CN106947615B - A kind of dish washing liquid - Google Patents
A kind of dish washing liquid Download PDFInfo
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- CN106947615B CN106947615B CN201710177381.4A CN201710177381A CN106947615B CN 106947615 B CN106947615 B CN 106947615B CN 201710177381 A CN201710177381 A CN 201710177381A CN 106947615 B CN106947615 B CN 106947615B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/188—Terpenes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/223—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin oxidised
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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Abstract
The invention discloses a kind of dish washing liquids, are related to commodity chemical field, and 0.1~3 weight %D- limonene, 15~30 weight % saponin(es, 13~18 weight % Tea Saponins are contained in the dish washing liquid.Main wash ingredient D- limonene in dish washing liquid produced by the invention, sapindoside, Tea Saponin, pomelo peel extracting solution is respectively from pomelo peel, soapberry pericarp, tea seed powder, unartificial chemical synthesis, the principle to counteract each other according to substance, D- limonene, sapindoside, Tea Saponin, the dish washing liquid of pomelo peel extracting solution and unclassified stores being composed, degreasing result is good, natural disinfection, bacteriostasis is strong, by experiments have shown that: the activity substance content of dish washing liquid provided by the invention be greater than 28%, decontamination force value is greater than 1.85, Escherichia coli, staphylococcus aureus, the sterilizing rate of pseudomonas aeruginosa is all larger than 99.9%.
Description
Technical field
The invention belongs to commodity chemical fields, more particularly, to a kind of dish washing liquid.
Background technique
With the development of science and technology largely having come into our life, the life with us with the dish washing liquid that petrochemical industry synthesizes
It is living inseparable.The main composition of dish washing liquid is the surfactant of sodium alkyl sulfonate and/or fatty alcohol-ether sodium sulfate, fatty acid
Diglycollic amide foam improver, solubilizer, essence, water, pigment and preservative etc..Sodium alkyl sulfonate and fatty alcohol-ether sodium sulfate are stone
The anionic surfactant being combined to, because of its fragrant, consistency is suitable for that degreasing cleaning ability is strong, foaming abundancy and persistently,
It is hard water resistance, in short term without overt toxicity, it is suitable for cleaning delicate items, it is cheap to wait many advantages and occupy mainstream product in the market position long
It sets.However the toxicologic study of nearly half a century is as a result, make consumer to such chemical dish washing liquid in the exposure of following several respects
Potential risk is recognized.
First, the harm to human body.Petrochemical industry synthetic surface activity will cause the functional disorder of skin, bald head, white hair, liver
The organ damages such as kidney make a very bad impression simultaneously for testis, ovary.If people excessively contacts the sewage containing dish washing liquid or eats
The food for remaining dish washing liquid will lead to the decline of the immune of people, blood and nervous function, can obtain calculosis etc..
Second, pollute environment.The United Nations is open in 1992 to be confirmed: the earth rivers and creeks, water quality, soil pollution sources unexpectedly
70% or more is in household water containing caused by petrochemical industry lotion and its discharge.
Third, harm association animals and plants.Sewage will lead to the dead or deformity variation that suffers from a severe illness after animal is drunk；Seed is met
The water of strong acid and strong base cannot germinate at all；The ecosystem of biology and plant in welding
Therefore, social sustainable development and its ecology being related to, environment, resource, it is economical the problems such as become international community and close
The focus of note, status have been thus lifted to the height of development strategy, and the concept of " Green Chemistry " is also come into being.According to greenization
The exploitation of meaning, Green detergent also attracts people's attention, and people are to non-stimulated, nontoxic；It is biodegradable rapidly,
Thoroughly；Detergency, bactericidal effect are good；The requirement of excellent, sustainable development the Green detergent of compatibility is more urgent, because
This, is able to satisfy above-mentioned requirements and can be increasingly subject to the welcome in market by the Green Cleanser based on natural material, had a extensive future.
In existing research, as patent CN105385515A (documents 1) discloses a kind of natural plants tea seed cleaning medicine
Powder；Patent CN102925299A discloses a kind of Green antimicrobial cleanser essence；Patent CN102766538A discloses a kind of Edible
Dish washing liquid etc..It is non-stimulated, nontoxic that above-mentioned technology solves chemical dish washing liquid；It is biodegradable rapid, thorough；Compatibility is excellent,
The requirement of sustainable development, but its activity substance content is low, detergency and bactericidal effect are poor.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of dish washing liquid, and it is an object of the present invention to provide a kind of activity substance content
High, detergency and the good dish washing liquid of bactericidal effect.Concrete scheme is as follows:
A kind of dish washing liquid, the dish washing liquid contain the surfactant of 28.1~51 weight %, which is D- lemon
Remaining content of lemon alkene, saponin(e and Tea Saponin, dish washing liquid can be water or the mixture of water and ethyl alcohol, glycerol.
It is further preferably, in the dish washing liquid containing 0.1~3 weight %D- limonene, 15~30 weight % saponin(es, 13~
18 weight % Tea Saponins.Above-mentioned D- limonene, saponin(e, Tea Saponin can directly commercially.
It is further non-stimulated, the nontoxic technical effect, the D- limonene that the present invention uses derives from pomelo peel
Extract, saponin(e derive from soapberry extract, and the Tea Saponin derives from tea seed extract.
Wherein, the (R)-4-isopropenyl-1-methyl-1-cyclohexene in shaddock bark extract, nontoxic, nuisanceless, can substitute makes in industrial cleaning at present
Various chemical solvents biological can all degrade, and have natural bactericidal effect, be identified as food in the world
Spice additive simultaneously uses in medicine simultaneously.
Saponin(e in soapberry extract is surfactant, and major surfactant ingredient is triterpene saponin (I), sesquialter
Terpene glycoside (II), fat oil and protein, are a kind of natural nonionic surfactants, all-natural product, no added
Who work synthetic detergent.Have the function of very strong reduction surface tension, (takes a shower, washes one's face, washing one's hands, washing for skin cleaning
Hair) and clothes washing, it is good to wash clean performance, effectively takes out stains, free from extraneous odour, antibacterial beauty is brightened, nti-freckle, anti-acne, prevention and treatment skin
Disease.It has no toxic and side effect to human body, 100% degradation is mild non-stimulated, free from environmental pollution, environmental benefit is good.
Tea Saponin also known as tea saponin in tea seed extract are by extracting in tea tree seed (tea seed, tea seeds)
A kind of glycoside compound is a kind of natural surfactant of good performance.
Meanwhile further preferably, the present invention also provides another dish washing liquid, which also contains 0.1~3 weight %
D- limonene, 15~30 weight % saponin(es, 13~18 weight % Tea Saponins and 1~6 weight % pomelo peel extracting solution, the D-
Limonene derives from shaddock bark extract and pomelo peel extracting solution, and the saponin(e derives from soapberry extract, the tea
Saponin derives from tea seed extract, and pomelo peel extracting solution is added in dish washing liquid can increase sterilization, fragrance and the drive of dish washing liquid
The effect to eliminate the unusual smell.
Further preferably, cosolvent of the dish washing liquid in above two scheme also containing 35~40 weight %, the cosolvent
For ethyl alcohol and/or glycerol, further preferably, cosolvent is the mixture of ethyl alcohol and glycerol, and its ratio be 1:10~13.The ratio
Cosolvent mixtures enable in dish washing liquid each substance mutually indissoluble, form transparent light golden yellow liquid.
Further preferably, thickener of the dish washing liquid in above two scheme also containing 2~6 weight %, the thickener are
At least one of edible level sodium carboxymethylcellulose, sodium alginate, xanthan gum, gelatin, the addition of thickener can make dish washing liquid
Viscosity increase, improve its cleaning effect.
Further preferably, stabilizer of the dish washing liquid in above two scheme also containing 2~6 weight %, the stabilizer are
The addition of at least one of sodium chloride, potassium chloride, ammonium chloride, stabilizer can increase its shelf-life.
Further preferably, the production method of the shaddock bark extract are as follows: alcohol extracting method, water extraction, in ethanol extract from water precipitation
One kind, wherein
The alcohol extracting method are as follows: pomelo peel is crushed and is put into extraction vessel, second is added according to the ratio of solid-to-liquid ratio 1:5
Alcoholic solution, 20~30KHZ, 10~300min of ultrasonication, is centrifugally separating to obtain supernatant, is then evaporated under reduced pressure, pressure
For 0.5~0.8 atmospheric pressure, vapo(u)rizing temperature is 65~75 DEG C, and obtained product is D- limonene；
The water extraction are as follows: fresh grapefruit skin is cleaned and is crushed to 30~70 mesh and is put into extraction vessel, by solid-liquid ratio
Distilled water is added in 1:5, and 1~3%NaCl of water weight is added, directly progress extraction by steam distillation, basic to oil reservoir height
It is constant to stop reacting；Oil-yielding stratum is separated after being then allowed to stand, and oil reservoir is transferred in the round-bottomed flask of Rotary Evaporators and is carried out
0.09MPa vacuum distillation, collecting 83~88 DEG C of product of distillation is D- limonene；
The ethanol extract from water precipitation are as follows: pomelo peel is crushed and is put into extraction vessel, is added according to the ratio of solid-to-liquid ratio 1:5
Enter ethanol solution, 20~30KHZ, 10~300min of ultrasonication is centrifugally separating to obtain supernatant, be added volume be 20~
30% distilled water stirs and is cooled to -8~-3 DEG C, then -20~-10 DEG C at a temperature of refrigerate 1~10h, after -20~-
10 DEG C are obtained by filtration filtrate, are finally evaporated under reduced pressure filtrate, pressure be 0.5~0.8 atmospheric pressure, vapo(u)rizing temperature be 65~
75 DEG C, obtained product is D- limonene.
For above-mentioned production method and routine techniques, the other impurities content in D- limonene can be effectively reduced, it can be with
The activity substance content of dish washing liquid is further increased, and the reduction of other impurities can increase the shelf-life of dish washing liquid；It is above-mentioned
Ethanol extract from water precipitation in production method is optimal case.
Further preferably, the production method of the pomelo peel extracting solution are as follows: pomelo peel is cleaned and is crushed, with ethyl alcohol and
Deionized water 0.5~1h of mixed liquid dipping after decocting 135~270min, through supercooling, filtering, extraction, obtains pomelo peel extraction
Liquid；Wherein ethyl alcohol accounting is 20~30% in mixed liquor.
Further preferably, the production method of the soapberry extract are as follows: by soapberry with deionized water impregnate 10~
12h breaks into powder after drying to constant weight, using Soxhlet extraction, after 120~240min, through supercooling, filtering, centrifuge separation, dense
Contracting, obtains sapindoside.
Further preferably, the production method of the tea seed extract are as follows: tea seed is polished into powder, is mentioned using Soxhlet
It takes, after 120~240min, cooling, filtering, is concentrated to get Tea Saponin centrifuge separation.
The invention has the benefit that main wash ingredient D- limonene in dish washing liquid produced by the invention, without trouble
Sub- saponin(e, Tea Saponin, pomelo peel extracting solution are respectively from pomelo peel, soapberry pericarp, tea seed powder, unartificial chemical synthesis,
The principle to counteract each other according to substance, D- limonene, sapindoside, Tea Saponin, pomelo peel extracting solution and unclassified stores
The dish washing liquid being composed, not only degreasing result is good, and natural disinfection, bacteriostasis are strong, by experiments have shown that: the present invention provide
Dish washing liquid activity substance content be greater than 28%, decontamination force value be greater than 1.85, Escherichia coli, staphylococcus aureus, verdigris
The sterilizing rate of pseudomonad is all larger than 99.9%.And the vitamin and other nutrients wanted containing a large amount of needed by human body,
It, also can nutrition and protection skin while reaching article-cleaning.The dish washing liquid is raw materials used to be all made of food grade, nontoxic,
It is environmentally protective, addition petrochemical industry class synthetic surfactant is not needed, containing natural pigment and fragrance, does not need addition technicolor
Element and essence, ensure that 100% ecological, environmental protective of detergent.This product is in addition to being applied to tableware, glass container and stainless steel, modeling
Except material container, the fields such as hand cleanser, bath foam can also be applied to, it is widely used to be worthy to be popularized；Product of the present invention is non-toxic
Residual, it is easy to clean, save water resource.Unique formula of the invention material source is extensive, has stronger decontamination simultaneously, also has
The multiple functions such as sterilization, degerming, protection and skin nutrition.This dish washing liquid is nontoxic, non-stimulated, and harm to the human body is small, and easy cleaning can
Complete biodegradable is environmentally protective.
Specific embodiment
Be described further below technical solution of the present invention, but claimed range be not limited to it is described.
Embodiment one
A kind of dish washing liquid is present embodiments provided, the ingredient of the dish washing liquid is as follows:
Table 1: dish washing liquid component list (unit: weight %)
Wherein D- limonene derives from shaddock bark extract, the production method of the shaddock bark extract are as follows: by shaddock peel powder
It is broken and be put into extraction vessel, ethanol solution, 20KHZ ultrasonication 300min, centrifugation is added according to the ratio of solid-to-liquid ratio 1:5
Isolated supernatant, is then evaporated under reduced pressure, and pressure is 0.8 atmospheric pressure, and vapo(u)rizing temperature is 75 DEG C, and obtained product is
D- limonene.
Saponin(e derives from soapberry extract, the production method of soapberry extract are as follows: by soapberry deionized water
12h is impregnated, breaks into powder after drying to constant weight, using Soxhlet extraction, after 240min, through supercooling, filtering, centrifuge separation, dense
Contracting, obtains sapindoside.
Tea Saponin is tea seed extract, the production method of the tea seed extract are as follows: tea seed is polished into powder, using Soxhlet
It extracts, after 240min, cooling, filtering, is concentrated to get Tea Saponin centrifuge separation.
The production method of the dish washing liquid are as follows: thickener is added to the water to and is added cosolvent, it after mixing evenly, will be other
Raw material is added in mixed liquor, and heating stirring is uniform, after cooling.
Embodiment two
A kind of dish washing liquid is present embodiments provided, the ingredient of the dish washing liquid is as follows:
Table 2: dish washing liquid component list (unit: weight %)
Wherein D- limonene derives from shaddock bark extract, the production method of the shaddock bark extract are as follows: by shaddock peel powder
It is broken and be put into extraction vessel, ethanol solution, 30KHZ ultrasonication 10min, centrifugation is added according to the ratio of solid-to-liquid ratio 1:5
Isolated supernatant, is then evaporated under reduced pressure, and pressure is 0.5 atmospheric pressure, and vapo(u)rizing temperature is 65 DEG C, and obtained product is
D- limonene.
Saponin(e derives from soapberry extract, the production method of soapberry extract are as follows: by soapberry deionized water
12h is impregnated, breaks into powder after drying to constant weight, using Soxhlet extraction, after 120min, through supercooling, filtering, centrifuge separation, dense
Contracting, obtains sapindoside.
Tea Saponin is tea seed extract, the production method of the tea seed extract are as follows: tea seed is polished into powder, using Soxhlet
It extracts, after 120min, cooling, filtering, is concentrated to get Tea Saponin centrifuge separation.
The production method of the dish washing liquid are as follows: thickener is added to the water to and is added cosolvent, it after mixing evenly, will be other
Raw material is added in mixed liquor, and heating stirring is uniform, after cooling.
Embodiment three
A kind of dish washing liquid is present embodiments provided, the ingredient of the dish washing liquid is as follows:
Table 3: dish washing liquid component list (unit: weight %)
Wherein D- limonene derives from shaddock bark extract, the production method of the shaddock bark extract are as follows: by shaddock peel powder
It is broken and be put into extraction vessel, ethanol solution, 25KHZ ultrasonication 150min, centrifugation is added according to the ratio of solid-to-liquid ratio 1:5
Isolated supernatant, is then evaporated under reduced pressure, and pressure is 0.6 atmospheric pressure, and vapo(u)rizing temperature is 70 DEG C, and obtained product is
D- limonene.
Saponin(e derives from soapberry extract, the production method of soapberry extract are as follows: by soapberry deionized water
11h is impregnated, breaks into powder after drying to constant weight, using Soxhlet extraction, after 200min, through supercooling, filtering, centrifuge separation, dense
Contracting, obtains sapindoside.
Tea Saponin is tea seed extract, the production method of the tea seed extract are as follows: tea seed is polished into powder, using Soxhlet
It extracts, after 200min, cooling, filtering, is concentrated to get Tea Saponin centrifuge separation.
The production method of the dish washing liquid are as follows: thickener is added to the water to and is added cosolvent, it after mixing evenly, will be other
Raw material is added in mixed liquor, and heating stirring is uniform, after cooling.
Example IV
A kind of dish washing liquid is present embodiments provided, the ingredient of the dish washing liquid is as follows:
Table 4: dish washing liquid component list (unit: weight %)
Wherein D- limonene derives from shaddock bark extract and pomelo peel extracting solution, in which:
The production method of pomelo peel extracting solution are as follows: pomelo peel is cleaned and crushed, is soaked with ethyl alcohol and deionized water mixed liquor
0.5h is steeped, after decocting 135min, through supercooling, filtering, extraction, obtains pomelo peel extracting solution；Wherein ethyl alcohol accounting is in mixed liquor
20%.
D- limonene content in pomelo peel extracting solution is 5~10% or so, except the D- limonene in pomelo peel extracting solution
Content, the D- limonene in dish washing liquid derive from shaddock bark extract, the production method of the shaddock bark extract are as follows: by fresh shaddock
Sub- skin is cleaned and is crushed to 30 mesh and is put into extraction vessel, is added distilled water by solid-liquid ratio 1:5, the 1%NaCl of addition water weight, directly
Row extraction by steam distillation is tapped into, being basically unchanged to oil reservoir height can stop reacting；Oil-yielding stratum is separated after being then allowed to stand, it will
Oil reservoir is transferred to progress 0.09MPa vacuum distillation in the round-bottomed flask of Rotary Evaporators, and collecting 83~88 DEG C of product of distillation is D-
Limonene；
Saponin(e derives from soapberry extract, the production method of soapberry extract are as follows: by soapberry deionized water
10h is impregnated, breaks into powder after drying to constant weight, using Soxhlet extraction, after 240min, through supercooling, filtering, centrifuge separation, dense
Contracting, obtains sapindoside.
Tea Saponin is tea seed extract, the production method of the tea seed extract are as follows: tea seed is polished into powder, using Soxhlet
It extracts, after 240min, cooling, filtering, is concentrated to get Tea Saponin centrifuge separation.
The production method of the dish washing liquid are as follows: thickener is added to the water to and is added cosolvent, it after mixing evenly, will be other
Raw material is added in mixed liquor, and heating stirring is uniform, after cooling.
Embodiment five
A kind of dish washing liquid is present embodiments provided, the ingredient of the dish washing liquid is as follows:
Table 5: dish washing liquid component list (unit: weight %)
Wherein D- limonene derives from shaddock bark extract and pomelo peel extracting solution, in which:
The production method of pomelo peel extracting solution are as follows: pomelo peel is cleaned and crushed, is soaked with ethyl alcohol and deionized water mixed liquor
1h is steeped, after decocting 270min, through supercooling, filtering, extraction, obtains pomelo peel extracting solution；Wherein ethyl alcohol accounting is in mixed liquor
30%.
D- limonene content in pomelo peel extracting solution is 5~10% or so, except the D- limonene in pomelo peel extracting solution
Content, the D- limonene in dish washing liquid derive from shaddock bark extract, the production method of the shaddock bark extract are as follows: by fresh shaddock
Sub- skin is cleaned and is crushed to 70 mesh and is put into extraction vessel, is added distilled water by solid-liquid ratio 1:5, the 3%NaCl of addition water weight, directly
Row extraction by steam distillation is tapped into, being basically unchanged to oil reservoir height can stop reacting；Oil-yielding stratum is separated after being then allowed to stand, it will
Oil reservoir is transferred to progress 0.09MPa vacuum distillation in the round-bottomed flask of Rotary Evaporators, and collecting 88 DEG C of product of distillation is D- lemon
Alkene；
Saponin(e derives from soapberry extract, the production method of soapberry extract are as follows: by soapberry deionized water
10h is impregnated, breaks into powder after drying to constant weight, using Soxhlet extraction, after 120min, through supercooling, filtering, centrifuge separation, dense
Contracting, obtains sapindoside.
Tea Saponin is tea seed extract, the production method of the tea seed extract are as follows: tea seed is polished into powder, using Soxhlet
It extracts, after 120min, cooling, filtering, is concentrated to get Tea Saponin centrifuge separation.
The production method of the dish washing liquid are as follows: thickener is added to the water to and is added cosolvent, it after mixing evenly, will be other
Raw material is added in mixed liquor, and heating stirring is uniform, after cooling.
Embodiment six
A kind of dish washing liquid is present embodiments provided, the ingredient of the dish washing liquid is as follows:
Table 6: dish washing liquid component list (unit: weight %)
Wherein D- limonene derives from shaddock bark extract and pomelo peel extracting solution, in which:
The production method of pomelo peel extracting solution are as follows: pomelo peel is cleaned and crushed, is soaked with ethyl alcohol and deionized water mixed liquor
0.8h is steeped, after decocting 200min, through supercooling, filtering, extraction, obtains pomelo peel extracting solution；Wherein ethyl alcohol accounting is in mixed liquor
25%.
D- limonene content in pomelo peel extracting solution is 5~10% or so, except the D- limonene in pomelo peel extracting solution
Content, the D- limonene in dish washing liquid derive from shaddock bark extract, the production method of the shaddock bark extract are as follows: by fresh shaddock
Sub- skin is cleaned and is crushed to 60 mesh and is put into extraction vessel, is added distilled water by solid-liquid ratio 1:5, the 2%NaCl of addition water weight, directly
Row extraction by steam distillation is tapped into, being basically unchanged to oil reservoir height can stop reacting；Oil-yielding stratum is separated after being then allowed to stand, it will
Oil reservoir is transferred to progress 0.09MPa vacuum distillation in the round-bottomed flask of Rotary Evaporators, and collecting 83~88 DEG C of product of distillation is D-
Limonene；
Saponin(e derives from soapberry extract, the production method of soapberry extract are as follows: by soapberry deionized water
11h is impregnated, breaks into powder after drying to constant weight, using Soxhlet extraction, after 200min, through supercooling, filtering, centrifuge separation, dense
Contracting, obtains sapindoside.
Tea Saponin is tea seed extract, the production method of the tea seed extract are as follows: tea seed is polished into powder, using Soxhlet
It extracts, after 200min, cooling, filtering, is concentrated to get Tea Saponin centrifuge separation.
The production method of the dish washing liquid are as follows: thickener is added to the water to and is added cosolvent, it after mixing evenly, will be other
Raw material is added in mixed liquor, and heating stirring is uniform, after cooling.
Embodiment seven
A kind of dish washing liquid is present embodiments provided, the ingredient of the dish washing liquid is as follows:
Table 7: dish washing liquid component list (unit: weight %)
Wherein D- limonene derives from shaddock bark extract and pomelo peel extracting solution, in which:
The production method of pomelo peel extracting solution are as follows: pomelo peel is cleaned and crushed, is soaked with ethyl alcohol and deionized water mixed liquor
0.5h is steeped, after decocting 135min, through supercooling, filtering, extraction, obtains pomelo peel extracting solution；Wherein ethyl alcohol accounting is in mixed liquor
20%.
D- limonene content in pomelo peel extracting solution is 5~10% or so, except the D- limonene in pomelo peel extracting solution
Content, the D- limonene in dish washing liquid derive from shaddock bark extract, the production method of the shaddock bark extract are as follows: by pomelo peel
Crush and be put into extraction vessel, according to solid-to-liquid ratio 1:5 ratio be added ethanol solution, 20KHZ ultrasonication 300min, from
The isolated supernatant of the heart, addition volume be 30% distilled water, stir and be cooled to -3 DEG C, then -10 DEG C at a temperature of it is cold
Hide 10h, after filtrate is obtained by filtration at -10 DEG C, finally filtrate is evaporated under reduced pressure, pressure be 0.8 atmospheric pressure, vapo(u)rizing temperature
It is 75 DEG C, obtained product is D- limonene.
Saponin(e derives from soapberry extract, the production method of soapberry extract are as follows: by soapberry deionized water
10h is impregnated, breaks into powder after drying to constant weight, using Soxhlet extraction, after 240min, through supercooling, filtering, centrifuge separation, dense
Contracting, obtains sapindoside.
Tea Saponin is tea seed extract, the production method of the tea seed extract are as follows: tea seed is polished into powder, using Soxhlet
It extracts, after 120min, cooling, filtering, is concentrated to get Tea Saponin centrifuge separation.
The production method of the dish washing liquid are as follows: thickener is added to the water to and is added cosolvent, it after mixing evenly, will be other
Raw material is added in mixed liquor, and heating stirring is uniform, after cooling.
Embodiment eight
A kind of dish washing liquid is present embodiments provided, the ingredient of the dish washing liquid is as follows:
Table 8: dish washing liquid component list (unit: weight %)
Wherein D- limonene derives from shaddock bark extract and pomelo peel extracting solution, in which:
The production method of pomelo peel extracting solution are as follows: pomelo peel is cleaned and crushed, is soaked with ethyl alcohol and deionized water mixed liquor
1h is steeped, after decocting 270min, through supercooling, filtering, extraction, obtains pomelo peel extracting solution；Wherein ethyl alcohol accounting is in mixed liquor
30%.
D- limonene content in pomelo peel extracting solution is 5~10% or so, except the D- limonene in pomelo peel extracting solution
Content, the D- limonene in dish washing liquid derive from shaddock bark extract, the production method of the shaddock bark extract are as follows: by pomelo peel
Crush and be put into extraction vessel, according to solid-to-liquid ratio 1:5 ratio be added ethanol solution, 30KHZ ultrasonication 10min, from
The isolated supernatant of the heart, addition volume be 20% distilled water, stir and be cooled to -8 DEG C, then -20 DEG C at a temperature of it is cold
Hide 1h, after filtrate is obtained by filtration at -20 DEG C, finally filtrate is evaporated under reduced pressure, pressure be 0.5 atmospheric pressure, vapo(u)rizing temperature
It is 65 DEG C, obtained product is D- limonene.
Saponin(e derives from soapberry extract, the production method of soapberry extract are as follows: by soapberry deionized water
10h is impregnated, breaks into powder after drying to constant weight, using Soxhlet extraction, after 240min, through supercooling, filtering, centrifuge separation, dense
Contracting, obtains sapindoside.
Tea Saponin is tea seed extract, the production method of the tea seed extract are as follows: tea seed is polished into powder, using Soxhlet
It extracts, after 240min, cooling, filtering, is concentrated to get Tea Saponin centrifuge separation.
The production method of the dish washing liquid are as follows: thickener is added to the water to and is added cosolvent, it after mixing evenly, will be other
Raw material is added in mixed liquor, and heating stirring is uniform, after cooling.
Embodiment nine
A kind of dish washing liquid is present embodiments provided, the ingredient of the dish washing liquid is as follows:
Table 9: dish washing liquid component list (unit: weight %)
Wherein D- limonene derives from shaddock bark extract and pomelo peel extracting solution, in which:
The production method of pomelo peel extracting solution are as follows: pomelo peel is cleaned and crushed, is soaked with ethyl alcohol and deionized water mixed liquor
0.8h is steeped, after decocting 200min, through supercooling, filtering, extraction, obtains pomelo peel extracting solution；Wherein ethyl alcohol accounting is in mixed liquor
25%.
D- limonene content in pomelo peel extracting solution is 5~10% or so, except the D- limonene in pomelo peel extracting solution
Content, the D- limonene in dish washing liquid derive from shaddock bark extract, the production method of the shaddock bark extract are as follows: by pomelo peel
Crush and be put into extraction vessel, according to solid-to-liquid ratio 1:5 ratio be added ethanol solution, 25KHZ ultrasonication 100min, from
The isolated supernatant of the heart, addition volume be 25% distilled water, stir and be cooled to -5 DEG C, then -15 DEG C at a temperature of it is cold
Hide 6h, after filtrate is obtained by filtration at -15 DEG C, finally filtrate is evaporated under reduced pressure, pressure be 0.6 atmospheric pressure, vapo(u)rizing temperature
It is 70 DEG C, obtained product is D- limonene.
Saponin(e derives from soapberry extract, the production method of soapberry extract are as follows: by soapberry deionized water
11h is impregnated, breaks into powder after drying to constant weight, using Soxhlet extraction, after 200min, through supercooling, filtering, centrifuge separation, dense
Contracting, obtains sapindoside.
Tea Saponin is tea seed extract, the production method of the tea seed extract are as follows: tea seed is polished into powder, using Soxhlet
It extracts, after 200min, cooling, filtering, is concentrated to get Tea Saponin centrifuge separation.
The production method of the dish washing liquid are as follows: thickener is added to the water to and is added cosolvent, it after mixing evenly, will be other
Raw material is added in mixed liquor, and heating stirring is uniform, after cooling.
Simultaneously in order to prove technical effect of the invention, the present invention also provides following tests examples:
Test material: embodiment one~nine selects city respectively marked as A1, A2, A3, A4, A5, A6, A7, A8, A9
The carving board dish washing liquid sold is as reference examples B1, and the clean medicinal powder for selecting patent CN105385515A technology to produce is as reference examples
B2；
1, active matter content measures
1) reagent: chloroform (GB/T 682) acetone (GB/T 682)
2) instrument: Soxhlet extractor, 250ml；Beaker, 100ml；Graduated cylinder, 50ml；Nutsch filter, 500ml；Glass filtration leakage
Bucket, G440ml；Glass triangle funnel, Φ 5cm；
3) test procedure
Safety measure: chloroform high volatility and toxic carries out in the sub- vent cabinet of operating process.
Weighing homogeneous sample 2g, (title standard in beaker, is set in (105 ± 2) DEG C drying box, is taken out after 2h to 0.001g), cold
But to room temperature, addition 50ml chloroform is placed in heating in 50 DEG C of water-baths and is allowed to be completely dissolved, beaker is removed and is cooled to room temperature
Standing sedimentation is toppled over supernatant to glass filtration funnel and is filtered, and greenery are collected into bottle,suction, then with the 40 of warm~
It washes repeatedly in 50 DEG C of trichlorine the Sino-Japanese War years and filters three times, use 20ml chloroform every time.
Chloroform soln is transferred in the bottom bottle of constant weight by bottle,suction by triangular funnel, with the trichlorine warmed on a small quantity
Methane shifts dissolved matter completely, and bottom bottle is connected recycling design on the water-bath of Soxhlet extractor, is evaporated to bottom bottle content
When, add 3ml acetone, after acetone evaporating completely, bottom bottle is put into (105 ± 2) DEG C drying box and dries 2h taking-up, is placed on drier
Interior cooling 30min, weighing.
4) result calculates:
Active matter content (%)=m1/m×100；
Wherein m1Indicate chloroform dissolved matter, g；M indicates the quality of sample, g.
The activity substance content of detection such as table 10:
Table 10: activity substance content (%)
| Test object | Activity substance content (%) |
| GB9985-2000 standard | ≥15 |
| A1 | 35 |
| A2 | 29 |
| A3 | 35 |
| A4 | 36 |
| A5 | 29 |
| A6 | 37 |
| A7 | 38 |
| A8 | 31 |
| A9 | 33 |
| B1 | 21 |
| B2 | 8 |
Measurement result shows that the activity substance content of dish washing liquid provided by the invention is higher than carving board dish washing liquid and documents
1 activity substance content.
2, detergency measures
It goes oil cut rate method to carry out detergency test to test object according to international GB9985-2000, obtains result such as 11 institute of table
Show:
Table 11: detergency test data
By above-mentioned data, it can be concluded that, the detergency of dish washing liquid provided by the invention is apparently higher than the existing carving of national standard
The clean medicinal powder that board dish washing liquid and documents 1 produce.
3, bactericidal effect is tested
Material is tested with the dilution proportion that material ratio is 1:10, then by 106The bacterium of cfu/ml is put into diluted test
Its sterilizing rate is detected in material, after 3h, result such as the following table 12:
Table 12: bactericidal property test result
As can be seen from Table 12, the dish washing liquid being prepared has good bactericidal effect, with 106The bacterium of cfu/ml
After contacting 3h, 99.9% is all larger than to the sterilizing rate of Escherichia coli, staphylococcus aureus, pseudomonas aeruginosa, hence it is evident that excellent
In the cleaning medicinal powder of carving board dish washing liquid and documents 1.
4, Degrading experiment
1) according to the content of " 1, active matter content measurement " measurement surfactant.
2) prepared by activated sludge, takes sanitary sewage to settle well sludge 800-1000g, is diluted in three times with 2~3L of water, stirs
It stands 10min to filter with double gauze, sewage is greyish white or yellowish-brown by blacking after being aerated for 24 hours, and mass fraction 4% is added and lives
The GB nutrient solution of sewage, continue to be aerated the quiet inspection of 2h it is primary, if as a result campanularian, follow fine worm, lid worm, Zoothamnium, the solely biologies such as contracting worm
It is a large amount of to occur (>=108A/L) stop aeration；
3) suspended matter determination of activated sludge: measuring biological sludge solution 100mL, after 30min is settled that upper layer is molten
Liquid inclines, and screening is dried in 105 DEG C of baking ovens, weighed after cooling, led to by fast grade filter paper filtering of the sediment Jing Guo known quality
The mass concentration that activated sludge suspended matter is calculated is crossed, the activated sludge that 15g/L is then made uses liquid；
4) test material: being diluted to the solution of 1g/L by culture experiment, is measured 500ml nutrient solution in 1L triangular flask, is added
Enter 1g/L test material 15mL, adds the activated sludge of 15g/L using liquid 5mL, covered after shaking up, 25 DEG C, 200r/min perseverance
72h is vibrated in warm shaking table；
5) surface-active contents of measurement treated test material, then by the drop of Conversion Calculation surfactant
Xie Du.
6) biological degradability of surfactant, as shown in table 13.
Table 13: the biological degradability of surfactant
The degree of degradation that can be seen that dish washing liquid provided by the invention upper table is similar with B2 made of pure herbal medicine, compares city
The degree of degradation for the carving board dish washing liquid sold is high, and degradable in four days rear surface activating agents of test, illustrates produced by the invention
Its degradability of dish washing liquid is strong and degradation speed is fast.
Claims (6)
1. a kind of dish washing liquid, which contains the surfactant of 28.1~51 weight %, which is D- lemon
Alkene, saponin(e and Tea Saponin；
The D- limonene derives from shaddock bark extract, and the saponin(e derives from soapberry extract, the tea soap
Usually it is derived from tea seed extract；
The production method of the shaddock bark extract are as follows: one of alcohol extracting method, water extraction, ethanol extract from water precipitation, wherein
The alcohol extracting method are as follows: pomelo peel is crushed and is put into extraction vessel, it is molten that ethyl alcohol is added according to the ratio of solid-to-liquid ratio 1:5
Liquid, 20~30KHZ, 10~300min of ultrasonication, is centrifugally separating to obtain supernatant, is then evaporated under reduced pressure, and pressure is
0.5~0.8 atmospheric pressure, vapo(u)rizing temperature are 65~75 DEG C, and obtained product is D- limonene；
The water extraction are as follows: fresh grapefruit skin is cleaned and is crushed to 30~70 mesh and is put into extraction vessel, is added by solid-liquid ratio 1:5
Enter distilled water, 1~3%NaCl of water weight is added, directly progress extraction by steam distillation, is basically unchanged i.e. to oil reservoir height
It can stop reacting；Oil-yielding stratum is separated after being then allowed to stand, and oil reservoir is transferred in the round-bottomed flask of Rotary Evaporators and carries out 0.09MPa
Vacuum distillation, collecting 83~88 DEG C of product of distillation is D- limonene；
The ethanol extract from water precipitation are as follows: pomelo peel is crushed and is put into extraction vessel, second is added according to the ratio of solid-to-liquid ratio 1:5
Alcoholic solution, 20~30KHZ, 10~300min of ultrasonication are centrifugally separating to obtain supernatant, and it is 20~30% steamings that volume, which is added,
Distilled water stirs and is cooled to -8~-3 DEG C, then -20~-10 DEG C at a temperature of refrigerate 1~10h, after in -20~-10 DEG C of mistakes
Filter obtains filtrate, is finally evaporated under reduced pressure filtrate, and pressure is 0.5~0.8 atmospheric pressure, and vapo(u)rizing temperature is 65~75 DEG C,
Obtained product is D- limonene；
Cosolvent of the dish washing liquid also containing 35~40 weight %, the cosolvent are the mixture of ethyl alcohol and glycerol, ratio
For 1:10~13.
2. dish washing liquid as described in claim 1, it is characterised in that: in the dish washing liquid containing 0.1~3 weight %D- limonene,
15~30 weight % saponin(es, 13~18 weight % Tea Saponins.
3. dish washing liquid as claimed in claim 1 or 2, it is characterised in that: pomelo peel of the dish washing liquid also containing 1~6 weight %
Extracting solution, the D- limonene derive from shaddock bark extract and pomelo peel extracting solution.
4. dish washing liquid as claimed in claim 1 or 2, it is characterised in that: thickener of the dish washing liquid also containing 2~6 weight %,
The thickener is at least one of edible level sodium carboxymethylcellulose, sodium alginate, xanthan gum, gelatin.
5. dish washing liquid as claimed in claim 1 or 2, it is characterised in that: stabilizer of the dish washing liquid also containing 2~6 weight %,
The stabilizer is at least one of sodium chloride, potassium chloride, ammonium chloride.
6. dish washing liquid as claimed in claim 3, it is characterised in that: the production method of the pomelo peel extracting solution are as follows: by shaddock
Sub- skin is cleaned and is crushed, with ethyl alcohol and deionized water 0.5~1h of mixed liquid dipping, after decocting 135~270min, through supercooling,
Filtering, extraction, obtain pomelo peel extracting solution；Wherein ethyl alcohol accounting is 20~30% in mixed liquor.
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| CN107400567A (en) * | 2017-08-18 | 2017-11-28 | 广西钱隆投资管理有限公司 | A kind of multipurpose liquid detergent and preparation method thereof |
| CN107794140A (en) * | 2017-10-19 | 2018-03-13 | 谭志华 | A kind of fruits and vegetables cleaning agent and preparation method thereof |
| CN109735395A (en) * | 2019-02-27 | 2019-05-10 | 福建果宝生物科技有限公司 | A kind of cleaning solution of edible plant extract |
| CN110628517A (en) * | 2019-09-27 | 2019-12-31 | 佛山市护宝生物环保科技有限公司 | Natural edible detergent and preparation method thereof |
| CN111893001A (en) * | 2020-06-15 | 2020-11-06 | 安徽共盈日化有限公司 | Lemon-flavor detergent and packaging container thereof |
| CN111748417A (en) * | 2020-07-31 | 2020-10-09 | 西安医学院 | Experimental apparatus cleaning fluid for cell biology and preparation method thereof |
| CN112126533A (en) * | 2020-09-28 | 2020-12-25 | 湖南雪峰源山茶油科技有限公司 | Preparation method of tea seed cake cleaning agent |
| CN115568469A (en) * | 2022-10-11 | 2023-01-06 | 湖南省林业科学院 | Compound water zooplankton inhibitor of tea saponin, preparation method and application thereof |
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| CN1223295A (en) * | 1998-01-12 | 1999-07-21 | 李平生 | Vegetable detergent |
| CN102021086A (en) * | 2009-09-17 | 2011-04-20 | 中国林业科学研究院亚热带林业研究所 | Natural plant detergent and preparation method thereof |
| CN105542985A (en) * | 2015-12-16 | 2016-05-04 | 梁品乾 | Natural tea seed washing lotion and preparation method thereof |
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2017
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1223295A (en) * | 1998-01-12 | 1999-07-21 | 李平生 | Vegetable detergent |
| CN102021086A (en) * | 2009-09-17 | 2011-04-20 | 中国林业科学研究院亚热带林业研究所 | Natural plant detergent and preparation method thereof |
| CN105542985A (en) * | 2015-12-16 | 2016-05-04 | 梁品乾 | Natural tea seed washing lotion and preparation method thereof |
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