CN106995544B - 含有金属负载富勒烯的聚乙烯材料及其制备方法 - Google Patents
含有金属负载富勒烯的聚乙烯材料及其制备方法 Download PDFInfo
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- CN106995544B CN106995544B CN201710201287.8A CN201710201287A CN106995544B CN 106995544 B CN106995544 B CN 106995544B CN 201710201287 A CN201710201287 A CN 201710201287A CN 106995544 B CN106995544 B CN 106995544B
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- fullerene
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- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 229910003472 fullerene Inorganic materials 0.000 title claims abstract description 51
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 40
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 40
- 239000002184 metal Substances 0.000 title claims abstract description 37
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 37
- -1 Polyethylene Polymers 0.000 title claims abstract description 33
- 239000000463 material Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003063 flame retardant Substances 0.000 claims abstract description 16
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract 3
- 239000000725 suspension Substances 0.000 claims description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 6
- 229910001510 metal chloride Inorganic materials 0.000 claims description 5
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical group Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 4
- 239000006228 supernatant Substances 0.000 claims description 4
- 238000005119 centrifugation Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000002390 rotary evaporation Methods 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 abstract description 3
- 239000001301 oxygen Substances 0.000 abstract description 3
- 238000010000 carbonizing Methods 0.000 abstract description 2
- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 238000012667 polymer degradation Methods 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 6
- 230000006698 induction Effects 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000002411 thermogravimetry Methods 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229940032296 ferric chloride Drugs 0.000 description 1
- 229940044631 ferric chloride hexahydrate Drugs 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0856—Iron
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
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CN109054395B (zh) * | 2018-06-27 | 2020-06-19 | 华南理工大学 | 一种耐高温无卤阻燃硅橡胶及其制备方法 |
CN109535567B (zh) * | 2018-12-18 | 2021-04-23 | 广州泽田餐饮用品实业有限公司 | 一种可光氧降解的聚丙烯复合材料及其制备方法与应用 |
CN109810406B (zh) * | 2018-12-29 | 2022-04-19 | 浙江大学宁波理工学院 | 高强度聚烯烃复合材料及其制备方法 |
CN110713651A (zh) * | 2019-09-29 | 2020-01-21 | 江苏金洋机械有限公司 | 一种铁路垫板用改性聚乙烯复合材料及其制备方法 |
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CN103408821A (zh) * | 2013-05-27 | 2013-11-27 | 浙江大学宁波理工学院 | 聚乙烯/富勒烯纳米复合材料及其制备方法 |
CN106046683A (zh) * | 2016-07-07 | 2016-10-26 | 西华大学 | 低烟阻燃高分子复合材料及其制备方法 |
CN106543534A (zh) * | 2016-11-02 | 2017-03-29 | 北京圣盟丰联科贸有限公司 | 多功能石墨烯/聚合物母粒及其制备方法 |
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CN101607197A (zh) * | 2008-06-18 | 2009-12-23 | 汉能科技有限公司 | 一种燃料电池催化剂的制备方法 |
CN102942169A (zh) * | 2012-10-01 | 2013-02-27 | 青岛科技大学 | 超临界流体技术制备负载金属富勒烯纳微米材料的方法 |
CN102923690A (zh) * | 2012-10-31 | 2013-02-13 | 青岛科技大学 | 负载过渡金属的富勒烯类纳微米材料的制备方法及其产品 |
CN103230604B (zh) * | 2013-04-19 | 2015-03-11 | 郑州大学 | 一种磁性水溶性富勒烯及其制备方法和应用 |
CN105001571B (zh) * | 2015-07-03 | 2017-11-03 | 北京理工大学 | 负载金属氧化物的活性炭协效膨胀阻燃电缆料及制备方法 |
CN106117606A (zh) * | 2016-06-14 | 2016-11-16 | 安徽建筑大学 | 氧化亚铜杂化石墨烯阻燃抑烟剂及其制备方法 |
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CN103408821A (zh) * | 2013-05-27 | 2013-11-27 | 浙江大学宁波理工学院 | 聚乙烯/富勒烯纳米复合材料及其制备方法 |
CN106046683A (zh) * | 2016-07-07 | 2016-10-26 | 西华大学 | 低烟阻燃高分子复合材料及其制备方法 |
CN106543534A (zh) * | 2016-11-02 | 2017-03-29 | 北京圣盟丰联科贸有限公司 | 多功能石墨烯/聚合物母粒及其制备方法 |
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Address after: 315100 No.1 Qianhu South Road, higher education park, Shounan street, Yinzhou District, Ningbo City, Zhejiang Province Patentee after: Zhejiang University of science and engineering Ningbo Address before: 315100, Qian 1, Yinzhou District, Ningbo, Zhejiang, Hunan Road Patentee before: Ningbo Institute of Technology, Zhejiang University |
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Effective date of registration: 20210827 Address after: 315300 West Industrial Park, Guanhaiwei town, Cixi City, Ningbo City, Zhejiang Province Patentee after: FU-DAY SCIENCE AND TECHNOLOGY Co.,Ltd. Address before: 315100 No.1 Qianhu South Road, higher education park, Shounan street, Yinzhou District, Ningbo City, Zhejiang Province Patentee before: Zhejiang University of science and engineering Ningbo |