CN105670408A - PVC wood-plastic coating layer of military-civil camouflage fabric - Google Patents

PVC wood-plastic coating layer of military-civil camouflage fabric Download PDF

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Publication number
CN105670408A
CN105670408A CN201610170874.0A CN201610170874A CN105670408A CN 105670408 A CN105670408 A CN 105670408A CN 201610170874 A CN201610170874 A CN 201610170874A CN 105670408 A CN105670408 A CN 105670408A
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China
Prior art keywords
coating layer
parts
plastic coating
pvc wood
wood plastic
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CN201610170874.0A
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Chinese (zh)
Inventor
李璐
曹春叶
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Jiangsu Fan Xin Novel Material Science And Technology Ltd
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Jiangsu Fan Xin Novel Material Science And Technology Ltd
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Priority to CN201610170874.0A priority Critical patent/CN105670408A/en
Publication of CN105670408A publication Critical patent/CN105670408A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0036—Polyester fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0065—Organic pigments, e.g. dyes, brighteners
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0068—Polymeric granules, particles or powder, e.g. core-shell particles, microcapsules
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/10—Transparent films; Clear coatings; Transparent materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/08—Properties of the materials having optical properties
    • D06N2209/0861—Transparent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1678—Resistive to light or to UV

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a PVC wood-plastic coating layer of military-civil camouflage fabric. The PVC wood-plastic coating layer comprises, by weight, 60-80 parts of PVC paste resin, 40-45 parts of transparent filler, 10-20 parts of coloring plant fiber, 4-5 parts of silane coupling agent, 0.5-1 part of halite, 1-1.5 parts of octadecanamide, 0.5-1 part of oxidized polyethlene wax, 2-3 parts of paraffin, 0.5-1.5 parts of dioctyl phthalate, 1-1.5 parts of ultraviolet stabilizer, 0.1-0.5 part of antioxidant, 0.5-1 part of zinc borate and 2-4 parts of magnesium hydroxide. The PVC wood-plastic coating layer produced by combining the transparent filler and the coloring plant fiber has the advantages that the original mechanical and chemical performance of the PVC wood-plastic coating layer is guaranteed while the transparency and glossiness of the PVC wood-plastic coating layer are increased; natural pigment is used, no odorous gas is generated after long-term use, the color of the decomposed pigment does not change too much, and the color diversity of the camouflage fabric is increased.

Description

The PVC wood plastic coating layer of dual-use colour camoufague cloth
Technical field
The present invention relates to the raw materials for production field of special cloth, particularly relate to the PVC wood plastic coating layer of a kind of dual-use colour camoufague cloth.
Background technology
Painting work refers to coat on paper, cloth, plastics film by pasty state polymkeric substance, molten polymer or molten polymer, the method of final obtained matrix material, obtain paper, cloth and plastics after coating and possessed multiple complex function, greatly strengthen the performance of material itself.
Colour camoufague cloth is professional in building tent in material, paulin room, the high performance material of the fluffy machine military equipment overcover of truck, traditional colour camoufague cloth is due to the restriction of its material itself, itself is at antiultraviolet, there is certain defect in anti-aging and water resistance, released one afterwards on the market to be processed by colour camoufague cloth by PVC coating, to strengthen other performances of colour camoufague cloth, but due to the restriction of PVC coatings applications formula own or raw material, certain change can be there is in the color of the colour camoufague cloth after being coated with, affect the screening performance of itself, and owing to coating layer own containing some technical grade colouring materials, these raw materials are under intense UV rays is irradiated, certain change can be there is in the color and luster of itself, even can produce peculiar smell, and part colour camoufague cloth is after long-time work, the tinting material of its coating inside itself can change, and causes the color of coating layer itself to change, and these all can affect the normal use of colour camoufague cloth.
Summary of the invention
For above-mentioned Problems existing, the object of the invention is that providing a kind of keeps colour camoufague cloth primary colors, and over-all properties is outstanding, it may also be useful to the life-span is long, the PVC wood plastic coating layer of the dual-use colour camoufague cloth of hygienic environment-protecting.
In order to achieve the above object, the technical solution used in the present invention is as follows: the PVC wood plastic coating layer of a kind of dual-use colour camoufague cloth, in described PVC wood plastic coating layer, the weight part number of each component is as follows: PVC paste resin 60～80 parts, transparent filler 40～45 parts, 10～20 parts, painted vegetable fibre, silane coupling agent 4～5 parts, halite 0.5～1 part, stearic amide 1～1.5 part, oxidized polyethlene wax 0.5～1 part, 2～3 parts, paraffin, dioctyl phthalate (DOP) 0.5～1.5 part, ultra-violet stabilizer 1～1.5 part, 0.1～0.5 part, oxidation inhibitor and zinc borate 0.5～1 part, magnesium hydroxide 2～4 parts.
Transparent filler of the present invention is glass powder, quartz sand and talcum powder three's mixture, wherein glass powder, quartz sand and talcum powder: weight ratio is 2:4～8:1; The amount ratio of transparent filler directly has influence on transparency and the glossiness of final PVC wood plastic coating layer, the true qualities of cloth in convenient display coating layer, wherein polymolecularity is carried in the main effect of glass powder, the main effect of talcum powder is the mobility improving transparent filler, both all have certain colour developing, therefore both consumptions are too much unsuitable, cross and the transparency of the finished product can be caused at most to decline.
Painted vegetable fibre of the present invention is tinting material and the mix products of bamboo fibers powder, and wherein the weight ratio of bamboo fibers powder and tinting material is 10:0.2～0.7; Tinting material of the present invention is the mixture of chlorophyll and xenthophylls, and wherein the blending ratio of chlorophyll and xenthophylls is 1～10:1～10; It is painted that painted vegetable fibre is mainly used in PVC coating, owing to this product application is in camouflage color cloth, therefore carries out co-pigmentation by bamboo fibers, chlorophyll and xenthophylls, ensures the consistence of PVC coating and camouflage color cloth color and luster; And chlorophyll decomposes after coloring treatment, itself and xenthophylls interact, and finally make the color and luster of PVC wood plastic coating layer itself change so that the color of product colour camoufague cloth changes, hidden effective.
Ultra-violet stabilizer of the present invention is the one in Ultraviolet Absorber UV-P, HMPA and UV light absorber UVP-327.
Oxidation inhibitor of the present invention is the one in antioxidant BHT, Ursol D and 2,6-tri-grades of butyl-4-methylphenols.
Bamboo fibers powder of the present invention is the powder particle by 1300～2000 eye mesh screens, and the diameier of described transparent filler is no more than 1000nm.
The production method of the PVC wood plastic coating layer of a kind of dual-use colour camoufague cloth of the present invention, its production method is as follows:
1) chlorophyll and the xenthophylls of getting respective quality ratio mix, mixed chlorophyll and xenthophylls are dissolved in a certain amount of ethanolic soln, the bamboo fibers powder of respective quality is put in ethanolic soln and soak, after soaking 48～72h, steam dry ethanolic soln, obtain painted after bamboo fibers powder.
2) the painted bamboo fibers powder obtained in step 1) is screened by screen cloth, the painted auxiliary material after being sieved.
3) transparent filler of respective quality is put in stirrer with oxidized polyethlene wax, paraffin and stearic amide mix, after fully mixing 2～3h, be placed in the baking oven of 100～120 DEG C and carry out drying operation, after drying 1h, obtain transparent auxiliary material.
4) the PVC paste resin of respective quality and other remaining raw materials are carried out married operation, fully after mixing 4h, obtain mixed coating masterbatch.
5) by step 2) in the transparent auxiliary material that obtains in the painted auxiliary material that obtains and step 3) carry out carrying out married operation at 150～160 DEG C, after fully mixed even, slowly add the coating masterbatch obtained in step 4), reinforced process carries out continuing cooling, after masterbatch adds completely, after continuing stirring 2～3h, obtain PVC wood plastic coating layer.
6), when PVC wood plastic coating layer step 5) obtained applies on cloth, glue spread is 120～140g/m2, temperature during oven dry is 155～180 DEG C, and temperature during plasticizing is 180～190 DEG C.
The cooling scope of the lasting cooling operation in step 5) of the present invention is 160 DEG C～60 DEG C, and rate of temperature fall is 5 DEG C/min, and when temperature drops to 60 DEG C, mixed coating masterbatch has fed in raw material.
Chlorophyll in step 1) of the present invention, xenthophylls and bamboo fibers all need to carry out high-temperature sterilization operation before mixing.
In step 6) of the present invention, cloth is above and below bilayer coating.
The cloth of PVC wood plastic coating layer of the present invention application is terylene filament fabric; Described terylene filament fabric is the high strength polyester filament yarn fabric of 500D × 500D or 1000D × 100D.
It is an advantage of the current invention that: the present invention is by changing the formula of original PVC wood plastic coating layer, adopt the PVC wood plastic coating layer of the combinations produce of transparent filler and painted vegetable fibre, on the basis ensureing the original machinery of PVC wood plastic coating layer and chemical property, improve its transparency and glossiness, make the colour camoufague cloth after processing show its true qualities, avoid industry pigment to the impact of colour camoufague cloth color; Simultaneously, the pigment of the product application of the present invention is natural pigment, it carries out co-pigmentation under the effect of vegetable fibre, after long-time work, it is exactly that decomposition to a certain extent occurs pigment, not only can not produce gas with foreign flavor, and too big change can not occur due to the color and luster of natural pigment after decomposing, improve the diversity of its colour camoufague cloth color and luster on the contrary.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Raw material in the formula of the present invention is the product buied on the market.
Halite in the formula of the present invention is the common mineral products halite of Jiangsu Province's Huaian city output.
Embodiment 1: the PVC wood plastic coating layer of a kind of dual-use colour camoufague cloth, in described PVC wood plastic coating layer, the weight part number of each component is as follows: PVC paste resin 60 parts, transparent filler 40 parts (11.4 parts, glass powder, quartz sand 22.9 parts, talcum powder 5.7 parts), 10 parts, painted vegetable fibre (9.35 parts, bamboo fibers powder, tinting material 0.65 part), silane coupling agent 4 parts, halite 0.5 part, stearic amide 1 part, oxidized polyethlene wax 0.5 part, 2 parts, paraffin, dioctyl phthalate (DOP) 0.5 part, ultra-violet stabilizer 1 part, 0.1 part, oxidation inhibitor and zinc borate 0.5 part, magnesium hydroxide 2 parts.
Embodiment 2: the PVC wood plastic coating layer of a kind of dual-use colour camoufague cloth, in described PVC wood plastic coating layer, the weight part number of each component is as follows: PVC paste resin 80 parts, transparent filler 45 parts (8.2 parts, glass powder, quartz sand 32.8 parts, talcum powder 4.1 parts), 20 parts, painted vegetable fibre (19.6 parts, bamboo fibers powder, tinting material 0.4 part), silane coupling agent 5 parts, halite 1 part, stearic amide 1.5 parts, oxidized polyethlene wax 1 part, 3 parts, paraffin, dioctyl phthalate (DOP) 1.5 parts, ultra-violet stabilizer 1.5 parts, 0.5 part, oxidation inhibitor and zinc borate 1 part, magnesium hydroxide 4 parts.
Embodiment 3: the PVC wood plastic coating layer of a kind of dual-use colour camoufague cloth, in described PVC wood plastic coating layer, the weight part number of each component is as follows: PVC paste resin 70 parts, transparent filler 42 parts (12 parts, glass powder, quartz sand 24 parts, talcum powder 6 parts), 15 parts, painted vegetable fibre (14.3 parts, bamboo fibers powder, tinting material 0.7 part), silane coupling agent 4.5 parts, halite 0.8 part, stearic amide 1 part, oxidized polyethlene wax 0.6 part, 2.4 parts, paraffin, dioctyl phthalate (DOP) 1.2 parts, ultra-violet stabilizer 1.4 parts, 0.4 part, oxidation inhibitor and zinc borate 0.8 part, magnesium hydroxide 3 parts.
Embodiment 4: the PVC wood plastic coating layer of a kind of dual-use colour camoufague cloth, in described PVC wood plastic coating layer, the weight part number of each component is as follows: PVC paste resin 70 parts, transparent filler 42 parts (9.33 parts, glass powder, quartz sand 28 parts, talcum powder 4.67 parts), 15 parts, painted vegetable fibre (14.15 parts, bamboo fibers powder, tinting material 0.85 part), silane coupling agent 4.5 parts, halite 0.8 part, stearic amide 1 part, oxidized polyethlene wax 0.6 part, 2.4 parts, paraffin, dioctyl phthalate (DOP) 1.2 parts, ultra-violet stabilizer 1.4 parts, 0.4 part, oxidation inhibitor and zinc borate 0.8 part, magnesium hydroxide 3 parts.
Embodiment 5: after each component formula in the PVC wood plastic coating layer of the present invention under the same conditions double-deck coating colour camoufague cloth, carrying out simultaneous test, the product result finally obtained is as shown in the table:
。
As can be seen from the above table, when the PVC wood plastic coating layer produced by the production method of the present invention and commercially available coating layer are coated on identical colour camoufague cloth, bigger change is there is in the performance of colour camoufague cloth own compared to commercially available comparative example, particularly the transparency of product itself is due to commercially available comparative example, and each component glass powder in transparent filler in the present invention: quartz sand: the ratio of talcum powder, when wherein component surpasses amount, transparency and the Guan Zedu of the finished product decline greatly, and at PVC paste resin and transparent filler, when the consumption of painted vegetable fibre changes, cause the mechanical properties decrease of the finished product, when the content of coloured fiber and ratio change, the colour fastness to light of the finished product is caused to decline.
Through comprehensive contrast, composition and the over-all properties of the product of formula production in embodiment 4 are the most outstanding.
Embodiment 6: carrying out simultaneous test under the formula in embodiment 4 adopts different production methods, the result of simultaneous test is as shown in the table:
。
As can be seen from the above table, glue spread in painting work process directly affects the radial fragmentation intensity of the finished product, glue spread is more big, the radial fragmentation intensity of product is more high, simultaneously, cooling scope in production process affects stripping strength and the transparency of the finished product, the end Wen Yuegao of the cooling of product itself, strength of glass is more high, but its transparency is contrary with it, due to the transparency meeting dramatic decrease of the product under hot conditions, and the rate of temperature fall of product itself also affects the transparency of the finished product, cooling rate is more fast, transparency is more big, but the too fast meeting of rate of temperature fall causes the mechanical properties decrease of product, therefore the rate of temperature fall of itself can not be too high.
It should be noted that, above-mentioned is only the better embodiment of the present invention, is not used for limiting protection scope of the present invention, and the arbitrary combination made on the basis of above-described embodiment or equivalents all belong to protection scope of the present invention.

Claims (10)

1. the PVC wood plastic coating layer of a dual-use colour camoufague cloth, it is characterized in that, in described PVC wood plastic coating layer, the weight part number of each component is as follows: PVC paste resin 60～80 parts, transparent filler 40～45 parts, 10～20 parts, painted vegetable fibre, silane coupling agent 4～5 parts, halite 0.5～1 part, stearic amide 1～1.5 part, oxidized polyethlene wax 0.5～1 part, 2～3 parts, paraffin, dioctyl phthalate (DOP) 0.5～1.5 part, ultra-violet stabilizer 1～1.5 part, 0.1～0.5 part, oxidation inhibitor and zinc borate 0.5～1 part, magnesium hydroxide 2～4 parts;
Described transparent filler is glass powder, quartz sand and talcum powder three's mixture, wherein glass powder, quartz sand and talcum powder: weight ratio is 2:4～8:1;
Described painted vegetable fibre is tinting material and the mix products of bamboo fibers powder, and wherein the weight ratio of bamboo fibers powder and tinting material is 10:0.2～0.7.
2. the PVC wood plastic coating layer of dual-use colour camoufague cloth according to claim 1, it is characterised in that, described ultra-violet stabilizer is the one in Ultraviolet Absorber UV-P, HMPA and UV light absorber UVP-327.
3. the PVC wood plastic coating layer of dual-use colour camoufague cloth according to claim 1, it is characterised in that, described oxidation inhibitor is the one in antioxidant BHT, Ursol D and 2,6-tri-grades of butyl-4-methylphenols.
4. the PVC wood plastic coating layer of dual-use colour camoufague cloth according to claim 1, it is characterised in that, described tinting material is the mixture of chlorophyll and xenthophylls, and wherein the blending ratio of chlorophyll and xenthophylls is 1～10:1～10.
5. the PVC wood plastic coating layer of dual-use colour camoufague cloth according to claim 1, it is characterised in that, described bamboo fibers powder is the powder particle by 1300～2000 eye mesh screens, and the diameier of described transparent filler is no more than 1000nm.
6. the production method of the PVC wood plastic coating layer of a dual-use colour camoufague cloth according to claim 1, it is characterised in that, described production method is as follows:
1) chlorophyll and the xenthophylls of getting respective quality ratio mix, mixed chlorophyll and xenthophylls are dissolved in a certain amount of ethanolic soln, the bamboo fibers powder of respective quality is put in ethanolic soln and soak, after soaking 48～72h, steam dry ethanolic soln, obtain painted after bamboo fibers powder;
2) the painted bamboo fibers powder obtained in step 1) is screened by screen cloth, the painted auxiliary material after being sieved;
3) transparent filler of respective quality is put in stirrer with oxidized polyethlene wax, paraffin and stearic amide mix, after fully mixing 2～3h, be placed in the baking oven of 100～120 DEG C and carry out drying operation, after drying 1h, obtain transparent auxiliary material;
4) the PVC paste resin of respective quality and other remaining raw materials are carried out married operation, fully after mixing 4h, obtain mixed coating masterbatch;
5) by step 2) in the transparent auxiliary material that obtains in the painted auxiliary material that obtains and step 3) carry out carrying out married operation at 150～160 DEG C, after fully mixed even, slowly add the coating masterbatch obtained in step 4), reinforced process carries out continuing cooling, after masterbatch adds completely, after continuing stirring 2～3h, obtain PVC wood plastic coating layer;
6), when PVC wood plastic coating layer step 5) obtained applies on cloth, glue spread is 12～140g/m2, temperature during oven dry is 155～180 DEG C, and temperature during plasticizing is 180～190 DEG C.
7. the production method of the PVC wood plastic coating layer of dual-use colour camoufague cloth according to claim 6, it is characterized in that, the cooling scope of the lasting cooling operation in described step 5) is 160 DEG C～60 DEG C, rate of temperature fall is 5 DEG C/min, when temperature drops to 60 DEG C, mixed coating masterbatch has fed in raw material.
8. the production method of the PVC wood plastic coating layer of dual-use colour camoufague cloth according to claim 6, it is characterised in that, the described chlorophyll in step 1), xenthophylls and bamboo fibers all need to carry out high-temperature sterilization operation before mixing.
9. the production method of the PVC wood plastic coating layer of dual-use colour camoufague cloth according to claim 6, it is characterised in that, in described step 6), cloth is above and below bilayer coating.
10. the production method of the PVC wood plastic coating layer of dual-use colour camoufague cloth according to claim 6, it is characterised in that, the cloth of described PVC wood plastic coating layer application is terylene filament fabric.
CN201610170874.0A 2016-03-24 2016-03-24 PVC wood-plastic coating layer of military-civil camouflage fabric Pending CN105670408A (en)

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CN201610170874.0A CN105670408A (en) 2016-03-24 2016-03-24 PVC wood-plastic coating layer of military-civil camouflage fabric

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Application Number Priority Date Filing Date Title
CN201610170874.0A CN105670408A (en) 2016-03-24 2016-03-24 PVC wood-plastic coating layer of military-civil camouflage fabric

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116285515A (en) * 2021-12-13 2023-06-23 杭州祥和纺织涂层有限公司 Ugli coating and coating preparation method coated with Ugli coating

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1732894A (en) * 2005-08-30 2006-02-15 浙江理工大学 Compound natural pigment camouflage ointment and preparation process thereof
CN103114447A (en) * 2013-03-08 2013-05-22 东莞市悠派户外用品制造有限公司 Environment-friendly PVC (Polyvinyl Chloride) coating reflective fabric
CN104032573A (en) * 2014-05-20 2014-09-10 卢斌 Coating waterproof cloth composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1732894A (en) * 2005-08-30 2006-02-15 浙江理工大学 Compound natural pigment camouflage ointment and preparation process thereof
CN103114447A (en) * 2013-03-08 2013-05-22 东莞市悠派户外用品制造有限公司 Environment-friendly PVC (Polyvinyl Chloride) coating reflective fabric
CN104032573A (en) * 2014-05-20 2014-09-10 卢斌 Coating waterproof cloth composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116285515A (en) * 2021-12-13 2023-06-23 杭州祥和纺织涂层有限公司 Ugli coating and coating preparation method coated with Ugli coating

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Application publication date: 20160615