CN106985313B - 一种橡胶脱模剂的制备方法 - Google Patents
一种橡胶脱模剂的制备方法 Download PDFInfo
- Publication number
- CN106985313B CN106985313B CN201710286071.6A CN201710286071A CN106985313B CN 106985313 B CN106985313 B CN 106985313B CN 201710286071 A CN201710286071 A CN 201710286071A CN 106985313 B CN106985313 B CN 106985313B
- Authority
- CN
- China
- Prior art keywords
- releasing agent
- parts
- rubber
- titanate esters
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 30
- 229920001971 elastomer Polymers 0.000 title claims abstract description 26
- 239000005060 rubber Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims abstract description 38
- -1 ethylene, propylene ethylidene Chemical group 0.000 claims abstract description 33
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 12
- 239000005977 Ethylene Substances 0.000 claims abstract description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical class [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 10
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002253 acid Substances 0.000 claims abstract description 10
- 125000004423 acyloxy group Chemical group 0.000 claims abstract description 10
- 239000013522 chelant Substances 0.000 claims abstract description 10
- 229920001577 copolymer Polymers 0.000 claims abstract description 9
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims abstract description 9
- DHGUOKRCSSAAPM-UHFFFAOYSA-N dimethoxy-octyl-(trifluoromethoxy)silane Chemical class FC(O[Si](OC)(OC)CCCCCCCC)(F)F DHGUOKRCSSAAPM-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000006185 dispersion Substances 0.000 claims abstract description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 19
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 description 6
- 239000013065 commercial product Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920001558 organosilicon polymer Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
- B29C33/60—Releasing, lubricating or separating agents
- B29C33/62—Releasing, lubricating or separating agents based on polymers or oligomers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/02—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type
- B29B7/22—Component parts, details or accessories; Auxiliary operations
- B29B7/28—Component parts, details or accessories; Auxiliary operations for measuring, controlling or regulating, e.g. viscosity control
- B29B7/283—Component parts, details or accessories; Auxiliary operations for measuring, controlling or regulating, e.g. viscosity control measuring data of the driving system, e.g. torque, speed, power
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/16—EPM, i.e. ethylene-propylene copolymers; EPDM, i.e. ethylene-propylene-diene copolymers; EPT, i.e. ethylene-propylene terpolymers
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
Abstract
本发明提供了一种橡胶脱模剂的制备方法：按重量份计，将乙烯‑丙烯‑亚乙基降冰片共聚物，十三氟辛基三甲氧基硅烷，异丙基三（二辛基焦磷酸酰氧基）乙撑钛酸酯和三乙醇胺的螯合物，双（乙酰丙酮）（乙氧基乙丙氧基）钛酸酯在常温下加入分散釜中，搅拌，令其分散，再加入二丙二醇二甲醚，搅拌，即得到橡胶脱模剂产品。
Description
技术领域
本发明涉及一种脱模剂的制备方法，特别是一种橡胶脱模剂的制备方法。
背景技术
脱模剂是用在两个彼此易于粘着的物体表面的一个界面涂层，它可使物体表面易于脱离、光滑及洁净。
脱模剂广泛应用于金属压铸、聚氨酯泡沫和弹性体、玻璃纤维增强塑料、注塑热塑性塑料、真空发泡片材和挤压型材等各种模压操作中。在模压中，有时其他塑料填加剂如增塑剂等会渗出到界面上，这时就需要一个表面脱除剂来除掉它。
橡胶广泛应用于交通运输，建筑房屋，汽车工业，日用商品，服装鞋包，医疗卫生，电器通讯，文教体育等各个行业。橡胶脱模剂指用于防止橡胶产品与模具表面粘连，并能使之顺利出模而不致撕裂的一类物质。使用时将它喷或涂于模腔表面，以形成一层有效的隔离层，质量优良的脱模剂能赋予相关产品更良好的产品外观，表面平滑，无凹凸；优良的脱模剂还能提高生产产品的良品率，大大提高产能的同时节约生产成本。
CN106042230A 公开了一种橡胶脱模剂，包括以下重量份的原料：聚四氟乙烯120-200份、甲基硅油25-60份、聚丙烯酰胺15-40份、脂肪醇10-30份、聚乙二醇醚15-40份、肪醇醚硫酸钠80-150份、酞酸正丁酯12-36份、二甲苯磺酸钠16-28份、云母粉20-50份、甲苯10-25份、异构醇聚氧乙烯醚5-15份、去离子水150-300份、交联剂15-30份、触媒5-15份。
CN106117925A 公开了一种制备橡胶鞋底用脱模剂，它包括聚四氟乙烯、柠檬酸、脂肪醇、烷基苯磺酸单乙醇胺、有机硅聚合物、二月桂酸二丁基锡，其中聚四氟乙烯10-14份、柠檬酸18-22份、脂肪醇5-10份、烷基苯磺酸单乙醇胺2-6份、有机硅聚合物1-5份、二月桂酸二丁基锡1-2份，以上份数均为质量份数。本发明所得到的制备橡胶鞋底用脱模剂，
现有的橡胶脱模剂产品，大多有着使用寿命较短，易损毁，涂层表面易存在不光滑部分的缺点，因此，研发一种新型橡胶脱模剂来改善这些缺点非常有必要。
发明内容
本发明目的在于解决现有技术中存在的上述技术问题，提供一种橡胶脱模剂。
本发明所述的一种橡胶脱模剂，主要通过以下步骤实现：
按重量份计，将乙烯-丙烯-亚乙基降冰片共聚物100份，十三氟辛基三甲氧基硅烷5-15份，异丙基三（二辛基焦磷酸酰氧基）乙撑钛酸酯和三乙醇胺的螯合物0.01-0.1份，双（乙酰丙酮）（乙氧基乙丙氧基）钛酸酯0.01-0.1份在常温下加入分散釜中，转速2000rpm，搅拌0.5-1.5h，令其分散，再加入二丙二醇二甲醚300-800份，转速500rpm，搅拌30-60min，即得到橡胶脱模剂产品。
所述的乙烯-丙烯-亚乙基降冰片共聚物为市售产品，如sigma-aldrich公司生产的产品；十三氟辛基三甲氧基硅烷为市售产品，如上海恩氟佳科技有限公司生产的产品；异丙基三（二辛基焦磷酸酰氧基）乙撑钛酸酯和三乙醇胺的螯合物为市售产品，如杭州杰西卡化工有限公司生产的产品；双（乙酰丙酮）（乙氧基乙丙氧基）钛酸酯为市售产品，如杭州杰西卡化工有限公司生产的产品；二丙二醇二甲醚为市售产品，如杭州杰西卡化工有限公司生产的产品。
与现有技术相比，本发明的橡胶脱模剂，具有以下有益效果：
本产品稳定性较强，具有较长的使用寿命，在保证橡胶光泽稳定的基础上，每次喷涂的涂膜可使用25次以上；涂层表面细腻光滑，不光滑瑕疵部分少，有益于保证橡胶产品的外观。
具体实施方式
以下实例仅仅是进一步说明本发明，并不是限制本发明保护的范围。
实施例1
在2000L分散釜中，加入乙烯-丙烯-亚乙基降冰片共聚物100Kg，十三氟辛基三甲氧基硅烷10Kg，异丙基三（二辛基焦磷酸酰氧基）乙撑钛酸酯和三乙醇胺的螯合物0.05Kg，双（乙酰丙酮）（乙氧基乙丙氧基）钛酸酯0.05Kg，在2000rpm的转速下搅拌1h，再加入二丙二醇二甲醚600Kg，在500rpm转速下搅拌45min，即得到橡胶脱模剂产品。编号M-1。
实施例2
在2000L分散釜中，加入乙烯-丙烯-亚乙基降冰片共聚物100Kg，十三氟辛基三甲氧基硅烷5Kg，异丙基三（二辛基焦磷酸酰氧基）乙撑钛酸酯和三乙醇胺的螯合物0.01Kg，双（乙酰丙酮）（乙氧基乙丙氧基）钛酸酯0.01Kg，在2000rpm的转速下搅拌0.5h，再加入二丙二醇二甲醚300Kg，在500rpm转速下搅拌30min，即得到橡胶脱模剂产品。编号M-2。
实施例3
在2000L分散釜中，加入乙烯-丙烯-亚乙基降冰片共聚物100Kg，十三氟辛基三甲氧基硅烷15Kg，异丙基三（二辛基焦磷酸酰氧基）乙撑钛酸酯和三乙醇胺的螯合物0.1Kg，双（乙酰丙酮）（乙氧基乙丙氧基）钛酸酯0.1Kg，在2000rpm的转速下搅拌1.5h，再加入二丙二醇二甲醚800Kg，在500rpm转速下搅拌60min，即得到橡胶脱模剂产品。编号M-3。
对比例1
不加入异丙基三（二辛基焦磷酸酰氧基）乙撑钛酸酯和三乙醇胺的螯合物，其他条件同实施例1。编号M-4。 对比例2
不加入双（乙酰丙酮）（乙氧基乙丙氧基）钛酸酯，其他条件同实施例1。编号M-5。
对比例3
在2000L分散釜中，加入乙烯-丙烯-亚乙基降冰片共聚物100Kg，十三氟辛基三甲氧基硅烷10Kg，异丙基三（二辛基焦磷酸酰氧基）乙撑钛酸酯和三乙醇胺的螯合物0.05Kg，双（乙酰丙酮）（乙氧基乙丙氧基）钛酸酯0.05Kg，二丙二醇二甲醚600Kg，在1500rpm的转速下搅拌1.5h，得到橡胶脱模剂产品。编号M-6。
实施例4
将实施例1-3和对比例1-3所制得的橡胶脱模剂产品涂抹在长宽为10x10cm的金属板上，在150℃下固化20min，检验脱模剂涂层的摩擦系数和表面不光滑部分面积占涂膜总面积的百分比。见表1。
表1：不同生产工艺所生产出的脱模剂产品涂膜的性质
| 编号 | 摩擦系数 | 不光滑面积占比/% |
| M-1 | 0.07 | 0.03 |
| M-2 | 0.10 | 0.04 |
| M-3 | 0.06 | 0.01 |
| M-4 | 0.14 | 0.10 |
| M-5 | 0.14 | 0.11 |
| M-6 | 0.12 | 0.05 |
Claims (1)
1.一种橡胶脱模剂的制备方法，其特征在于包括以下组份：
组分 重量份
乙烯-丙烯-亚乙基降冰片共聚物 100
十三氟辛基三甲氧基硅烷 5-15
异丙基三（二辛基焦磷酸酰氧基）乙撑钛酸酯和三乙醇胺的螯合物 0.01-0.1
双（乙酰丙酮）（乙氧基乙丙氧基）钛酸酯 0.01-0.1
二丙二醇二甲醚 300-800；
按重量份计，将乙烯-丙烯-亚乙基降冰片共聚物100份，十三氟辛基三甲氧基硅烷5-15份，异丙基三（二辛基焦磷酸酰氧基）乙撑钛酸酯和三乙醇胺的螯合物0.01-0.1份，双（乙酰丙酮）（乙氧基乙丙氧基）钛酸酯0.01-0.1份在常温下加入分散釜中，转速2000rpm，搅拌0.5-1.5h，令其分散，再加入二丙二醇二甲醚300-800份，转速500rpm，搅拌30-60min，即得到橡胶脱模剂产品。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710286071.6A CN106985313B (zh) | 2017-04-27 | 2017-04-27 | 一种橡胶脱模剂的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710286071.6A CN106985313B (zh) | 2017-04-27 | 2017-04-27 | 一种橡胶脱模剂的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106985313A CN106985313A (zh) | 2017-07-28 |
| CN106985313B true CN106985313B (zh) | 2018-09-18 |
Family
ID=59417262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710286071.6A Active CN106985313B (zh) | 2017-04-27 | 2017-04-27 | 一种橡胶脱模剂的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106985313B (zh) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09155880A (ja) * | 1995-11-30 | 1997-06-17 | Nok Corp | 焼付型離型剤 |
| EP1336643A1 (de) * | 2002-04-17 | 2003-08-20 | Goldschmidt AG | Verwendung von lösemittel-, wasser- und emulgatorfreien Organopolysiloxanformulierungen als Gleitmittel für profilierte Dichtungen |
| CN102490294A (zh) * | 2011-11-14 | 2012-06-13 | 厦门市豪尔新材料有限公司 | 一种能多次脱模的离型剂及其制备方法 |
| CN102615746A (zh) * | 2012-03-22 | 2012-08-01 | 中山市新辉化学制品有限公司 | 一种脱模剂及其制备方法 |
-
2017
- 2017-04-27 CN CN201710286071.6A patent/CN106985313B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09155880A (ja) * | 1995-11-30 | 1997-06-17 | Nok Corp | 焼付型離型剤 |
| EP1336643A1 (de) * | 2002-04-17 | 2003-08-20 | Goldschmidt AG | Verwendung von lösemittel-, wasser- und emulgatorfreien Organopolysiloxanformulierungen als Gleitmittel für profilierte Dichtungen |
| CN102490294A (zh) * | 2011-11-14 | 2012-06-13 | 厦门市豪尔新材料有限公司 | 一种能多次脱模的离型剂及其制备方法 |
| CN102615746A (zh) * | 2012-03-22 | 2012-08-01 | 中山市新辉化学制品有限公司 | 一种脱模剂及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106985313A (zh) | 2017-07-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8507418B2 (en) | Siloxane-based composition which is intended for tire molding/stripping | |
| CN105623828B (zh) | 一种用于高粘附性树脂基材料的脱模剂及其制备方法 | |
| US2789933A (en) | Manufacture of rubber articles | |
| CN103339171B (zh) | 可固化有机硅氧烷嵌段共聚物乳剂 | |
| EP2581139B1 (en) | Surfactant composition, coating solution containing the surfactant composition, and rubber article treated by the coating solution. | |
| CN106042230B (zh) | 一种橡胶脱模剂及其制备方法 | |
| CN108582928A (zh) | 一种pu贴合硅橡胶拉链膜、涂布工艺及其应用 | |
| CN102643481A (zh) | 经济型汽车装饰裙板和压条用聚丙烯材料及其制备方法 | |
| CN106985313B (zh) | 一种橡胶脱模剂的制备方法 | |
| JPS58180555A (ja) | オルガノポリシロキサン潤滑剤 | |
| CN105295723A (zh) | 一种固化型涂层组合物及其应用 | |
| CN111303447A (zh) | 一种转向乳化-原位聚合制备水性有机硅橡塑脱模剂的方法 | |
| CN105542474B (zh) | 一种铝镀银导电橡胶板及其制备方法 | |
| DE3152328A1 (de) | Verfahren zur herstellung eines pneumatischen oder halbpneumatischen reifens | |
| CN103788562B (zh) | 用于包覆射粘的热塑性弹性体组合物 | |
| CN103057006A (zh) | 轮胎脱模剂的制备方法 | |
| CA1239238A (en) | Rubber lubricant composition | |
| JPS58167693A (ja) | オルガノポリシロキサン潤滑剤 | |
| CN107011748A (zh) | 用于玻纤塑胶件表面喷涂处理的玻纤处理剂及其应用 | |
| EP3957472A1 (en) | Release agent composition for tire molding and bladder for tire molding | |
| CN105619666B (zh) | 一种具有流变性的可重复使用的水性脱模剂的制备 | |
| CN114656642A (zh) | 一种有机氟硅乳液脱模剂及其制备方法 | |
| CN108468229A (zh) | 一种硅橡胶防水拉链布及其涂布工艺 | |
| CN202907854U (zh) | 一种制有橡塑材料防护层的劳保手套 | |
| CN110358464A (zh) | 一种防刮耐老化超柔软高透tpu保护膜及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201118 Address after: 629300 pear dam, Industrial Development Zone, Daying County, Sichuan, Suining Patentee after: SUINING SENDI AUTO PARTS MANUFACTURING Co.,Ltd. Address before: 432000 Hubei city of Xiaogan province high tech Zone Qun Sheng Cun Nan Qu Bian min Lu 5 floor, room 91 Patentee before: Wang Qiyu |
|
| TR01 | Transfer of patent right |