood composition, 30 wt% of the colorant is added, and mixed using a stirring mixer at a temperature of 60 ° C. to form a synthetic wood composition.
(6) 상기 합성 목재 조성물을 압출기를 이용하여 180 ℃의 온도에서 30 kgf/㎠ 의 압력으로 압출하여 합성 목재의 재료를 제조한다.(6) The synthetic wood composition is extruded using a extruder at a temperature of 180 ° C. at a pressure of 30 kgf / cm 2 to prepare a material of synthetic wood.
(7) 상기 합성 목재 재료를 냉각 및 절단하고 진공포장한다.(7) The synthetic wood material is cooled, cut and vacuum packed.
<실시예 2> 커피 분말이 첨가된 무공해 갈대 합성 목재 제조단계<Example 2> pollution-free reed synthetic wood manufacturing step to which coffee powder is added
(1) 습도 제어기를 사용하여 습도를 3 % 내지 5 %로 유지시킨 후, 100 Mesh의 입자크기로 분쇄한 목분 35 중량% 및 갈대분 25 중량%를 용기에 넣고 60 ℃ 내지 70 ℃의 온도로 가열하여 포름알데히드를 제거한다.(1) After maintaining the humidity at 3% to 5% by using the humidity controller, put 35% by weight of the wood powder and 25% by weight of the crushed wood powder into a particle size of 100 Mesh into a container at a temperature of 60 ℃ to 70 ℃ Heat removes formaldehyde.
(2) 상기 포름알데히드를 제거한 목분 및 분쇄한 갈대에 염료를 첨가하고 적외선 광열등을 이용하여 40 ℃ 내지 50 ℃의 온도에서 목분 및 분쇄한 갈대 입자 자체를 염색한다.(2) A dye is added to the wood powder and the pulverized reed from which the formaldehyde has been removed, and the wood powder and the pulverized reed particles themselves are dyed at a temperature of 40 ° C. to 50 ° C. using an infrared light lamp.
(3) 상기 염색된 목분 및 분쇄한 갈대를 원적외선 온풍기를 이용하여 70 ℃ 내지 80 ℃의 온도에서 목분 및 분쇄한 갈대의 수분함량이 8 % 내지 12 %가 되도록 건조한다.(3) The dyed wood flour and pulverized reeds are dried using a far-infrared air blower at a temperature of 70 ° C. to 80 ° C. so that the water content of the wood flour and pulverized reeds becomes 8% to 12%.
(4) 상기 건조한 목분 및 분쇄한 갈대에 합성수지 8 중량%를 70 ℃ 내지 80 ℃의 온도 하에서 혼합하여 예비 합성 목재 조성물을 만든다.(4) 8% by weight of a synthetic resin is mixed with the dried wood powder and pulverized reed under a temperature of 70 ° C to 80 ° C to form a pre-synthetic wood composition.
(5) 상기 예비 합성 목재 조성물에 가공조제, UV 흡수제 및 미네랄 충전제 10 중량%를 첨가하고, 착색제 20 중량% 및 커피 분말 10 중량%를 첨가하여 60 ℃의 온도에서 교반 혼합기를 이용하여 혼합하여 합성 목재 조성물을 만든다.(5) Add 10% by weight of the processing aid, the UV absorber and the mineral filler to the pre-synthetic wood composition, add 20% by weight of the colorant and 10% by weight of the coffee powder, and mix by mixing using a stirring mixer at a temperature of 60 ° C. Make a wood composition.
(6) 상기 합성 목재 조성물을 압출기를 이용하여 180 ℃의 온도에서 30 kgf/㎠ 의 압력으로 압출하여 합성 목재의 재료를 제조한다.(6) The synthetic wood composition is extruded using a extruder at a temperature of 180 ° C. at a pressure of 30 kgf / cm 2 to prepare a material of synthetic wood.
(7) 상기 합성 목재 재료를 냉각 및 절단하고 진공포장한다.(7) The synthetic wood material is cooled, cut and vacuum packed.
상기 <실시예 1> 및 <실시예 2>의 단계 (1)에서 예비 합성 목재 조성물을 혼합하기 전에 포름알데히드를 제거함으로써, 합성 목재에서 방출되는 포름알데히드의 농도를 0.08 ppm 내지 0.1 ppm으로 줄일 수 있다. 상기 농도는 WHO 및 일본실내환경 기준치를 나타내는 것으로 포름알데히드의 농도별로 인체에 미치는 영향은 다음 [표 1]과 같다.By removing formaldehyde before mixing the presynthetic wood composition in step (1) of <Example 1> and <Example 2>, the concentration of formaldehyde released from the synthetic wood can be reduced to 0.08 ppm to 0.1 ppm. have. The concentration indicates the WHO and Japanese indoor environmental standards, and the effect on the human body by the concentration of formaldehyde is shown in Table 1 below.
표 1
농도 (ppm) 발생하는 병상과 기준치
0.01 포름알데히드 측정기의 측정 하한치
0.04 민감한 아이들은 아토피(Atopy, 선천성 과민증)성 피부염이 생김, 신경조직의 자극이 시작됨
0.05 ~ 1.0 냄새를 느낌. 캐나다, 캘리포니아 실내기준치
0.08 WHO기준. 일본 실내환경 기준(후생성지침)
0.1 독일에서는 이 이상의 농도가 방출되는 제품의 판매금지
0.2 눈에서의 자극이 시작됨
0.25 ~ 0.33 호흡기 장해가 시작됨
0.5 목의 자극이 시작되는 최저치. 산업위생학회 허용농도(공장 등의 최고치)
1.0 5년간 생활하면 1만 명 중 14 명이 암이 발생함
2.0 ~ 3.0 눈을 찌르는 듯한 고통이 생김
4.0 눈물이 나옴
10.0 ~ 20.0 격렬하게 눈물이 나옴. 정상적인 호흡이 곤란함
30.0 ~ 50.0 5 내지 10 분에 급성중독을 일으킴. 독성 폐기종으로 사망할 수도 있음포름알데히드 측정기의 측정 상한치(50.0 ppm)
Table 1
Concentration (ppm) Occurring beds and reference values
0.01 Lower limit of measurement of formaldehyde measuring instrument
0.04 Sensitive children develop atopic dermatitis, nervous system irritation begins
0.05 to 1.0 Feeling the smell. Canada, California Indoor Standard
0.08 WHO standard. Japanese Indoor Environment Standards (Welfare Guidelines)
0.1 Prohibit the sale of products with higher concentrations in Germany
0.2 Irritation in the eye begins
0.25 to 0.33 Respiratory tract initiation
0.5 Lowest point at which throat irritation begins. Industrial Hygiene Society Allowable Concentration (Maximum of Factory, etc.)
1.0 After five years of life, 14 out of 10,000 people will develop cancer
2.0 to 3.0 I have a pain in my eyes.
4.0 Tears come out
10.0-20.0 Violently tears come out. Difficulty breathing
30.0 to 50.0 Causes acute poisoning in 5 to 10 minutes. Possibility to die of toxic emphysema Upper limit of measurement of formaldehyde meter (50.0 ppm)
상기 [표 1]에서 보는 바와 같이, 0.08 ppm 내지 0.1 ppm은 WHO의 기준치로서 인체에 무해한 농도이므로, 본 발명의 무공해 갈대 합성 목재는 친환경적이며 인체에 유해한 물질을 최소화할 수 있는 합성 목재인 것을 알 수 있다.As shown in Table 1, since 0.08 ppm to 0.1 ppm is a concentration of harmless to the human body as a reference value of the WHO, the pollution-free reed synthetic wood of the present invention is an environmentally friendly and can be seen that the synthetic wood that can minimize the harmful substances to the human body Can be.

Claims (10)

  1. (a) 목분 및 분쇄한 갈대에서 포름알데히드를 제거하는 단계;(a) removing formaldehyde from wood flour and ground reeds;
    (b) 상기 포름알데히드를 제거한 목분 및 분쇄한 갈대에 염료를 첨가하여 염색하는 단계;(b) dyeing by adding dye to the wood powder from which the formaldehyde has been removed and the pulverized reed;
    (c) 상기 염색된 목분 및 분쇄한 갈대를 건조하는 단계;(c) drying the dyed wood flour and ground reeds;
    (d) 상기 건조한 목분 및 분쇄한 갈대에 합성수지를 혼합하여 예비 합성 목재 조성물을 형성하는 단계;(d) mixing a synthetic resin with the dried wood powder and ground reeds to form a pre-synthetic wood composition;
    (e) 상기 예비 합성 목재 조성물에 가공조제, UV 흡수제, 미네랄 충전제 및 착색제로 이루어진 군으로부터 선택된 어느 하나 이상을 첨가하여 합성 목재 조성물을 형성하는 단계; 및(e) adding at least one selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to form the synthetic wood composition; And
    (f) 상기 합성 목재 조성물을 압출 성형하는 단계를 포함하는 무공해 갈대 합성 목재의 제조방법.(f) a method for producing a pollution-free reed synthetic wood comprising the step of extruding the synthetic wood composition.
  2. 제1항에 있어서,The method of claim 1,
    상기 단계 (a)는 50 ℃ 내지 80 ℃에서 수행되는 것을 특징으로 하는 무공해 갈대 합성 목재의 제조방법.Step (a) is a method for producing a pollution-free reed synthetic wood, characterized in that carried out at 50 ℃ to 80 ℃.
  3. 제1항에 있어서,The method of claim 1,
    상기 단계 (b)는 30 ℃ 내지 60 ℃에서 수행되는 것을 특징으로 하는 무공해 갈대 합성 목재의 제조방법.Step (b) is a method for producing a pollution-free reed synthetic wood, characterized in that carried out at 30 ℃ to 60 ℃.
  4. 제1항에 있어서, The method of claim 1,
    상기 목분은 합성 목재 조성물의 총 중량대비 30 중량% 내지 40 중량%;The wood flour is 30 to 40% by weight relative to the total weight of the synthetic wood composition;
    상기 분쇄한 갈대는 합성 목재 조성물의 총 중량대비 20 중량% 내지 30 중량%;The pulverized reed is 20 to 30% by weight relative to the total weight of the synthetic wood composition;
    상기 합성수지는 합성 목재 조성물의 총 중량대비 5 중량% 내지 10 중량%;The synthetic resin is 5 to 10% by weight based on the total weight of the synthetic wood composition;
    상기 가공조제, UV 흡수제 및 미네랄 충전제는 합성 목재 조성물의 총 중량대비 5 중량% 내지 15 중량%; 및The processing aids, UV absorbers and mineral fillers are 5% to 15% by weight relative to the total weight of the synthetic wood composition; And
    상기 착색제는 합성 목재 조성물의 총 중량대비 20 중량% 내지 30 중량%인 것을 특징으로 하는 무공해 갈대 합성 목재의 제조방법.The colorant is a method for producing a pollution-free reed synthetic wood, characterized in that 20 to 30% by weight relative to the total weight of the synthetic wood composition.
  5. 제1항에 있어서,The method of claim 1,
    상기 단계 (c)는 예비 합성 목재 조성물의 수분 함량이 5 % 내지 15 %가 되도록 건조하는 것을 특징으로 하는 무공해 갈대 합성 목재의 제조방법.The step (c) is a method for producing a pollution-free reed synthetic wood, characterized in that the drying so that the moisture content of the pre-synthetic wood composition is 5% to 15%.
  6. 제1항에 있어서,The method of claim 1,
    상기 단계 (e)에서 가공조제는 결합제, 윤활제, 항산화제, 난연제 및 열안정제로 이루어진 군으로부터 선택된 어느 하나 이상인 것을 특징으로 하는 무공해 갈대 합성 목재의 제조방법.The processing aid in step (e) is a method for producing a pollution-free reed synthetic wood, characterized in that any one or more selected from the group consisting of binders, lubricants, antioxidants, flame retardants and heat stabilizers.
  7. 제1항 내지 제6항 중 어느 하나의 항에 따른 방법으로 제조된 무공해 갈대 합성 목재.A pollution-free reed synthetic wood prepared by the method according to any one of claims 1 to 6.
  8. (a) 목분 및 분쇄한 갈대에서 포름알데히드를 제거하는 단계;(a) removing formaldehyde from wood flour and ground reeds;
    (b) 상기 포름알데히드를 제거한 목분 및 분쇄한 갈대에 염료를 첨가하여 염색하는 단계;(b) dyeing by adding dye to the wood powder from which the formaldehyde has been removed and the pulverized reed;
    (c) 상기 염색된 목분 및 분쇄한 갈대를 건조하는 단계;(c) drying the dyed wood flour and ground reeds;
    (d) 상기 건조한 목분 및 분쇄한 갈대에 합성수지를 혼합하여 예비 합성 목재 조성물을 형성하는 단계;(d) mixing a synthetic resin with the dried wood powder and ground reeds to form a pre-synthetic wood composition;
    (e) 상기 예비 합성 목재 조성물에 가공조제, UV 흡수제, 미네랄 충전제 및 착색제로 이루어진 군으로부터 선택된 어느 하나 이상을 첨가하여 합성 목재 조성물을 형성하는 단계; (e) adding at least one selected from the group consisting of processing aids, UV absorbers, mineral fillers and colorants to form the synthetic wood composition;
    (f) 상기 합성 목재 조성물에 커피 분말을 첨가하는 단계; 및(f) adding coffee powder to the synthetic wood composition; And
    (g) 상기 커피 분말이 첨가된 합성 목재 조성물을 압출 성형하는 단계를 포함하는 무공해 갈대 합성 목재의 제조방법.(g) a method for producing a pollution-free reed synthetic wood comprising the step of extruding the synthetic wood composition to which the coffee powder is added.
  9. 제8항에 있어서, The method of claim 8,
    상기 목분은 합성 목재 조성물의 총 중량대비 30 중량% 내지 40 중량%;The wood flour is 30 to 40% by weight relative to the total weight of the synthetic wood composition;
    상기 분쇄한 갈대는 합성 목재 조성물의 총 중량대비 20 중량% 내지 30 중량%;The pulverized reed is 20 to 30% by weight relative to the total weight of the synthetic wood composition;
    상기 합성수지는 합성 목재 조성물의 총 중량대비 5 중량% 내지 10 중량%;The synthetic resin is 5 to 10% by weight based on the total weight of the synthetic wood composition;
    상기 가공조제, UV 흡수제 및 미네랄 충전제는 합성 목재 조성물의 총 중량대비 5 중량% 내지 15 중량%;The processing aids, UV absorbers and mineral fillers are 5% to 15% by weight relative to the total weight of the synthetic wood composition;
    상기 착색제는 합성 목재 조성물의 총 중량대비 15 중량% 내지 25 중량%; 및The colorant 15% to 25% by weight relative to the total weight of the synthetic wood composition; And
    상기 커피 분말은 합성 목재 조성물의 총 중량대비 5 중량% 내지 10 중량%인 것을 특징으로 하는 무공해 갈대 합성 목재의 제조방법.The coffee powder is a method for producing a pollution-free reed synthetic wood, characterized in that 5% to 10% by weight relative to the total weight of the synthetic wood composition.
  10. 제8항 또는 제9항에 따른 방법으로 제조된 무공해 갈대 합성 목재.A pollution-free reed synthetic wood prepared by the process according to claim 8.
PCT/KR2013/001598 2012-02-27 2013-02-27 Chemical-free synthetic wood using reed and method for manufacturing same WO2013129847A1 (en)

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