CN103539410B - Novel polymer cement waterproof coating formula - Google Patents
Novel polymer cement waterproof coating formula Download PDFInfo
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- CN103539410B CN103539410B CN201310557831.4A CN201310557831A CN103539410B CN 103539410 B CN103539410 B CN 103539410B CN 201310557831 A CN201310557831 A CN 201310557831A CN 103539410 B CN103539410 B CN 103539410B
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Abstract
The invention provides a novel polymer cement waterproof coating formula with excellent usability and construction performance. The novel polymer cement waterproof coating formula consists of a liquid material and a powder material, wherein in terms of parts by weight of the formula, the liquid material comprises the following components: 100 parts of water, 45-50 parts of styrene, 35-40 parts of methyl methacrylate, 0.5-0.8 part of alkoxy silane, 0.5-1 part of methylcellulose, 3-5 parts of polyvinyl alcohol and 0.2-0.5 part of sodium persulfate; the powder material comprises the following components: 100 parts of white cement, 10-20 parts of silicon powder, 2-4 parts of urea and 0.1-0.2 part of polycarboxylic water reducer; the mixing ratio of the liquid material to the powder material in terms of weight ratio is (0.3-0.4): 1.
Description
Technical field
The present invention relates to the technical field of coating, a kind of Novel polymer cement waterproof paint formula is particularly provided.
Background technology
Water-proof material is widely used in building materials protection field, use waterproof paint to buildings to carry out after application can by buildings and external environment isolated, prevent the corrosion because the moisture intrusion buildings material in the corrosive liquid such as rainwater, underground water and air causes thus, extend the work-ing life of material of construction.
And using comparatively generally polymer cement waterproof paint at present, polymer cement waterproof paint is the two-component coating be composited as cement, silica powder and additive etc. with inorganic powder as acrylic ester elastic emulsion, ethene-vinyl acetate emulsion etc. with polymer emulsion.Because this coating is made up of " polymer emulsion-cement " two-pack, therefore there is the characteristic of " tempering toughness with gentleness ", the extensibility of existing polymer coating film, water-repellancy, also have hydraulic cementing materials intensity high, easily and the advantage that bonds of wet base.Can the ratio of telomerized polymer emulsion and cement, meet the requirement of different engineering to snappiness and intensity etc., constructional method is convenient.Meanwhile, this kind of coating, using water as dispersion agent, solves environmental pollution that the organic solvent type such as tar, pitch waterproof paint causes and the harm to HUMAN HEALTH.So at home and abroad development rapidly, becomes the up-and-coming youngster in waterproof paint.
Although this kind of polymer cement waterproof paint has good weathering resistance and alkali resistance, but this kind of coating in the curing process, the shrinking percentage of cement is larger, therefore the coating residual stress after solidification is larger, after using for some time, easily there is cracking in paint film, affects waterproof effect thus, reduces work-ing life.Meanwhile, in long-term use procedure, the easy water absorption and swelling of coating, makes to be coated with the performance such as film strength, cohesive force and significantly declines, thus cause its water-proof function greatly to weaken.In addition, the thixotropy of polymer cement waterproof paint is poor, the elevation construction situation in practice of construction process, and very easily sagging causes construction surface to be difficult to strike off, thus affects attractive in appearance and water resistance etc.Moreover polymer cement waterproof paint often needs
Therefore, develop a kind of novel polymer cement waterproof paint formula with excellent use properties and workability and the complete processing adapted with it, there is very important Research Significance and boundless application prospect.
Summary of the invention
Namely object of the present invention is to provide a kind of novel polymer cement waterproof paint formula with excellent use properties and workability, and it is made up of liquid material and powder.
Novel polymer cement waterproof paint formula in the present invention is specific as follows: with parts by weight,
Liquid material comprises, 100 parts, water, vinylbenzene 45-50 part, methyl methacrylate 35-40 part, organoalkoxysilane 0.5-0.8 part, methylcellulose gum 0.5-1 part, polyvinyl alcohol 3-5 part; Sodium Persulfate 0.2-0.5 part;
Powder comprises, white cement 100 parts, silica flour 10-20, urea 2-4 part, poly carboxylic acid series water reducer 0.1-0.2 part;
Described liquid material component and powder component blending ratio are by weight 0.3-0.4:1.
As preferably, cinnamic content is 48 parts;
As preferably, the content of methyl methacrylate is 37 parts;
As preferably, organoalkoxysilane is 3-methacryloxypropyl trimethoxy silane, and its content is 0.6 part;
As preferably, the content of methylcellulose gum is 0.7 part;
As preferably, the content of polyvinyl alcohol is 4 parts;
As preferably, the content of silica flour is 15 parts;
As preferably, the content of urea is 3 parts;
As preferably, the content of poly carboxylic acid series water reducer is 0.2 part.
Namely advantage of the present invention is, devises a kind of polymer cement waterproof paint formula of uniqueness, by cooperatively interacting of liquid material and powder, obtains the novel polymer cement waterproof paint with excellent use properties and workability.
Embodiment
Content of the present invention is described in detail below by specific embodiment.
Embodiment.
Configure respectively according to each component proportion given by table 1 and prepare liquid material and powder, wherein liquid material and powder respectively using water and white cement be 100 parts as benchmark:
One, the preparation of liquid material:
1), first the water of 70 parts in proportioning and the polyvinyl alcohol of 1/4 amount are inserted have thermometer, agitator, nitrogen import
In the reaction vessel of pipe and reflux exchanger, use nitrogen purging while stirring, keep after being heated to 85 DEG C;
2), by the polyvinyl alcohol of 3/4 amount of remainder add in the water of 20 parts and make solution, and vinylbenzene, methyl methacrylate, 3-methacryloxypropyl trimethoxy silane, methylcellulose gum are added in solution carry out emulsification, prepare emulsion;
3), Sodium Persulfate is added in the water of 10 parts and prepare initiator solution;
4), by step 2) in initiator solution in emulsion and step 3) together instill in the reaction vessel in step 1), dropping limit, limit is stirred, and drips completely, stirs and carry out polyreaction in 2 hours;
5), liquid material is obtained by adding a small amount of ammoniacal liquor adjust ph to 8.5 after solution cooling.
Two, the preparation of powder:
White cement, specific surface area are greater than 2 × 10
5cm
2the silica flour of/g, urea, poly carboxylic acid series water reducer mixing, be stirred well to and evenly obtain powder.
During use, liquid material and powder are mixed with the part by weight of 0.4:1, and stirring becomes slip, coating 2mm carries out performance test on Calucium Silicate powder sheet material.
Table 1
1. the evaluation of application property is difficult to floating coating thickness for standard with obviously sagging during the thick painting of visual inspection generation with during scumbling;
2. water-permeable evaluation is tested with reference to JIS A6909;
3. water tolerance evaluation is soaked in the warm water of 50 DEG C, to occur that the obvious albefaction time is for standard;
4. freeze-thaw resistance evaluation is soaked 1 hour in 10 DEG C of water after coating is freezed 2h under-20 DEG C of environment, so repeatedly, to occur significantly ftractureing back number for standard;
5. curing shrinkage rate is measured after 30 days in coating standing and drying.
Cinnamic interpolation mainly reduces water-absorbent and the water-permeable of paint film, thus the effect of the water-repellancy of performance raising system, moisture resistance, anti-freeze, at least should be 45 parts to play the cinnamic addition of above-mentioned effect, but its addition crosses the overall performance that can affect system at most, should be controlled it below 50 parts.
The waterproof paint with methyl methacrylate has excellent water-repellancy and moisture resistance equally, methyl methacrylate can also improve the adherence, coating etc. of system and base material simultaneously, for playing its effect, its addition should be at least 35 parts, but its addition crosses the overall performance that can affect system at most, should be controlled it below 40 parts.
Organoalkoxysilane is due to the cause of its dehydrating condensation, the crosslinked action promoting emulsion system can be played to a certain extent, thus improve the adherence, coating etc. of system and base material, simultaneously by the interaction of itself and vinylbenzene, methyl methacrylate, paint film after system can be made to apply has suitable elasticity, thus avoid due to organic system and inorganic system contraction, rate of expansion is different and the cracking that causes.For playing its effect, its addition should be at least 0.5 part, but its addition is crossed and may be caused at most crosslinked excessively affecting the overall performance of system, should control it below 0.8 part.
The interpolation of methylcellulose gum uses mainly as tackifier, due to its Be very effective, its can improve well system intensity thus avoid ftracture generation, it is more improved the effect of the floating performance of coating system simultaneously, in order to play above-mentioned effect, its addition at least should be 0.5 part, but its addition can not be too high, otherwise significantly will reduce the resistance to water-whitening energy of system, therefore its addition should not more than 1 part.
The Main Function of polyvinyl alcohol uses as emulsifying dispersant, and it can offset the effect that resistance to water-whitening that methylcellulose gum brings can decline to a certain extent simultaneously.For playing its effect, the addition of polyvinyl alcohol at least should be 3 parts, but the too much interpolation of polyvinyl alcohol will cause the water resistance of system to decline, and therefore its addition is no more than 5 parts.Simultaneously in order to obtain enough dispersion effects, the number-average molecular weight of polyvinyl alcohol should between 800-2500, the too high or too low inefficacy that all may cause dissemination due to unbalance in its molecule between hydrophilic group and oleophilic group of molecular weight.
Sodium Persulfate is as the initiator of polyreaction, and its addition, greatly about 0.2-0.5 part, gets final product carrying out smoothly of guarantee system polyreaction.
White cement is as the basis of powder, and the guarantee for system intensity is significant, and for meeting the requirement of the basic properties such as intensity, in system, ratio can not be too low for it.But its ratio is as large in too high then ageing impact, be unfavorable for the stable of system.
Silica flour can give the thixotropic property of system excellence and floating performance, thus greatly improve the workability of system, due to the interpolation of silica flour, system even reaches more than 100mm at coating thickness and does not also drop, even and if coating thickness is as thin as about 1mm still can keep even.In order to reach above-mentioned effect, the addition of silica flour at least should be 10 parts, but too much interpolation does not have lasting significantly improvement, can too increase the viscosity of system and affect construction operation on the contrary, can increase cost cost simultaneously, therefore preferred below 20 parts.
The interpolation of urea can not increase the contraction significantly reducing coating under the prerequisite of shrinking and lowering agent, thus avoid the dry shrinkage the final paint film cracking caused that cause due to the existence of a large amount of powder, correspondingly also without the need to additionally adding the expanding material such as gypsum, lime.In order to play above-mentioned effect, the addition of urea at least should reach more than 2 parts, but excessive interpolation then likely makes inside expand because of the crystallization tendency of urea and causes the destruction of paint film, therefore should control its addition below 4 parts.
Poly carboxylic acid series water reducer, except reducing water consumption, can also improve the storge quality of system.For playing above-mentioned effect, its addition should be 0.1 part, but should be inexcessive, otherwise can cause the decline of storge quality on the contrary.
Through the polymer cement waterproof paint that formula of the present invention and preparation technology obtain, there is excellent use properties and workability, the service requirements day by day improved can be met.
Claims (9)
1. a polymer cement waterproof paint, is made up of liquid material and powder, it is characterized in that: with parts by weight,
Liquid material comprises, 100 parts, water, vinylbenzene 45-50 part, methyl methacrylate 35-40 part, organoalkoxysilane 0.5-0.8 part, methylcellulose gum 0.5-1 part, polyvinyl alcohol 3-5 part; Sodium Persulfate 0.2-0.5 part;
Powder comprises, white cement 100 parts, silica flour 10-20, urea 2-4 part, poly carboxylic acid series water reducer 0.1-0.2 part;
Described liquid material component and powder component blending ratio are by weight 0.3-0.4:1.
2. polymer cement waterproof paint according to claim 1, is characterized in that: cinnamic content is 48 parts.
3. polymer cement waterproof paint according to claim 1, is characterized in that: the content of methyl methacrylate is 37 parts.
4. polymer cement waterproof paint according to claim 1, is characterized in that: organoalkoxysilane is 3-methacryloxypropyl trimethoxy silane, and its content is 0.6 part.
5. polymer cement waterproof paint according to claim 1, is characterized in that: the content of methylcellulose gum is 0.7 part.
6. polymer cement waterproof paint according to claim 1, is characterized in that: the content of polyvinyl alcohol is 4 parts.
7. polymer cement waterproof paint according to claim 1, is characterized in that: the content of silica flour is 15 parts.
8. polymer cement waterproof paint according to claim 1, is characterized in that: the content of urea is 3 parts.
9. polymer cement waterproof paint according to claim 1, is characterized in that: the content of poly carboxylic acid series water reducer is 0.2 part.
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CN105884296A (en) * | 2016-04-11 | 2016-08-24 | 苏州百联建筑工程有限公司 | Cement-containing waterproof paint |
CN107572879B (en) * | 2017-09-30 | 2020-08-11 | 潍坊骏兴防水材料有限公司 | Special polymer waterproof slurry for kitchens and bathrooms and preparation method thereof |
CN113355000A (en) * | 2021-07-02 | 2021-09-07 | 南开大学 | Special polymer cement paint containing inorganic powder in liquid material |
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CN1386809A (en) * | 2002-05-23 | 2002-12-25 | 中国建筑材料科学研究院 | Water-proof polymer-cement paint with low polymer/cement ratio and high performance and its preparing process |
CN101608087A (en) * | 2009-07-24 | 2009-12-23 | 佛山市顺德区巴德富实业有限公司 | Polymer cement waterproof coating acrylic emulsion |
CN101811851A (en) * | 2009-12-18 | 2010-08-25 | 河南省绿韵建材有限公司 | Polymer cement-base waterproof coating dry powder |
CN101891859A (en) * | 2009-05-18 | 2010-11-24 | 成都科杰高新技术发展有限公司 | Elastic styrene acrylic emulsion for polymer cement waterproof coating and preparation method thereof |
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JPH0350146A (en) * | 1989-07-17 | 1991-03-04 | Showa Denko Kk | Mortar composition |
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CN1386809A (en) * | 2002-05-23 | 2002-12-25 | 中国建筑材料科学研究院 | Water-proof polymer-cement paint with low polymer/cement ratio and high performance and its preparing process |
CN101891859A (en) * | 2009-05-18 | 2010-11-24 | 成都科杰高新技术发展有限公司 | Elastic styrene acrylic emulsion for polymer cement waterproof coating and preparation method thereof |
CN101608087A (en) * | 2009-07-24 | 2009-12-23 | 佛山市顺德区巴德富实业有限公司 | Polymer cement waterproof coating acrylic emulsion |
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Effective date of registration: 20210519 Address after: 215000 Huangqiao Street East Street, Xiangcheng District, Suzhou City, Jiangsu Province Patentee after: Suzhou dongtinghe Intelligent Technology Development Co., Ltd Address before: 215132 Wangfang Road, Huangqiao Town, Xiangcheng District, Suzhou City, Jiangsu Province Patentee before: SUZHOU GUSU NEW BUILDING MATERIAL Co.,Ltd. |
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