CN106935596A - A kind of preparation method of flexible base board - Google Patents

A kind of preparation method of flexible base board Download PDF

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Publication number
CN106935596A
CN106935596A CN201710098365.6A CN201710098365A CN106935596A CN 106935596 A CN106935596 A CN 106935596A CN 201710098365 A CN201710098365 A CN 201710098365A CN 106935596 A CN106935596 A CN 106935596A
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China
Prior art keywords
flexible substrates
glass substrate
flexible
edge
fixed
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CN201710098365.6A
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Chinese (zh)
Inventor
王选芸
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Wuhan China Star Optoelectronics Technology Co Ltd
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Wuhan China Star Optoelectronics Technology Co Ltd
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Priority to CN201710098365.6A priority Critical patent/CN106935596A/en
Priority to PCT/CN2017/076599 priority patent/WO2018152889A1/en
Publication of CN106935596A publication Critical patent/CN106935596A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
    • H01L27/1214Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
    • H01L27/1218Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs with a particular composition or structure of the substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/7806Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices involving the separation of the active layers from a substrate
    • H01L21/7813Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices involving the separation of the active layers from a substrate leaving a reusable substrate, e.g. epitaxial lift off
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
    • H01L27/1214Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
    • H01L27/1259Multistep manufacturing methods
    • H01L27/1262Multistep manufacturing methods with a particular formation, treatment or coating of the substrate

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

The invention discloses a kind of preparation method of flexible base board, including:Flexible substrates are formed on the glass substrate;The flexible substrates are mutually peeled off with the glass substrate;The edge of the flexible substrates is fixed on the glass substrate;Residual substrate processing procedure is completed in the flexible substrates;The flexible substrates are cut along desired trajectory, to obtain the flexible base board;Wherein, the desired trajectory is located at the inside in the region surrounded by the edge.The method can effectively discharge produced membrane stress in flexible substrates film forming processing procedure so that the flexible base board being made will not produce warpage, enhance the reliability of flexible base board and corresponding flexible device.

Description

A kind of preparation method of flexible base board
Technical field
The invention belongs to display technology field, more particularly to a kind of preparation method of flexible base board.
Background technology
So-called flexible base board, is a kind of board structure that device is prepared on the substrate surface that flexible material is constituted.With The continuous renewal of Display Technique and development, the flexible flexible device being made of flexible base board are expected to turn into photoelectricity of future generation The main flow equipment of sub- device.Such as display, chip, circuit, power supply, sensor flexible device, they can not only realize passing The irrealizable function of system opto-electronic device institute, while having the advantage of low cost, also helps improvement Consumer's Experience.
Existing flexible base board has that stress is difficult release.Such as conventional flexible AMOLED devices, use at present Base material be generally polyimides (PI) or PEN (PEN), in the FEOL of flexible AMOLED In need to carry out high-temperature process to flexible substrates, because the thermal expansion coefficient difference between base material and glass is larger, therefore, Thermal stress can be produced in high temperature process., it is necessary to by flexible base board after manufacturing process on the whole plates for completing flexible base board Mutually peeled off with glass substrate, flexible base board can discharge thermal stress, in turn result in the curling of flexible base board, can also be to flexibility when serious The performance of the devices such as the thin film transistor (TFT) on substrate is affected greatly.
Therefore, need a kind of method of proposition badly, between releasing such glass substrate and flexible substrates due to thermal expansion coefficient difference Caused membrane stress, improves the buckle resistance energy of flexible base board.
The content of the invention
One of technical problems to be solved by the invention be propose a kind of method with releasing such glass substrate and flexible substrates it Between membrane stress caused by thermal expansion coefficient difference.
In order to solve the above-mentioned technical problem, embodiments herein provide firstly a kind of preparation method of flexible base board, Including:Flexible substrates are formed on the glass substrate;The flexible substrates are mutually peeled off with the glass substrate;By the flexible base The edge at bottom is fixed on the glass substrate;Residual substrate processing procedure is completed in the flexible substrates;Along desired trajectory to institute State flexible substrates to be cut, to obtain the flexible base board;Wherein, the desired trajectory is located at the area surrounded by the edge The inside in domain.
Preferably, the edge by the flexible substrates is fixed on the glass substrate, is specifically included:Will be described soft Property substrate is laid on the surface of the glass substrate;In the fixed material of edge coating of the flexible substrates, and make described Fixed material is contacted with the surface of the glass substrate;The fixed material is processed, so that the side of the flexible substrates Edge is fixed on the glass substrate.
Preferably, the edge by the flexible substrates is fixed on the glass substrate, is specifically included:In the glass Fixed material is coated on glass substrate, the coating position of the fixed material corresponds to the edge of the flexible substrates;Will be described soft Property substrate is laid on the surface of the glass substrate, makes the fixed material completely by the edges cover of the flexible substrates; The fixed material is processed, so that the edge of the flexible substrates is fixed on the glass substrate.
Preferably, it is non-volatile within the temperature range of the fixed material is at 450 DEG C or more than 450 DEG C.
Preferably, the fixed material is identical with the material of the flexible substrates.
Preferably, the fixed material includes polyimides or PEN.
Preferably, the fixed material is processed, so that the edge of the flexible substrates is fixed on the glass base On plate, including:Carry out hot setting to the fixed material within the temperature range of 200-400 DEG C, the hot setting is held The continuous time is 5-10min.
Preferably, the flexible substrates are mutually peeled off with the glass substrate using laser method.
Preferably, the energy range of the laser is 300-500mJ/cm2, the scanning overlapping range of laser is 20-60%.
Preferably, the minimum range between the desired trajectory and the edge keeps the skew of 5-10mm.
Compared with prior art, one or more embodiments in such scheme can have the following advantages that or beneficial effect Really:
In the manufacturing process of flexible base board, by first mutually peeling off flexible substrates with glass substrate, then make flexible substrates The mode mutually fixed with glass substrate of edge, effectively discharge produced membrane stress in flexible substrates film forming processing procedure, So that the flexible base board being made will not produce warpage, the reliability of flexible base board and corresponding flexible device is improve.
Other advantages of the invention, target, and feature will be illustrated in the following description to a certain extent, and And to a certain extent, based on being will be apparent to those skilled in the art to investigating hereafter, Huo Zheke To be instructed from the practice of the present invention.Target of the invention and other advantages can be wanted by following specification, right Specifically noted structure in book, and accompanying drawing is asked to realize and obtain.
Brief description of the drawings
Accompanying drawing is used for providing to the technical scheme of the application or further understanding for prior art, and constitutes specification A part.Wherein, the accompanying drawing of expression the embodiment of the present application is used to explain the technical side of the application together with embodiments herein Case, but do not constitute the limitation to technical scheme.
Fig. 1 is the schematic flow sheet of the preparation method of the flexible base board according to first embodiment of the invention;
Fig. 2 a- Fig. 2 f are the process chart of the preparation method of the flexible base board according to second embodiment of the invention;
Fig. 3 is the top view of Fig. 2 f;
Fig. 4 a- Fig. 4 f are the process chart of the preparation method of the flexible base board according to third embodiment of the invention;
Fig. 5 is the top view of Fig. 4 c.
Specific embodiment
Describe embodiments of the present invention in detail below with reference to drawings and Examples, how the present invention is applied whereby Technological means solves technical problem, and reaches the implementation process of relevant art effect and can fully understand and implement according to this.This Shen Each feature that please be in embodiment and embodiment, can be combined with each other under the premise of not colliding, the technical scheme for being formed Within protection scope of the present invention.
First embodiment:
As shown in figure 1, the preparation method of flexible base board according to a first embodiment of the present invention specifically includes following steps:
Step S110, flexible substrates are formed on the glass substrate.
Step S120, flexible substrates are mutually peeled off with glass substrate.
Step S130, the edge of flexible substrates is fixed on the glass substrate.
Step S140, on a flexible substrate completion residual substrate processing procedure.
Step S150, flexible substrates are cut along desired trajectory, to obtain flexible base board.
Specifically, in step s 110, one layer of flexible material is first coated on the surface of the glass substrate of hard, for making The substrate of standby flexible base board.The flexible material for being used can be flexible material commonly used in the prior art, for example, can be poly- Polyimide PI or PEN PEN.
In a specific embodiment of the invention, flexible material is coated and toasted by the way of coating. Making technology parameter could be arranged to, and carry out hot setting to flexible material within the temperature range of 120-450 DEG C, and high temperature is solid The duration of change is 30-60min, and programming rate maintains 4-7 DEG C/min.The flexible substrates thickness of dry film of formation is 10-20 μ m。
In the step s 120, flexible substrates and glass substrate are completely exfoliated (lift-off).
Lift-off manufacturing process is that glass substrate is contacted with flexible substrates using the means with high-energy-density The flexible substrates of interface (atom bed boundary) carry out ablation, cause glass substrate to be separated from each other with flexible substrates.
In the present embodiment, specifically flexible substrates can mutually be peeled off with glass substrate using laser method.To soft Property substrate and glass substrate when being peeled off, the energy range of laser is generally 300-500mJ/cm2, the scanning overlap model of laser It is 20-60% to enclose.
In step s 130, it should be noted that flexible substrates is mutually fixed with glass substrate in edge, it is flexible Other are used to form metal level and the part of insulating barrier remains in that the state being separated from each other with glass substrate in substrate.
In step S140, described residual substrate processing procedure refer in addition to the forming step of flexible substrates remaining be used for The processing step of metal level and insulating barrier is formed on a flexible substrate.Formation, the data wire of thin film transistor (TFT) can for example be included And the formation and the operation such as formation of each insulating barrier of scan line.It is not limited in the present embodiment, can be according to reality Needs are implemented.
After step S140 is completed, in the flexible substrates for carrying out edge fixation with glass substrate, actually formed Constitute the entire infrastructure of flexible base board.
In step S150, the inside in the region that the edge that described desired trajectory is located at above-mentioned fixation is surrounded, and should ensure that Minimum range between the desired trajectory and the edge of above-mentioned fixation maintains the side-play amount of 5-10mm, in order to eliminate the thin of residual Membrane stress.
In embodiments of the present invention, flexible substrates are fixed on the surface of glass substrate in the way of edge is fixed, by It is to be laid in glass baseplate surface by way of edge is fixed in flexible substrates, therefore implements residual substrate on a flexible substrate During processing procedure, will not be influenceed by thermal coefficient of expansion.Finally after the completion of processing procedure, the flexible substrates fixed with edge are cut Cut, stressless flexible device can be obtained.
The preparation method of the embodiment of the present invention can be effectively discharged in existing flexible base board processing procedure, due to flexible substrates and glass The difference of the thermal coefficient of expansion between glass substrate and the stress that produces, improve the stability of flexible product.
Second embodiment:
In the present embodiment, it is further provided method on the glass substrate is fixed at a kind of edge by flexible substrates, Comprise the following steps:
Step S1301, flexible substrates are laid on the surface of glass substrate.
Step S1302, the fixed material of edge coating in flexible substrates, and make to fix the surface of material and glass substrate Contact.
Step S1303, fixed material is processed, so that the edge of flexible substrates is fixed on the glass substrate.
Above-mentioned various method steps are described in detail with reference to Fig. 2 a- Fig. 2 f.
Fig. 2 a- Fig. 2 f give complete flexible base board processing procedure, and as shown in Figure 2 a, expression is to be formed on the glass substrate The manufacturing process of flexible substrates.1 expression is glass substrate, 2 tools for being flexible substrates, forming flexible substrates 2 for representing in figure Body implementation method may be referred to the step S110 in first embodiment.
As shown in Figure 2 b, expression is the manufacturing process that flexible substrates 2 are mutually peeled off with glass substrate 1.As can be seen that , it is necessary to make laser be shone from the side of glass substrate 1 when being peeled off to flexible substrates 2 and glass substrate 1 using laser method Penetrate the contact interface of flexible substrates 2 and glass substrate 1.
The flexible substrates 2 obtained after stripping are directly laid on the surface of glass substrate 1.
As shown in Figure 2 c, one week fixed material 3 is coated in the edge of flexible substrates 2, and makes to fix material 3 and glass base The surface contact of plate 1.
In a specific embodiment, fixed material 3 needs to meet being heated to 450 DEG C, or is heated to 450 DEG C During the temperature of the above, still ensure that without volatility.Because, it is necessary to carry out height to fixed material 3 in subsequent treatment Temperature treatment, if fixed material has volatility, it is likely that polluted to flexible substrates 2.
In another specific embodiment, in order to avoid fixed material 3 produces pollution to flexible substrates 2, can also select Select and fix material with the material identical of flexible substrates 2.For example, when the material of flexible substrates 2 is polyimides PI or poly- naphthalenes two During formic acid glycol ester PEN, corresponding fixed material can also select to be PI or PEN.
As shown in Figure 2 d, fixed material is processed.Assuming that have chosen in figure 2 c identical with the material of flexible substrates 2 Fixed material, such as PI or PEN, the PI and PEN of coating are solution shape.The treatment tool to PI or PEN in step S1303 Body includes that carry out hot setting to PI or PEN within the temperature range of 200-400 DEG C, the duration of hot setting is 5- 10min。
Because fixation material 3 is identical with the material of flexible substrates 2, therefore, in figure 2d, it is expressed as flexible substrates 2 and consolidates Determine the structure that material 3 forms an integral type.
Next, as shown in Figure 2 e, residual substrate processing procedure is completed in flexible substrates 2, referring specifically in first embodiment The step of S140.
After residual substrate processing procedure is completed, flexible substrates 2 are cut along desired trajectory, as shown in figure 2f.In Fig. 2 f Dotted line be used to represent the position of line of cut.Top view with reference to shown in Fig. 3, what the rectangular broken line frame in Fig. 3 was represented is desirable Flexible base board size, when being cut along the rectangular broken line frame, what D was indicated in figure 3 is the rectangular broken line frame, and soft Property built-in edge between substrate 2 and glass substrate 1 between minimum range, to ensure that the flexible base board after cutting is not remained Membrane stress, should make the value of D be maintained 5-10mm.
Method on the glass substrate is fixed at the edge by flexible substrates in the embodiment of the present invention, it is only necessary to original soft Property substrate manufacturing process in the step of add the fixed material of coating and fixed material processed (it should be noted that The step of flexible substrates are mutually peeled off with glass substrate belongs to and changes former process sequence, but does not increase new technique actually Step), therefore, do not dramatically increase the operation of existing process processing procedure, it is easy to implement, and the cost of production will not be dramatically increased.
3rd embodiment:
In the present embodiment, there is provided method on the glass substrate is fixed at another edge by flexible substrates, including Following steps:
The fixed material of step S1310, on the glass substrate coating, the coating position of fixed material corresponds to flexible substrates Edge.
Step S1320, flexible substrates are laid on the surface of glass substrate, make to fix material completely by flexible substrates Edges cover.
Step S1330, fixed material is processed, so that the edge of flexible substrates is fixed on the glass substrate.
Above-mentioned steps are illustrated with reference to Fig. 4 a- Fig. 4 f, wherein, Fig. 4 a, Fig. 4 b, Fig. 4 e and Fig. 4 f may refer to Fig. 2 a, Fig. 2 b, Fig. 2 e and Fig. 2 f in second embodiment.
As illustrated in fig. 4 c, after flexible substrates 2 are mutually peeled off with glass substrate 1, flexible substrates 2 from glass substrate 1 are made Remove on surface.Fixed material 3 is coated on the surface of glass substrate 1, the coating position of fixed material 3 corresponds to flexible substrates 2 Edge, may refer to the top view shown in Fig. 5, fixed material 3 surrounds a rectangle corresponding with the edge of flexible substrates 2 Region, and the rectangular area is slightly less than the edge of flexible substrates 2.
Next, as shown in figure 4d, flexible substrates 2 are laid on the surface of glass substrate 1 again.It is readily appreciated that It is that the major part for making flexible substrates 2 falls in the rectangular area surrounded in fixed material 3, while flexible substrates 2 are completely covered Fixed material 3.
In this embodiment, it is preferred to use fix material with the material identical of flexible substrates 2, avoiding between different materials Cross-diffusion produce pollution.
In the embodiment of the present invention, put down in the way of edge is fixed and flexible substrates interfix with glass substrate, therefore Will not be influenceed by thermal coefficient of expansion during processing procedure, be conducive to improving the stability of flexible device.
The preparation method of the flexible base board in the present embodiment can be widely applied in the manufacturing process such as flexible AMOLED.
Although disclosed herein implementation method as above, described content is only to facilitate understanding the present invention and adopting Implementation method, is not limited to the present invention.Any those skilled in the art to which this invention pertains, are not departing from this On the premise of the disclosed spirit and scope of invention, any modification and change can be made in the formal and details implemented, But scope of patent protection of the invention, must be still defined by the scope of which is defined in the appended claims.

Claims (10)

1. a kind of preparation method of flexible base board, including:
Flexible substrates are formed on the glass substrate;
The flexible substrates are mutually peeled off with the glass substrate;
The edge of the flexible substrates is fixed on the glass substrate;
Residual substrate processing procedure is completed in the flexible substrates;
The flexible substrates are cut along desired trajectory, to obtain the flexible base board;
Wherein, the desired trajectory is located at the inside in the region surrounded by the edge.
2. preparation method according to claim 1, it is characterised in that the edge by the flexible substrates is fixed on institute State on glass substrate, specifically include:
The flexible substrates are laid on the surface of the glass substrate;
In the fixed material of edge coating of the flexible substrates, and the fixed material is set to be connect with the surface of the glass substrate Touch;
The fixed material is processed, so that the edge of the flexible substrates is fixed on the glass substrate.
3. preparation method according to claim 1, it is characterised in that the edge by the flexible substrates is fixed on institute State on glass substrate, specifically include:
Fixed material is coated on the glass substrate, the coating position of the fixed material corresponds to the side of the flexible substrates Edge;
The flexible substrates are laid on the surface of the glass substrate, make the fixed material completely by the flexible substrates Edges cover;
The fixed material is processed, so that the edge of the flexible substrates is fixed on the glass substrate.
4. the preparation method according to Claims 2 or 3, it is characterised in that the fixed material is at 450 DEG C or at 450 DEG C It is non-volatile within the temperature range of above.
5. the preparation method according to Claims 2 or 3, it is characterised in that the fixed material and the flexible substrates Material is identical.
6. the preparation method according to Claims 2 or 3, it is characterised in that the fixed material includes polyimides or poly- (ethylene naphthalate).
7. preparation method according to claim 6, it is characterised in that process the fixed material, so that described The edge of flexible substrates is fixed on the glass substrate, including:
Hot setting, the duration of the hot setting are carried out to the fixed material within the temperature range of 200-400 DEG C It is 5-10min.
8. preparation method according to claim 1, it is characterised in that using laser method by the flexible substrates and institute Glass substrate is stated mutually to peel off.
9. preparation method according to claim 8, it is characterised in that the energy range of the laser is 300-500mJ/ cm2, the scanning overlapping range of laser is 20-60%.
10. preparation method according to claim 1, it is characterised in that between the desired trajectory and the edge most Small distance keeps the skew of 5-10mm.
CN201710098365.6A 2017-02-22 2017-02-22 A kind of preparation method of flexible base board Pending CN106935596A (en)

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PCT/CN2017/076599 WO2018152889A1 (en) 2017-02-22 2017-03-14 Preparation method for flexible substrate

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CN110828505A (en) * 2018-07-23 2020-02-21 京东方科技集团股份有限公司 Manufacturing method and manufacturing device of flexible panel
CN110828505B (en) * 2018-07-23 2022-06-07 京东方科技集团股份有限公司 Manufacturing method and manufacturing device of flexible panel
CN110473985A (en) * 2019-08-27 2019-11-19 云谷(固安)科技有限公司 A kind of production method of flexible base board, flexible display panels and flexible base board
CN111613580A (en) * 2020-05-21 2020-09-01 深圳市华星光电半导体显示技术有限公司 Preparation method of flexible substrate and flexible substrate
CN111613580B (en) * 2020-05-21 2023-04-18 深圳市华星光电半导体显示技术有限公司 Preparation method of flexible substrate and flexible substrate

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