CN106928869A - A kind of polyethylene is anti-, drain plate binding agent - Google Patents
A kind of polyethylene is anti-, drain plate binding agent Download PDFInfo
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- CN106928869A CN106928869A CN201710299388.3A CN201710299388A CN106928869A CN 106928869 A CN106928869 A CN 106928869A CN 201710299388 A CN201710299388 A CN 201710299388A CN 106928869 A CN106928869 A CN 106928869A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
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- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of polyethylene is anti-, drain plate binding agent, including following mass fraction component：60 80 parts of deionized water, 3 20 parts of polyvinyl alcohol, 1.6 18 parts of inorganic composite flame retardants, 0.2 1.2 parts of inorganic crosslinking agent, 0.01 0.2 parts of silicone emulsion, 0.2 3 parts of mould inhibitor, 7 10 parts of hydrogenated rosin glyceride, 212 parts of mercapto benzimidazoles, 23 parts of HPMA, 12 parts of magnesium silicate, 0.7 1 parts of hexafluoroacetylacetone etc..Binding agent of the invention is using bark powder as structure reinforcing agent, coordinate high-viscosity polyvinyl alcohol, so that the gel for being formed has the feature of fiber, make gel that there is certain toughness, while finished product viscosity is improved, the toughness of finished product is improve again, and with good fire-retardant and water resistance, and environmental protection.
Description
Technical field
The invention belongs to afforest technical field of drainage, and in particular to a kind of polyethylene is anti-, drain plate binding agent.
Background technology
Anti-, drain bar is to be made circular cone convex by punching press by polystyrene or polyethylene plastic cement base plate to form, circle
The top surface of conuli platform is glued one layer of filtering geotextiles, to prevent dirt particles from passing through, duct is made so as to avoid drainage channel from blocking
Draining is smooth.
Prevent in the prior art, drain bar end face is connected with filter cloth work cloth using general glue, and prevent, drain bar
Other end is laid immediately on building structure layer, if like this anti-, drain bar is damaged, will be to building structure layer
Cause to damage, so as to the situation for causing leak occurs.
The content of the invention
Goal of the invention：The present invention is directed to deficiency of the prior art, proposes that a kind of polyethylene is prevented, drain plate is bonded
Agent, using bark powder as structure reinforcing agent, coordinates high-viscosity polyvinyl alcohol so that the gel of formation has the spy of fiber
Levy, make gel that there is certain toughness, while finished product viscosity is improved, the toughness of finished product is improve again, and with good
Fire-retardant and water resistance, and environmental protection.
Technical scheme：A kind of polyethylene of the present invention is anti-, drain plate binding agent, including following mass fraction
Component：
Deionized water 60-80 parts, polyvinyl alcohol 3-20 parts, inorganic composite flame retardants 1.6-18 parts, inorganic crosslinking agent 0.2-
1.2 parts, silicone emulsion 0.01-0.2 parts, mould inhibitor 0.2-3 parts, hydrogenated rosin glyceride 7-10 parts, 2- mercapto benzene
Parallel imidazoles 1-2 parts, HPMA 2-3 parts, magnesium silicate 1-2 parts, hexafluoroacetylacetone 0.7-1 parts, calcium aluminate 2-3 parts,
0.6-2 parts of 1- hydroxycyclohexyl phenyl ketones, methacrylic acid 0.4-1 parts, biological binding agent 4-7 parts, acrylic acid 1-3
Part, maleic anhydride modified polyethylene 1-2 parts, heterogeneous ten alcohol polyoxyethylene ether 2-3 parts, potassium peroxydisulfate 1-2 parts, methyl acrylate 2-
3 parts, 2-4 parts of polyadipate hexylene glycol ester.
Further, including following mass fraction component：
Deionized water 70-80 parts, polyvinyl alcohol 8-20 parts, inorganic composite flame retardants 3-18 parts, inorganic crosslinking agent 0.5-1.2
Part, silicone emulsion 0.1-0.2 parts, mould inhibitor 1-3 parts, hydrogenated rosin glyceride 8-10 parts, 2- mercapto benzimidazoles
1.5-2 parts, HPMA 2.5-3 parts, magnesium silicate 1.5-2 parts, hexafluoroacetylacetone 0.8-1 parts, calcium aluminate 2.5-3 parts,
1.2-2 parts of 1- hydroxycyclohexyl phenyl ketones, methacrylic acid 0.8-1 parts, biological binding agent 5-7 parts, acrylic acid 2-3
Part, maleic anhydride modified polyethylene 1.5-2 parts, heterogeneous ten alcohol polyoxyethylene ether 2.5-3 parts, potassium peroxydisulfate 1.5-2 parts, acrylic acid
Methyl esters 2.5-3 parts, 3-4 parts of polyadipate hexylene glycol ester.
Further, including following mass fraction component：
75 parts of deionized water, 12 parts of polyvinyl alcohol, 10 parts of inorganic composite flame retardants, 1 part of inorganic crosslinking agent, silicone emulsion
0.15 part, 2 parts of mould inhibitor, 9 parts of hydrogenated rosin glyceride, 1.8 parts of 2- mercaptos benzimidazole, HPMA 2.8
Part, 1.8 parts of magnesium silicate, 0.9 part of hexafluoroacetylacetone, 2.8 parts of calcium aluminate, 1.5 parts of 1- hydroxycyclohexyl phenyl ketones,
0.9 part of methacrylic acid, 6 parts of biological binding agent, 2.5 parts of acrylic acid, 1.8 parts of maleic anhydride modified polyethylene, the alcohol of isomery ten
2.8 parts of APEO, 1.8 parts of potassium peroxydisulfate, 2.8 parts of methyl acrylate, 3.5 parts of polyadipate hexylene glycol ester.
Further, described inorganic composite flame retardants press 1 by APP and zinc sulfate：0.01~0.08
Mass ratio is mixed.
Further, the alcoholysis degree scope of described polyvinyl alcohol is between 40%-99%, its degree of polymerization 500-
Between 2000.
Further, described inorganic crosslinking agent using sodium sulphate, zinc sulfate, boric acid, borax, bichromate, chromic nitrate,
The combination of one or more in the complex compound of chromium, cuprammonium hydroxide or organic titanate.
Further, described mould inhibitor is benzoic acid, Sodium Benzoate, propionic acid and its esters, sorbic acid and its esters, takes off
The group of one or more in acetate hydrogen, citric acid and sodium citrate hydroxybenzoate, sodium Diacetate or dimethyl fumarate
Close.
Further, described biological binding agent is made up of the raw material of following weight parts：
Sodium sulfite 0.4-0.5, structure reinforcing agent 4-5, acetate starch 10-11, propane diols phenylate 4-5, polyacrylamide
Amine 4-6, aluminium citrate 0.7-2, APG 1-2, water soluble phenol resin 1-3, water 180-200；
Polyacrylamide is added in 6-10 times of water, solution is configured to, water soluble phenol resin is added, adjusting PH is
6-8, adds structure reinforcing agent, sodium sulfite, stirs, and obtains liquid a；
Acetate starch, propane diols phenylate are mixed, the 80-90% of remaining water weight is added, mixing is stirred at 60-70 DEG C
10-14 minutes, obtain liquid b；
Remaining each raw material is mixed, is stirred, obtain liquid c；
Liquid a is mixed with liquid b, 300-350 revs/min dispersed with stirring 6-10 minutes, add liquid c, stir rearmounted
Heated at constant temperature 10-12 hours in 80-85 DEG C of water-bath, the biological binding agent is obtained final product；
Further, the preparation method of described structure reinforcing agent is the NaOH that 30-40% will be put into after elm break flour
Soaked 2-3 hours in solution, take out drying.
Beneficial effect：Binding agent of the invention, as structure reinforcing agent, coordinates high-viscosity polyethylene using bark powder
Alcohol so that the gel of formation has the feature of fiber, makes gel have certain toughness, while finished product viscosity is improved, and
The toughness of finished product is improve, and with good fire-retardant and water resistance, and environmental protection.
Specific embodiment
With reference to specific embodiment, the invention will be further described：
Embodiment 1
A kind of polyethylene is anti-, drain plate binding agent, including following mass fraction component：
60 parts of deionized water, 3 parts of polyvinyl alcohol, 1.6 parts of inorganic composite flame retardants, 0.2 part of inorganic crosslinking agent, silicone emulsion
0.01 part, 0.2 part of mould inhibitor, 7 parts of hydrogenated rosin glyceride, 1 part of 2- mercaptos benzimidazole, 2 parts of HPMA,
1 part of magnesium silicate, 0.7 part of hexafluoroacetylacetone, 2 parts of calcium aluminate, 0.6 part of 1- hydroxycyclohexyl phenyl ketones, metering system
0.4 part of acid, 4 parts of biological binding agent, 1 part of acrylic acid, 1 part of maleic anhydride modified polyethylene, heterogeneous ten alcohol polyoxyethylene ether 2
Part, 1 part of potassium peroxydisulfate, 2 parts of methyl acrylate, 2 parts of polyadipate hexylene glycol ester.
As the further optimization of the present embodiment：
Described inorganic composite flame retardants press 1 by APP and zinc sulfate：0.01 mass ratio is mixed.
Between 40%-99%, its degree of polymerization is between 500-2000 for the alcoholysis degree scope of described polyvinyl alcohol.
Described inorganic crosslinking agent uses sodium sulphate.
Described mould inhibitor is benzoic acid.
What described biological binding agent was made up of the raw material of following weight parts：
Sodium sulfite 0.4, structure reinforcing agent 4, acetate starch 10, propane diols phenylate 4, polyacrylamide 4, citric acid
Aluminium 0.7, APG 1, water soluble phenol resin 1, water 180；
Polyacrylamide is added in 6 times of water, solution is configured to, water soluble phenol resin is added, regulation PH is 6-8,
Structure reinforcing agent, sodium sulfite are added, is stirred, obtain liquid a；
Acetate starch, propane diols phenylate are mixed, the 80-90% of remaining water weight is added, 10 points of mixing is stirred at 60 DEG C
Clock, obtains liquid b；
Remaining each raw material is mixed, is stirred, obtain liquid c；
Liquid a is mixed with liquid b, 300 revs/min of dispersed with stirring 6 minutes add liquid c, and 80 DEG C are placed in after stirring
Heated at constant temperature 10 hours in water-bath, obtain final product the biological binding agent；
The preparation method of described structure reinforcing agent is that leaching in the sodium hydroxide solution of 30-40% will be put into after elm break flour
Bubble 2 hours, takes out drying.
Embodiment 2
A kind of polyethylene is anti-, drain plate binding agent, including following mass fraction component：
80 parts of deionized water, 20 parts of polyvinyl alcohol, 18 parts of inorganic composite flame retardants, 1.2 parts of inorganic crosslinking agent, silicone emulsion
0.2 part, 3 parts of mould inhibitor, 10 parts of hydrogenated rosin glyceride, 2 parts of 2- mercaptos benzimidazole, 3 parts of HPMA, silicon
2 parts of sour magnesium, 1 part of hexafluoroacetylacetone, 3 parts of calcium aluminate, 2 parts of 1- hydroxycyclohexyl phenyl ketones, methacrylic acid 1
Part, 7 parts of biological binding agent, 3 parts of acrylic acid, 2 parts of maleic anhydride modified polyethylene, 3 parts of heterogeneous ten alcohol polyoxyethylene ether, over cure
2 parts of sour potassium, 3 parts of methyl acrylate, 4 parts of polyadipate hexylene glycol ester.
As the further optimization of the present embodiment：
Described inorganic composite flame retardants press 1 by APP and zinc sulfate：0.08 mass ratio is mixed.
Between 40%-99%, its degree of polymerization is between 500-2000 for the alcoholysis degree scope of described polyvinyl alcohol.
Described inorganic crosslinking agent uses boric acid.
Described mould inhibitor is propionic acid and its esters.
What described biological binding agent was made up of the raw material of following weight parts：
Sodium sulfite 0.5, structure reinforcing agent 5, acetate starch 11, propane diols phenylate 5, polyacrylamide 6, citric acid
Aluminium 2, APG 2, water soluble phenol resin 3, water 200；
Polyacrylamide is added in 10 times of water, solution is configured to, water soluble phenol resin is added, regulation PH is 6-8,
Structure reinforcing agent, sodium sulfite are added, is stirred, obtain liquid a；
Acetate starch, propane diols phenylate are mixed, the 80-90% of remaining water weight is added, 14 points of mixing is stirred at 70 DEG C
Clock, obtains liquid b；
Remaining each raw material is mixed, is stirred, obtain liquid c；
Liquid a is mixed with liquid b, 350 revs/min of dispersed with stirring 10 minutes add liquid c, and 85 DEG C are placed in after stirring
Water-bath in heated at constant temperature 12 hours, obtain final product the biological binding agent；
The preparation method of described structure reinforcing agent is that leaching in the sodium hydroxide solution of 30-40% will be put into after elm break flour
Bubble 3 hours, takes out drying.
Embodiment 3
A kind of polyethylene is anti-, drain plate binding agent, including following mass fraction component：
75 parts of deionized water, 12 parts of polyvinyl alcohol, 10 parts of inorganic composite flame retardants, 1 part of inorganic crosslinking agent, silicone emulsion
0.15 part, 2 parts of mould inhibitor, 9 parts of hydrogenated rosin glyceride, 1.8 parts of 2- mercaptos benzimidazole, HPMA 2.8
Part, 1.8 parts of magnesium silicate, 0.9 part of hexafluoroacetylacetone, 2.8 parts of calcium aluminate, 1.5 parts of 1- hydroxycyclohexyl phenyl ketones,
0.9 part of methacrylic acid, 6 parts of biological binding agent, 2.5 parts of acrylic acid, 1.8 parts of maleic anhydride modified polyethylene, the alcohol of isomery ten
2.8 parts of APEO, 1.8 parts of potassium peroxydisulfate, 2.8 parts of methyl acrylate, 3.5 parts of polyadipate hexylene glycol ester.
As the further optimization of the present embodiment：
Described inorganic composite flame retardants press 1 by APP and zinc sulfate：0.05 mass ratio is mixed.
Between 40%-99%, its degree of polymerization is between 500-2000 for the alcoholysis degree scope of described polyvinyl alcohol.
Described inorganic crosslinking agent uses bichromate and chromic nitrate.
Described mould inhibitor is dehydroacetic acid.
What described biological binding agent was made up of the raw material of following weight parts：
Sodium sulfite 0.45, structure reinforcing agent 4.5, acetate starch 10.5, propane diols phenylate 4.5, polyacrylamide 5,
Aluminium citrate 1, APG 1.5, water soluble phenol resin 2, water 190；
Polyacrylamide is added in 8 times of water, solution is configured to, water soluble phenol resin is added, regulation PH is 6-8,
Structure reinforcing agent, sodium sulfite are added, is stirred, obtain liquid a；
Acetate starch, propane diols phenylate are mixed, the 80-90% of remaining water weight is added, 12 points of mixing is stirred at 65 DEG C
Clock, obtains liquid b；
Remaining each raw material is mixed, is stirred, obtain liquid c；
Liquid a is mixed with liquid b, 320 revs/min of dispersed with stirring 8 minutes add liquid c, and 82 DEG C are placed in after stirring
Heated at constant temperature 11 hours in water-bath, obtain final product the biological binding agent；
The preparation method of described structure reinforcing agent is that leaching in the sodium hydroxide solution of 30-40% will be put into after elm break flour
Bubble 2.5 hours, takes out drying.
Binding agent of the invention, as structure reinforcing agent, coordinates high-viscosity polyvinyl alcohol using bark powder so that formed
Gel there is the feature of fiber, make gel that there is certain toughness, while finished product viscosity is improved, finished product is improve again
Toughness, and with good fire-retardant and water resistance, and environmental protection.
The present invention is formed crosslinking and is produced using the hydroxyl reaction on the compound and polyvinyl alcohol molecule of active group
Thing, seals the hydroxyl on polyvinyl alcohol molecule, reduces the water imbibition of polyvinyl alcohol, improves the water-fast grade of polyvinyl alcohol.Poly- second
Enol is nonpoisonous and tasteless aqueous high molecular material, is a kind of binding agent of green by solvent of water.A bit particularly important, makees
Be the binding agent of green draining, polyvinyl alcohol can be degraded by microorganisms in natural environment, final product be carbon, hydrogen, oxygen and
Water, it is very environmentally friendly.Contain great amount of hydroxy group on polyvinyl alcohol molecule, so it has very strong bonding with cement and gypsum material
Property.Binding agent maximum feature of the invention is, is that part of hydroxyl is enclosed after appropriate addition crosslinking agent, is the resistance to of polyvinyl alcohol
Aqueous raising；The presence of fire retardant in formula, is that the oxygen index (OI) of product reaches 35 or so.
The above, is only presently preferred embodiments of the present invention, and any formal limitation is not made to the present invention, though
So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any to be familiar with this professional technology people
Member, without departing from the scope of the present invention, when making a little change or modification using the technology contents of the disclosure above
It is the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, according to technical spirit of the invention
Any simple modification, equivalent variations and the modification made to above example, still fall within the range of technical solution of the present invention.
Claims (9)
1. a kind of polyethylene is anti-, drain plate binding agent, it is characterised in that：Component including following mass fraction：
Deionized water 60-80 parts, polyvinyl alcohol 3-20 parts, inorganic composite flame retardants 1.6-18 parts, inorganic crosslinking agent 0.2-
1.2 parts, silicone emulsion 0.01-0.2 parts, mould inhibitor 0.2-3 parts, hydrogenated rosin glyceride 7-10 parts, 2- mercapto benzene
Parallel imidazoles 1-2 parts, HPMA 2-3 parts, magnesium silicate 1-2 parts, hexafluoroacetylacetone 0.7-1 parts, calcium aluminate 2-3 parts,
0.6-2 parts of 1- hydroxycyclohexyl phenyl ketones, methacrylic acid 0.4-1 parts, biological binding agent 4-7 parts, acrylic acid 1-3
Part, maleic anhydride modified polyethylene 1-2 parts, heterogeneous ten alcohol polyoxyethylene ether 2-3 parts, potassium peroxydisulfate 1-2 parts, methyl acrylate 2-
3 parts, 2-4 parts of polyadipate hexylene glycol ester.
2. a kind of polyethylene according to claim 1 is anti-, drain plate binding agent, it is characterised in that：Including following matter
Measure the component of number：
Deionized water 70-80 parts, polyvinyl alcohol 8-20 parts, inorganic composite flame retardants 3-18 parts, inorganic crosslinking agent 0.5-1.2
Part, silicone emulsion 0.1-0.2 parts, mould inhibitor 1-3 parts, hydrogenated rosin glyceride 8-10 parts, 2- mercapto benzimidazoles
1.5-2 parts, HPMA 2.5-3 parts, magnesium silicate 1.5-2 parts, hexafluoroacetylacetone 0.8-1 parts, calcium aluminate 2.5-3 parts,
1.2-2 parts of 1- hydroxycyclohexyl phenyl ketones, methacrylic acid 0.8-1 parts, biological binding agent 5-7 parts, acrylic acid 2-3
Part, maleic anhydride modified polyethylene 1.5-2 parts, heterogeneous ten alcohol polyoxyethylene ether 2.5-3 parts, potassium peroxydisulfate 1.5-2 parts, acrylic acid
Methyl esters 2.5-3 parts, 3-4 parts of polyadipate hexylene glycol ester.
3. a kind of polyethylene according to claim 1 is anti-, drain plate binding agent, it is characterised in that：Including following matter
Measure the component of number：
75 parts of deionized water, 12 parts of polyvinyl alcohol, 10 parts of inorganic composite flame retardants, 1 part of inorganic crosslinking agent, silicone emulsion
0.15 part, 2 parts of mould inhibitor, 9 parts of hydrogenated rosin glyceride, 1.8 parts of 2- mercaptos benzimidazole, HPMA 2.8
Part, 1.8 parts of magnesium silicate, 0.9 part of hexafluoroacetylacetone, 2.8 parts of calcium aluminate, 1.5 parts of 1- hydroxycyclohexyl phenyl ketones,
0.9 part of methacrylic acid, 6 parts of biological binding agent, 2.5 parts of acrylic acid, 1.8 parts of maleic anhydride modified polyethylene, the alcohol of isomery ten
2.8 parts of APEO, 1.8 parts of potassium peroxydisulfate, 2.8 parts of methyl acrylate, 3.5 parts of polyadipate hexylene glycol ester.
4. a kind of polyethylene according to claim 1-3 any one is anti-, drain plate binding agent, it is characterised in that：
Described inorganic composite flame retardants press 1 by APP and zinc sulfate：0.01~0.08 mass ratio is mixed.
5. a kind of polyethylene according to claim 1-3 any one is anti-, drain plate binding agent, it is characterised in that：
Between 40%-99%, its degree of polymerization is between 500-2000 for the alcoholysis degree scope of described polyvinyl alcohol.
6. a kind of polyethylene according to claim 1-3 any one is anti-, drain plate binding agent, it is characterised in that：
Described inorganic crosslinking agent uses sodium sulphate, zinc sulfate, boric acid, borax, bichromate, chromic nitrate, the complex compound of chromium, cuprammonium hydrogen
The combination of one or more in oxide or organic titanate.
7. a kind of polyethylene according to claim 1-3 any one is anti-, drain plate binding agent, it is characterised in that：
Described mould inhibitor is benzoic acid, Sodium Benzoate, propionic acid and its esters, sorbic acid and its esters, dehydroacetic acid, citric acid and lemon
The combination of one or more in lemon acid sodium hydroxybenzoate, sodium Diacetate or dimethyl fumarate.
8. a kind of polyethylene according to claim 1-3 any one is anti-, drain plate binding agent, it is characterised in that：
What described biological binding agent was made up of the raw material of following weight parts：
Sodium sulfite 0.4-0.5, structure reinforcing agent 4-5, acetate starch 10-11, propane diols phenylate 4-5, polyacrylamide
Amine 4-6, aluminium citrate 0.7-2, APG 1-2, water soluble phenol resin 1-3, water 180-200；
Polyacrylamide is added in 6-10 times of water, solution is configured to, water soluble phenol resin is added, adjusting PH is
6-8, adds structure reinforcing agent, sodium sulfite, stirs, and obtains liquid a；
Acetate starch, propane diols phenylate are mixed, the 80-90% of remaining water weight is added, mixing is stirred at 60-70 DEG C
10-14 minutes, obtain liquid b；
Remaining each raw material is mixed, is stirred, obtain liquid c；
Liquid a is mixed with liquid b, 300-350 revs/min dispersed with stirring 6-10 minutes, add liquid c, stir rearmounted
Heated at constant temperature 10-12 hours in 80-85 DEG C of water-bath, the biological binding agent is obtained final product.
9. a kind of polyethylene according to claim 8 is anti-, drain plate binding agent, it is characterised in that：Described structure
The preparation method of reinforcing agent is will to be put into the sodium hydroxide solution of 30-40% to soak 2-3 hours after elm break flour, is taken
Go out drying.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710299388.3A CN106928869A (en) | 2017-05-02 | 2017-05-02 | A kind of polyethylene is anti-, drain plate binding agent |
| PCT/CN2017/111232 WO2018201691A1 (en) | 2017-05-02 | 2017-11-16 | Binding agent for use with polyethylene water resistant drainage board |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710299388.3A CN106928869A (en) | 2017-05-02 | 2017-05-02 | A kind of polyethylene is anti-, drain plate binding agent |
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| CN106928869A true CN106928869A (en) | 2017-07-07 |
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| WO (1) | WO2018201691A1 (en) |
Cited By (3)
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| CN108329552A (en) * | 2018-02-24 | 2018-07-27 | 四会市启德信息咨询服务有限公司 | A kind of corrosion-resistant high electrolyte release rate battery separator material |
| CN108441147A (en) * | 2018-03-15 | 2018-08-24 | 韩德辉 | A kind of low noise glue and preparation method thereof |
| WO2018201691A1 (en) * | 2017-05-02 | 2018-11-08 | 南通沪望塑料科技发展有限公司 | Binding agent for use with polyethylene water resistant drainage board |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117467355B (en) * | 2023-12-22 | 2024-03-08 | 山东嘉德包装材料有限公司 | Adhesive for degradable tableware and preparation method thereof |
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| US8143335B2 (en) * | 2003-03-28 | 2012-03-27 | Momentive Specialty Chemicals Inc. | Adhesive composition |
| CN105001807A (en) * | 2015-06-26 | 2015-10-28 | 蚌埠市鸿安精密机械有限公司 | Solid film timber glue |
| CN105623562A (en) * | 2016-03-24 | 2016-06-01 | 佛山市三水永恒达粘合剂有限公司 | Special mosaic adhesive and preparation method therefor |
| CN106928869A (en) * | 2017-05-02 | 2017-07-07 | 南通沪望塑料科技发展有限公司 | A kind of polyethylene is anti-, drain plate binding agent |
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| CN104277722A (en) * | 2014-10-20 | 2015-01-14 | 常熟市鑫磊木业制造厂 | Adhesive for wood floor |
| CN104403603A (en) * | 2014-10-22 | 2015-03-11 | 上海大学 | Flame-retardant cross-linked polyvinyl alcohol binder and preparation method thereof |
| CN104388019A (en) * | 2014-12-06 | 2015-03-04 | 赵冯 | Hot melt adhesive |
| CN105017995A (en) * | 2015-06-26 | 2015-11-04 | 蚌埠市鸿安精密机械有限公司 | Metallocene polyethylene wood adhesive |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2018201691A1 (en) * | 2017-05-02 | 2018-11-08 | 南通沪望塑料科技发展有限公司 | Binding agent for use with polyethylene water resistant drainage board |
| CN108329552A (en) * | 2018-02-24 | 2018-07-27 | 四会市启德信息咨询服务有限公司 | A kind of corrosion-resistant high electrolyte release rate battery separator material |
| CN108441147A (en) * | 2018-03-15 | 2018-08-24 | 韩德辉 | A kind of low noise glue and preparation method thereof |
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| WO2018201691A1 (en) | 2018-11-08 |
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